CN102741386A - Improvements relating to fabric treatment compositions - Google Patents
Improvements relating to fabric treatment compositions Download PDFInfo
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- CN102741386A CN102741386A CN2008801185972A CN200880118597A CN102741386A CN 102741386 A CN102741386 A CN 102741386A CN 2008801185972 A CN2008801185972 A CN 2008801185972A CN 200880118597 A CN200880118597 A CN 200880118597A CN 102741386 A CN102741386 A CN 102741386A
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- treatment composition
- fabric treatment
- probiotic agent
- agent
- probiotic
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/381—Microorganisms
Abstract
A fabric treatment composition for use in a laundering process comprises at least one or mixture of surfactants selected from anionic surfactant, nonionic surfactant, and cationic surfactant, a probiotic microorganism, and a deposition aid, which results in the deposition of the probiotic onto fabric during a laundry treatment process.
Description
Technical field
The present invention relates to fabric treatment composition, especially, relate to fabric treatment composition, it comprises so-called ' probiotic agent (probiotic) ' particle.
Background
The notion of probiotic agent it is believed that it is to develop from the hypothesis that Nobel laureate's Russian scientist Metchnikoff (Metchnikoff) proposes, and Metchnikoff supposes that Bulgarian peasant's long healthy life is because they use fermented-milk products.It is believed that when using, fermentation bacillus (lactobacillus spp (Lactobacillus)) influences the micro-flora (microflora) of colon energetically, reduces toxic microbial activities.
This intestines micro-flora constitutes the active microbial environment of metabolism, and by low relatively multifarious genus domination, its part as relatively stable group in the intestines of healthy individuals exists.
Based on WHO and FAO (FAO/WHO 2002) and ILSI Europe working group guide about probiotic agent; Probiotic agent can be defined as: " mikrobe that lives; it can give the functional or benefit that keeps healthy of a kind of or more kinds of proof especially except that basic nutrition for the human consumer being absorbed with liberal quantity or part when applying ".
Wherein, the mikrobe in people's enteron aisle is lactobacillus genus and the genus bifidobacterium (Bifidobacterium) that Gram-positive produces lactic acid.Most of probiotic agent are from lactobacillus spp and genus bifidobacterium, and have been selected, because they have the ability that holds out against the stomach transportation and adhere to intestinal epithelial cells.
These strains can occupy (colonise) intestines instantaneously, give some health care benefit through being integrated into existing micro-flora and it is believed that to the human consumer.In recent years, the consumption of " probiotic agent " improves significantly.
Intestines are not berth unique parts of mikrobe of human body.Human skin has (resident), the instantaneous and temporary transient stop micro-flora of stop.The mikrobe that stops is in running balance with host tissue, and micro-flora can be considered to the integration component (integral component) of normal human skin.The great majority of these mikrobes are Gram-positives, and rest on the skin surface and in folliculus.
The host has various structures, molecule and mechanism, and its restriction instantaneous and temporary transient stop thing (resident) and control stop the colony and the dominance (dominance) of thing group.These comprise various forms of local skin structures, hydration, nutrient substance and suppressor factor.The microbiota that stops ties up to be occupied niche to get into the transition state aspect with refusal is useful, and it possibly be deleterious and communicable.And stopping thing is important in changing immunity system.
Prior art
EP 110550 proposes to use probiotic agent to be used to regulate the skin micro-flora.These can directly be applied to skin with the form of lotion or shampoo.
WO 02/028402A1 disclose the use probiotic lactobacillus be used for balancing skin under stress condition (for example uv-radiation) immunologic function with reduce skin and under such condition, produce the tendency of anaphylaxis.The carrier system of probiotic agent is food, medicament prodn or the cosmetic product that is used for oral or topical application.
WO 06/000992A1 discloses make-up composition, and it can be used to prevent and/or treat responsive and/or dry skin, handle through combine at least a divalence inorganic cation with pre-biotic microorganism.
WO 05/089560A1 discloses the product based on water and milk, and it comprises pre-biotic microorganism, and it is stable after the storage down at 10 ℃, and its carbohydrate containing metabolite not.Product is used to picked-up, and wherein they are of value to the intestines micro-flora.
WO2005080539 discloses a kind of method and has been used to prepare stain remover and is used for clean textile, and wherein probiotic agent is introduced in the working method.Then, these microorganisms are removed enzyme and other activess of stain, so that after cleaning process, reduce the influence of stain remover to environment.
Prior art does not all have hint in fabric treatment composition, to use the probiotic agent particle, and like the fabric cleaning products, wherein the pre-biotic microorganism particle can utilize deposition aid to be deposited on the fabric carrier during washing methods such as purging method.
BRIEF SUMMARY OF THE INVENTIONA is described
We have confirmed that now the probiotic agent particle can be introduced in the fabric treatment composition, and are delivered on the fabric through the washing application.With after skin closely contacts, it is believed that these probiotic agent particles can be transferred on the skin from fabric, possibly give benefit recited above.
The invention definition
In first aspect, the invention provides the fabric treatment composition that is used for washing methods (laundary process), it contains:
A) tensio-active agent, it is selected from AS, nonionogenic tenside, cats product and its mixture;
B) probiotic agent particle; With
C) deposition aid.
In second aspect of the present invention, a kind of method of probiotic agent particle on textile article that deposit is provided, it comprises the following steps:
Utilization is handled textile article according to the cleaning composition of first aspect present invention.
Further, the invention provides and comprise probiotic agent particulate textile article, it is that treatment process through second aspect present invention obtains.
Detailed description of the invention
The probiotic agent particle
In order to reach the purpose of this patent, the probiotic agent that uses among this paper is defined according to genus and kind usually, and possibly also comprise strain.Use common abbreviation, lactic acid Bacillus bifidus (Bifidobacterium lactis) Bb-12 for example, it can be abbreviated as B.lactis Bb-12; And bifidobacterium (Bifidobacterium bifidus) Bb-12, it can be abbreviated as B.bifidumBb-12.
The pre-biotic microorganism particle can have vigor (living) form, inactivated form or dead form to use.These mikrobes can be used in any stage of its life cycle (for example spore or vegetative cell state), existed or do not exist to promote metabolism or keep the static material when needing of metabolism.
Colony forming unit as known in the art (cfu) is meant when measuring through the counting of microbiology on agar plate, the number of bacterial cell.
The level that typically is included in the probiotic agent in the present composition is counted 0.003～0.5wt% with the gross weight of compsn, preferred 0.005～0.05wt%, most preferably 0.005～0.025wt%.
Be generally used for the present invention especially suitable probiotic agent be selected from ascomycetes such as yeast belong (Saccharomyces), inferior sieve yeast belong (Yarrowia), Ke Lufeishi yeast belong (Kluyveromyces), spore torulopsis (Torulaspora) is arranged, schizosaccharomyces pombe (Schizosaccharomyces pombe), Debaryomyces (Debaromyces), Candida (Candida), pichia belong to (Pichia), aspergillus (Aspergillus) and penicillium (Penicillium), the bacterium of genus bifidobacterium (Bifidobacterium), lopsided Pseudomonas (Bacteroides), fusobacterium (Fusobacterium), honeybee Coccus (Melissococcus), Propioibacterium, faecalis (Enterococcus), lactococcus spp (Lactococcus), Staphylococcus (Staphylococcus), Peptostrepococcus, Bacillaceae (Bacillus), Mycosphaerella (Pediococcus), micrococcus sp (Micrococcus), Leuconostoc (Leuconostoc), Weissella, Aerococcus (Aerococcus), lactococcus spp (Oenococcus) and lactobacillus (Lactobacillus) and its mixture.
The more specifically instance that is applicable to pre-biotic microorganism of the present invention is bifidobacterium adolescentis (Bifidobacterium adolescentis), bifidobacterium viable bacteria (Bifidobacteriumbifidum), bifidobacterium infantis (Bifidobacterium infantis), lactic acid Bacillus bifidus (Bifidobacterium lactis), bifidus longum bb (Bifidobacterium longum), Lactobacterium acidophilum (Lactobacillus acidophilus), nutrition probiotic lactobacillus (Lactobacillusalimentarius), lactobacterium casei (Lactobacillus casei) subspecies Casei, lactobacterium casei Shirota, lactobacillus paracasei (Lactobacillus paracasei), lactobacillus curvatus (Lactobacillus curvatus), lactobacillus delbruckii lactic acid subspecies (Lactobacillus delbruckiisubsp.Lactis), Lactobacillus gasseri (Lactobacillus gasseri), lactobacillus johnsonii (Lactobacillus johnsonii), lactobacillus reuteri (Lactobacillus reuteri), lactobacillus rhamnosus (Lactobacillus rhamnosus) (Lactobacillus rhamnosus GG), lactobacillus sake (Lactobacillus sake), lactobacillus lactis bacteria (Lactococcus lactis), thermophilus streptococcus (Streptococcus thermophilus), meat suis (Straphylococcus carnosus) and wood sugar suis (Staphylococcus xylosus) and its mixture.
Preferred species are lactobacillus johnsonii, lactobacillus paracasei, bifidobacterium adolescentis, bifidus longum bb and lactic acid Bacillus bifidus NCC 2818 (also being called as (Bb 12) (ATCC27536)); It contains in Institute Pasteur (28 rue du Docteur Roux according to budapest treaty respectively; F-75024 Paris Cedex 15); Name in 30/06/92,12/01/99,15/04/99 and 10/06/2005:CNCM I-1225, CNCM I-2116, CNCM I-2168, CNCM I-2170 and CNCM I-3446 preservation with following respectively, and bifidus longum bb belongs to (BB536).Lactic acid Bacillus bifidus (CNCM I-3446) strain can (P.O.Box 407 for Chr.Hansen A/S, 10-12Boege AlIe, and DK-2970Hoersholm Denmark) obtains from Hansen.
Mikrobe must be able to hold out against the pH condition (typically pH512) in the cleaning composition of the present invention, and the environmental temperature fluctuation (comprising the freeze thawing temperature) that compsn is experienced when storing has good resistance.For the application's purpose, the meaning of " freeze thawing " temperature is that wherein temperature can descend (typically night) to less than 5 ℃, then rises in the daytime for example above 20 ℃ in family and commercial environment those temperature that memory period typically experiences in the two.Such fluctuation is in colder weather and is common in winter.In warm climate, probiotic agent should to higher surrounding temperature and typical case wherein fluctuation for example 20 to 40 ℃ resistance is arranged.
According to the present invention, the probiotic agent biomass can be refrigerated, dry powder, perhaps wet when fermention medium separates (for example from).Introduce preparation biomass can after the dosage after constituting preparation, through with a kind of component oil phase mixed together for example, perhaps be added through before adding active material, being dispersed in aqueous phase.For the stain remover powder composition, in adding compsn to before, biomass can be the particle form with protectiveness wax.
Probiotics
Probiotics is a kind of or more kinds of bacterial growth of selective stimulating and/or active material.Most of possible probioticss are sugar (monose and disaccharides) and glucide (for example oligosaccharides), but the also known probiotics that other types are arranged.
The hypertrophy of probiotic agent is not expected itself in the present composition, because this possibly cause the reduction of product property.Known in the art static with the maintenance microorganism active with lower concentration use disinfectant.This restraining effect to microorganism growth can be removed after the product dilution.The instance that is used for suitable disinfectant of the present invention comprises Proxel (1, the 2-benzisothiazole-3-ketone), for example can be from Univar, and Avecia and Uniqema obtains; And Kathon CG (methylchloroisothiazandnone and methylisothiazolinone), can obtain from Rhom and Haas.
In the further known washing cleansing composition, the tensio-active agent of high density and the high pH condition inhibition microorganism growth that can play a role.
Deposition aid
Mikrobe deposits in the basic unit (substrate) and can accomplish through any suitable route from detergent compositions of the present invention.
For example, through filtration the time, probiotic agent particulate granularity is so so that particle is trapped between the fiber of fabric.Pore size is suitable between the size of filtration mechanism requirement particle or population and yarn.
Granularity typically is in the 1-30 micrometer range.Bigger particle begins by naked eyes visible, and smaller particles trends towards when cleaning, being removed.Approximately the particle of 5-15 micron is that eyes are invisible and show well through filter deposition to fabric.
Mikrobe also possibly pass through filtration method, pass through the polymer builder deposition from detergent compositions deposition of the present invention, accomplishes or enhancing when sending or after sending.
The polymkeric substance that is suitable for deposited particles is disclosed in WO9709406, and wherein high MW polyoxyethylene (PEO) is used for washing sedimentary clay particle in (main wash) the master; EP0299575B1 and WO9527037, gather ethyleneimine and are used for sedimentary clay particle in main washing wherein high MW PEO, polyacrylic ester, SEPIGEL 305, Z 150PH; EP0387426B1 (P&G), it utilizes similar polymkeric substance and guar gum tabulation.
WO 01/07546A1 discloses suitable rinse stage polymer deposition auxiliary agent and has been used for emulsion droplet and comprises cationic guar gum polymkeric substance, cationic polyacrylamide, cationic potato starch and cationic cellulose derivative.
The suitable instance of cationic polymers comprises for example Jaguar (ex Rhone Poulenc), cationic cellulose derivative Celquats (ex NationalStarch), Flocaid (ex National Starch), cationic potato starch SoftGel (exAralose), cationic polyacrylamide PCG (ex Allied Colloids) for example for example for example of cationic guar gum polymkeric substance.Low charge density cationic polymers auxiliary agent is preferred, and compsn wherein of the present invention is the stain remover that contains AS.Suitable low charge density positively charged ion comprises modified potato starch SoftgelBDA and Softgel BDA CS series (ex Avebe).
Suitable nonionic deposition aid comprises HMW PEO WSRN 750 (ex UnionCarbide).
The sedimentary size range of polymer builder is preferably between the 0.5-30 micron, more preferably between the 1-20 micron.
Be used to deposit probiotic agent particulate preferred method; Method especially for use the deposition probiotic agent from main washing is the target polymer deposition; Be to use disclosed polysaccharide conjugation techniques in WO 99/36469, WO2004/056890A1, WO2005/21186A1; Wherein use water-soluble or water can disperse polysaccharide conjugates in main washing method process with deposition of benefit agent to fabric, wherein said polysaccharide conjugates comprises main polymer chain and is attached to the beneficial agent group on the main polymer chain through the hydrolysis-stable key.Similarly, US6773811B2 has described and has had the particle that adheres to the cellulose polysaccharide on it (Mierocrystalline cellulose monoacetate-CMA); EP1117756B1 requires protection β 1-4 to connect polysaccharide (LBG, wood sugar glucose etc.), and it has some beneficial agents that adhere to.In the present invention, the probiotic agent particle can arrive this type polysaccharide main chain through the key Chemical bond of hydrolysis-stable.
This is used for the main polysaccharide conjugation methods of washing and has the advantage of target basic unit, so that the pre-biotic microorganism that has only polymkeric substance to adhere to deposits on the fabric rather than unwanted greasy dirt particle.
For the polysaccharide conjugation methods, preferred biomass size range between the 1-15 micron, preferred 1～5 micron.This method need be on probiotic agent depositing nano size PVAC polymer shell, between particle and polymkeric substance, to form chemical bond.
The classification of another deposition aid polymkeric substance is the polymkeric substance that comprises phthalic ester.The advantage that these polymkeric substance have is that they are substantial (substantive) for the polyester type material.They are based on the polymkeric substance that can derive from dicarboxyl acid and polyvalent alcohol; The polymkeric substance that particularly comprises phthalic ester; More preferably, comprise the unitary polymkeric substance that derives from (gathering) terepthaloyl moietie (PEG) and (gathering) ethylene glycol terephthalate (PET) or polyoxyethylene terephthalate (POET).Most preferably, polymkeric substance is selected from the group that comprises PET/POET, PEG/POET, PET/PEG and phthalic ester/glycerine/ethylene glycol polymer.
This type material can extensively obtain for the washing composition tDesigners, because they are usually as soil release agent polymkeric substance (soil-release polymers).
Any polymkeric substance soil release agent well known by persons skilled in the art may be used to according to compsn of the present invention.The polymkeric substance soil release agent is characterised in that to have and makes the hydrophilic hydrophilic section of the hydrophobic surface for example polyester and the nylon of fiber; And hydrophobic section is to be deposited on the hydrophobic fiber; And accomplish to clean with rinse cycle after adhere to above that, so as the fixer (anchor) of hydrophilic section.This is generally used for being implemented in soil release agent handles painted can easierly in follow-up wash procedure, being removed that the back takes place.
The polymer deposition auxiliary agent that can be used for this paper comprises having a kind of or more kinds of those soil release agents that contain the nonionic hydrophilic component of ethylene oxide, T 46155, propylene oxide or polyoxypropylene section especially, and a kind of or more kinds of hydrophobic components that contains the terephthalate section.Typically, the oxyalkylene section of these deposition aids has 1 to about 400 the polymerization degree, though higher level can be used, preferred 100 to about 350, and more preferably 200 to about 300.
One type of preferred deposition aid is to have ethylene glycol terephthalate and the polyoxyethylene terephthalate multipolymer of block at random.The preferred molecular weight of this base polymer deposition aid is in the scope of the about 55kD of about 5kD-.
Another preferred polymer deposition auxiliary agent is the polyester with the unitary repeating unit of ethylene glycol terephthalate; It comprises the polyoxyethylene terephthalate units of the ethylene glycol terephthalate unit of 10-15wt% together with 90-80wt%, is derived from the polyoxyethylene glycol of molecular-weight average 0.2kD-40kD.The instance of this base polymer comprises commercially available material ZELCON 5126 (from DuPont) that gets and MILEASE T (from ICI).The instance of relevant polymkeric substance can be found among the US4702857.
Another preferred polymer deposition auxiliary agent is the sulfonated products of linear ester oligomer basically, and it comprises the oligomer ester main chain and the terminal portions that is covalently attached to main chain of terephthaloyl and oxyalkylene oxygen base (oxyalkyleneoxy) repeating unit.These soil release agents fully are described among the US 4968451.Other polymkeric substance soil release agents that are fit to comprise the terephthalate polyester of US 4711730, and the negatively charged ion end of US4721580 adds the block polyester oligomer compound of cap oligomer ester and US 4702857.
Preferred polymer deposition auxiliary agent also comprises the soil release agent of US4877896, and it discloses negatively charged ion, and particularly sulfo group aroyl (sulfoarolyl), end add the cap terephthalate.
Another preferred deposition aid is to have terephthaloyl unit sulfo group, different terephthaloyl unit, oxygen vinyloxy group (oxyethyleneoxy) and Oxy-1, the oligomer of the repeating unit of 2-propylene units.Repeating unit forms the main chain of oligomer, and preferably stops with modification isethionate end cap.Such preferred especially deposition aid comprises the about different phenyl-diformyl base of a sulfo group unit, 5 terephthaloyl unit, oxygen vinyloxy group and Oxy-1s; The end cap unit of 2-propenyloxy group unit (ratio is 1.7-about 1.8) and two 2-(2-hydroxyl-oxethyl)-ethyl sulfonic acid sodium.Said soil release agent comprises that also the oligomer of the about 20wt% of about 0.5wt%-, crystallization reduce stablizer, are preferably selected from xylenesulfonate, cumene sulfonate, tosylate and its mixture.
Polysaccharide and PET/POET conjugation methods can make up.If the PET/POET polymkeric substance is used for conjugation methods, then the probiotic agent particle can become to polyester and polyester cotton (polycotton) more important (substantive).
The probiotic agent particle of encapsulation
The probiotic agent particle can be protected through any suitable encapsulation (encapsulation) technology in compsn.A preferable methods is included as the probiotic agent particle and coats (coating) polymkeric substance; Wherein the water-soluble of polymeric film can be regulated by the level according to tensio-active agent, and be described like US 20040065578 (A1) and WO2006007911 (A1) (the two all authorizes Unilever).This allows through in cleaning or rinsing, diluting dissolving films, so that unsheltered (bare) probiotic agent is deposited in the basic unit.
The instance of these polymkeric substance comprises the hydrophobically modified polyvalent alcohol, and wherein solubleness can be modified, and is absorbed in the level of its lip-deep tensio-active agent through adjusting.This has realized a kind of delivery system of design, wherein can be absorbed in the tensio-active agent level on the film surface through regulating to reduce especially, triggers the promoting agent that discharges this type thin-film package.
Found further that the lip-deep tensio-active agent level be absorbed in the polymeric film that comprises the hydrophobically modified polyvalent alcohol can be lowered, through the dilution table surface-active agent concentration in the environment and/or through improving temperature around.This realization can be controlled in cleaning or in rinsing and discharge unsheltered probiotic agent particle from the compsn packing forms, depends on the type of polymeric film.
Have been found that through utilizing the modification group for example to utilize for example PVOH film of or more acetal groups hydrophobically modified soluble polymeric films; Film is kept perfectly when having external surfactants basically; For example cracked in the rinse cycle process of washing operation for example in the clean cycle process of washing operation, and when surfactant concentration fully reduces.
Polymeric film comprises the main polymer chain derived from water-soluble polymers usually.
The main polymer chain that polymeric film comprises is derived from such polymkeric substance, and this polymkeric substance preferably can be with 0.3g.dm under 20 ℃
-3Or bigger level, more preferably 0.5g.dm
-3Or dissolving of bigger level or dispersion.
Polymeric film comprises the PVOH of the polyvalent alcohol of hydrophobically modified, particularly hydrophobically modified usually.
Being used for polymeric film of the present invention is such material, and its solubleness in water depends on existing surfactant concentrations.Usually, surfactant concentrations is low more, and then the solubleness of polymeric film is big more, and its by broken (break down) must be fast more.
Do not hope to be subject to theory, it is believed that hydrophobic ingredient and the tensio-active agent in the polymeric film reacts to form gel network, this gel network makes that the film of mating surface promoting agent is insoluble; Yet the interaction between polymeric film and the tensio-active agent is broken when delivery system dilution and/or heating, and then makes polymeric film can dissolve and discharge the probiotic agent particle.
According to the preferred method from package release probiotic agent of the present invention, comprise the heating delivery system.This method is useful especially in active agent delivery, when particularly sending active cosmetic agent and pharmaceutically active agents to human body.In these were used, the raising of temperature may trigger the release of probiotic agent particulate when delivery system contacts with human body.
Usually, when being suspended in the water phase surfactant mixture that exists in the delivery system, the probiotic agent particle will discharge soon from the polymeric film package in the time of in being suspended in deionized water.In preferred embodiments, in water, probiotic agent from polymeric film discharge needed time ratio delivery system in the existing water phase surfactant mixture the needed time want much shorter.In the time of 20 ℃, the needed time possibly be concentration 5g.dm in water
-3Water phase surfactant mixture in the required time be lower than 1/3rd, particularly be lower than 1/7th.
When using deriveding group that polyvalent alcohol is derived, obtain the hydrophobically modified polyvalent alcohol.This polyvalent alcohol is by the deriveding group hydrophobically modified.
Preferred deriveding group comprises those based on those of precursor group, and it is selected from acetal, ketal, ester, fluorinated organic compounds, ether, alkane, alkene, aromatic substance.Preferred especially precursor group is for example butyraldehyde, octanal, dodecyl aldehyde, 2-ethyl hexanal, hexanaphthene carboxyl aldehyde, itral and a 4-amino butyraldehyde dimethylacetal of aldehyde, though obvious easily to those skilled in the art other the suitable precursor group with necessary ClogP also is applicable to polymeric film of the present invention.
Preferred especially deriveding group is an acetal, and it can derive from aldehyde or their function equivalent (for example dimethyl--or diethyl acetal).
Preferred hydrophobically modified polyvalent alcohol is through the acetal groups hydrophobically modified, and those that particularly have 4 to 22 carbon atoms and aromatic group especially be benzaldehyde derivative for example.Utilize the aromatic aldehyde hydrophobic modification delivery polymer film (have outstanding interact) that come to light, cause better moving delivery system with tensio-active agent.Substituted phenyl aldehyde for example 2-phenyl aldehyde sulfonic acid also can be used with its salt.
On main polymer chain, can there be other modification groups.For example, amine can be preferably involved as the modification group, because this makes the variation reply pH for example and/or ionic strength, polymkeric substance is more solvable.
Deriveding group can comprise hydrocarbyl chain.Such hydrocarbyl chain can be randomly by for example oxygen or the nitrogen replacement of a kind of or more kinds of heteroatoms.
Be incorporated into the alkyl chain length preferably 3 to 22 of the deriveding group of main polymer chain, more preferably 4 to 18, be more preferably 4 to 15, most preferably 4 to 10, for example 4 to 8.It is undesirable being shorter than 3 alkyl chain length because in using, gel-like structure that polymeric film and Surfactants at Interface form usually too a little less than and make polymeric film break too easily.
Alkyl chain length greater than 22 is undesirable, because obtain the insufficient or not reaction of reaction of the fertile material and the main polymer chain of deriveding group from it.
It is preferred 3 to 22 to obtain the alkyl chain length of fertile material of deriveding group from it, and more preferably 4 to 18.
In this respect, the carbon number in the hydrocarbyl group comprises all carbon of intrachain that are incorporated into other functional groups in the derived material.For example, butyraldehyde has 4 alkyl chain length.
Derived material preferably is present in the polymkeric substance, and level is for calculating by weight 0.1 to 40%, based on the gross weight of polymkeric substance, and more preferably 2 to 30%, most preferably 5 to 15%, for example 8 to 12%.
At main polymer chain during based on PVOH; Derived material preferably exists with such level, and it makes that deriveding group and the right number ratio of free hydroxyl group are 1: 3 to 1: 30 on the main chain, more preferably 1: 4 to 1: 20; Most preferably 1: 7 to 1: 15, for example 1: 8 to 1: 13.
Ratio is lower than 1: 30, then the solubleness of polymeric film tend to too big, even when having tensio-active agent.Ratio surpasses 1: 3, then the solubleness of polymeric film tend to too low, even when not having tensio-active agent.
Comprise for example PVOH of water soluble resin from its preferred polymers that forms derived polymers film main chain of the present invention; Ether of cellulose; Polyethylene oxide (hereinafter to be referred as " PEO "); Starch; Vinylpyrrolidone polymer (hereinafter to be referred as " PVP "); SEPIGEL 305; The polyvinyl methyl ether toxilic anhydride; Poly-maleic anhydride; SMA styrene maleic anhydride; Natvosol; Methylcellulose gum; Polyoxyethylene glycol; CMC 99.5; Polyacrylate; Alginate; Acrylamide copolymer; Guar gum; Casein; Ethene-toxilic anhydride resin series; Polymine; Type 3U; Ethylmethylcellulose; Hydroxyethylmethyl-cellulose.Water miscible PVOH film-forming resin is preferred especially.
Usually, preferred water miscible PVOH base film-forming polymer should have low relatively molecular-weight average and high-caliber hydrolytic action.The polymkeric substance based on PVOH that is preferred for this paper has 1,000 to 300,000 molecular-weight average, and is preferred 2,000 to 100,000, and most preferably 2,000 to 75,000.The level of hydrolytic action be defined as by hydroxyl ,-the substituted resin of OH group (PVOH stems from through hydrolytic action and gathers (vinyl acetate)) on the reaction Percent Complete of acetate group.The hydrolytic action scope of 60-99% is preferred, and preferred hydrolytic action scope is about 88-99%.When being used for the application, term " PVOH " comprises and gathers (vinyl acetate) compound that its hydrolytic action level is disclosed herein.
Being used for preferred especially polymkeric substance/polyvalent alcohol of the present invention is expressed from the next:
Wherein, the mean number ratio of z and x in 1: 200 to 1: 6 scope, more preferably 1: 100 to 1: 8; Most preferably 1: 50 to 1: 12; For example 1: 30 to 1: 14, y was the acetic ester of participating in after the parent compound hydrolytic action, and its preferable range is 1-20%; More preferably 1-10%, most preferably 1-5% and R are alkyl, thiazolinyl or the aromatic yl groups with 3 to 22 carbon atoms.More preferably R is alkyl or the aromatic yl group with 3 to 6 carbon atoms.
According to aforementioned patent US 20040065578 (A1) and WO2006007911 (A1) (all authorizing Unilever), can give structural strength for polymeric film.
The PVP film shows for the outstanding of various surfaces and adheres to, and comprises glass, metal and plastics.Unmodified Vinylpyrrolidone polymer film is suitably suction.Dried Vinylpyrrolidone polymer film has 1.25g.cm
-3Density, 1.53 specific refractory power.Tackiness during higher levels of humidity can minimize in the Vinylpyrrolidone polymer film through mixing the insensitive properties-correcting agent of suitable water, for example 10% aryl sulfonamide formaldehyde resin.
Be used for suitable softening agent based on the film of PVP and can be being selected from following a kind of or more kinds of: SULPHOSUCCINIC ACID ESTER is three (2-ethylhexyl) SULPHOSUCCINIC ACID ESTER, isopropyl phosphoric acid diphenyl ester, three butoxyethyl group SULPHOSUCCINIC ACID ESTERs for example; Polyvalent alcohol is glycerine, Sorbitol Powder, glycol ether diperlargonate, polyethylene glycol di2-ethylhexoate, dibutyl tartrate for example; Polyol ester for example hydroxyl polycaprolactone, hydroxyl gather the L-rac-Lactide; Rudimentary phthalic ester is dimethyl phthalate, diethyl phthalate, Witcizer 300 for example; With sulphonamide for example toluol sulfonamide, N-ethyltoluene sulphonamide.
Preferred water miscible film can also for example roll, casts, extrudes, reach other traditional methods through the mold technology of standard from the PEO resins.The polyethylene oxide film can be limpid or opaque and intrinsic flexible, tough and tensile and most oils and grease had resistance.These polyethylene oxide resin films provide than the better solubleness of other water-soluble plastics, and do not sacrifice intensity or toughness.Outstanding flat folding, viscosity and the sealability ability of water miscible polyethylene oxide film make it have the characteristic of good mechanically operable.
Be used for suitable softening agent based on the film of PEO and can be being selected from following a kind of or more kinds of: SULPHOSUCCINIC ACID ESTER is three (2-ethylhexyl) SULPHOSUCCINIC ACID ESTER, isopropyl phosphoric acid diphenyl ester, three butoxyethyl group SULPHOSUCCINIC ACID ESTERs for example; Polyvalent alcohol is glycerine, Sorbitol Powder, glycol ether diperlargonate, polyethylene glycol di2-ethylhexoate, dibutyl tartrate for example; Rudimentary phthalic ester is dimethyl phthalate, diethyl phthalate, Witcizer 300 for example; With sulfanilamide (SN) for example toluene sulfanilamide (SN), N-ethyltoluene sulfanilamide (SN).
Except the tensio-active agent that exhausts absorption, can also adopt and trigger the agent source.Suitable examples comprises that those that be described in WO02/102956 (A1) for example are used to cause the source/material of pH, temperature, electrolytic condition, light, time or molecule structure change.Such triggering agent can be made up use each other and for example sheared triggering and release, and wherein film moves at health and is destroyed down so that exposed probiotic agent is exposed to skin.
The probiotic agent of preparation encapsulation
The solution of PVOH in water through following preparation 10wt%: with in 100gPVOH (Mowiol20-98, trade mark, ex Kuraray Specialities) and the 900g deionized water adding flask and be heated to 70 ℃.In this, add 10ml hydrochloric acid (36% aqueous solution) with catalyzed reaction, and add butyraldehyde subsequently.Subsequently, in inert atmosphere, stirred the mixture 5 minutes, afterwards, stop heating and further at room temperature continue stirring 20 hours at 70 ℃.Subsequently, using sodium hydroxide solution that reaction mixture is transferred to pH is 7.
Resulting solution is precipitated in acetone generating acetalation (acetalised) PVOH polymkeric substance, and with acetone (500ml) with follow and clean repeatedly by water (50ml).Subsequently in 70 ℃ of following dried overnight of vacuum to generate white polymer.
The degree of acetalation is 10.4% through analysis.(vinyl alcohol)-butyral (PVA-BA) resin that gathers that will as above prepare with deionized water is diluted to 7%m/m solution, and passes through to stir suspension 5mg probiotic agent powder (polymkeric substance-probiotic agent stock solution) to it.
From the detergent compositions that the nozzle container dropwise joins stock solution the table 1 to be limited, utilize three paddle stirrer agitated liquid simultaneously.The existence of tensio-active agent causes polymeric film to be deposited in around the probiotic agent particle.Can assemble particle diameter with the probiotic agent of controlling package that flows through agitation strength and jet size.
For the stain remover power applications, stock solution can be sprayed on the basic powder bed and carry out drying.
Fabric treatment composition
Fabric treatment composition of the present invention is applicable to washing methods.Instance comprises infusion product and the main product of washing.Compsn of the present invention is laundry composition preferably, especially main (fabric cleaning) compsn of washing.
Compsn of the present invention can present any profile for example solid such as powder or particle, tablet, solid bar, cream, gel or liquid, particularly based on aqueous liquid, spraying, bar (stick), dipping matrix, foam or mousse.Especially, compsn can be liquid, powder or tablet cleaning composition.
Liquid product of the present invention can have the pH in from 5 to 12 scopes.This pH scope preferably still keeps stable through the storage time of this product.
Activeconstituents in the compsn is tensio-active agent preferably.Can comprise and surpass a kind of activeconstituents.For some application; Can use the mixture of activeconstituents; For example main cleaning composition can also comprise fabric softener; Detergent compositions of the present invention can comprise surface active cpd (tensio-active agent), and it is selected from soap, non-soap anionic, positively charged ion, nonionic, both sexes and zwitter-ion surface active cpd and its mixture.Can utilize many suitable surface active cpds and fully be described in the document, for example by Schwarts, Perry and Berch is at " Surface-Active Agents and Detergents ", Volume I and II.
Compsn can also comprise lipid acid for example C8 to C24 alkyl or thiazolinyl monocarboxylic acid or its polymkeric substance.Preferred fatty acid is non-saponified, and more preferably lipid acid is free, for example oleic acid, LAURIC ACID 99 MIN or tallow fatty acid.The level of fatty acid material is preferably more than 0.1wt%, more preferably more than 0.2wt%.
It can also comprise that some can be used to the monoalkyl cationic surfactant of the main cleaning composition of fabric.Operable cats product comprises general formula R 1R2R3R4N
+X
-Quaternary ammonium salt; Wherein the R group is long or short hydrocarbon chain; Typically be that alkyl, hydroxyalkyl or ethoxylated alkyl and X are that (for example R1 is the C8-C22 alkyl to gegenion; Preferred C8-C10 or C12-C14 alkyl, R2 is that methyl and R3 can be the compounds of methyl or hydroxyethyl groups with R4 identical or differently); And cationic ester (for example cholinesterase).
The selection of surface active cpd (tensio-active agent) and existing amount will depend on the purposes of desired detergent compositions.Know as skilled formulator, in fabric cleaning composition, can select the different surface active agents system to be used to hand-wash product and be used to dissimilar washing machines employed products.
Compsn of the present invention can comprise linear alkylbenzene sulfonate, particularly has the linear alkylbenzene sulfonate of C8 to the C15 alkyl chain length.Preferably, the level of linear alkylbenzene sulfonate be 0wt% to 30wt%, more preferably 1wt% is to 25wt%, most preferably 2wt% presses the total weight of compsn to 15wt%.
Compsn of the present invention can comprise other AS, its extra amount with above-mentioned per-cent.Suitable AS is well known to those skilled in the art.Example comprises that primary and secondary alkyl-sulphate, particularly C8 are to the C15 primary alkyl sulphates; Sulfated alkyl ether; Alkene sulfonate; Alkylxylene sulfonate; The dialkyl sulfosuccinate; And fatty sulfonate.Sodium salt is normally preferred.
Detergent compositions of the present invention possibly also comprise non-ionics.Operable non-ionics comprises the primary and secondary fatty alcohol ethoxylate; Particularly by the C8 of the every mol of alcohol ethoxylation of average 1 to 20 moles of ethylene oxide to the C20 fatty alcohol, be more especially by the C10 of the every mol of alcohol ethoxylation of average 1 to 10 moles of ethylene oxide to C15 primary and secondary fatty alcohol.
The non-ethoxylated non-ionics comprises APG, glycerol monoethers and polyhydroxyamide (glucamide).
Preferably, the level of non-ionics be 0wt% to 30wt%, more preferably 1wt% is to 25wt%, most preferably 2wt% presses the total weight of compsn to 15wt%.
The total amount of existing tensio-active agent also will rely on desired end-use, and can be up to 60wt%, for example at the compsn that is used for the hand cleaning fabric.Be used for the compsn of mechanical cleaning fabric, 5 to 40wt% amount is normally suitable.Typically, by the weight of compsn, the tensio-active agent that compsn will comprise 2wt% at least is 2-60% for example, preferred 15-40%, most preferably 25-35%.
Be applicable to great majority automatically the detergent compositions of fabric washing machines comprise the non-soap surfactant of anionic usually, perhaps non-ionics, perhaps two kinds of combinations with any proper proportion, randomly with soap together.
Compsn of the present invention when washing fabric cleaning composition with deciding, also comprises a kind of or more kinds of washing assistant usually.The total amount of washing assistant in compsn typically is 5 to 80wt%, and preferred 10 to 60wt%, press the weight of compsn and calculate.
The inorganic builders that can exist comprises yellow soda ash, if expectation combines with the crystal seed of lime carbonate, as disclosed in GB 1 437 950 (Unilever); Crystal and unbodied aluminosilicate, for example zeolite is as disclosed in GB 1 473 201 (Henkel); Unbodied aluminosilicate is as disclosed in GB 1 473 202 (Henkel); With blended crystal/unbodied aluminosilicate, as disclosed in GB 1 470 250 (Procter & Gamble); With multilayer silicate, as disclosed in EP 164 514B (Hoechst).Inorganic phosphate builders for example ortho-phosphoric acid, tetra-sodium and tripolyphosphate sodium salt also is applicable to the present invention.
Compsn preferred package alkali metal containing of the present invention, preferred manosil AS sodium salt washing assistant.Sodium aluminium silicate usually can with 10 to 70% calculate by weight (anhydrous basis) amount add preferred 25 to 50wt%.
Alkali metal aluminosilicate can be crystal or unbodied or its mixture, and it has general formula: 0.8-1.5 Na
2O.Al
2O
3.0.8-6 SiO
2
These materials comprise some combination water and require to have the calcium ion-exchanged amount of 50mg CaO/g at least.Preferred sodium aluminium silicate comprises 1.5-3.5SiO2 unit (in following formula).Unbodied and crystalline material can prepare through the reaction between water glass and the sodium aluminate easily, like what in document, fully describe.Suitable crystal sodium aluminium silicate IX detersive power washing assistant for example is described among the GB 1 429 143 (Procter&Gamble).Preferred the type sodium aluminium silicate is known commercially available zeolite A and X and its mixture.
Zeolite can be commercially available zeolite 4A, is widely used in now in the laundry stain remover powder.Yet according to the preferred embodiments of the invention, the zeolite builders that adds the present composition is at most aluminium zeolite P (zeolite MAP), as described in EP 384 070A (Unilever) with require protection.Zeolite MAP is defined as the alkali metal aluminosilicate of zeolite P type, and the weight ratio of its silicon and aluminium is no more than 1.33, preferably in 0.90 to 1.33 scope, more preferably in 0.90 to 1.20 scope.
Particularly preferably be zeolite MAP, its silicon and aluminium weight ratio are no more than 1.07, and more preferably about 1.00.The calcium binding capacity of zeolite MAP is the every g anhydrous material of 150mg CaO at least normally.
The organic washing-assisting detergent that can exist comprises polycarboxylate polymkeric substance for example polyacrylic ester, vinylformic acid/maleic acid and vinylformic acid phosphinate; The monomer polycarboxylate for example Citrate trianion, glyconate, oxygen two butyratess, glycerine list-, two-and three butyratess, ethyloic oxydisuccinic acid salt, ethyloic oxygen malonate, cinchomeronic acid salt (dipicolinates), hydroxyethylamino diacetin and alkyl and thiazolinyl malonate and SUMATRIPTAN SUCCINATE; With sulfonated soap.This tabulation is not detailed.
Preferred especially organic washing-assisting detergent is a Citrate trianion, and suitably with 5 to 30wt%, preferred 10 to 25wt% amount is used; And acrylic polymers, more particularly vinylformic acid/maleic acid suitably arrives 15wt% with 0.5, and preferred 1 to 10wt% amount is used.
Washing assistant, inorganic and organic, preferably with an alkali metal salt particularly sodium-salt form exist.
Possibly also suitably comprise bleaching system according to compsn of the present invention.Fabric cleaning composition can make us desirably comprising peroxy bleaching compound, for example inorganic persalt or organic peroxide acid, and it can produce hydrogen peroxide in the aqueous solution.
Suitable peroxy bleaching compound comprises for example for example alkali metal perborate, percarbonate, perphosphate, persilicate and persulphate of urea peroxide and inorganic persalt of organo-peroxide.Preferred inorganic persalt is sodium perborate monohydrate and tetrahydrate and SPC-D.
Particularly preferably be SPC-D, it has the protective coating opposing by the moisture stabilization removal.Having the SPC-D that contains sodium metaborate and water glass protective coating is disclosed among GB 2 123 044B (Kao).
Peroxy bleaching compound is suitably with 0.1 to 35wt%, and preferred 0.5 to 25wt% amount exists.Peroxy bleaching compound can combine bleach-activating agent (bleach precursor) to be used in combination to improve the bleaching action under the low cleaning temperature.Bleach precursor is suitably with 0.1 to 8wt%, and preferred 0.5 to 5wt% amount exists.
Preferred bleach precursor is a peroxycarboxylic acid precursors, is more especially peracetic acid precursors and crosses the n-nonanoic acid precursor.Be applicable to that preferred especially bleach precursor of the present invention is N, N, N ', N '-tetra acetyl ethylene diamine (TAED) and nonanoyl oxygen Supragil GN (SNOBS).Expect that also novel quaternary ammonium and phosphine bleach precursor are disclosed among US 4 751 015 and US 4 818 426 (Lever BrothersCompany) and EP 402 971A (Unilever), and be disclosed in the cationic bleach agent precursor among EP 284 292A and the EP303 520A (Kao).
The SYNTHETIC OPTICAL WHITNER system can replenish peroxy acid or substituted by peroxy acid, and the example of such peracid can be found in US 4 686 063 and US 5 397 501 (Unilever).The peracid that preferred example is an imino-peroxycarboxylic acid type is described among EP A 325 288, EP A 349 940, DE 382 3172 and the EP 325 289.More preferred example is phthalimido peroxy-hexanoic acid (PAP).Such peracid suitably exists with the preferred 0.5-10% of 0.1-12%.
Bleach-stable agent (transition metal chelator) also can exist.Suitable bleach-stable agent comprises for example Dequest (trade mark) and non-SULPHOSUCCINIC ACID ESTER stablizer EDDS (EDDS) for example of ethylenediamine tetraacetate (EDTA), polyphosphonates.These bleach-stable agent also can be used for removing stain and are particularly comprising low-level SYNTHETIC OPTICAL WHITNER kind or do not having in the product of SYNTHETIC OPTICAL WHITNER kind.
Preferred especially SYNTHETIC OPTICAL WHITNER system comprises peroxy bleaching agent compound (preferred SPC-D is randomly together with activator of bleaching agent) and transition metal bleach agent catalyzer, and description and requirement are protected among EP 458 397A, EP 458 398A and EP 509 787A (Unilever).
Can also comprise a kind of or more kinds of enzyme according to compsn of the present invention.
Suitable enzyme comprises proteolytic enzyme, glycase, cellulase, oxydase, peroxidase and lipase, and it is suitable for joining in the detergent compositions.Preferred proteolytic enzymes (proteolytic enzyme) is the protein material of catalytic activity, and it is degraded when being present in the fabric stain of hydrolysis reaction or changes the kinds of protein of stain.They can be any suitable origin for example plant, animal, bacterium or yeast originates.
Various qualities and origin in various pH scopes (4-12), have active proteolytic ferment or proteolytic enzyme be can utilize and be used for of the present invention.The example of suitable proteolytic ferment is a subtilisin; It is to obtain from specific subtilis (B.subtilis), bacillus licheniformis (B.licheniformis) bacterial strain; The for example commercial subtilisin Maxatase (trade mark) that can obtain; By Genencor International N.V., Delft, Holland provides; And Alcalase (Trade Mark), by Novozymes Industri A/S, Copenhagen, Denmark provides.
Particularly suitable is the proteolytic enzyme that obtains from bacillus; It has maximum activity in 8～12 pH scope; It can for example obtain from following commerce: Novozymes Industri A/S, registered trademark is Esperase (trade mark) and Savinase (trade mark).These are described in GB 1 243 785 with the preparation of isozyme.Other commercial protease are Kazusase (trade mark can obtain from Showa-Denko of Japan), Optimase (Miles Kali-Chemie; Hannover; And Superase (trade mark can obtain from Pfizer of U.S.A.) trade mark of West Germany).
Usually with the amount employing detergency enzymes of particle form with about 0.1～approximately 3.0wt%.Yet, can use any suitable profile.
Compsn of the present invention can contain basic metal, and preferred yellow soda ash is handled with being convenient to improve detersive power.Can be suitably there be preferred 2～40wt% in yellow soda ash with the amount of 1～60wt%.Yet containing seldom or not having the compsn of yellow soda ash also is within the scope of the invention.
Can for example lipid acid (perhaps fatty acid soaps), sugar, acrylate or acrylate/acid/maleic acid copolymers or water glass improve flow of powder through adding small quantities of powder structural agent (structurant).A kind of preferred pulvered structure agent (structurant) is a fatty acid soaps, suitably exists with 1 to 5wt% amount.
Detergent compositions is used for leading clear stain remover with the washing lotion pH that typically provides 7 to 10.5 in being diluted in washing lotion (during the typical cleaning interval) time.
Suitably through following preparation particulate detergent compositions: the heat insensitive composition slurry that spraying drying is suitable, spray those then and be not suitable for the composition through the slurry processing when dosage or after dosage.Skilled stain remover formulator can confirm that what composition should be included in the slurry or should not be included in wherein.
Particulate detergent compositions of the present invention has preferably at least that 400g/ rises to few tap density, more preferably 500g/ liter at least.Special preferably combination compositions has the tap density that 650g/ at least rises, more preferably 700g/ liter at least.
This type powder can be through following preparation: the spray-dired powder of (post-tower) densification behind the tower, perhaps through for example dry mixed and the granulation of complete non-tower method; In two kinds of situation, can advantageously use high-speed mixer/granulator.Use the method for high-speed mixer/granulator to be disclosed in for example EP 340 013A, EP 367 339A are among EP 390 251A and EP 420 317A (Unilever).
Can be through following preparation liquid detergent composition: mix its necessary and optional ingredients so that the compsn that contains component with necessary concentration to be provided with any desired order.According to liquid compsn of the present invention can also be tight form, and it means with traditional liquid detergents compares, and it will comprise low-level water.
The other materials that may reside in the detergent compositions of the present invention comprises water glass; Anti redeposition agent is cellulose polymer compound for example; The soil release agent polymkeric substance; Inorganic salt are sodium sulfate for example; Perhaps profoamer (depending on the circumstances); Proteolyze and lipolytic enzyme; Dyestuff; Coloured speckle; White dyes, optical white for example singlet oxygen and radical photoinitiator fade and decouple polymkeric substance.This tabulation is not detailed.
Fabric treatment composition of the present invention can also comprise the for example hydrophilic or lipophilic jelling agent of the auxiliary agent that is generally used for makeup, medicine and/or dermatology field, hydrophilic or lipophilic acvator, sanitas, inhibitor, solvent, spices, filler, screening agent, sterilant, odour absorbents and dyestuff.The amount of these various auxiliary agents be generally used for consider those of field, for example be 0.01 to 20% of composition total weight.According to their character, these auxiliary agents be directed into the fat phase and/or introduce aqueous phase.
Basic unit (substrate)
When being used to wash, basic unit can be that any desired probiotic agent particle that deposits above that receives the basic unit that handles like cleaning or rinse method with it.
Especially, basic unit can be a textile fabric.
Handle
Can carry out through any suitable method with compositions-treated of the present invention basic unit, as cleaning, soaking into or rinsing basic unit, also can be through directly using as spraying, rubbing (rubbing), intersperse (spotting), smear or the like.
This processing can comprise the water-bearing media that basic unit's contact is comprised material of the present invention.
In the processing that separates with the home washings method of routine, (or industry) that can be used as spray composite provides processing for example to be used for family is applied to fabric.Suitable spraying diverting device is disclosed in WO 96/15310 (Procter & Gamble) and introduces this paper as a reference.Perhaps, compsn can be through the molten iron case, independently iron holder or cannon spray head apply, and be of EP1201816 and WO99/27176.
Embodiment
With reference now to following non-limiting example, embodiment of the present invention is described.Only if spell out, all ratios all are that the weight percent with composition total weight provides, except the probiotic agent particle provides with mg.
Table 1. contains the composition of the fabric cleaning liquid of probiotic agent
| Embodiment | 1 | 2 | 3 | 4 |
| Lactobacillus genus (powder) (mg) | 5.1 | 5.1 | ? | ? |
| Lactobacterium acidophilum and bifidobacterium * | ? | ? | 5.1 | 5.1 |
| The polymer deposition auxiliary agent | ? | ? | ? | ? |
| Jaguar?C13-S | 0.30 | ? | ? | ? |
| Softgel?BDA | ? | 1.0 | ? | ? |
| ZELCON?5126 | ? | ? | 0.3 | ? |
| Polyox?WSR?N-750 | ? | ? | ? | 0.3 |
| The stain remover composition | ? | ? | ? | ? |
| Nonionic 7EO, side chain (100%) | 11.70 | 7.00 | 11.70 | 7.00 |
| Lipid acid 5908 (100%) | 2.65 | 1.5 | 2.65 | 1.5 |
| SLES?3EO?(70％) | 16.71 | 10 | 16.71 | 10 |
| Cationic?Praepagen?HY | 2.30 | 1 | 2.30 | 1 |
| NaCl (26% solution) | 0.96 | 4.61 | 0.96 | 4.61 |
| NaOH solution (50%) | 1.40 | 0.74 | 1.40 | 0.74 |
| 1,2-benzisothiazole-3-ketone (20%) (Proxel) | 0.05 | 0.08 | 0.05 | 0.08 |
| Ucar 35 (100%) | 3.00 | 1.00 | 3.00 | 1.00 |
| Boric acid (100%) | 0.50 | 0.5 | 0.50 | 0.5 |
| Spices | 0.5 | 0.35 | 0.5 | 0.35 |
| Water | To 100 | To 100 | To 100 | To 100 |
Jaguar and Softgel are respectively cationic gum and yam starch polymkeric substance.
ZELCON is non-ionic hydrophilic polyester copolymer, and it has the unitary duplicated segment of ethylene terephthalate.
POLYOX WSR N-750 (ex Amerchol) is non-ion deposition auxiliary agent, and it is the PEG of about 7M based on MW.
Probiotic agent capsule (ex Boots Pharmacy) contains Microcrystalline Cellulose, Vltra tears, Magnesium Stearate.
Lactobacterium acidophilum 4.5mg, cfu=2.2x10
8, bifidobacterium 0.6mg, cfu=7.5x10
7
Claims (15)
1. be used for the fabric treatment composition of washing methods, it comprises:
A) tensio-active agent, it is selected from AS, nonionogenic tenside, cats product and its mixture,
B) the probiotic agent particle and
C) deposition aid.
2. according to the fabric treatment composition of claim 1, wherein the probiotic agent particle is selected from lactobacillus genus, genus bifidobacterium, streptococcus, lactococcus genus, enterococcus spp and its mixture.
3. according to the fabric treatment composition of claim 2, wherein probiotic agent is selected from lactobacillus johnsonii, lactobacillus paracasei, bifidobacterium adolescentis, bifidus longum bb, lactic acid Bacillus bifidus NCC2818 (also being called as (Bb12) (ATCC27536)).
4. according to each fabric treatment composition in the aforementioned claim, wherein in the gross weight of compsn, the probiotic agent particle is with 0.003～0.5wt%, preferred 0.005～0.1wt%, and most preferably the amount of 0.005～0.05wt% exists.
5. according to each fabric treatment composition in the aforementioned claim, wherein probiotic agent is the form that is selected from vigor (living) form, inactivated form and dead form.
6. according to each fabric treatment composition in the aforementioned claim, wherein the probiotic agent particle is spore or vegetative cell state.
7. according to each fabric treatment composition in the aforementioned claim, wherein deposition aid be selected from polyoxyethylene (PEO), polymine (PEI), gather (propenoate), gather (acrylic amide), cationic starch, polyethyleneterephthalate-polyoxyethylene terephthalate (PET/POET) polymkeric substance and its mixture.
8. according to each fabric treatment composition of claim 1～6, wherein deposition aid is polysaccharide or polyphenyl dioctyl phthalate second diester-polyoxyethylene terephthalate (PET/POET) conjugate of Chemical bond in particle surface.
9. according to each fabric treatment composition of claim 1～6, wherein deposition aid is the low charge density cationic polymers.
10. according to the fabric treatment composition of claim 9, wherein the low charge density cationic polymers is a modified potato starch.
11. according to each fabric treatment composition in the aforementioned claim, wherein the probiotic agent particle is packed.
12. according to the fabric treatment composition of claim 11, wherein probiotic agent is by the polyvalent alcohol of coated by hydrophobic modification.
13. according to each fabric treatment composition in the aforementioned claim, it is a fabric cleaning composition.
14. deposition probiotic agent particulate method on textile article, it comprises the step of utilizing the fabric treatment composition processing textile article that each limited in the aforementioned claim.
15. comprise probiotic agent particulate textile article, it is that treatment process through claim 14 obtains.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0719161.2A GB0719161D0 (en) | 2007-10-01 | 2007-10-01 | Improvements relating to fabrick treatment compositions |
| GB0719161.2 | 2007-10-01 | ||
| PCT/EP2008/062242 WO2009043709A1 (en) | 2007-10-01 | 2008-09-15 | Improvements relating to fabric treatment compositions |
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| CN102741386A true CN102741386A (en) | 2012-10-17 |
| CN102741386B CN102741386B (en) | 2014-12-17 |
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| CN200880118597.2A Active CN102741386B (en) | 2007-10-01 | 2008-09-15 | Improvements relating to fabric treatment compositions |
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|---|---|
| EP (1) | EP2195407B1 (en) |
| CN (1) | CN102741386B (en) |
| AR (1) | AR068584A1 (en) |
| AT (1) | ATE502099T1 (en) |
| BR (1) | BRPI0817741B1 (en) |
| DE (1) | DE602008005620D1 (en) |
| ES (1) | ES2363114T3 (en) |
| GB (1) | GB0719161D0 (en) |
| PL (1) | PL2195407T3 (en) |
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| US20060177429A1 (en) * | 1997-04-18 | 2006-08-10 | Sean Farmer | Methods for inhibiting microbial infections associated with sanitary products and for enhancing sanitary product degradation, systems and compositions |
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- 2008-09-15 CN CN200880118597.2A patent/CN102741386B/en active Active
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- 2008-09-15 AT AT08804202T patent/ATE502099T1/en not_active IP Right Cessation
- 2008-09-15 WO PCT/EP2008/062242 patent/WO2009043709A1/en active Application Filing
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| US20060177429A1 (en) * | 1997-04-18 | 2006-08-10 | Sean Farmer | Methods for inhibiting microbial infections associated with sanitary products and for enhancing sanitary product degradation, systems and compositions |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111344387A (en) * | 2017-11-13 | 2020-06-26 | 格林拜里有限公司 | Bacterial preparation, method for producing a cleaning solution, cleaning solution and method for cleaning dirty objects |
| CN112384603A (en) * | 2018-07-06 | 2021-02-19 | 雷克特本克斯尔万尼施公司 | Composition comprising a metal oxide and a metal oxide |
Also Published As
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| BRPI0817741A2 (en) | 2015-03-31 |
| EP2195407A1 (en) | 2010-06-16 |
| BRPI0817741B1 (en) | 2017-06-06 |
| ES2363114T3 (en) | 2011-07-20 |
| WO2009043709A1 (en) | 2009-04-09 |
| CN102741386B (en) | 2014-12-17 |
| EP2195407B1 (en) | 2011-03-16 |
| AR068584A1 (en) | 2009-11-18 |
| PL2195407T3 (en) | 2011-08-31 |
| GB0719161D0 (en) | 2007-11-07 |
| ATE502099T1 (en) | 2011-04-15 |
| ZA201001832B (en) | 2011-05-25 |
| DE602008005620D1 (en) | 2011-04-28 |
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