CN102757621A - Wet-type composite friction material and preparation method thereof - Google Patents
Wet-type composite friction material and preparation method thereof Download PDFInfo
- Publication number
- CN102757621A CN102757621A CN2012102398245A CN201210239824A CN102757621A CN 102757621 A CN102757621 A CN 102757621A CN 2012102398245 A CN2012102398245 A CN 2012102398245A CN 201210239824 A CN201210239824 A CN 201210239824A CN 102757621 A CN102757621 A CN 102757621A
- Authority
- CN
- China
- Prior art keywords
- carbon fiber
- fiber sheet
- parts
- friction material
- type composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Braking Arrangements (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a wet-type composite friction material and a preparation method thereof. The wet-type composite friction material comprises the following components in parts by weight: 40-80 parts of carbon fiber cloth which is used as a material framework, 10-30 parts of thermosetting resin, 8-15 parts of curing agent and 1-5 parts of friction performance adjusting agent, as well as 10-45 parts of solvent. The preparation method comprises the following steps of: sequentially mixing phenolic resin, ethanediamine and ceramic grains by taking acetone or absolute ethyl alcohol as the solvent; carrying out ultrasonic dispersion to prepare a uniformly-mixed immersing solution with a moderate viscosity; and then, immersing the carbon fiber cloth, drying and carrying out hot-pressing curing and subsequent curing heat treatment on the carbon fiber cloth. The wet-type composite friction material and the preparation method thereof have the advantages of simple process, high material strength, high and stable wet-type movable and static friction coefficients, and extremely good durability and reliability.
Description
Technical field
The present invention relates to a kind of composite friction material, related in particular to a kind of can be in oil, particularly in vehicle, engineering machinery and the boats and ships iso-variable velocity device oil as power transmission and arresting wet type composite friction material and preparation method thereof.
Background technology
Wet-type friction material is widely used on vehicle, engineering machinery, mining machinery and military equipment owing to have advantages such as heat dispersion is good, abrasion loss is little, friction factor is stable.Wet-type friction material commonly used at present has copper base friction material, paper friction material and matrix material etc., and the Wet-type friction material of widespread usage mainly is sintered bronze friction materials and paper friction material, and composite friction material also is in the development stage.The research and development of Wet-type friction material have at present obtained certain achievement; Frictional behaviour also improves; Like one Chinese patent application number is 201010554100.0 to disclose a kind of heavily loaded differential mechanism with Wet-type friction material and preparation method thereof, and it is to be to strengthen body with the carbon cloth, and modified phenolic resins is a matrix; With graphite and aluminum oxide is frictional property regulator, adds multiple filler and is prepared from.One Chinese patent application may further comprise the steps: 1) puncture into carbon fiber sheet as precast body with the carbon felt or with the thomel 3 D weaving number for 201110189608.X discloses a kind of carbon fiber woven cloth friction materials preparation method and application that is used for humid clutch; 2) precast body places in the dipping stove, and the dipping stove contains SiO
2, ZrO
2, ferro-boron, ferromanganese, one or more friction agents of ferrochrome high temperature resistant brake facing resol, control dipping back precast body density is 1.68g/cm
3～2g/cm
33) will flood the back precast body is that the impregnated cloth pressurized heat solidifies; 4) impregnated cloth is after pressurized heat solidifies, and the impregnated cloth stamping-out of gained is become required shape, at a coated with adhesive of impregnated cloth, makes impregnated cloth and supports the steel backing thermal caking.But these Wet-type friction materials still exist, and frictional coefficient is low, abrasion loss is big, the big and pollution lubricating wet goods problem of fluctuation during the The friction coefficient operation conditions change, can not satisfy the request for utilization of all kinds of heavy vehicles and engineering machinery humid clutch.Therefore, be badly in need of a kind of novel Wet-type friction material and preparation method thereof on the market, to satisfy clutch coupling and the drift stop under present high specific pressure, high linear speed and the high unit friction power operating mode with better weather resistance and safety.
Summary of the invention
The objective of the invention is to deficiency, a kind of Wet-type friction material with better weather resistance and safety and preparation method thereof is provided to prior art.
To achieve these goals, the present invention has adopted following technical scheme: a kind of wet type composite friction material is characterized in that: its component comprises as the carbon fiber sheet of material skeleton, thermosetting resin, solidifying agent and frictional property regulator; The parts by weight of said each component are:
40～80 parts of carbon fiber sheets,
10～30 parts of thermosetting resins,
8～15 parts in solidifying agent,
1～5 part of regulator,
The parts by weight of each component are preferably:
60～70 parts of carbon fiber sheets,
15～25 parts of thermosetting resins,
8～10 parts in solidifying agent,
2～4 parts of regulators,
Described carbon fiber sheet is the carbon fiber sheet of quadrature line or oblique line; Described thermosetting resin is the epoxy resin of binding type.
Described solidifying agent is a quadrol; Described regulator is a nano-ceramic particle; Described solvent is selected from a kind of of acetone and absolute ethyl alcohol.
The oxirane value of described epoxy resin is 0.24～0.45.
Described nano-ceramic particle is selected from nano SiC ceramic particle, nano TiC ceramic particle and nanometer TiB
2A kind of in the ceramic particle.
The particle diameter of described nano-ceramic particle is 20～100nm.
The preparation method of wet type composite friction material of the present invention may further comprise the steps successively:
(1) parts by weight by each component take by weighing carbon fiber sheet, thermosetting resin, solidifying agent, regulator and solvent; Then thermosetting resin, solidifying agent, regulator and solvent are carried out ultrasonic dispersing 20～40min; Be mixed into steeping fluid, and the temperature that in mixing process, keeps steeping fluid is at 30～50 ℃;
(2) after liquid to be impregnated is made into, carbon fiber sheet is put into steeping fluid soak 10～20min, take out carbon fiber sheet then and put into air dry oven and carry out drying in 50～90 ℃, be 18～36h time of drying; Carbon fiber sheet is fixed with acupuncture on the Z direction in drying process.
(3) 3～10 layers warp immersion, dried carbon fiber sheet are put into vulcanizing press in 130～160 ℃ of hot-press solidifying 10～30min, temperature rise is lower than 6 ℃/min in hot pressing, exits 3 times;
(4) carbon fiber sheet after will suppressing is put into 180～220 ℃ loft drier and is cured thermal treatment 8～15h, and temperature rise is 3～5 ℃/min; At last, it being cooled to room temperature gets product.
The parts by weight of each component described in the preparation method are:
40～80 parts of carbon fiber sheets,
10～30 parts of thermosetting resins,
8～15 parts in solidifying agent,
1～5 part of regulator,
Carbon fiber sheet described in the preparation method is the carbon fiber sheet of quadrature line or oblique line; Described thermosetting resin is the epoxy resin of binding type, and the oxirane value of epoxy resin is 0.24～0.45.
Solidifying agent described in the preparation method selects quadrol; Described regulator is a nano-ceramic particle, is selected from nano SiC ceramic particle, nano TiC ceramic particle and nanometer TiB
2A kind of in the ceramic particle; Described solvent is selected from a kind of in acetone, absolute ethyl alcohol and the ethylene glycol-acetate.
The particle diameter of the nano-ceramic particle described in the preparation method is 20～100nm.
In preparation method of the present invention, it is laboratory Ultrasonic Cleaners commonly used that the part component is carried out the instrument that ultrasonic dispersing uses; Like SK250LH dual-frequency ultrasonic wave cleanser, there are two kinds of frequencies of 59KHz and 40KHz to select, the UW of high frequency has very strong perviousness, can make mixing, the degassing, deaeration, dispersion and extract quicker, more abundant.Adopt the ultrasonic cleaner of other models also passable, like SK3200LH dual-frequency ultrasonic wave cleanser, SK2200 high-frequency ultrasonic cleanser etc.Do not have the restriction of too many technical parameter carrying out this process of ultrasonic dispersing, only need thermosetting resin, solidifying agent, regulator and solvent put into to mix to get final product.
Advantage of the present invention:
(1) nano-ceramic particle/epoxy resin // ethanol/solidifying agent steeping fluid prescription has originality; Can satisfy two-dimentional charcoal cloth range upon range of/epoxy resin friction materials viscosity, curing and requirement of strength; Also, make that the preparation process is easy, compare with Wet-type friction materials such as powder metallurgy friction material, paper friction materials applicable to other resin-matrix friction materials; Level of automation is high, reduces preparation cost greatly;
(2) adopt nano-ceramic particle as single filler, can effectively control the rubbing factor size, improve the heat resisting temperature of epoxy resin, prevent in the filler working process because of the wearing and tearing pollution lubricating oil that comes off;
(3) adopt needle punching fixed carbon cloth, effectively controlled the cracking and the buckling deformation of charcoal cloth lamination;
(4) technology of the present invention is simple, energy consumption is low, good, the high mechanical strength of material homogeneity, obdurability, thermomechanical property is good, rubbing factor is stable, Heat stability is good, fabulous weather resistance and safety, low rate of wear, long service life; Be fit to the clutch coupling of multiple sedan limousine, heavy vehicle clutch, engineering machinery, mining machinery, very wide application prospect is arranged.
Embodiment
Below in conjunction with embodiment the present invention is further specified.
Embodiment 1:
Each composition weight of wet type composite friction material: carbon fiber sheet 400 grams, oxirane value are 0.24 epoxy resin 100 grams, and quadrol 50 grams, particle diameter are nano SiC ceramic particle 10 grams of 20nm, acetone 100 grams.
The preparation process:
(1) the above-mentioned epoxy resin that takes by weighing, quadrol, nano SiC ceramic particle, acetone are carried out ultrasonic dispersing 20min, and be mixed into steeping fluid, the temperature that in mixing process, keeps steeping fluid is about 30 ℃;
(2) carbon fiber sheet is put into the steeping fluid for preparing and soak 10min, take out carbon fiber sheet then and put into air dry oven and carry out dry 36h in 50 ℃;
(3) put into vulcanizing press in 130 ℃ of hot-press solidifying 30min with 3 layers through immersion, dried carbon fiber sheet, temperature rise is lower than 6 ℃ in hot pressing, exits 3 times;
(4) carbon fiber sheet after will suppressing is put into 180 ℃ loft drier and is cured thermal treatment 15h, and temperature rise is 3 ℃/min; At last, it being cooled to room temperature gets product.
(5) friction materials with gained detects through MM-2000 type friction material test machine, pressure 2MPa, and rotating speed 3500r/min, recording static friction factor is 0.136, and dynamic friction factor is 0.135 ~ 0.157, and 300 arresting wear rates of material are 1.0 * 10
-8Cm
3/ J.
Embodiment 2:
Each composition weight of wet type composite friction material: carbon fiber sheet 800 grams, oxirane value are 0.45 epoxy resin 300 grams, and acid anhydrides 80 grams, particle diameter are nano TiC ceramic particle 50 grams of 100nm, absolute ethyl alcohol 450 grams.
The preparation process:
(1) the above-mentioned epoxy resin that takes by weighing, quadrol, nano TiC ceramic particle, absolute ethyl alcohol are carried out ultrasonic dispersing 25min, and be mixed into steeping fluid, the temperature that in mixing process, keeps steeping fluid is about 50 ℃;
(2) carbon fiber sheet is put into the steeping fluid for preparing and soak 20min, take out carbon fiber sheet then and put into air dry oven and carry out dry 18h in 90 ℃;
(3) put into vulcanizing press in 160 ℃ of hot-press solidifying 10min with 10 layers through immersion, dried carbon fiber sheet, temperature rise is lower than 6 ℃ in hot pressing, exits 3 times;
(4) carbon fiber sheet after will suppressing is put into 220 ℃ loft drier and is cured thermal treatment 8h, and temperature rise is 3 ℃/min; At last, it being cooled to room temperature gets product.
(5) friction materials with gained detects through MM-2000 type friction material test machine, pressure 2MPa, and rotating speed 3500r/min, recording static friction factor is 0.130, and dynamic friction factor is 0.132 ~ 0.143, and 300 arresting wear rates of material are 0.95 * 10
-8Cm
3/ J.
Embodiment 3:
Each composition weight of wet type composite friction material: carbon fiber sheet 600 grams, oxirane value are 0.3 epoxy resin 150 grams, quadrol 60 grams, and particle diameter is the nanometer TiB of 40nm
2Ceramic particle 20 grams, acetone 150 grams.
The preparation process:
(1) with the above-mentioned epoxy resin that takes by weighing, quadrol, nanometer TiB
2Ceramic particle, acetone carry out ultrasonic dispersing 25min, and are mixed into steeping fluid, and the temperature that in mixing process, keeps steeping fluid is about 40 ℃;
(2) carbon fiber sheet is put into the steeping fluid for preparing and soak 13min, take out carbon fiber sheet then and put into air dry oven and carry out dry 20h in 60 ℃;
(3) put into vulcanizing press in 135 ℃ of hot-press solidifying 25min with 4 layers through immersion, dried carbon fiber sheet, temperature rise is lower than 6 ℃ in hot pressing, exits 3 times;
(4) carbon fiber sheet after will suppressing is put into 190 ℃ loft drier and is cured thermal treatment 14h, and temperature rise is 4 ℃/min; At last, it being cooled to room temperature gets product.
(5) friction materials with gained detects through MM-2000 type friction material test machine, pressure 2MPa, and rotating speed 3500r/min, recording static friction factor is 0.138, and dynamic friction factor is 0.140 ~ 0.151, and 300 arresting wear rates of material are 1.1 * 10
-8Cm
3/ J.
Embodiment 4:
Each composition weight of wet type composite friction material: carbon fiber sheet 700 grams, oxirane value are 0.40 epoxy resin 250 grams, and quadrol 70 grams, particle diameter are nano TiC ceramic particle 40 grams of 80nm, absolute ethyl alcohol 300 grams.
The preparation process:
(1) the above-mentioned epoxy resin that takes by weighing, quadrol, nano TiC ceramic particle, absolute ethyl alcohol are carried out ultrasonic dispersing 30min, and be mixed into steeping fluid, the temperature that in mixing process, keeps steeping fluid is about 45 ℃;
(2) carbon fiber sheet is put into the steeping fluid for preparing and soak 17min, take out carbon fiber sheet then and put into air dry oven and carry out dry 24h in 75 ℃;
(3) put into vulcanizing press in 150 ℃ of hot-press solidifying 20min with 8 layers through immersion, dried carbon fiber sheet, temperature rise is lower than 6 ℃ in hot pressing, exits 3 times;
(4) carbon fiber sheet after will suppressing is put into 200 ℃ loft drier and is cured thermal treatment 9h, and temperature rise is 5 ℃/min; At last, it being cooled to room temperature gets product.
(5) friction materials with gained detects through MM-2000 type friction material test machine, pressure 2MPa, and rotating speed 3500r/min, recording static friction factor is 0.136, and dynamic friction factor is 0.135 ~ 0.157, and 300 arresting wear rates of material are 0.89 * 10
-8Cm
3/ J.
Embodiment 5:
Each composition weight of wet type composite friction material: carbon fiber sheet 650 grams, oxirane value are 0.35 epoxy resin 200 grams, and quadrol 65 grams, particle diameter are nano SiC ceramic particle 30 grams of 65nm, acetone 225 grams.
The preparation process:
(1) the above-mentioned epoxy resin that takes by weighing, quadrol, nano SiC ceramic particle, acetone are carried out ultrasonic dispersing 35min, and be mixed into steeping fluid, the temperature that in mixing process, keeps steeping fluid is about 30 ℃;
(2) carbon fiber sheet is put into the steeping fluid for preparing and soak 10min, take out carbon fiber sheet then and put into air dry oven and carry out dry 36h in 50 ℃;
(3) put into vulcanizing press in 155 ℃ of hot-press solidifying 15min with 6 layers through immersion, dried carbon fiber sheet, temperature rise is lower than 6 ℃ in hot pressing, exits 3 times;
(4) carbon fiber sheet after will suppressing is put into 210 ℃ loft drier and is cured thermal treatment 10h, and temperature rise is 4 ℃/min; At last, it being cooled to room temperature gets product.
(5) friction materials with gained detects through MM-2000 type friction material test machine, pressure 2MPa, and rotating speed 3500r/min, recording static friction factor is 0.131, and dynamic friction factor is 0.140 ~ 0.150, and 300 arresting wear rates of material are 1.2 * 10
-8Cm
3/ J.
Embodiment 6:
Each composition weight of wet type composite friction material: carbon fiber sheet 600 grams, oxirane value are 0.32 epoxy resin 200 grams, and quadrol 65 grams, particle diameter are nano SiC ceramic particle 25 grams of 55nm, acetone 280 grams.
The preparation process:
(1) the above-mentioned epoxy resin that takes by weighing, acid anhydrides, nano SiC ceramic particle, acetone are carried out ultrasonic dispersing 40min, and be mixed into steeping fluid, the temperature that in mixing process, keeps steeping fluid is about 30 ℃;
(2) carbon fiber sheet is put into the steeping fluid for preparing and soak 10min, take out carbon fiber sheet then and put into air dry oven and carry out dry 36h in 50 ℃;
(3) put into vulcanizing press in 160 ℃ of hot-press solidifying 10min with 5 layers through immersion, dried carbon fiber sheet, temperature rise is lower than 6 ℃ in hot pressing, exits 3 times;
(4) carbon fiber sheet after will suppressing is put into 200 ℃ loft drier and is cured thermal treatment 10h, and temperature rise is 3 ℃/min; At last, it being cooled to room temperature gets product.
(5) friction materials with gained detects through MM-2000 type friction material test machine, pressure 2MPa, and rotating speed 3500r/min, recording static friction factor is 0.140, and dynamic friction factor is 0.145 ~ 0.165, and 300 arresting wear rates of material are 1.1 * 10
-8Cm
3/ J.
Embodiment 7:
Each composition weight of wet type composite friction material: carbon fiber sheet 400 grams, oxirane value are 0.24 epoxy resin 100 grams, quadrol 50 grams, and particle diameter is the nanometer TiB of 20nm
2Ceramic particle 10 grams, acetone 100 grams.
The preparation process:
(1) with the above-mentioned epoxy resin that takes by weighing, quadrol, nanometer TiB
2Ceramic particle, acetone carry out ultrasonic dispersing 25min, and are mixed into steeping fluid, and the temperature that in mixing process, keeps steeping fluid is about 30 ℃;
(2) carbon fiber sheet is put into the steeping fluid for preparing and soak 10min, take out carbon fiber sheet then and put into air dry oven and carry out dry 36h in 50 ℃;
(3) put into vulcanizing press in 130 ℃ of hot-press solidifying 30min with 7 layers through immersion, dried carbon fiber sheet, temperature rise is lower than 6 ℃ in hot pressing, exits 3 times;
(4) carbon fiber sheet after will suppressing is put into 220 ℃ loft drier and is cured thermal treatment 8h, and temperature rise is 3 ℃/min; At last, it being cooled to room temperature gets product.
(5) friction materials with gained detects through MM-2000 type friction material test machine, pressure 2MPa, and rotating speed 3500r/min, recording static friction factor is 0.136, and dynamic friction factor is 0.134 ~ 0.149, and 300 arresting wear rates of material are 0.87 * 10
-8Cm
3/ J.
Embodiment 8:
Each composition weight of wet type composite friction material: carbon fiber sheet 450 grams, oxirane value are 0.24 epoxy resin 100 grams, and quadrol 50 grams, particle diameter are nano SiC ceramic particle 10 grams of 20nm, acetone 130 grams.
The preparation process:
(1) the above-mentioned epoxy resin that takes by weighing, Dyhard RU 100, ceramic of nano SiC, acetone are carried out ultrasonic dispersing 30min, and be mixed into steeping fluid, the temperature that in mixing process, keeps steeping fluid is about 30 ℃;
(2) carbon fiber sheet is put into the steeping fluid for preparing and soak 15min, take out carbon fiber sheet then and put into air dry oven and carry out dry 36h in 50 ℃;
(3) put into vulcanizing press in 130 ℃ of hot-press solidifying 30min with 3 layers through immersion, dried carbon fiber sheet, temperature rise is lower than 6 ℃ in hot pressing, exits 3 times;
(4) carbon fiber sheet after will suppressing is put into 180 ℃ loft drier and is cured thermal treatment 15h, and temperature rise is 3 ℃/min; At last, it being cooled to room temperature gets product.
(5) friction materials with gained detects through MM-2000 type friction material test machine, pressure 2MPa, and rotating speed 3500r/min, recording static friction factor is 0.130, and dynamic friction factor is 0.136 ~ 0.150, and 300 arresting wear rates of material are 0.93 * 10
-8Cm
3/ J.
Embodiment 9:
Each composition weight of wet type composite friction material: carbon fiber sheet 800 grams, oxirane value are 0.45 epoxy resin 300 grams, and quadrol 80 grams, particle diameter are nano TiC ceramic particle 50 grams of 100nm, acetone 450 grams.
The preparation process:
(1) the above-mentioned epoxy resin that takes by weighing, acid anhydrides, nano TiC ceramic particle, acetone are carried out ultrasonic dispersing 40min, and be mixed into steeping fluid, the temperature that in mixing process, keeps steeping fluid is about 50 ℃;
(2) carbon fiber sheet is put into the steeping fluid for preparing and soak 20min, take out carbon fiber sheet then and put into air dry oven and carry out dry 18h in 90 ℃;
(3) put into vulcanizing press in 160 ℃ of hot-press solidifying 10min with 10 layers through immersion, dried carbon fiber sheet, temperature rise is lower than 6 ℃ in hot pressing, exits 3 times;
(4) carbon fiber sheet after will suppressing is put into 220 ℃ loft drier and is cured thermal treatment 8h, and temperature rise is 3 ℃/min; At last, it being cooled to room temperature gets product.
(5) friction materials with gained detects through MM-2000 type friction material test machine, pressure 2MPa, and rotating speed 3500r/min, recording static friction factor is 0.133, and dynamic friction factor is 0.140 ~ 0.153, and 300 arresting wear rates of material are 1.2 * 10
-8Cm
3/ J.
Embodiment 10:
Each composition weight of wet type composite friction material: carbon fiber sheet 400 grams, oxirane value are 0.24 epoxy resin 100 grams, and quadrol 50 grams, particle diameter are nano SiC ceramic particle 10 grams of 20nm, acetone 100 grams.
The preparation process:
(1) the above-mentioned epoxy resin that takes by weighing, quadrol, ceramic of nano SiC, acetone are carried out ultrasonic dispersing 25min, and be mixed into steeping fluid, the temperature that in mixing process, keeps steeping fluid is about 30 ℃;
(2) carbon fiber sheet is put into the steeping fluid for preparing and soak 10min, take out carbon fiber sheet then and put into air dry oven and carry out dry 30h in 75 ℃;
(3) put into vulcanizing press in 140 ℃ of hot-press solidifying 25min with 5 layers through immersion, dried carbon fiber sheet, temperature rise is lower than 6 ℃ in hot pressing, exits 3 times;
(4) carbon fiber sheet after will suppressing is put into 180 ℃ loft drier and is cured thermal treatment 15h, and temperature rise is 3 ℃/min; At last, it being cooled to room temperature gets product.
(5) friction materials with gained detects through MM-2000 type friction material test machine, pressure 2MPa, and rotating speed 3500r/min, recording static friction factor is 0.132, and dynamic friction factor is 0.136 ~ 0.142, and 300 arresting wear rates of material are 0.96 * 10
-8Cm
3/ J.
Claims (5)
1. wet type composite friction material, it is characterized in that: its component comprises as the carbon fiber sheet of material skeleton, thermosetting resin, solidifying agent, regulator and solvent; The parts by weight of said each component are:
40～80 parts of carbon fiber sheets,
10～30 parts of thermosetting resins,
8～15 parts in solidifying agent,
1～5 part of regulator,
Described carbon fiber sheet is the carbon fiber sheet of quadrature line or oblique line;
Described thermosetting resin is the epoxy resin of binding type;
Described solidifying agent is a quadrol;
Described regulator is a nano-ceramic particle;
Described solvent is selected from a kind of in acetone and the absolute ethyl alcohol.
2. wet type composite friction material according to claim 1 is characterized in that: the oxirane value of described epoxy resin is 0.24～0.45.
3. wet type composite friction material according to claim 1 is characterized in that: described nano-ceramic particle is selected from nano SiC ceramic particle, nano TiC ceramic particle and nanometer TiB
2A kind of in the ceramic particle.
4. wet type composite friction material according to claim 1 is characterized in that: the particle diameter of described nano-ceramic particle is 20～100nm.
5. method for preparing wet type composite friction material as claimed in claim 1, it is characterized in that: this preparation method may further comprise the steps successively:
(1) parts by weight by each component take by weighing carbon fiber sheet, thermosetting resin, solidifying agent, regulator and solvent; Then thermosetting resin, solidifying agent, regulator and solvent are carried out at ultrasonic dispersing 20～40min; Be mixed into steeping fluid, and the temperature that in mixing process, keeps steeping fluid is at 30～50 ℃;
(2) after liquid to be impregnated is made into, carbon fiber sheet is put into steeping fluid soak 10～20min, take out carbon fiber sheet then and put into air dry oven and carry out drying in 50～90 ℃, be 18～36h time of drying;
(3) put into vulcanizing press in 130～160 ℃ of hot-press solidifying 10～30min with 3～10 layers through immersion, dried carbon fiber sheet, in hot pressing, be lower than 6 ℃/min, exit 2～4 times from the temperature rise of room temperature to hot pressing temperature;
(4) carbon fiber sheet after will suppressing is put into 180～220 ℃ loft drier and is cured thermal treatment 8～15h, and temperature rise is 3～5 ℃/min; At last, it being cooled to room temperature gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210239824.5A CN102757621B (en) | 2012-07-12 | 2012-07-12 | Wet-type composite friction material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210239824.5A CN102757621B (en) | 2012-07-12 | 2012-07-12 | Wet-type composite friction material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102757621A true CN102757621A (en) | 2012-10-31 |
| CN102757621B CN102757621B (en) | 2014-07-23 |
Family
ID=47052295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210239824.5A Expired - Fee Related CN102757621B (en) | 2012-07-12 | 2012-07-12 | Wet-type composite friction material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102757621B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881295A (en) * | 2014-03-31 | 2014-06-25 | 陕西科技大学 | Method for preparing nano-particle modified carbon cloth reinforced wet friction material |
| CN109988392A (en) * | 2019-03-28 | 2019-07-09 | 广西民族大学 | A kind of basalt fiber cloth/resin base Wet-type friction material and preparation method thereof |
| CN110655908A (en) * | 2019-10-11 | 2020-01-07 | 山东万邦新材料科技有限公司 | Preparation method of carbon fiber friction material |
| CN111691069A (en) * | 2020-05-18 | 2020-09-22 | 苏州大学 | Puncture-resistant fiber composite membrane and preparation method thereof |
| CN113123162A (en) * | 2021-04-09 | 2021-07-16 | 西北工业大学 | Preparation method of double-substrate paper-based friction material with excellent performance |
| CN114196159A (en) * | 2021-11-15 | 2022-03-18 | 泰山体育产业集团有限公司 | Layered carbon fiber reinforced friction material and preparation process thereof |
| CN115385711A (en) * | 2022-07-05 | 2022-11-25 | 烟台凯泊复合材料科技有限公司 | Composite-structure light ceramic brake disc and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101178105A (en) * | 2007-11-26 | 2008-05-14 | 杭州前进齿轮箱集团有限公司 | Wet-type carbon-carbon friction material, friction element and manufacturing method |
| JP2009263449A (en) * | 2008-04-23 | 2009-11-12 | Showa Highpolymer Co Ltd | Wet friction material |
| CN101671537A (en) * | 2009-08-29 | 2010-03-17 | 桂林星火机械制造有限公司 | Carbon fiber cloth composite friction material and application thereof for manufacturing friction layer of vehicle powder metallurgy synchronizer tooth ring |
| CN102031087A (en) * | 2010-11-18 | 2011-04-27 | 西北工业大学 | Wet friction material for heavy-duty differential and preparation method thereof |
-
2012
- 2012-07-12 CN CN201210239824.5A patent/CN102757621B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101178105A (en) * | 2007-11-26 | 2008-05-14 | 杭州前进齿轮箱集团有限公司 | Wet-type carbon-carbon friction material, friction element and manufacturing method |
| JP2009263449A (en) * | 2008-04-23 | 2009-11-12 | Showa Highpolymer Co Ltd | Wet friction material |
| CN101671537A (en) * | 2009-08-29 | 2010-03-17 | 桂林星火机械制造有限公司 | Carbon fiber cloth composite friction material and application thereof for manufacturing friction layer of vehicle powder metallurgy synchronizer tooth ring |
| CN102031087A (en) * | 2010-11-18 | 2011-04-27 | 西北工业大学 | Wet friction material for heavy-duty differential and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 张永振: "《材料的干摩擦学》", 30 July 2007 * |
| 王秀飞: "《中南大学博士学位论文》", 29 December 2010 * |
| 高惠民: "《矿物复合摩擦材料》", 30 June 2007 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881295A (en) * | 2014-03-31 | 2014-06-25 | 陕西科技大学 | Method for preparing nano-particle modified carbon cloth reinforced wet friction material |
| CN103881295B (en) * | 2014-03-31 | 2016-04-06 | 陕西科技大学 | A kind of modified by nano particles carbon cloth strengthens the preparation method of Wet-type friction material |
| CN109988392A (en) * | 2019-03-28 | 2019-07-09 | 广西民族大学 | A kind of basalt fiber cloth/resin base Wet-type friction material and preparation method thereof |
| CN109988392B (en) * | 2019-03-28 | 2021-11-23 | 广西民族大学 | Basalt fiber cloth/resin-based wet friction material and preparation method thereof |
| CN110655908A (en) * | 2019-10-11 | 2020-01-07 | 山东万邦新材料科技有限公司 | Preparation method of carbon fiber friction material |
| CN111691069A (en) * | 2020-05-18 | 2020-09-22 | 苏州大学 | Puncture-resistant fiber composite membrane and preparation method thereof |
| CN111691069B (en) * | 2020-05-18 | 2021-10-08 | 苏州大学 | Puncture-resistant fiber composite membrane and preparation method thereof |
| CN113123162A (en) * | 2021-04-09 | 2021-07-16 | 西北工业大学 | Preparation method of double-substrate paper-based friction material with excellent performance |
| CN114196159A (en) * | 2021-11-15 | 2022-03-18 | 泰山体育产业集团有限公司 | Layered carbon fiber reinforced friction material and preparation process thereof |
| CN115385711A (en) * | 2022-07-05 | 2022-11-25 | 烟台凯泊复合材料科技有限公司 | Composite-structure light ceramic brake disc and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102757621B (en) | 2014-07-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102757621B (en) | Wet-type composite friction material and preparation method thereof | |
| CN102993635B (en) | Method for preparing clutch facing through taking water soluble phenol-formaldehyde resin as adhesion agent | |
| VR et al. | Effect of silicon coupling grafted ferric oxide and e-glass fibre in thermal stability, wear and tensile fatigue behaviour of epoxy hybrid composite | |
| CN108794979B (en) | High-compression-strength and high-tensile-ratio carbon fiber composite material and preparation method thereof | |
| CN110843294A (en) | Preparation method of high-speed working condition self-lubricating fabric liner composite material | |
| CN102878232A (en) | Ceramic-fiber-paper-based friction plate and production method thereof | |
| CN111546722A (en) | Reinforced high-thermal-conductivity mica tape and preparation method thereof | |
| CN110452398B (en) | Preparation method of self-lubricating fabric liner composite material with interface consumption and heat aggregation under high-speed working condition | |
| CN112795134B (en) | Two-dimensional nano-material modified carbon fiber fabric self-lubricating composite material and preparation method thereof | |
| CN103726399B (en) | A kind of blended fiber strengthens paper friction material and preparation method thereof | |
| CN103881295A (en) | Method for preparing nano-particle modified carbon cloth reinforced wet friction material | |
| CN102729540B (en) | Vehicle silencing sheet and preparation method thereof | |
| Zhao et al. | Simultaneously tuning interfacial and interlaminar properties of glass fiber fabric/epoxy laminated composites via modifying fibers with graphene oxide | |
| CN103320092A (en) | Method for preparing wet friction material of nano silicon carbide modified carbon cloth | |
| CN108866456A (en) | A kind of stainless steel fibre enhancing Al alloy composite and preparation method thereof | |
| CN110819064A (en) | High-thermal-conductivity wear-resistant self-lubricating liner and preparation method thereof | |
| CN106930138A (en) | A kind of Graphene is modified paper friction material and preparation method | |
| CN114015110A (en) | Low-shrinkage phenolic aerogel and preparation method thereof | |
| CN103030922B (en) | Water-soluble phenolic resin solution for woven friction materials and preparation method thereof | |
| CN109988392A (en) | A kind of basalt fiber cloth/resin base Wet-type friction material and preparation method thereof | |
| CN103541266A (en) | Pumping filtration-based preparation method of paper-based friction material | |
| CN105697624A (en) | 2.5-dimensional carbon fiber/aramid fiber woven perform reinforced cashew nut shell oil modified phenolic resin-based friction material | |
| CN107542818A (en) | To retro-speed and the resin-matrix friction material of temperature muting sensitive sense and preparation method thereof | |
| CN109024055B (en) | Preparation method of high-wear-resistance paper-based friction material | |
| CN114806500A (en) | Low-noise friction material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160129 Address after: 530006, Guangxi University For Nationalities, 188 East University Road, the Guangxi Zhuang Autonomous Region, Nanning Patentee after: Guangxi National Univ. Address before: 530007, the Guangxi Zhuang Autonomous Region, Nanning Science Park Avenue, East Fourth Road, Nanning Overseas Students Pioneer Park, 4 floor, No. B09 Patentee before: Guangxi Nanning Chuangzhihui Material Technology Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140723 Termination date: 20200712 |