CN102719048A - Production formula and process of heat-welded pre-wetting-pavement self adhesion type POE (Polyolefin elastomer) waterproof roll subjected to graft modification by maleic anhydride - Google Patents
Production formula and process of heat-welded pre-wetting-pavement self adhesion type POE (Polyolefin elastomer) waterproof roll subjected to graft modification by maleic anhydride Download PDFInfo
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- CN102719048A CN102719048A CN2012101961897A CN201210196189A CN102719048A CN 102719048 A CN102719048 A CN 102719048A CN 2012101961897 A CN2012101961897 A CN 2012101961897A CN 201210196189 A CN201210196189 A CN 201210196189A CN 102719048 A CN102719048 A CN 102719048A
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- waterproof roll
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- maleic anhydride
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Abstract
The invention provides a production formula and a production process of heat-welded pre-wetting-pavement self adhesion type POE (Polyolefin Elastomer) waterproof roll subjected to graft modification by maleic anhydride. The production process comprises the steps of adding all raw materials into an internal mixer according to the formula proportion and uniformly mixing for15min at the mixing temperature being 110 DEG C-130 DEG C, and then discharging; pouring glue on an open mill 560, reducing the temperature to be smaller than or equal to 90 DEG C, filtering impurities by a glue filter, thinning and mixing on an open mill 450, uniformly mixing and then discharging strips; conducting extrusion molding by an extruder, vulcanizing the molded roll in a continuous uniformly which is 20m long under the condition that the temperature is 170 DEG C and the pressure is 0.3MPa; and coating polypropylene fiber, dacron or acrylic on a POE layer subjected to graft modification by maleic anhydride to form a surface layer. The heat-welded pre-wetting-pavement self adhesion type POE (Polyolefin Elastomer) waterproof roll subjected to graft modification by maleic anhydride prepared by the production formula and the production process has the advantages of high strength and thermoplastic fusion property of plastics, the properties of POE, and improved adhesion strength.
Description
Technical field
The present invention relates to a kind of production formula and technology of water-proof material, especially a kind of thermo-welding is prewetted and is spread the production formula and the technology of selfadhesive modified by maleic acid anhydride graft POE waterproof roll.
Background technology
Traditional EPDM rubber waterproof rolling material, chlorinated polyethylene waterproof roll, chlorosuphonated-polyethylene waterproof roll are subordinate to macromolecular sheet material class waterproof roll; The tackiness agent that adopt bonding bonding with sealing tape more; Such adhering method exists the coiled material overlap bonding not firm; Be prone to cracking phenomena, have influence on the whole waterproof effect of coiled material, can not form the waterproof layer of complete one; And tackiness agent and sealing tape can not reach equal work-ing life with the coiled material body, also can have influence on the result of use of waterproof layer.
Summary of the invention
The objective of the invention is to avoid the bonding problem of EPDM rubber waterproof rolling material, chlorinated polyethylene waterproof roll, chlorosuphonated-polyethylene waterproof roll; Make it form whole waterproof layer, and the production formula and the technology that provide a kind of thermo-welding to prewet shop selfadhesive modified by maleic acid anhydride graft POE waterproof roll.
Technical scheme that the present invention adopts is: thermo-welding is prewetted and is spread the production formula and the technology of selfadhesive modified by maleic acid anhydride graft POE waterproof roll, and its production formula is: (weight part)
POE（7380） 100
Maleic anhydride resin 10-30
APP30S 100-150
Light calcium carbonate 200-250
Carbon black N330 20-50
Clorafin 10-20
DOP 10-20
Sulphur 0-5
Anti-aging agent RD 0-5
Antioxidant 4010 0-5
TMTD 0-5。
Best production formula is: (weight part)
POE（7380） 100
Maleic anhydride resin 20
APP30S 100
Light calcium carbonate 220
Carbon black N330 35
Clorafin 10
DOP 20
Sulphur 3
Anti-aging agent RD 5
Antioxidant 4010 5
TMTD 2.5。
The prewet production technique of shop selfadhesive modified by maleic acid anhydride graft POE waterproof roll of described thermo-welding is:
1) press formula rate and add all raw material in the Banbury mixer, the banburying time is 15min, and the banburying temperature is 110-130 ℃, makes it mixing evenly, blowing;
2) fall in 560 mills glue, be cooled to≤90 ℃ after following bar, through the rubber strainer impurity screening, in 450 mills, approach logically, mixing, mixingly descend bar after even;
3) extruder for shaping, the coiled material after the moulding vulcanizes under 170 ℃, the condition of 0.3MPa through 20 meters long endless vulcanization jar;
4) on modified by maleic acid anhydride graft POE layer, covering polypropylene fibre, terylene or acrylic is surface layer.
Compared with prior art, advantage of the present invention is: through formula adjustment, in prescription, introduce the thermoplastics composition; POE sulfuration coiled material is carried out modification, make its HS that had both had plastics, thermoplastification melting property, have the characteristic of POE simultaneously; Can at high temperature weld it, the coiled material after the welding forms an integral body, has solved the bonding problem of macromolecular sheet materials such as EPDM rubber waterproof rolling material; Improved bonding strength, made waterproof layer form the waterproof layer of an integral body.
Embodiment
Thermo-welding is prewetted and is spread the production formula and the technology of selfadhesive modified by maleic acid anhydride graft POE waterproof roll, and production formula is: (weight part)
POE（7380） 100
Maleic anhydride resin 20
APP30S 100
Light calcium carbonate 220
Carbon black N330 35
Clorafin 10
DOP 20
Sulphur 3
Anti-aging agent RD 5
Antioxidant 4010 5
TMTD 2.5。
Production technique, for: 1) press formula rate and add all raw material in the Banbury mixer, the banburying time is 15min, and the banburying temperature is 110-130 ℃, makes it mixing evenly, blowing;
2) fall in 560 mills glue, be cooled to≤90 ℃ after following bar, through the rubber strainer impurity screening, in 450 mills, approach logically, mixing, mixingly descend bar after even;
3) extruder for shaping, the coiled material after the moulding vulcanizes under 170 ℃, the condition of 0.3MPa through 20 meters long endless vulcanization jar;
4) on modified by maleic acid anhydride graft POE layer, covering polypropylene fibre, terylene or acrylic is surface layer.
Get EPDM rubber waterproof rolling material special bonding glue, EPDM rubber waterproof rolling material special adhesive adhesive tape; EPDM rubber waterproof rolling material is carried out adhesive test, and heat-obtaining welds the shop selfadhesive modified by maleic acid anhydride graft POE waterproof roll of prewetting and does the thermo-welding test.
Result's contrast:
Claims (3)
1. thermo-welding is prewetted and is spread the production formula and the technology of selfadhesive modified by maleic acid anhydride graft POE waterproof roll, it is characterized in that production formula is: (weight part)
POE（7380） 100
Maleic anhydride resin 10-30
APP30S?100-150
Light calcium carbonate 200-250
Carbon black N330 20-50
Clorafin 10-20
DOP?10-20
Sulphur 0-5
Anti-aging agent RD 0-5
Antioxidant 4010 0-5
TMTD 0-5。
2. thermo-welding according to claim 1 is prewetted and is spread the production formula and the technology of selfadhesive modified by maleic acid anhydride graft POE waterproof roll, it is characterized in that best production formula is: (weight part)
POE（7380） 100
Maleic anhydride resin 20
APP30S?100
Light calcium carbonate 220
Carbon black N330 35
Clorafin 10
DOP?20
Sulphur 3
Anti-aging agent RD 5
Antioxidant 4010 5
TMTD 2.5。
3. thermo-welding according to claim 1 is prewetted and is spread the production formula and the technology of selfadhesive modified by maleic acid anhydride graft POE waterproof roll, it is characterized in that its production technique is:
1) press formula rate and add all raw material in the Banbury mixer, the banburying time is 15min, and the banburying temperature is 110-130 ℃, makes it mixing evenly, blowing;
2) fall in 560 mills glue, be cooled to≤90 ℃ after following bar, through the rubber strainer impurity screening, in 450 mills, approach logically, mixing, mixingly descend bar after even;
3) extruder for shaping, the coiled material after the moulding vulcanizes under 170 ℃, the condition of 0.3MPa through 20 meters long endless vulcanization jar;
4) on modified by maleic acid anhydride graft POE layer, covering polypropylene fibre, terylene or acrylic is surface layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101961897A CN102719048B (en) | 2012-06-14 | 2012-06-14 | Production formula and process of heat-welded pre-wetting-pavement self adhesion type POE (Polyolefin elastomer) waterproof roll subjected to graft modification by maleic anhydride |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101961897A CN102719048B (en) | 2012-06-14 | 2012-06-14 | Production formula and process of heat-welded pre-wetting-pavement self adhesion type POE (Polyolefin elastomer) waterproof roll subjected to graft modification by maleic anhydride |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102719048A true CN102719048A (en) | 2012-10-10 |
| CN102719048B CN102719048B (en) | 2013-11-27 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2012101961897A Expired - Fee Related CN102719048B (en) | 2012-06-14 | 2012-06-14 | Production formula and process of heat-welded pre-wetting-pavement self adhesion type POE (Polyolefin elastomer) waterproof roll subjected to graft modification by maleic anhydride |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110228253A (en) * | 2019-06-12 | 2019-09-13 | 江苏凯伦建材股份有限公司 | A kind of high barrier sheet and preparation method thereof of fire-retardant puncture resistant |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101033325A (en) * | 2006-03-08 | 2007-09-12 | 广东榕泰实业股份有限公司 | Thermoplastic elastomer compositions and preparation method thereof |
| CN101585940A (en) * | 2009-04-23 | 2009-11-25 | 曹天志 | Method for preparing TZ-POEP-fire-retardant TPO waterproof coiled material |
| CN101585212A (en) * | 2009-04-23 | 2009-11-25 | 曹天志 | A kind of preparation method of TZ-PSBSR thermal weld rubber plastic blend waterproof roll |
-
2012
- 2012-06-14 CN CN2012101961897A patent/CN102719048B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101033325A (en) * | 2006-03-08 | 2007-09-12 | 广东榕泰实业股份有限公司 | Thermoplastic elastomer compositions and preparation method thereof |
| CN101585940A (en) * | 2009-04-23 | 2009-11-25 | 曹天志 | Method for preparing TZ-POEP-fire-retardant TPO waterproof coiled material |
| CN101585212A (en) * | 2009-04-23 | 2009-11-25 | 曹天志 | A kind of preparation method of TZ-PSBSR thermal weld rubber plastic blend waterproof roll |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110228253A (en) * | 2019-06-12 | 2019-09-13 | 江苏凯伦建材股份有限公司 | A kind of high barrier sheet and preparation method thereof of fire-retardant puncture resistant |
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| CN102719048B (en) | 2013-11-27 |
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