CN1027635C

CN1027635C - Infrared and ultraviolet radiation absorbing green glass composition

Info

Publication number: CN1027635C
Application number: CN 90110046
Authority: CN
Inventors: 程兆台
Original assignee: Libbey Owens Ford Co
Current assignee: Pilkington North America Inc
Priority date: 1989-11-16
Filing date: 1990-11-16
Publication date: 1995-02-15
Anticipated expiration: 2005-11-16
Also published as: CN1052647A

Abstract

Green-colored, infrared energy and ultraviolet radiation absorbing glass compositions comprise conventional soda-lime-silica float glass ingredients, a high concentration of moderately reduced iron, and ceric oxide. The resultant glass exhibits an Illuminant A visible light transmittance greater than 70 %, a total solar energy transmittance less than about 46 %, and an ultraviolet radiation transmittance less than about 38 %, at glass thicknesses in the range of 3 mm to 5 mm. Optionally, a portion of the ceric oxide can be replaced with a predetermined quantity of titanium oxide.

Description

Infrared and ultraviolet radiation absorbing green glass composition

The present invention relates generally to absorb infrared and green glass composition uv-radiation, relate in particular to the green glass composition that has certain energy absorption and light transmission performance simultaneously.Preferred glass has the narrow predominant wavelength and the colour purity of defined.The present invention is specially adapted to produce automobile and architectural window glass, wherein wishes the visible light transmissivity height, and sun power and uv-radiation transmitance are low.

People know usually, make the soda lime glass that absorbs ir radiation by mixing iron therein.Iron in glass generally with iron protoxide (FeO) and ferric oxide (Fe ₂O ₃) two kinds of forms exist.Balance between iron protoxide and ferric oxide amount has directly and influence in essence the color of glass and light transmission.When ferrous oxide content increases (result of ferric oxide chemical reduction), infrared absorption increases and uv-absorbing reduces.FeO is with respect to Fe ₂O ₃Concentration transform to higher direction, cause that the color of glass becomes deep green or blue-greenish colour from yellow or yellow-green colour, the visible light transmissivity of glass is reduced.Therefore, in order to make the bigger and don't sacrifice visible light transmissivity of the glass infrared absorption that obtains, think in the prior art and must produce the low (Fe of total iron amount ₂O ₃Major part is reduced to FeO) glass.Total low glass of iron amount generally all is to use a kind of iron content (to press Fe ₂O ₃Meter) is lower than the batch composition production of about 0.70～0.75 weight %.For example, 3,652, disclosed the ultrared blue soda lime glass composition of a kind of absorption in No. 303 United States Patent (USP)s, the visible light transmissivity of this glass when 1/4 inch thickness be greater than 70%, wherein by mix in solution commercial weight metallic tin also or tin protochloride total iron of at least 80% remained under the ferrous state.

Also comprise cerium in many glass compositions, so that have ultraviolet absorbability.For example,, disclose in No. 715 United States Patent (USP)s, add 3～6 weight % cerium oxide so that prepare nonferrous yellowish pink glass composition 1,414; This patent points out that also cerium oxide reduces the visible light transmissivity of glass.

1,637, No. 439 United States Patent (USP) is pointed out, uses the uv-absorbing agent of the cerium oxide of 5～10 weight % as the mazarine glass composition.This glass for example can be used for observing open-hearth practice, and it is to make navy blue by adding 0.1～0.5 weight % cobalt oxide.In fact high density oxidation cerium has absorbed otherwise can be through whole uv-radiation of eye-protection glasses.Obviously, this glass composition has the low visible light transmitance, and is unsuitable for making automobile or architectural window glass.

1,936, No. 231 U.S. Patent Publications a kind of flint glass, wherein add small amounts iron as ultraviolet ray block agent, its consumption should can keep its high visible light transmissivity to the glass of making less.Total iron amount of being advised is about 0.35 weight %.This patent points out further that also can add scadium compound blocks agent as uv-radiation, obtains the low glass composition of total iron content.The glass composition that obtains so still keeps its colorless appearance and high visible light permeability matter.

2,524, No. 719 United States Patent (USP) discloses a kind of rose-colored glass composition.Wherein in glass batch, add iron as the infrared energy absorption agent, add selenium as ultra-violet absorber.It is said in order to help cerium to absorb uv-radiation, can add the above cerium oxide of 3 weight %.

Disclose the ultraviolet glass composition of a kind of absorption in 2,860, No. 059 United States Patent (USP), its total concentration of iron is low, according to putting down in writing this composition at the sort of turquoise glass that is better than being used as usually automobile and architectural window glass aspect the visible light transmissivity.In order to make this glass keep its colorless appearance and high visible light transmissivity, high Fe content is 0.6 weight %.Add among the said glass so that the uv-radiation absorptivity is provided with titanium dioxide with up to the cerium oxide of 0.5 weight %.

2,444, No. 976 United States Patent (USP) has been introduced a kind of aurene, and it has extremely low ultraviolet ray transmissivity and very high visible light transmissivity, is particularly suitable for as the aircraft glazing.As the thermal absorption composition, this glass contains ferric oxide and a large amount of cerium oxide (1.5～3%) and titanium oxide (6～9%) simultaneously.

Afterwards, 4,792, No. 536 U.S. Patent Publications a kind ofly be used to produce the method that absorbs infrared energy glass, total concentration of iron of this glass is low, its major part is reduced into FeO.According to further introduction, said infrared energy sorption can total iron amount of a large amount be improved by mixing more in this glass composition, and claims: visible light transmissivity thereby can be reduced to it is believed that under the level that is suitable for use as vehicle glass.Disclosed method adopts fusing of two stages and clarification operation, and this provides sufficient reductive condition, makes the iron amount that is under the ferrous state be increased to given low total concentration of iron level, i.e. the level of the total concentration of iron of 0.45～0.65 weight %.This patent points out that said iron must lack to having 35% to be reduced to FeO, and preferably 50% above iron must be reduced to ferrous state in the total iron content.According to further introduction, 0.25～0.5 weight % cerium oxide can be joined the iron total concn low, contain in the glass composition of the iron that highly is reduced, so that absorb uv-radiation.According to record, should avoid using the cerium oxide of greater concn, otherwise can damage total light transmission of glass.As 4,792, the fertile a kind of glass examples of institute's support method in No. 536 United States Patent (USP)s discloses out a kind of little glass of total concentration of iron that contains in composition example 11, has 30% to be reduced to FeO in total iron, but also contains 1% cerium oxide.At 4mm thickness, its total sun power transmitance is about 52%, and the uv-radiation transmitance is about 37%.This quite high total sun power transmitance value is caused by low total concentration of iron, and this quite high uv-radiation transmitance value is by lower concentration Fe ₂O ₃(wherein major part is reduced into FeO) causes.

A kind of like this green glass that preferably adopts traditional float glass technology production automobile and architectural window glass to use, it has and is at least 70% high twinkler A visible light transmissivity, low total sun power transmitance less than about 46% and less than about 38% low uv-radiation transmitance, and nominal glass thickness is in, and 3～5mm scope is interior (should be known, this thickness of glass of quoting as proof is the total thickness of glass, and the glazing unit with same thickness can be made up of individual layer, bilayer or multiple glazing plate, and its total thickness is in the pointed scope).Green glass composition with these outstanding light transmitting property can not be according to the disclosed mode of prior art, adopt total concentration of iron low, contain height glass composition production reduced iron and that use cerium oxide.And, adopt to contain the high glass of total concentration of iron and reach this purpose and contradict with instruction of the prior art again.

Must be noted that any is, prior art above-mentioned is collected and is studied as just clue of the present invention; If there is not power provided by the present invention, it is impossible at all that these different schemes make up differently.

According to the present invention, found a kind of green glass composition unexpectedly, (3～5mm) times its twinkler A visible light transmissivity is at least 70% at general thickness of glass, total sun power transmitance is lower than about 46%, and the uv-radiation transmitance be lower than about 38% and preferably be not more than about 34% (the radiation transmitance is the result draw according to following wavelength region: ultraviolet is 300～400 millimicrons, visible light is 400～770 millimicrons, and total sun power is 300～1230 millimicrons).This composition comprises soda lime glass, wherein contains (% meter by weight) as neccessary composition: about 0.51～0.96Fe ₂O ₃, about 0.15～0.33FeO and about 0.2～1.4CeO ₂Also can utilize and mix about 0.02～0.85 weight %TiO ₂Reduce CeO ₂Consumption.In soda lime glass, there is the TiO that is lower than about 0.02 weight % with trace usually ₂The twinkler C predominant wavelength of these glass is about 498～525(preferred 498～519) millimicron, and also colour purity is about 2～4%, preferred about 2～3%.These glass are in order to Fe ₂O ₃Total concentration of iron of expression greater than about 0.7% batch composition produce (said total iron contained in glass composition or admixtion is meant with Fe in the glass industry ₂O ₃Total iron that form is represented.But when the molten glass admixtion, part is reduced into FeO in this total iron amount, and remaining is Fe ₂O ₃Should be known in said " Fe in this specification and claims based on this point ₂O ₃", be meant the reduction weight percentage of ferric oxide in glass composition afterwards.So-called " with Fe ₂O ₃Total iron of expression " be meant before the reduction contained total iron amount in glass batch.In addition, when being reduced into FeO, Fe ₂O ₃Not only produce FeO, but also produce oxygen.The loss of this oxygen can reduce the content of two kinds of iron cpds.Therefore, contained FeO and Fe in the glass composition that generates ₂O ₃Content is less than in the admixtion with Fe ₂O ₃Total iron amount of expression).

Glass composition of the present invention is particularly suitable for producing as green glass automobile or architectural window glass, that absorb infrared energy and uv-radiation.Therefore, the sheet glass of this composition can quench or tempering, also can anneal and laminated together by getting involved transparent resin layer (for example being made up of polyvinyl butyral), for example uses as windshield glass.In general, as the sheet glass that windshield glass is used, thickness is about 1.7～2.5mm; And behind the tempering as the sheet glass of porthole or rear window, thickness is about 3～5mm.

Unless otherwise indicated, otherwise said percentage ratio (%) in this specification sheets and claims all refers to weight %.Use wavelength dispersion X-ray fluorescent to measure CeO ₂, TiO ₂With total iron (with Fe ₂O ₃Expression) weight %.Utilize spectrophotometer, total iron reductive percentage ratio is measured in the at first radiation transmission effect of working sample under the 1060nm wavelength in this way.Utilize the 1060nm transmission value to calculate optical density(OD) then by following formula:

Optical density(OD)=10g ₁₀(100/T) (T is the transmissivity under the 1060nm in the formula).Obtain reduction ratio (%) with this optical density value by following formula then:

Reduction ratio=(110) * (optical density(OD))/(by the thickness of glass of mm) * (total Fe ₂O ₃Wt%)

For as vapour windshield glass purposes, the glass that absorbs energy and uv-radiation must satisfy the requirement of federal standard, and these code requirement twinklers A visible light transmissivity is greater than 70%.The glass that use on the automobile present age is thin more, and with regard to easy more said 70% the twinkler A standard that reaches, but this also causes the transmitance of infrared energy and uv-radiation is strengthened.Therefore, automaker just is being devoted to suitably to adjust apparatus of air conditioning and is being compensated bigger thermal load, and has to mix more uv radiation stability agent so that prevent its degraded in fabric and inner plastic components.

Green glass composition of the present invention is made total glass thickness when being plate about 3～5mm, the twinkler A visible light transmissivity that demonstrates can reach 70% at least, and can make total infrared energy and uv-radiation transmitance value more much lower than disclosed composition in the prior art.Total sun power transmitance of the present composition is lower than about 46% under the thickness of glass of selecting in 3～5mm scope.Said total sun power transmitance preferably is lower than about 45% under this thickness.The total transmitance of sun power is a tolerance of sun power transmitance in whole sun power wavelength regions.It is an integrated value that is included in transmitance to area under the wavelength curve under visible, infrared and the ultraviolet wavelength.

In 3～5mm scope under the selected thickness of glass, the uv-radiation transmitance of the present composition generally is not more than about 34% less than about 38%.Said uv-radiation transmitance value is that representative transmitance in the 300-400nm wavelength region is enclosed an integrated value of deciding area under to wavelength curve.By between 300～400nm, the distribution of Perry Moon air mass 2 solar spectrum energy (being saved from " Prososed Standard Solar-Radiation Curves for Engineering Use ", Perry Moon, M.I.T., Jour.nal of the Franklin Institute, No 230, PP.583-617(1940)) quadrature, remove the scattering energy that in same SPECTRAL REGION, sees through then, calculated the uv-radiation transmitance of glass composition of the present invention by this sample.

Suitable admixtion of the present invention (utilizing traditional preparing glass charge composition mixing device to mix makes) comprises sand, Wingdale, rhombspar, soda ash, saltcake or gypsum, rouge and powder, carbon and cerium compound neccessary compositions such as (as cerium oxide or cerous carbonates), and selectivity composition titanium compound (as titanium oxide).In traditional glassmaking furnace, these materials are fused together by well-established law, make the green glass composition that absorbs infrared energy and uv-radiation, can its continuous great waves be annotated on molten metal trough by float glass technology then.The sheet glass of Sheng Chaning can be made building window glass like this, and perhaps cutting and moulding (for example with the pressurization bending method) is automotive glass.

The soda lime glass composition that generates comprises (wt%):

A) about 65～75SiO ₂,

B) about 10～15Na ₂O,

C) 0～about 4K ₂O,

D) about 1～5MgO,

E) about 5～15CaO,

F) 0～about 3Al ₂O ₃,

G) about 0.51～0.96Fe ₂O ₃,

H) about 0.15～0.33FeO and

I) about 0.2～1.4CeO ₂

The glass composition that generates is preferred to be made up of the following ingredients of % meter by weight basically:

A) about 70～73SiO ₂,

B) about 12～14Na ₂O,

C) 0～about 1K ₂O,

D) about 3～4MgO,

E) about 6～10CaO,

F) 0～about 2Al ₂O ₃,

G) about 0.51～0.96Fe ₂O ₃,

H) about 0.15～0.33FeO and

I) about 0.2～1.4CeO ₂

Cerium oxide amount in said glass also can reduce by mixing titanium dioxide therein.For transmitance, predominant wavelength and the above-mentioned colour purity that keeps required scope, during with the cerium oxide in the titanium dioxide replacement glass, must reduce with Fe ₂O ₃The weight % of total iron of expression, and must improve and be reduced to Fe ₂The per-cent of O.Make a kind of glass like this, the % meter contains by weight:

A) about 65～75SiO ₂,

B) about 10～15Na ₂O,

C) 0～about 4K ₂O,

D) about 1～5MgO,

E) about 5～15CaO,

F) 0～about 3Al ₂O ₃,

G) Fe about 0.5(0.48)～0.9(0.92) ₂O ₃,

H) 0.15～0.33 left and right sides FeO,

I) about 0.1～1.36 left and right sides CeO ₂With

J) 0.02～0.85 left and right sides TiO ₂

Should be noted that and mix a small amount of TiO ₂The time, for one of the every weight percent of above-mentioned character that keeps glass TiO ₂Two CeO that must replace weight percent ₂But work as TiO ₂When amount increases, TiO ₂Additive effect reduction is arranged slightly.For example, contain 1.0wt%CeO at first ₂Do not add TiO ₂Composition, require to use about 0.3wt%TiO ₂Replace about 0.5wt%CeO ₂, and the character that still keeps glass is (so, at higher amount TiO ₂During replacement, 1wt%TiO ₂To replace about 1.5wt%CeO ₂).Use the glass composition of titanium dioxide, preferably form (% meter by weight) by following ingredients basically:

A) 70～73 left and right sides SiO ₂,

B) 12～14 left and right sides Na ₂O,

C) 0～1 left and right sides K ₂O,

D) 3～4 left and right sides MgO,

E) 6～10 left and right sides CaO,

F) 0～2 left and right sides Al ₂O ₃,

G) left and right sides Fe 0.5(0.48)～0.9(0.92) ₂O ₃,

H) 0.15～0.33 left and right sides FeO

I) 0.1～1.36 left and right sides CeO ₂With

J) 0.02～0.85 left and right sides TiO ₂,

Silicon-dioxide forms glass matrix; And sodium oxide, potassium oxide, magnesium oxide and calcium oxide play the fusing assistant work in order to reduce the temperature of fusion of glass.Aluminum oxide is regulated glass viscosity, and stops devitrification.And, MgO, CaO and Al ₂O ₃Deng the weather resistance of acting in conjunction with improvement glass.Saltcake and gypsum play the finings effect, and carbon is known reductive agent.

Add iron (usually with Fe ₂O ₃Form), and partly be reduced into FeO.Total iron amount is very important in the admixtion, and presses Fe ₂O ₃Meter must equal about 0.7～1.25wt%.Equally, reducing degree is also very crucial, must equal 23～29%.Be reduced to the critical range of the reducing degree defined of low iron to total iron with by high ferro above, cause Fe in the glass ₂O ₃And Fe ₂O concentration be divided into reach about 0.51～0.96wt% and 0.15～0.33wt% about.If the amount that iron is reduced has surpassed said critical range, then the glass colour of Xing Chenging is dark excessively.And twinkler A visible light transmissivity can drop to below 70%.In addition, the glass batch melting process is because FeO amount increase obstruction heat is more and more difficult through melt inside.If reductive iron amount subcritical amount is perhaps used lower total iron amount, then total sun power transmitance of desired thickness glass can be increased to about more than 46%.At last, if total iron amount of using is higher than critical amount, the heat that then can be penetrated into melt inside reduces, and the batch melting process will become more difficult.Obviously, high total concentration of iron and the low reduction ratio that is reduced to FeO are very crucial for the performance of glass, this with prior art in opposite at the instruction of glass composition with high visible light transmissivity and low infrared energy and uv-radiation transmitance.

In addition, cerium oxide ultra-violet absorber concentration is the same with iron all has material impact to the balance through performance.The concentration that exists of cerium oxide must be in the scope of 0.2～1.4wt% left and right sides.The cerium oxide of greater concn can absorb the more radiation in 400～450nm wavelength region, makes glass colour become yellow-green colour by green.It is about more than 38% that the cerium oxide of lower concentration can make the uv-radiation transmitance bring up to.Can use 0.1～1.36wt% left and right sides CeO simultaneously ₂With 0.02～0.85wt% left and right sides TiO ₂, the quantity that replaces independent use above-mentioned is the CeO about 0.2～1.4wt% ₂Cerium oxide and titanium oxide are also used, have and the higher requirement of independent use, cerium oxide has same operability and practicality, and these compositions be higher than the said upper limit or be lower than said lower limit all can to glass absorb and color characteristics on produce harmful effect, situation is with top said identical to independent use cerium oxide.

From the above, the synergistic effect under the restriction of the threshold concentration of iron and cerium oxide, and to Fe ₂O ₃Be reduced to the critical restriction of the reducing degree regulation of FeO, all be to produce a kind of like this green glass composition, the twinkler A visible light transmissivity of this glass is greater than 70%, and total sun power transmitance is less than about 46%, and the uv-radiation transmitance is little about 38%, preferably less than about 34%.

In addition, the feature of green glass of the present invention is that twinkler C predominant wavelength is in about 498～525nm, and colour purity is about 2～4%.The purity of the viewing glass of automobile is an important parameter, and should remain on low on the practical level of energy.See that by comparison blue glass purity is not more than about 10%, therefore be unsuitable for as automotive glazings.

Just as described above, the present invention is specifically related to the glazing that thickness is 3～5mm.The soda lime glass examples of the present invention that thickness is in this specified range is described as follows.These glass all have following performance: working flare A visible light transmissivity 〉=70%, total sun power transmitance is less than about 46%, and the uv-radiation transmitance is less than about 36%.(table is seen the literary composition back)

Embodiment 1～16

With typical each composition of soda lime glass batch and neccessary composition and titanium compound selection component mixed together such as rouge and powder, cerium compound and carbonaceous reducing agent, fusing produces the 4mm heavy sheet glass sample that some meet requirement of the present invention then, and these glass sample features of making are as follows: (table is seen the literary composition back)

A kind of windshield according to the invention comprises that two nominal thickness respectively are the green glass plate of 2.2mm, and intervention one deck nominal thickness is 0.030 inch polyvinyl butyral acetal middle layer between two plates; Said green glass is formed (by %): 71.73SiO ₂, 13.78Na ₂O, 8.64CaO, 4.00MgO, 0.776 total iron (are pressed Fe ₂O ₃Meter) (wherein 24.3% being reduced into FeO), trace (0.017) TiO ₂, 0.12Al ₂O ₃, 0.14SO ₃, 0.0003Cr ₂O ₃, 0.89CeO ₂And 0.009La ₂O ₃; Its performance is as follows: twinkler A transmitance 71.4%, total sun power transmitance 43.0%, ultraviolet ray transmissivity 16.3%, predominant wavelength 518.6nm and colour purity 2.5%.

A kind of similar windshield of the present invention is that 0.03 inch polyvinyl butyral acetal middle layer is formed by getting involved one deck nominal thickness in the middle of two green glass plates, and the nominal thickness of every layer of sheet glass is 1.8mm; The composition of green glass comprises (by %): 0.834 total iron (is pressed Fe ₂O ₃Meter, and wherein have 26.8% be reduced into FeO), trace (0.016) TiO ₂And 0.913CeO ₂; Its performance is as follows: twinkler A transmitance 72.2%, and total sun power transmitance 44.1%, ultraviolet permeability 17.1%, predominant wavelength 511nm, colour purity is 2.4%.

The table I

Gross weight % 3mm 4mm 5mm in the glass

Fe ₂O ₃0.71～0.95 0.54～0.65 0.51～0.59

FeO 0.26～0.32 0.18～0.22 0.14～0.17

CeO ₂0.8～1.4 0.55～1.2 0.2～0.7

Reduction ratio (%) 23～29 23～29 23～29

The table II

Gross weight % 3mm 4mm 5mm in the glass

Fe ₂O ₃0.68～0.92 0.51～0.62 0.48～0.56

FeO 0.26～0.32 0.18～0.22 0.14～0.17

CeO ₂0.5～1.2 0.3～0.75 0.1～0.4

TiO ₂0.02～0.85 0.02～0.45 0.02～0.3

Reduction ratio (%) 23～29 23～29 23～29

The table III

The character of 4mm glass

Embodiment 1 embodiment 2 embodiment 3 embodiment 4 embodiment 5

Total iron is (with Fe ₂O ₃The % meter) .782 .789 .783 .788 .788

Iron is reduced to the reduction ratio (%) 25.1 25.7 26.2 27.3 27.5 of FeO

Fe ₂O ₃（%） .586 .586 .578 .573 .571

FeO（%） .177 .182 .185 .194 .195

CeO ₂（%） .913 .909 .915 .914 .913

TiO ₂（%） 0 0 0 0 0

Twinkler A transmitance (%) 72.8 72.3 72.2 71.2 71.5

Total sun power transmitance (%) 45.9 45.1 44.8 43.9 43.7

Ultraviolet permeability (%) 33.0 33.2 33.3 33.5 33.5

Predominant wavelength (nm) 512.8 509.2 508.2 505.2 504.5

Colour purity (%) 2.4 2.4 2.5 2.8 2.9

Embodiment 6 embodiment 7 embodiment 8 embodiment 9 embodiment 10 embodiment 11

Total iron is (with Fe ₂O ₃Meter) .784 .78 .78 .84 .81 .833

Iron is reduced to the reduction ratio (%) 27.7 27.4 27.0 25.8 26.7 26.5 of FeO

Fe ₂O ₃（%） .567 .566 .569 .623 .594 .612

FeO（%） .195 .192 .190 .195 .195 .199

CeO ₂（%） .911 .6 .6 .91 .56 .915

TiO ₂（%） 0 .2 .2 0 .25 .021

Twinkler A transmitance (%) 71.6 70.4 70.2 71.5 71.7 71.3

Total sun power transmitance (%) 43.6 42.9 43.1 43.7 43.8 43.5

Ultraviolet permeability (%) 33.6 30.7 30.1 33.2 33.1 33.4

Predominant wavelength (nm) 504.6 507.9 507.6 506.5 514.1 505.8

Colour purity (%) 2.9 2.8 2.9 2.6 2.5 2.8

Embodiment 12 embodiment 13 embodiment 14 embodiment 15 embodiment 16

Total iron is (with Fe ₂O ₃Meter) .813 .84 .74 .74 .85

Iron is reduced to the reduction ratio (%) 26.7 23.0 24.8 28.8 16.4 of FeO

Fe ₂O ₃（%） .596 .647 .556 .527 .711

FeO（%） .195 .174 .165 .192 .125

CeO ₂（%） .563 .498 .5 .5 .7

TiO ₂（%） .253 25 0 0 0

Twinkler A transmitance (%) 71.7 71.0 74.2 72 74.9

Total sun power transmitance (%) 43.8 45.0 47.8 44.3 51.2

Ultraviolet permeability (%) 33.1 33.3 39.4 40.1 28.9

Predominant wavelength (nm) 514.1 519.0 498.6 495.7 550.8

Colour purity (%) 2.5 2.4 3.3 4.4 4.1

Prophesy property embodiment 17～21

Embodiment 17 embodiment 18 embodiment 19 embodiment 20 embodiment 21 embodiment 22

Total iron is (with Fe ₂O ₃%) .76 .74 .74 .86 .86 .88

Iron is reduced to the reduction ratio (%) 23 24 23 25 27 26 of FeO

Fe ₂O ₃（%） .585 .562 .570 .645 .628 .651

FeO（%） .157 .160 .153 .194 .209 .205

CeO ₂（%） .2 .3 .4 .5 .6 .7

TiO ₂（%） 0 0 0 0 0 0

Twinkler A transmitance (%) 70.6 70.6 71.2 71.1 70.0 70.1

Total sun power transmitance (%) 42.4 42.5 43.3 42.7 41.2 41.1

Ultraviolet permeability (%) 35.2 35.3 34.1 34.4 35.1 32.0

Thickness (mm) 555444

Embodiment 11 and 12 composed as follows fully:

Embodiment 11 embodiment 12

SiO ₂71.58 71.64

Na ₂O 13.75 13.97

CaO 8.42 8.38

MgO 4.14 3.97

Fe ₂O ₃.833 .813

TiO ₂.021 .253

Al ₂O ₃.12 .16

SO ₃.13 .14

K ₂O 0 .02

Cr ₂O ₃.0002 .0003

CeO ₂.915 .563

La ₂O ₃.008 .006

Claims

1, a kind of green soda lime glass that absorbs infrared energy and uv-radiation is characterized in that wherein comprising (% meter by weight) as neccessary composition:

0.51～0.96Fe ₂O ₃

0.15～0.33FeO and

0.2～1.4CeO ₂The FeO representative of said weight % is with Fe ₂O ₃The reduction ratio of total iron of expression is 23～29%; With

Said glass is in 3～5mm scope under the thickness, and twinkler A visible light transmissivity is greater than 70%, total sun power transmitance less than 46% and also the uv-radiation transmitance less than 38%.

2, a kind of green soda lime glass that absorbs infrared energy and uv-radiation is characterized in that wherein comprising (% by weight) meter as neccessary composition:

0.48～0.92Fe ₂O ₃

0.15～0.33FeO，

0.1～1.36CeO ₂With

0.02～0.85TiO ₂; The FeO representative of said weight % is with Fe ₂O ₃The reduction ratio of total iron of expression is about 23～29%; With

3, claim 1 or 2 described green glasses is characterized in that twinkler C predominant wavelength is 498～525nm, and colour purity is 2～4%.

4, the said green glass of claim 3, wherein twinkler C predominant wavelength is about 498～518, colour purity is 2～3%, total sun power transmitance less than 45% and also the uv-radiation transmitance less than 34%.

5, the said green glass of claim 1 is characterized in that comprising (% meter by weight) as neccessary composition:

0.54～0.65Fe ₂O ₃

0.18～0.22FeO and

0.55～1.2CeO ₂，

Wherein said weight %FeO is equivalent to Fe ₂O ₃The reduction ratio of total iron of expression is 23～29%; Said glass is under the 4mm nominal thickness, and twinkler A visible light transmissivity is greater than 70%, and total sun power transmitance is less than 46%, and the uv-radiation transmitance is less than 36%.

6, the described green glass of claim 1 is characterized in that wherein comprising (% meter by weight) as neccessary composition:

0.71～0.95Fe ₂O ₃，

0.26～0.32FeO and

0.8～1.4CeO ₂

Wherein said weight %FeO representative is with Fe ₂O ₃The reduction ratio of total iron of expression is 23～29%; Said glass under the 3mm nominal thickness twinkler A visible light transmissivity greater than 70%, total sun power transmitance less than 46% and also the uv-radiation transmitance less than 36%.

7, the described green glass of claim 1 is characterized in that wherein comprising (% meter by weight) as neccessary composition:

0.51～0.59Fe ₂O ₃，

0.14～0.1.7FeO and

0.2～0.7CeO ₂，

Wherein said weight %FeO is equivalent to Fe ₂O ₃The reduction ratio of total iron of expression is about 23～29%; Said glass is under the 5mm nominal thickness, and twinkler A visible light transmissivity is greater than 70%, total sun power transmitance less than 46% and also the uv-radiation transmitance less than 36%.

8, claim 1 or 2 described green glasses is characterized in that wherein comprising (% meter by weight):

65～75SiO ₂，

10～15Na ₂O，

0～4K ₂O，

1～5MgO，

5～15CaO and

0～3Al ₂O ₃。

9, the described green glass of claim 10 is characterized in that wherein comprising (% meter by weight):

70～73SiO ₂，

12～14Na ₂O，

0～1K ₂O，

3～4MgO，

6～10CaO and

0～2Al ₂O ₃。

10, the described green glass of claim 2 is characterized in that as neccessary composition comprising (% meter) by weight:

0.51～0.62Fe ₂O ₃，

0.18～0.22FeO，

0.3～0.75CeO ₂With 0.02～0.45TiO ₂, wherein the FeO of said weight % representative is with Fe ₂O ₃The reduction ratio of total iron of expression is 23～29%; Said glass is under the 4mm nominal thickness, and twinkler A visible light transmissivity is greater than 70%, total solar energy transmitance less than 46% and also the uv-radiation transmitance less than 36%.

11, the described green glass of claim 2 is characterized in that comprising (% meter by weight) as neccessary composition:

0.48～0.59Fe ₂O ₃，

0.14～0.17FeO，

0.1～0.4CeO ₂And 0.02～0.35TiO ₂, wherein said weight %FeO representative is with Fe ₂O ₃The reduction ratio of total iron of expression is 23～29%; Said glass is under the 5mm nominal thickness, and twinkler A visible light transmissivity is greater than 70%, total solar energy transmitance less than 46% and also the uv-radiation transmitance less than 36%.

12, the described green glass of claim 2 is characterized in that comprising (% meter by weight) as neccessary composition:

0.68～0.92Fe ₂O ₃，

0.26～0.32FeO，

0.5～1.2CeO ₂With 0.02～0.85TiO ₂, wherein the FeO of said weight % is equivalent to Fe ₂O ₃The reduction ratio of total iron of representative is 23～29%; Said glass is under the 3mm nominal thickness, and twinkler A visible light transmissivity is greater than 70%, total solar energy transmitance less than 46% and also the uv-radiation transmitance less than 36%.

13, claim 1 or 2 described green glasses are as a kind of application of automotive glazings, it is characterized in that, said glazing is in 3～5mm scope under the thickness, and twinkler A visible light transmissivity is greater than 70%, total sun power transmitance less than 46% and also the uv-radiation transmitance less than 38%.

14, the described application of claim 13 is characterized in that the uv-radiation transmitance less than 36%, and twinkler C predominant wavelength is 498～518nm, and colour purity is 2～3%.