CN102732116A - Anti-yellowing paint and preparation method thereof - Google Patents
Anti-yellowing paint and preparation method thereof Download PDFInfo
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- CN102732116A CN102732116A CN2012102325047A CN201210232504A CN102732116A CN 102732116 A CN102732116 A CN 102732116A CN 2012102325047 A CN2012102325047 A CN 2012102325047A CN 201210232504 A CN201210232504 A CN 201210232504A CN 102732116 A CN102732116 A CN 102732116A
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- xanthochromia
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- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003973 paint Substances 0.000 title abstract description 9
- 238000004383 yellowing Methods 0.000 title abstract 5
- 239000000839 emulsion Substances 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000003112 inhibitor Substances 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 9
- 239000000049 pigment Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000080 wetting agent Substances 0.000 claims abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000005034 decoration Methods 0.000 claims abstract description 5
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims description 18
- 239000011248 coating agent Substances 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 8
- 230000008719 thickening Effects 0.000 claims description 8
- 238000004581 coalescence Methods 0.000 claims description 6
- 239000004816 latex Substances 0.000 claims description 5
- 229920000126 latex Polymers 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000009775 high-speed stirring Methods 0.000 claims description 4
- -1 poly carboxylic acid amine salt Chemical class 0.000 claims description 4
- 239000001038 titanium pigment Substances 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 3
- ZHTRFSJGUKYTPR-UHFFFAOYSA-N 2-octyl-1,2-thiazolidin-4-one Chemical group CCCCCCCCN1CC(=O)CS1 ZHTRFSJGUKYTPR-UHFFFAOYSA-N 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- 235000010446 mineral oil Nutrition 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical group [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 239000006184 cosolvent Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000005201 scrubbing Methods 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229940106580 ginkgo biloba leaf extract Drugs 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses an anti-yellowing paint and a preparation method thereof. The anti-yellowing paint is used for wall decoration. The anti-yellowing paint is composed of pure water, a thickening agent, a multifunctional agent, a dispersant, a wetting agent, a defoaming agent, a mildew inhibitor, a functional pigment, common titanium dioxide, a filler, acrylic emulsion, a film forming agent, a cosolvent and bactericide. According to the invention, the anti-yellowing paint has outstanding weathering resistance, outstanding hue stability, excellent scrubbing resistance and excellent pollution resistance.
Description
Technical field
The invention belongs to technical field of coatings, relate in particular to a kind of coating of anti-xanthochromia the and preparation method thereof.
Background technology
At present, increasing along with the building decoration outer wall material, the demand of color and weather resistance are paid attention to by people day by day, and the competitive edge of traditional exterior wall latex paint weakens gradually.Find many shortcomings such as exterior wall latex paint ubiquity weathering resistance in the market is poor, form and aspect poor stability, pollution resistance difference through market survey.In a single day metope behind the decoration has spot, and metope can not be accomplished to clean up fully, or can not keep secular form and aspect feeling of freshness.
Summary of the invention
Defective in view of above-mentioned prior art exists the objective of the invention is to propose a kind of coating of anti-xanthochromia the and preparation method thereof, and the color weathering resistance is poor in the solution prior art, form and aspect poor stability, the defective of abrasion resistance and pollution resistance difference.
The object of the invention will be achieved through following technical scheme:
The present invention provides a kind of coating of anti-the xanthochromia, is used for wall decoration, and each moity and weight percent are following:
Pure water 30%～40%
Thickening material 0.3%～0.35%
Multifunctional assistant 0.1%～0.2%
Dispersion agent 0.4%～0.6%
Wetting agent 0.1%～0.2%
Skimmer 0.2%～0.3%
Mould inhibitor 0.06%～0.1%
Functional pigment 1.0%～2.0%
Ordinary titanium powder 4.0%～5.0%
Filler 30%～35%
ACRYLIC EMULSION 15%～18%
Film coalescence aid 1.2%～1.5%
Solubility promoter 1.5%～1.8%
Sterilant 0.1%～0.15%.
Preferably, above-mentioned a kind of coating of anti-the xanthochromia, wherein: said thickening material is a Natvosol; Said multifunctional assistant is the PH regulator; Said dispersion agent is the poly carboxylic acid amine salt; Said wetting agent is a nonionogenic tenside; Said skimmer is a mineral oil antifoam agent; Said mould inhibitor is a n-octyl isothiazolinone mould inhibitor; Said functional pigment is a Nano titanium dioxide; Said filler is kaolin and lime carbonate; Said ACRYLIC EMULSION is a modified acrylic acid emulsion; Said membrane-forming agent is a water-soluble film forming agent; Said solubility promoter is a Ucar 35; Said sterilant is a benzisothiazole ketone sterilant.
Preferably, above-mentioned a kind of coating of anti-the xanthochromia, wherein:: said modified acrylic acid emulsion carries out modification for utilizing the wet monomer that adheres to contain siloxy and urea groups to latex polymer, thereby has changed the tack of latex polymer and to the supporting capacity of color stuffing.
The present invention also provides a kind of preparation method of the above-mentioned coating of anti-the xanthochromia, comprises the steps:
Step 1: at ambient temperature, pure water, thickening material, multifunctional assistant are dropped in the reaction kettle, stirred 15 minutes～20 minutes, thickening material is dissolved fully;
Step 2: add dispersion agent, wetting agent, 1/2 skimmer and mould inhibitor stirred 10 minutes～20 minutes;
Step 3: add functional pigment with 1200 rev/mins～1500 rev/mins high speed dispersion 3 minutes～5 minutes;
Step 4: add white titanium pigment and filler with 1500 rev/mins～1800 rev/mins high-speed stirring 15 minutes～20 minutes, to fineness≤70 micron;
Step 5: add ACRYLIC EMULSION, film coalescence aid, solubility promoter, sterilant and remaining 1/2 skimmer, stir and got product in 10 minutes～15 minutes.
Outstanding effect of the present invention is: the present invention has overcome the defective of prior art, makes coating have outstanding weathering resistance and form and aspect stability, excellent abrasion resistance and pollution resistance.The present invention utilizes modified acrylic acid emulsion, the sticking power under initial sticking power, immersion and the severe condition thereof of inorganic substrate is significantly increased, so water-fast, the washable wiping performance of rubber-emulsion paint is multiplied; Utilize the Powdered nano titanium oxide of rutile-type white loose; From size; Usually the size of the fine particles of generation physicochemical property noticeable change is below 100 nanometers; The shielding ultraviolet rays effect is strong, have Ginkgo Biloba Leaf Extract, antibiotic, from effect such as clean, anti-aging, thereby the stability of prolongation form and aspect; Solubility promoter can soften or dissolve the emulsion particle in the emulsion, and collaborative membrane-forming agent promotes the formation of paint film, and internal stress very closely is provided; Thereby can effectively stop the migration and the infiltration of spot; In addition, solubility promoter also can reduce film coated surface tension force, can reduce the water-absorbent of filming; Thereby improve the stain resistance of filming, the water-based spot is had superpower removal ability.
Embodiment
Through specific embodiment method of the present invention is described below, but the present invention is not limited thereto.Experimental technique described in the following embodiment like no specified otherwise, is ordinary method; Said reagent and material like no specified otherwise, all can obtain from commercial sources.
Embodiment 1:
A kind of coating of anti-xanthochromia step of preparation present embodiment is (below be weight percentage) as follows:
(1) under the room temperature condition, in reaction kettle, adds 38.69% pure water, 0.35% Natvosol and 0.2% multifunctional assistant;
(2) stir 15 minutes～20 minutes to the dispersion agent that adds 0.4% after Mierocrystalline cellulose dissolves fully again, 0.1% wetting agent, 0.15% skimmer and 0.06% mould inhibitor, dispersed with stirring is 15 minutes under the normal temperature;
(3) add 1.2% functional pigment, with 1200 rev/mins～1500 rev/mins high speed dispersion 3 minutes～5 minutes;
(4) filler that adds 4.5% white titanium pigment and 35% is with 1500 rev/mins～1800 rev/mins high-speed stirring 15 minutes～20 minutes, to fineness qualified (≤70 microns);
(5) add 16% modified acrylic acid emulsion, 1.5% film coalescence aid, 1.6% solubility promoter, 0.1% sterilant and 0.15% skimmer, stir and got product in 10 minutes～15 minutes.
The alkali resistance of present embodiment product, water tolerance detect according to the standard of GB/T 9755-2001, and pass through.
The artificial ageing resistance property detection of present embodiment product: 600h is non-foaming, do not peel off, flawless; Efflorescence: 1 grade; Variable color: 1 grade.
Embodiment 2:
A kind of coating of anti-xanthochromia step of preparation present embodiment is (below be weight percentage) as follows:
(1) at ambient temperature, in reaction kettle, add 35.53% pure water, 0.32% Natvosol and 0.15% multifunctional assistant;
(2) stir 15 minutes～20 minutes to the dispersion agent that adds 0.6% after Mierocrystalline cellulose dissolves fully again, 0.1% wetting agent, 0.15% skimmer and 0.1% mould inhibitor, dispersed with stirring is 15 minutes under the normal temperature;
(3) add 1.5% functional pigment, with 1200 rev/mins～1500 rev/mins high speed dispersion 3 minutes～5 minutes;
(4) filler that adds 5% white titanium pigment and 35% is with 1500 rev/mins～1800 rev/mins high-speed stirring 15 minutes～20 minutes, to the qualified back of fineness (≤70 microns);
(5) add 18% modified acrylic acid emulsion, 1.5% film coalescence aid, 1.8% solubility promoter, 0.1% sterilant and 0.15% skimmer, stir and got product in 10 minutes～15 minutes.
The abrasion resistance testing data: with scribble benzene emulsion be the common exterior coating of filmogen as model, the contrast plate of processing with this coating of anti-the xanthochromia compares (glue spread of exterior coating is with reference to GB/T9755-2001), the result is as shown in the table:
| Model | Abrasion resistance (inferior) | The contrast plate | Abrasion resistance (inferior) |
| Model one | 2000 | Embodiment 1 | 10000 |
| Model two | 3000 | Embodiment 2 | 12000 |
The present invention still has numerous embodiments, and all employing equivalents or equivalent transformation and all technical schemes of forming all drop within protection scope of the present invention.
Claims (4)
1. the coating of anti-the xanthochromia is used for wall decoration, it is characterized in that each moity and weight percent are following:
Pure water 30%～40%
Thickening material 0.3%～0.35%
Multifunctional assistant 0.1%～0.2%
Dispersion agent 0.4%～0.6%
Wetting agent 0.1%～0.2%
Skimmer 0.2%～0.3%
Mould inhibitor 0.06%～0.1%
Functional pigment 1.0%～2.0%
Ordinary titanium powder 4.0%～5.0%
Filler 30%～35%
ACRYLIC EMULSION 15%～18%
Film coalescence aid 1.2%～1.5%
Solubility promoter 1.5%～1.8%
Sterilant 0.1%～0.15%.
2. a kind of coating of anti-xanthochromia the according to claim 1 is characterized in that: said thickening material is a Natvosol; Said multifunctional assistant is the PH regulator; Said dispersion agent is the poly carboxylic acid amine salt; Said wetting agent is a nonionogenic tenside; Said skimmer is a mineral oil antifoam agent; Said mould inhibitor is a n-octyl isothiazolinone mould inhibitor; Said functional pigment is a Nano titanium dioxide; Said filler is kaolin and lime carbonate; Said ACRYLIC EMULSION is a modified acrylic acid emulsion; Said membrane-forming agent is a water-soluble film forming agent; Said solubility promoter is a Ucar 35; Said sterilant is a benzisothiazole ketone sterilant.
3. a kind of coating of anti-xanthochromia the according to claim 2 is characterized in that: said modified acrylic acid emulsion carries out modification for utilizing the wet monomer that adheres to that contains siloxy and urea groups to latex polymer.
4. the preparation method of the coating of anti-xanthochromia the as claimed in claim 1 is characterized in that comprising the steps:
Step 1: at ambient temperature, pure water, thickening material, multifunctional assistant are dropped in the reaction kettle, stirred 15 minutes～20 minutes, thickening material is dissolved fully;
Step 2: add dispersion agent, wetting agent, 1/2 skimmer and mould inhibitor stirred 10 minutes～20 minutes;
Step 3: add functional pigment with 1200 rev/mins～1500 rev/mins high speed dispersion 3 minutes～5 minutes;
Step 4: add white titanium pigment and filler with 1500 rev/mins～1800 rev/mins high-speed stirring 15 minutes～20 minutes, to fineness≤70 micron;
Step 5: add ACRYLIC EMULSION, film coalescence aid, solubility promoter, sterilant and remaining 1/2 skimmer, stir and got product in 10 minutes～15 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210232504.7A CN102732116B (en) | 2012-07-06 | 2012-07-06 | Anti-yellowing paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210232504.7A CN102732116B (en) | 2012-07-06 | 2012-07-06 | Anti-yellowing paint and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN102732116A true CN102732116A (en) | 2012-10-17 |
| CN102732116B CN102732116B (en) | 2014-12-24 |
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| CN201210232504.7A Active CN102732116B (en) | 2012-07-06 | 2012-07-06 | Anti-yellowing paint and preparation method thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865346A (en) * | 2014-03-04 | 2014-06-18 | 哈尔滨绿科科技有限公司 | Pollution-free multifunctional external environment-friendly coating as well as preparation method and application of coating |
| CN103881516A (en) * | 2014-04-16 | 2014-06-25 | 雅士利涂料（苏州）有限公司 | One coat paint prepared by organic and inorganic compound emulsion and preparation method thereof |
| CN104293036A (en) * | 2014-09-27 | 2015-01-21 | 安徽铁创新材料科技有限公司 | Weather-resistant water-based paint for building exterior wall decoration and preparation method of water-based paint |
| CN104472506A (en) * | 2014-12-25 | 2015-04-01 | 翎华（上海）国际贸易有限公司 | Formula of 1,2- benzisothiazole-3-ketone compounds |
| CN107216738A (en) * | 2016-03-21 | 2017-09-29 | 台州市黄岩铭志装饰材料有限公司 | A kind of water soluble acrylic acid paint and preparation method thereof |
| CN107674569A (en) * | 2017-11-07 | 2018-02-09 | 浙江高得宝利新材料有限公司 | A kind of preparation method of the environment-friendly water-based polyurethanes insulating moulding coating of color inhibition |
| CN108285710A (en) * | 2018-02-09 | 2018-07-17 | 上海马利画材销售有限公司 | A kind of color compositions and preparation method thereof and purposes |
| CN110643256A (en) * | 2019-09-16 | 2020-01-03 | 山西大学 | Water-based environment-friendly wall paint capable of being repeatedly written with water and preparation method thereof |
| CN112322131A (en) * | 2020-12-04 | 2021-02-05 | 雅士利涂料（苏州）有限公司 | Bright and super-weather-resistant adhesive paint for exterior wall and preparation method thereof |
| CN114015305A (en) * | 2021-11-26 | 2022-02-08 | 九江立帆科技有限公司 | Impact-resistant high-weather-resistance water-based exterior wall surface water-based paint and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103865346A (en) * | 2014-03-04 | 2014-06-18 | 哈尔滨绿科科技有限公司 | Pollution-free multifunctional external environment-friendly coating as well as preparation method and application of coating |
| CN103881516A (en) * | 2014-04-16 | 2014-06-25 | 雅士利涂料（苏州）有限公司 | One coat paint prepared by organic and inorganic compound emulsion and preparation method thereof |
| CN103881516B (en) * | 2014-04-16 | 2016-08-24 | 雅士利涂料（苏州）有限公司 | Paint for priming paint and top lacquer that a kind of organic-inorganic composite emulsion prepares and preparation method thereof |
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| CN104472506A (en) * | 2014-12-25 | 2015-04-01 | 翎华（上海）国际贸易有限公司 | Formula of 1,2- benzisothiazole-3-ketone compounds |
| CN107216738A (en) * | 2016-03-21 | 2017-09-29 | 台州市黄岩铭志装饰材料有限公司 | A kind of water soluble acrylic acid paint and preparation method thereof |
| CN107674569A (en) * | 2017-11-07 | 2018-02-09 | 浙江高得宝利新材料有限公司 | A kind of preparation method of the environment-friendly water-based polyurethanes insulating moulding coating of color inhibition |
| CN108285710A (en) * | 2018-02-09 | 2018-07-17 | 上海马利画材销售有限公司 | A kind of color compositions and preparation method thereof and purposes |
| CN108285710B (en) * | 2018-02-09 | 2020-05-01 | 上海马利画材销售有限公司 | Pigment composition and preparation method and application thereof |
| CN110643256A (en) * | 2019-09-16 | 2020-01-03 | 山西大学 | Water-based environment-friendly wall paint capable of being repeatedly written with water and preparation method thereof |
| CN112322131A (en) * | 2020-12-04 | 2021-02-05 | 雅士利涂料（苏州）有限公司 | Bright and super-weather-resistant adhesive paint for exterior wall and preparation method thereof |
| CN114015305A (en) * | 2021-11-26 | 2022-02-08 | 九江立帆科技有限公司 | Impact-resistant high-weather-resistance water-based exterior wall surface water-based paint and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN102732116B (en) | 2014-12-24 |
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