CN102743989A - Silicon dioxide suspending liquid - Google Patents

Silicon dioxide suspending liquid Download PDF

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Publication number
CN102743989A
CN102743989A CN2012101800999A CN201210180099A CN102743989A CN 102743989 A CN102743989 A CN 102743989A CN 2012101800999 A CN2012101800999 A CN 2012101800999A CN 201210180099 A CN201210180099 A CN 201210180099A CN 102743989 A CN102743989 A CN 102743989A
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CN
China
Prior art keywords
silicon dioxide
suspending liquid
dispersant
silica suspension
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012101800999A
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Chinese (zh)
Inventor
向敏
董文全
袁愈辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU BAIMING HIGH TEMPERATURE CERAMICS CO Ltd
Original Assignee
SUZHOU BAIMING HIGH TEMPERATURE CERAMICS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUZHOU BAIMING HIGH TEMPERATURE CERAMICS CO Ltd filed Critical SUZHOU BAIMING HIGH TEMPERATURE CERAMICS CO Ltd
Priority to CN2012101800999A priority Critical patent/CN102743989A/en
Publication of CN102743989A publication Critical patent/CN102743989A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a silicon dioxide suspending liquid, which comprises the following components by weight: 10-50 parts of silica micropowder, 0.05-0.75 parts of dispersant, 0.05-0.30 parts of xanthan gum and 50-90 parts of water. According to the invention, the silicon dioxide suspending liquid takes silica micropowder as a base, takes sodium polyacrylate or sodium polymethacrylate as a dispersant, and uses the suspension stability of the xanthan gum. The silicon dioxide suspending liquid has the advantages of high solid content and stable storage, and is suitable for a plurality of operation modes such as pumping and spraying, the preparation process is convenient, and the application range of the pH value is wide.

Description

Silica suspension
Technical field
The present invention relates to a kind of suspension, relate in particular to a kind of silica suspension.
Background technology
The aqueous slurry of silica or suspension have been applied to many fields, particularly refractory material, papermaking, concrete industry.The silica suspension that present every profession and trade is used all hopes to have higher solid content, and the suspension of high solids content has higher viscosity usually, causes to use difficulty, and the storage time is restricted the phenomenon that deposition is arranged or flocculate.Silica suspension is mostly again preferably is through strict, complicated production technology for commercial high solids content, storge quality, through multiple dispersant such as organic and inorganic, and strict Acidity of Aikalinity (pH value), the current potential property of holding slurry, manufacturing cost is higher.
Summary of the invention
Deficiency to the prior art existence.Technical problem to be solved by this invention provides a kind of silica suspension, and high solids content, stable storing are suitable for several work modes such as pumping, spraying, and be easy to make.
Silica suspension is made up of following component: silicon powder 10-50 part, dispersant 0.05-0.75 part, xanthans 0.05-0.30 part and water 50-90 part by weight.
Preferably, said silica suspension is made up of following component: silicon powder 30-40 part, dispersant 0.10-0.40 part, xanthans 0.10-0.20 part and water 70-80 part by weight.
Said dispersant is a kind of or its mixture in Sodium Polyacrylate and the sodium polymethacrylate.
Silica suspension of the present invention is the basis with the silicon powder, and said silicon powder is by natural quartz (SiO 2) or vitreous silica (natural quartz is through high-temperature fusion, cooled amorphous state SiO 2) fine silica powder that forms through multiple tracks processes such as broken, ball milling (or vibration, airflow milling), flotation, pickling purification, high purity water processing.Fineness is less than 1 micron account for more than 80%, and average grain diameter is at the 0.1-0.3 micron, and specific area is 20-28m 2/ g.
Using polypropylene acid sodium of the present invention or sodium polymethacrylate are as dispersant.As a kind of new and effective liquefacient, Sodium Polyacrylate or sodium polymethacrylate are applied in the multiple dispersion more and more.The inventor finds, this dispersant, to silicon-dioxide powdery to separate the effect of coagulating remarkable especially, extremely the Sodium Polyacrylate of trace just can play good peptizaiton like 0.05wt%, even and the long-term storage of process the phenomenon of flocculating can not appear.
Xanthans according to the invention is claimed yellow glue, xanthan gum, yellow unit cell polysaccharide again, is a kind of monospore polysaccharide that is produced by false xanthomonas fermentation.Xanthans colloidal sol molecular energy forms the ultra banded spiral EVA that combines, and constitutes the network structure of fragile similar glue, so can support the form of solid particle, drop and bubble, demonstrates very strong stable emulsifying effect and higher suspension ability.In the present invention, mainly utilized this performance of xanthans, carried out suspending stabilized the silicon powder dispersion.
Silica suspension of the present invention can adopt industry conventional method to be prepared from, and for example: earlier dispersant and xanthans are dissolved in the water, add silicon powder again, high-speed stirred is disperseed, and can make silica suspension after old one day.
Among the present invention, less demanding to pH value, in the PH=3-10 broad range, all can be adjusted to stabilising system, look the applied environment of suspension and allocate.
Need to prove that for improving other performances, silica suspension of the present invention can be introduced additives such as antifoaming agent, anticorrisive agent in right amount to improve its corresponding serviceability.
Silica suspension of the present invention, high solids content, stable storing are suitable for several work modes such as pumping, spraying, and easy to make, and the pH value scope of application is wide.
The specific embodiment
Below in conjunction with embodiment the present invention is made further detailed description.
Embodiment 1:
The silica suspension prescription:
Water 240kg;
Silicon powder 160kg;
Sodium Polyacrylate 216g;
Xanthans 320g.
Xanthans and Sodium Polyacrylate are dissolved in the water, add silicon powder again, high-speed stirred evenly can make silica suspension.
Embodiment 2:
The silica suspension prescription:
Water 240kg;
Silicon powder 160kg;
Sodium polymethacrylate 300g;
Xanthans 320g.
Earlier dispersant and xanthans are dissolved in the water, add silicon powder again, high-speed stirred is even, disperses, and can make stable silica suspension after old one day.
Embodiment 3:
Data by the corresponding embodiment 3 of table 1 take by weighing each raw material, adopt embodiment 2 said methods can make stable silica suspension.
Embodiment 4:
Data by the corresponding embodiment 4 of table 1 take by weighing each raw material, adopt embodiment 2 said methods can make stable silica suspension.
Embodiment 5:
Data by the corresponding embodiment 5 of table 1 take by weighing each raw material, adopt embodiment 2 said methods can make stable silica suspension.
Embodiment 6:
Data by the corresponding embodiment 6 of table 1 take by weighing each raw material, adopt embodiment 2 said methods can make stable silica suspension.
Embodiment 7:
Data by the corresponding embodiment 7 of table 1 take by weighing each raw material, adopt embodiment 2 said methods can make stable silica suspension.
Table 1: silica suspension formula table unit: kilogram
? Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7
Water 90 50 80 70 60
Silicon powder 10 50 40 30 40
Sodium Polyacrylate 0.05 0.35 / 0.20 /
Sodium polymethacrylate / 0.40 0.10 0.20 0.15
Xanthans 0.30 0.05 0.10 0.20 0.18
Through testing: the prepared silica suspension of the foregoing description 1-7, flow regime is all good, all can adopt pump to carry, but spraying operation does not have sedimentation, does not have flocculation after storing 60 days.
Said silicon powder, fineness is less than 1 micron account for more than 80%, and average grain diameter is at the 0.1-0.3 micron, and specific area is 20-28m 2/ g.
The above; Be merely the specific embodiment of the present invention; But protection scope of the present invention is not limited thereto; Any those of ordinary skill in the art are in the technical scope that the present invention disclosed, and variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.

Claims (3)

1. silica suspension is characterized in that, is made up of by weight following component: silicon powder 10-50 part, dispersant 0.05-0.75 part, xanthans 0.05-0.30 part and water 50-90 part.
2. silica suspension as claimed in claim 1 is characterized in that, is made up of by weight following component: silicon powder 30-40 part, dispersant 0.10-0.40 part, xanthans 0.10-0.20 part and water 70-80 part.
3. according to claim 1 or claim 2 silica suspension, it is characterized in that: said dispersant is a kind of or its mixture in Sodium Polyacrylate and the sodium polymethacrylate.
CN2012101800999A 2012-06-04 2012-06-04 Silicon dioxide suspending liquid Pending CN102743989A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012101800999A CN102743989A (en) 2012-06-04 2012-06-04 Silicon dioxide suspending liquid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012101800999A CN102743989A (en) 2012-06-04 2012-06-04 Silicon dioxide suspending liquid

Publications (1)

Publication Number Publication Date
CN102743989A true CN102743989A (en) 2012-10-24

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CN2012101800999A Pending CN102743989A (en) 2012-06-04 2012-06-04 Silicon dioxide suspending liquid

Country Status (1)

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CN (1) CN102743989A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104190280A (en) * 2014-09-05 2014-12-10 无锡贺邦金属制品有限公司 Silicon suspension and preparation method thereof
CN108773916A (en) * 2018-05-25 2018-11-09 苏州佑君环境科技有限公司 A kind of water quality monitoring sensor scale remover

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1042554A (en) * 1988-11-08 1990-05-30 罗纳·布朗克化学公司 The stable aqueous suspension of precipitated silica
CN101746765A (en) * 2008-12-01 2010-06-23 贵州海天铁合金磨料有限责任公司 Method and device for separating and purifying silicon dioxide micropowder from electric furnace dust
WO2010136190A1 (en) * 2009-05-29 2010-12-02 Esk Ceramics Gmbh & Co. Kg Suspension for producing a layer increasing the coefficient of friction, molded part having such a layer increasing the coefficient of friction, method for the production thereof, and use thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1042554A (en) * 1988-11-08 1990-05-30 罗纳·布朗克化学公司 The stable aqueous suspension of precipitated silica
CN101746765A (en) * 2008-12-01 2010-06-23 贵州海天铁合金磨料有限责任公司 Method and device for separating and purifying silicon dioxide micropowder from electric furnace dust
WO2010136190A1 (en) * 2009-05-29 2010-12-02 Esk Ceramics Gmbh & Co. Kg Suspension for producing a layer increasing the coefficient of friction, molded part having such a layer increasing the coefficient of friction, method for the production thereof, and use thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘阳等: "表面活性剂在陶瓷料浆中的应用", 《中国陶瓷》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104190280A (en) * 2014-09-05 2014-12-10 无锡贺邦金属制品有限公司 Silicon suspension and preparation method thereof
CN108773916A (en) * 2018-05-25 2018-11-09 苏州佑君环境科技有限公司 A kind of water quality monitoring sensor scale remover

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Application publication date: 20121024