CN102732800A - Fe-Ni-Cr soft magnetic alloy and preparation method thereof - Google Patents
Fe-Ni-Cr soft magnetic alloy and preparation method thereof Download PDFInfo
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- CN102732800A CN102732800A CN2012101890336A CN201210189033A CN102732800A CN 102732800 A CN102732800 A CN 102732800A CN 2012101890336 A CN2012101890336 A CN 2012101890336A CN 201210189033 A CN201210189033 A CN 201210189033A CN 102732800 A CN102732800 A CN 102732800A
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- 229910018487 Ni—Cr Inorganic materials 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 229910001004 magnetic alloy Inorganic materials 0.000 title abstract description 4
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 33
- 239000000956 alloy Substances 0.000 claims abstract description 33
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 9
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 20
- 239000011651 chromium Substances 0.000 claims description 13
- 238000000498 ball milling Methods 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 8
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 239000011812 mixed powder Substances 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000004886 process control Methods 0.000 claims description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 229910002555 FeNi Inorganic materials 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 4
- 230000005415 magnetization Effects 0.000 abstract description 3
- 239000012776 electronic material Substances 0.000 abstract description 2
- 229910002056 binary alloy Inorganic materials 0.000 abstract 1
- 230000035699 permeability Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000011358 absorbing material Substances 0.000 description 3
- 229910000889 permalloy Inorganic materials 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000000696 magnetic material Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 238000012857 repacking Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000000192 social effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
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Abstract
A Fe-Ni-Cr soft magnetic alloy and a preparation method thereof relate to the electronic material technology. The magnetic alloy comprises the following components in percentage by weight: fe: 52% -63%, Ni: 36%, Cr: 1 to 12 percent. The invention can obtain good soft magnetic properties such as saturation magnetization and high magnetic conductivity, and the like, and obtain wave absorbing property superior to FeNi binary system alloy.
Description
Technical field
The present invention relates to electronic material technology.
Background technology
Get into after 21 century, various countries are more deep for the research of stealthy technique, developed so far more than ten kind of absorbing material material.Utilize radar absorbing (RAM) can reduce the RCS of target.The effect of microwave absorption is even more important; All the aircraft of use matrix material seldom; Must apply microwave absorbing material keeping stealthy requirement in parts such as aircraft hardware, passenger cabin, radar modules, and these parts are very high to the microwave absorption performance requriements, in addition in the repacking of existing weapons; Apply microwave and inhale material in construction with safeguard because of having great convenience and low expense has remarkable advantages; And owing to combined microwave absorption, aircraft can more be considered aerodynamic configuration when research and development, to improve the operation handiness of aircraft.Except military aspect; Along with further developing of electronic communication and various microwave electrical equipment; Various electronic apparatus application increasing, electromagenetic wave radiation has become a kind of new social effects of pollution, the EMI that electromagenetic wave radiation causes; Not only can influence the normal operation of various electronicss, and harm also arranged healthy.Therefore absorbing material has also obtained at aspects such as information propagation, electron device, microwave protections to use widely.Fe base soft magnetic materials is high because of its magnetic permeability in microwave absorption, and loss is little, and good stability is so be studied and use widely.But now widely used most of Fe base soft magnetic materials is difficult to realize reducing the problem of anisotropy field.
And the FeNi permalloy has low anisotropy field; Thereby has very big advantage for improving magnetic permeability lifting absorbing property; And the FeNi permalloy has this excellent soft magnetic performance of very high magnetic permeability under low-intensity magnetic field, thereby develops into use field one of non-retentive alloy the most widely.But the FeNi alloy will obtain low anisotropy field need be realized under the condition of chilling, is difficult to obtain the FeNi permalloy of high magnetic permeability under the general condition.But add after the proper C r element, can suppress the formation of the non magnetic phase of Ni3Fe, thereby reduce anisotropy field, improve magnetic permeability; And need under the condition of chilling, just can not obtain the FeNiCr alloy of excellent soft magnetic performance yet, replace expensive Ni to have very big economic worth and market application foreground yet with cheap Cr.
Summary of the invention
Technical problem to be solved by this invention is that a kind of excellent flaky nanocrystalline magnetic micro-powder of excellent performance is provided.
The technical scheme that the present invention solve the technical problem employing is, a kind of Fe-Ni-Cr non-retentive alloy is characterized in that, by weight percentage, component is: Fe:52%～63%, Ni:36%, Cr:1%～12%.
More specifically, each component is: Fe:60%, Ni:36%, Cr:4%.
The preparation method of described Fe-Ni-Cr non-retentive alloy comprises the steps:
1) according to the weight percent of each component, gets following raw material respectively: iron powder, nickel powder and chromium powder;
2) be configured to mixed powder according to weight percent, the adition process control agent, ball milling obtains the Fe-Ni-Cr powdered alloy.
Said process control agent is an absolute ethyl alcohol; Adopt planetary ball mill, rotating speed is 300r/min; Ball is the zirconium ball in the ball grinder, and sphere diameter is 12mm; The ball that adds, the weight ratio of material and absolute ethyl alcohol is a ball: material: absolute ethyl alcohol=6:1:1.6.
Ferrous powder granules degree 60～100 μ m, purity >=98%; Nickel powder granularity 3～6 μ m, purity>99%; Chromium powder granularity 80～120 μ m, purity >=99.9%.
The invention has the beneficial effects as follows that it is simple that the present invention prepares Fe-Ni-Cr nano soft magnetic alloy powder technology, obtains excellent flaky nanocrystalline magnetic micro-powder easily.Like Fig. 5, Fig. 6 and shown in Figure 7 can access good soft magnetic performances such as the saturation magnetization that is higher than in the past and high magnetic permeability, obtains the absorbing property more excellent than FeNi two component system alloy.
The specific saturation magnetization that adopts vibrating sample magnetometer test micro mist and coercive force also are pressed into the coaxial composite sample of internal diameter 3mm, external diameter 7mm after with magnetic and paraffin uniform mixing in the ratio of 3:1.Adopt its magnetic spectrum of Agilent 8720ET Microwave Net vector analysis appearance test, shown in accompanying drawing in 500MHz～18GHz range of frequency.
Description of drawings
Fig. 1-4 is the XRD spectrum behind the Fe-Ni-Cr powder process different time ball milling of the present invention: wherein,
Fig. 1 is Fe:Ni:Cr=63:36:1;
Fig. 2 is Fe:Ni:Cr=60:36:4;
Fig. 3 is Fe:Ni:Cr=58:36:8;
Fig. 4 is Fe:Ni:Cr=52:36:12.
Fig. 5 is the static magnetic spectrum parameter of Fe-Ni-Cr nanometer crystal alloy powder of the present invention.
Fig. 6 is the real part graphic representation of the compound magnetic permeability of Fe-Ni-Cr nanometer crystal alloy powder Fe-Ni-Cr powder of the present invention.
Fig. 7 is the imaginary part graphic representation of the compound magnetic permeability of Fe-Ni-Cr powder of the present invention.
Embodiment
Present embodiment provides a kind of Fe-Ni-Cr non-retentive alloy, and the component of this alloy and weight percent are: Fe 63%, and Ni 36%, and Cr 1%.
The preparation method of said alloy is following:
Step 1:, get following raw material respectively according to the weight percent of each component: iron powder (granularity 60～100 μ m, purity >=98%), nickel powder (granularity 3～6 μ m, purity>99%) and chromium powder (granularity 80～120 μ m, purity >=99.9%);
Step 2: be configured to mixed powder according to weight percent, getting sphere diameter is the zirconium ball of 12mm, and according to ball: material: absolute ethyl alcohol is that the proportional arrangement of 6:1:1.6 is put into ball grinder, with planetary type ball-milling method ball milling to 165 hour acquisition Fe-Ni-Cr powdered alloy.
Embodiment 2:
Present embodiment provides a kind of Fe-Ni-Cr non-retentive alloy, and the component of this alloy and weight percent are: Fe 60%, and Ni 36%, and the preparation method of Cr 4%. said alloys is following:
Step 1:, get following raw material respectively according to the weight percent of each component: iron powder (granularity 60～100 μ m, purity >=98%), nickel powder (granularity 3～6 μ m, purity>99%) and chromium powder (granularity 80～120 μ m, purity >=99.9%);
Step 2: be configured to mixed powder according to weight percent, getting sphere diameter is the zirconium ball of 12mm, and according to ball: material: absolute ethyl alcohol is that the proportional arrangement of 6:1:1.6 is put into ball grinder, with planetary type ball-milling method ball milling to 155 hour acquisition Fe-Ni-Cr powdered alloy.
Embodiment 3:
Present embodiment provides a kind of Fe-Ni-Cr non-retentive alloy, and the component of this alloy and weight percent are: Fe 56%, and Ni 36%, and the preparation method of Cr 8%. said alloys is following:
Step 1:, get following raw material respectively according to the weight percent of each component: iron powder (granularity 60～100 μ m, purity >=98%), nickel powder (granularity 3～6 μ m, purity>99%) and chromium powder (granularity 80～120 μ m, purity >=99.9%);
Step 2: be configured to mixed powder according to weight percent, getting sphere diameter is the zirconium ball of 12mm, and according to ball: material: absolute ethyl alcohol is that the proportional arrangement of 6:1:1.6 is put into ball grinder, with planetary type ball-milling method ball milling to 105 hour acquisition Fe-Ni-Cr powdered alloy.
Embodiment 4:
Present embodiment provides a kind of Fe-Ni-Cr non-retentive alloy, and the component of this alloy and weight percent are: Fe 56%, and Ni 36%, and the preparation method of Cr 12%. said alloys is following:
Step 1:, get following raw material respectively according to the weight percent of each component: iron powder (granularity 60～100 μ m, purity >=98%), nickel powder (granularity 3～6 μ m, purity>99%) and chromium powder (granularity 80～120 μ m, purity >=99.9%);
Step 2: be configured to mixed powder according to weight percent, getting sphere diameter is the zirconium ball of 12mm, and according to ball: material: absolute ethyl alcohol is that the proportional arrangement of 6:1:1.6 is put into ball grinder, with planetary type ball-milling method ball milling to 95 hour acquisition Fe-Ni-Cr powdered alloy.
Claims (5)
1. a Fe-Ni-Cr non-retentive alloy is characterized in that, by weight percentage, component is: Fe:52%～63%, Ni:36%, Cr:1%～12%.
2. Fe-Ni-Cr non-retentive alloy as claimed in claim 1 is characterized in that, each component is: Fe:60%, Ni:36%, Cr:4%.
3. the preparation method of Fe-Ni-Cr non-retentive alloy as claimed in claim 1 is characterized in that, comprises the steps:
1) according to the weight percent of each component, gets following raw material respectively: iron powder, nickel powder and chromium powder;
2) be configured to mixed powder according to weight percent, the adition process control agent, ball milling obtains the Fe-Ni-Cr powdered alloy.
4. the preparation method of Fe-Ni-Cr non-retentive alloy as claimed in claim 3 is characterized in that, said process control agent is an absolute ethyl alcohol; Adopt planetary ball mill, rotating speed is 300r/min; Ball is the zirconium ball in the ball grinder, and sphere diameter is 12mm; The ball that adds, the weight ratio of material and absolute ethyl alcohol is a ball: material: absolute ethyl alcohol=6:1:1.6.
5. the preparation method of Fe-Ni-Cr non-retentive alloy as claimed in claim 3 is characterized in that, ferrous powder granules degree 60～100 μ m, purity >=98%; Nickel powder granularity 3～6 μ m, purity>99%; Chromium powder granularity 80～120 μ m, purity >=99.9%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201210189033.6A CN102732800B (en) | 2012-06-10 | 2012-06-10 | A kind of Fe-Ni-Cr non-retentive alloy and preparation method |
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| CN201210189033.6A CN102732800B (en) | 2012-06-10 | 2012-06-10 | A kind of Fe-Ni-Cr non-retentive alloy and preparation method |
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| CN102732800A true CN102732800A (en) | 2012-10-17 |
| CN102732800B CN102732800B (en) | 2015-10-28 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107452458A (en) * | 2017-07-05 | 2017-12-08 | 深圳顺络电子股份有限公司 | A kind of ferroalloy magnetic material and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03191041A (en) * | 1989-12-20 | 1991-08-21 | Nisshin Steel Co Ltd | Fe-ni-cr series soft magnetic alloy |
| JPH03277718A (en) * | 1990-03-27 | 1991-12-09 | Nisshin Steel Co Ltd | Production of ni-fe-cr soft-magnetic alloy |
| CN1269588A (en) * | 1999-04-02 | 2000-10-11 | 安费尤吉纳精密公司 | Soft-magnetic alloy used in clock and watch |
| US6190465B1 (en) * | 1997-07-04 | 2001-02-20 | Imphy Ugine Precision | Soft magnetic alloy of the Fe-Ni-Cr-Ti type for a magnetic circuit of a high-sensitivity relay |
| JP2004065942A (en) * | 2002-06-14 | 2004-03-04 | Sumitomo Metal Ind Ltd | Clad material for induction heating and its manufacturing method |
-
2012
- 2012-06-10 CN CN201210189033.6A patent/CN102732800B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03191041A (en) * | 1989-12-20 | 1991-08-21 | Nisshin Steel Co Ltd | Fe-ni-cr series soft magnetic alloy |
| JPH03277718A (en) * | 1990-03-27 | 1991-12-09 | Nisshin Steel Co Ltd | Production of ni-fe-cr soft-magnetic alloy |
| US6190465B1 (en) * | 1997-07-04 | 2001-02-20 | Imphy Ugine Precision | Soft magnetic alloy of the Fe-Ni-Cr-Ti type for a magnetic circuit of a high-sensitivity relay |
| CN1269588A (en) * | 1999-04-02 | 2000-10-11 | 安费尤吉纳精密公司 | Soft-magnetic alloy used in clock and watch |
| JP2004065942A (en) * | 2002-06-14 | 2004-03-04 | Sumitomo Metal Ind Ltd | Clad material for induction heating and its manufacturing method |
Non-Patent Citations (2)
| Title |
|---|
| 何正明等: "Fe100-xNix系合金超细粉末的结构和磁性研究", 《上海大学学报(自然科学版)》 * |
| 邓姝皓等: "电沉积制备铁-镍-铬纳米晶合金箔工艺的正交设计", 《中南大学学报(自然科学版)》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107452458A (en) * | 2017-07-05 | 2017-12-08 | 深圳顺络电子股份有限公司 | A kind of ferroalloy magnetic material and preparation method thereof |
| CN107452458B (en) * | 2017-07-05 | 2020-10-13 | 深圳顺络汽车电子有限公司 | Iron alloy magnetic material and preparation method thereof |
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| CN102732800B (en) | 2015-10-28 |
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