CN102747382B - Insulation and anti-oxidation method and insulation cladding system when aluminium cell produces - Google Patents
Insulation and anti-oxidation method and insulation cladding system when aluminium cell produces Download PDFInfo
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- CN102747382B CN102747382B CN201110100663.7A CN201110100663A CN102747382B CN 102747382 B CN102747382 B CN 102747382B CN 201110100663 A CN201110100663 A CN 201110100663A CN 102747382 B CN102747382 B CN 102747382B
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- Prior art keywords
- insulation
- aluminium cell
- cladding system
- anode
- aluminium
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- 238000009413 insulation Methods 0.000 title claims abstract description 54
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 48
- 239000004411 aluminium Substances 0.000 title claims abstract description 45
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 238000005253 cladding Methods 0.000 title claims abstract description 36
- 230000003064 anti-oxidating Effects 0.000 title claims abstract description 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N al2o3 Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 19
- 239000010959 steel Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 15
- 229910001884 aluminium oxide Inorganic materials 0.000 claims abstract description 11
- 239000003792 electrolyte Substances 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000002362 mulch Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 6
- 229910002114 biscuit porcelain Inorganic materials 0.000 claims description 5
- 210000000078 Claw Anatomy 0.000 claims description 3
- 238000010301 surface-oxidation reaction Methods 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000011819 refractory material Substances 0.000 abstract description 12
- 239000011248 coating agent Substances 0.000 abstract description 11
- 238000000576 coating method Methods 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 238000010276 construction Methods 0.000 abstract description 4
- 238000005868 electrolysis reaction Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000005611 electricity Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- PZZOEXPDTYIBPI-UHFFFAOYSA-N 2-[[2-(4-hydroxyphenyl)ethylamino]methyl]-3,4-dihydro-2H-naphthalen-1-one Chemical compound C1=CC(O)=CC=C1CCNCC1C(=O)C2=CC=CC=C2CC1 PZZOEXPDTYIBPI-UHFFFAOYSA-N 0.000 description 1
- 206010010741 Conjunctivitis Diseases 0.000 description 1
- 230000001154 acute Effects 0.000 description 1
- 230000000903 blocking Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002001 electrolyte material Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
Abstract
The invention discloses insulation and anti-oxidation method and insulation cladding system when a kind of aluminium cell produces, the present invention uses steel beam column plate and heat insulating refractory material block connect on each anode that the insulation cladding system portable, made of one piece formed covers on aluminium cell and cover in the groove end of aluminium cell and the position of groove sidepiece, and aluminium cell the most i.e. can be incubated and prevent its anode surface from aoxidizing effectively.The present invention has discarded the mode of the mixing coating material layer of aluminium oxide used in the prior art and electrolyte composition completely.The present invention is compared with prior art, the present invention not only have easy to operate, operating cost is low, laborsaving, save time, the advantage of work efficiency, but also have simple in construction, insulation and oxidation-protective effect preferably and stablize, economize on resources, less demanding to experience and the technical merit of operator, be easy to mass and the advantages such as production of standardizing.
Description
Technical field
The present invention relates to insulation and anti-oxidation method and insulation cladding system when a kind of aluminium cell produces, belong to aluminum electricity
Solve groove insulation and anti-oxidation technology field.
Background technology
At present, existing aluminium cell in production run, commonly used on the anode of aluminium cell cover one layer by not
The mode of the bulk coating material layer of the electrolyte granular of one-size size and alumina particle mixing composition carries out being incubated and preventing
Only anode surface oxidation, this coating material layer is added mainly by overhead traveling crane and artificial making forms.Existing this employing bulk covers
The bed of material carries out being incubated and the mode of anti-oxidation, there is following problem in production and application:
1, the laying of existing coating material layer is completely by operator's experience, the became uneven of coating material layer, overburden cover
Uniformity be difficult to ensure that, thus cause be incubated uniformity poor.
2, existing aluminium oxide and electrolyte mixing mulch, when electrolysis temperature raises, particularly generating effect or groove
Condition fluctuates for a long time, is easily melted in groove, causes groove condition and self heat-insulating property to deteriorate;
3, the main component of existing coating material layer is aluminium oxide and electrolyte granular, and its mobility is preferable, the most very
It is susceptible to the rough sledding such as anodic oxidation, feed opening blocking, acute catarrhal conjunctivitis.
4, due to the effect of high temperature, make coating material layer crust harder, when change poles operates, need to employ multifunction crane special
The pneumatic tup dolly of door, uses tup to punch crust layer by force, just can extract anode scrap, add workload, waste time and energy.
5, during change poles, crust block and alumina powder are often fallen in electrolyte, cause electrolytic bath condition unstable, voltage wave
Dynamic big, cause power consumption to lose.
6, in electrolysis design process flow, in order to add mulch, the conveying of related oxidized aluminum, overhead traveling crane charging, electricity must be increased
Solve that matter is broken and the system configuration such as induction system, add system investments and systematic running cost is used.
7, in electrolysis production technological process, in order to open mulch crust when changing anode, it is necessary to configuration is electrolysed many merits
The crust breaking tool cart of energy overhead traveling crane, adds system investments and systematic running cost is used.
8, in electrolysis production material flow, the circulating load of electrolyte material is bigger, and sizable portion in circulating load
Dividing from anode-covered material, this causes recycle stock treating capacity to rise, and adds processing cost, meanwhile, and this partial electrolyte pledge
Material too increases fund and overstocks.
Owing to there are the problems referred to above, insulation and anti-oxidation mode when the most existing aluminium cell produces are the most inadequate
Preferable.
Summary of the invention
It is an object of the invention to: provide a kind of simple in construction, easy to operate, operating cost is relatively low, laborsaving, save time and
And insulation and oxidation-protective effect preferable aluminium cell are incubated when producing and anti-oxidation method and insulation cladding system, to overcome
The deficiencies in the prior art.
The present invention is achieved in that when a kind of aluminium cell of the present invention produces, insulation and anti-oxidation method are to adopt
Can the insulation cladding system of disassembly and assembly quickly and easily covering of composition is connected with steel beam column plate and heat insulating refractory material block
With covering in the groove end of aluminium cell and the position of groove sidepiece on each anode on aluminium cell, the most i.e. can replace
For the existing mulch mixed by electrolyte block and aluminium oxide, effectively it is incubated anode and prevents its surface oxidation.
When being covered on the anode on aluminium cell by insulation cladding system, first laying a layer thickness on anode is 1
~the aluminium oxide bisque of 3cm, the most again insulation cladding system is covered on the aluminium oxide bisque on anode.
Insulation cladding system is being covered on the anode on aluminium cell and is covering at the groove end of aluminium cell and groove
During the position of sidepiece, at the gap between insulation cladding system and insulation cladding system and insulation cladding system and institute
Aluminium oxide is all filled at gap at gap between the anode steel claw being enclosed within and between insulation cladding system and aluminium cell
Powder.
When a kind of aluminium cell of present invention invention produces, insulation and anti-oxidation insulation cladding system are: this device
Being connected by steel beam column plate and heat insulating refractory material block and form, it is whole that heat insulating refractory material block is connected as one by bolt and steel beam column plate
Body.
It is connected as holistic steel beam column plate above by bolt and heat insulating refractory material block is unitary solid structure.
It is provided with for being enclosed within sun being connected as above by bolt on holistic steel beam column plate and heat insulating refractory material block
Extremely go up the through hole on steel pawl.
Owing to have employed technique scheme, the present invention has abandoned aluminium oxide used in the prior art and electrolysis completely
The mode of the mixing coating material layer of matter composition.The present invention, on the basis of guaranteeing insulation and anti-oxidation function, greatly reduces structure
Crushing required for building existing coating material layer, carry, the construction investment of the system such as charging and operating cost;And dimension can be reduced
Hold the crust breaking that existing mulch produces, workload and the time of building, receive the operations such as limit by laying bricks or stones;Existing mulch can be avoided at change poles
Time crust and alumina powder fall in groove, the groove condition that causes fluctuation, thus reduce fluctuation energy consumption;Can not groove condition and bath temperature
Impact, maintains stable insulation and anti-oxidation function;Mulch circular treatment expense can be reduced and raw material fund overstocks, and
And the insulation cladding system of the present invention can reuse, therefore greatly reduce the waste of resource, effectively reduce production
Cost;And in use, the insulation cladding system of the molding made the most in batch only need to be placed in aluminium electroloysis by operator
Can complete operation on groove and on anode, therefore experience and technical merit to operator are less demanding.So, the present invention is with existing
Have technology to compare, the present invention not only have easy to operate, operating cost is low, laborsaving, save time, the advantage of work efficiency, but also
Have simple in construction, insulation and oxidation-protective effect preferably, economize on resources, less demanding to experience and the technical merit of operator,
It is easy to the advantage such as mass and standardization production.
Accompanying drawing illustrates,
Fig. 1 is the structural representation that apparatus of the present invention cover when using on the end and anode of aluminium cell;
Fig. 2 is the structural representation that apparatus of the present invention cover when using on the sidepiece and anode of aluminium cell;
Description of reference numerals: 1-steel beam column plate, 2-heat insulating refractory material block, 3-bolt, 4-anode, 5-aluminium cell,
The groove end of 5.1-aluminium cell, the groove sidepiece of 5.2-aluminium cell.
Detailed description of the invention,
The present invention is described in further detail with embodiment below in conjunction with the accompanying drawings.
Embodiments of the invention: when implementing the present invention, when first producing by a kind of aluminium cell producing the present invention
Insulation and anti-oxidation insulation cladding system, as depicted in figs. 1 and 2, this device is by steel beam column plate 1 He for this apparatus structure schematic diagram
Heat insulating refractory material block 2 connects composition, and steel beam column plate 1 can use general steel plate to make, and heat insulating refractory material block 2 can use existing
The material with corrosion-resistant and fire resistance make, during making, by the heat insulating refractory material block 2 made by bolt 3 with
It is overall that steel beam column plate 1 is connected as one;Holistic steel beam column plate 1 can be connected as by passing through bolt 3 and heat insulating refractory material block 2 is made
As the insulation cladding system of unitary solid structure, the insulation cladding system of this unitary solid structure can be used for aluminium coating electrolysis
The groove end 5.1 of groove 5 or the groove sidepiece 5.2(of aluminium coating electrolysis bath 5 are as depicted in figs. 1 and 2);It is convenient to during in order to use cover
On anode 4, be connected as by bolt 3 on holistic steel beam column plate 1 and heat insulating refractory material block 2 producing simultaneously for
It is enclosed within the through hole on steel pawl on anode, the most i.e. can obtain for covering the insulation cladding system on anode 4 (such as Fig. 1 and Fig. 2
Shown in).After making the insulation cladding system of the present invention, can implement the present invention a kind of aluminium cell produce time insulation and
Anti-oxidation method, directly overlayed by the insulation cladding system of portable, the made of one piece of the present invention on aluminium cell is every
With covering in the position (as depicted in figs. 1 and 2) of the groove end of aluminium cell and groove sidepiece on individual anode, the most i.e. can have
Aluminium cell is incubated and prevents its anode surface from aoxidizing by effect ground.In order to reach preferably to be incubated and oxidation-protective effect,
When being covered on the anode on aluminium cell by insulation cladding system, on anode, first lay the oxidation that a layer thickness is 1~3cm
Aluminium powder layer, covers insulation cladding system on the aluminium oxide bisque on anode the most again;Insulation cladding system is being covered simultaneously
Cover on the anode on aluminium cell and cover when the position of the groove end of aluminium cell and groove sidepiece, covering dress in insulation
Put and be incubated at the gap between cladding system and at gap between insulation cladding system and the anode steel claw being enclosed within and
Alumina powder is all filled at gap between insulation cladding system and aluminium cell.
Claims (2)
1. insulation and anti-oxidation method when an aluminium cell produces, it is characterised in that: use steel beam column plate and thermal insulation fire-resistant
What material block connected composition the insulation cladding system of disassembly and assembly quickly and easily can cover each sun on aluminium cell
Extremely go up and cover in the groove end of aluminium cell and the position of groove sidepiece, the most i.e. can substitute existing by electrolyte block with oxygen
Change the mulch of aluminum mixing, be effectively incubated anode and prevent its surface oxidation;Insulation cladding system is being covered in aluminium electroloysis
Time on anode on groove, on anode, first lay the aluminium oxide bisque that a layer thickness is 1~3cm, the most again insulation is covered dress
Put on the aluminium oxide bisque covered on anode.
Insulation and anti-oxidation method when aluminium cell the most according to claim 1 produces, it is characterised in that: will be incubated
Cladding system covers on the anode on aluminium cell and covers when the position of the groove end of aluminium cell and groove sidepiece,
At gap between insulation cladding system and insulation cladding system and between insulation cladding system and the anode steel claw being enclosed within
Gap at and insulation cladding system and aluminium cell between gap at all fill alumina powder.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110100663.7A CN102747382B (en) | 2011-04-21 | Insulation and anti-oxidation method and insulation cladding system when aluminium cell produces |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110100663.7A CN102747382B (en) | 2011-04-21 | Insulation and anti-oxidation method and insulation cladding system when aluminium cell produces |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102747382A CN102747382A (en) | 2012-10-24 |
CN102747382B true CN102747382B (en) | 2016-12-14 |
Family
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5286359A (en) * | 1991-05-20 | 1994-02-15 | Reynolds Metals Company | Alumina reduction cell |
CN1094764A (en) * | 1993-05-05 | 1994-11-09 | 濉溪铝厂 | The refinery practice of aluminium |
CN101054689A (en) * | 2007-02-13 | 2007-10-17 | 沈阳铝镁设计研究院 | End heat preservation structure for aluminum electrolysis bath |
CN201037154Y (en) * | 2007-05-31 | 2008-03-19 | 中国铝业股份有限公司 | Oxidation resistance anode |
CN201459253U (en) * | 2009-06-24 | 2010-05-12 | 中国铝业股份有限公司 | Device for ensealing anode insulation materials for pre-baked aluminium electrolytic cell |
CN201553785U (en) * | 2009-12-04 | 2010-08-18 | 贵阳铝镁设计研究院 | Aluminum electrolysis bath lateral part heat-insulating structure |
CN202054905U (en) * | 2011-04-21 | 2011-11-30 | 贵阳铝镁设计研究院有限公司 | Heat-preserving and anti-oxidation heat-preserving covering device during aluminum electrolytic-cell production |
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5286359A (en) * | 1991-05-20 | 1994-02-15 | Reynolds Metals Company | Alumina reduction cell |
CN1094764A (en) * | 1993-05-05 | 1994-11-09 | 濉溪铝厂 | The refinery practice of aluminium |
CN101054689A (en) * | 2007-02-13 | 2007-10-17 | 沈阳铝镁设计研究院 | End heat preservation structure for aluminum electrolysis bath |
CN201037154Y (en) * | 2007-05-31 | 2008-03-19 | 中国铝业股份有限公司 | Oxidation resistance anode |
CN201459253U (en) * | 2009-06-24 | 2010-05-12 | 中国铝业股份有限公司 | Device for ensealing anode insulation materials for pre-baked aluminium electrolytic cell |
CN201553785U (en) * | 2009-12-04 | 2010-08-18 | 贵阳铝镁设计研究院 | Aluminum electrolysis bath lateral part heat-insulating structure |
CN202054905U (en) * | 2011-04-21 | 2011-11-30 | 贵阳铝镁设计研究院有限公司 | Heat-preserving and anti-oxidation heat-preserving covering device during aluminum electrolytic-cell production |
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