CN102703180B - Glass powder lubricant used for hot-rolling of seamless steel pipes - Google Patents
Glass powder lubricant used for hot-rolling of seamless steel pipes Download PDFInfo
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- CN102703180B CN102703180B CN 201210167028 CN201210167028A CN102703180B CN 102703180 B CN102703180 B CN 102703180B CN 201210167028 CN201210167028 CN 201210167028 CN 201210167028 A CN201210167028 A CN 201210167028A CN 102703180 B CN102703180 B CN 102703180B
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- glass powder
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- lubricant
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- powder lubricant
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- 239000000843 powder Substances 0.000 title claims abstract description 67
- 239000011521 glass Substances 0.000 title claims abstract description 63
- 239000000314 lubricant Substances 0.000 title claims abstract description 51
- 229910000831 Steel Inorganic materials 0.000 title abstract description 6
- 239000010959 steel Substances 0.000 title abstract description 6
- 238000005098 hot rolling Methods 0.000 title abstract 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 17
- 229910052582 BN Inorganic materials 0.000 claims abstract description 15
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 12
- 239000000194 fatty acid Substances 0.000 claims description 12
- 229930195729 fatty acid Natural products 0.000 claims description 12
- -1 glycerin fatty acid esters Chemical class 0.000 claims description 12
- 235000011187 glycerol Nutrition 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 238000002156 mixing Methods 0.000 abstract description 12
- 229910021538 borax Inorganic materials 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 238000005261 decarburization Methods 0.000 abstract description 5
- 238000009413 insulation Methods 0.000 abstract description 5
- 239000007788 liquid Substances 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 4
- 239000003292 glue Substances 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 230000001050 lubricating effect Effects 0.000 abstract 2
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 abstract 2
- 239000013543 active substance Substances 0.000 abstract 1
- 125000005456 glyceride group Chemical group 0.000 abstract 1
- 230000017525 heat dissipation Effects 0.000 abstract 1
- 238000003801 milling Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 238000012856 packing Methods 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 7
- 229910001069 Ti alloy Inorganic materials 0.000 description 6
- 238000005242 forging Methods 0.000 description 5
- 239000004328 sodium tetraborate Substances 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 230000003064 anti-oxidating effect Effects 0.000 description 4
- RSCACTKJFSTWPV-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 RSCACTKJFSTWPV-UHFFFAOYSA-N 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000007769 metal material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 238000009785 tube rolling Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000004594 Masterbatch (MB) Substances 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 230000001737 promoting effect Effects 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 235000015110 jellies Nutrition 0.000 description 2
- 239000008274 jelly Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 101150084325 FRS1 gene Proteins 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001192 hot extrusion Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229910000601 superalloy Inorganic materials 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses a glass powder lubricant used for hot-rolling of seamless steel pipes, wherein the glass powder lubricant is characterized by being prepared by the following raw materials: 20-40 parts of glass powder by weight, 5-20 parts of boron nitride by weight, 10-30 parts of sodium borate by weight, and 5-10 parts of fatty glyceride by weight. After being mixed with boron nitride melt and sodium borate melt, the glass powder in the glass powder lubricant can automatically generate a lubricating film which is featured with high property in resisting extreme pressure. The film is liquid mixed glue and has good lubricating property in the pipe hot-milling process at 1000-1200 DEG C after being mixed with an active agent whether the relative sliding velocity of friction couple pairs is large or small, so as to exert the effect of heat dissipation and heat insulation. And meanwhile, oxidization and decarburization are avoided, so that the novel glass powder lubricant is formed by mixing the above components at certain proportions.
Description
Technical field
The present invention relates to the covering property novel lubricant for hot rolled seamless steel tube, particularly for the glass powder lubricant of hot rolled seamless steel tube.
Background technology
Carrying out titanium alloy, superalloy causes inner wall oxide, decarburization easily and oozes hydrogen when stainless steel and other metal materials is rolling.Need a kind of lubricant can play anti-oxidation, as to prevent decarburization, antiseepage hydrogen effect, also need the phenotype drag of good lubricated, adiabatic and reduction forging simultaneously, in the work-ing life of improving mould, forging can obtain higher surface quality.
Chinese patent publication number CN101376142 discloses a kind of glass powder that uses as the production technique of titanium or titanium alloy section bar special lubricant for squeezing, also glass lubricant evenly can be attached on the masterbatch by the form of passing with solid-state form after the masterbatch heating.Glass lubricant plays lubricated, and is anti-oxidation, the effect of protective money metal surface.It also can be applicable to other metallic substance that adds hot-work by extrusion machine.Can also be applied to simultaneously the protection against oxidation layer in the metallic substance forging process.The present invention adds the metallic substance of hot-work with titanium or titanium alloy and other by extrusion machine, and through extrusion machine, extrusion molding has reduced cost significantly, and economic benefit obviously improves; Adopt inexpensive glass powder as lubricant rather than use metallic lubricant, can not cause masterbatch to pollute, improved the section bar surface quality.
Chinese patent publication number CN101735879 discloses a kind of titanium alloy extrusion lubricant and preparation and using method, and lubricant is made up of following compositions by weight percentage: W glass: 60~65%, heat resistant type water soluble cellulose: 20~25%, water: 10~20%.Prepare W glass in proportion, shrend, oven dry obtains the W glass powder through grinding, and with W glass powder, heat resistant type water soluble cellulose, water mixing and ball milling, obtains titanium alloy extrusion lubricant again.This titanium alloy extrusion lubricant use temperature can not be above 1000 ℃.
Chinese patent publication number CN1618566 discloses a kind of squeezing-forging and has met forming technology, and its protecting lubricant that adopts is made up of GL08 glass powder, GL09 glass powder and FRS1 resin glue.This protecting lubricant can only use down at 800 ℃~960 ℃.
Summary of the invention
Technical problem to be solved by this invention is can not be higher than 1000 ℃ problem and a kind of glass powder lubricant is provided at existing lubricant use temperature, the use temperature of this glass powder lubricant is higher than 1000 ℃, in the tube rolling process, can play the resistance to deformation of anti-oxidation, anti-decarburization, antiseepage hydrogen, thermal insulation and reduction forging, and raising die life, play heat radiation and heat insulation effect simultaneously, significantly reduce hot extrusion pipe surface pressing pit, defectives such as ditch bar, roughness value reduces significantly.
Technical problem to be solved by this invention can be achieved through the following technical solutions:
The glass powder lubricant, its feedstock production by following weight part forms: 20~40 parts in glass powder, 5~20 parts of boron nitride, 10~30 parts of boraxs, 5~10 parts of glycerin fatty acid esters.
In a preferred embodiment of the invention, described glass powder lubricant is formed by the feedstock production of following weight part: 40 parts in glass powder, 30 parts of boron nitride, 20 parts of boraxs, 10 parts of glycerin fatty acid esters.
Preparation method of the present invention is: above-mentioned each component materials is mixed, get mixing powder and obtain the regulation granularity by fully effective stirring and processing, packing is preserved, warehouse-in.
The autonomous strong lubricant film of anti-extreme pressure ability that generates of glass powder in the glass powder lubricant of the present invention and boron nitride melting attitude and borax melting attitude mixing energy.This film is the liquid jelly that mixes, with promoting agent be blended in 1000~1200 ℃ of following tube rollings the time friction couple relative sliding velocity when no matter large or small, good lubricity is arranged, can play heat radiation and heat insulation effect.Simultaneously, can be anti-oxidation, anti-decarburization, thus above component mix by a certain percentage, be a kind of novel glass powder lubricant.
Embodiment
Further specify the present invention below in conjunction with embodiment.
Embodiment 1
The glass powder lubricant is formed by the feedstock production of following weight part: 20 parts in glass powder, 5 parts of boron nitride, 10 parts of boraxs, 5 parts of glycerin fatty acid esters; Described promoting agent
The preparation method of glass powder lubricant is: above-mentioned each component materials is mixed, get mixing powder and obtain the regulation granularity by fully effective stirring and processing, packing is preserved, warehouse-in.
Technical parameter
pH 10;
Non-volatile matter (m/m) % 30;
Moisture≤1.0%.
Embodiment 2
The glass powder lubricant is formed by the feedstock production of following weight part: 30 parts in glass powder, 8 parts of boron nitride, 15 parts of boraxs, 8 parts of glycerin fatty acid esters.
The preparation method of glass powder lubricant is: above-mentioned each component materials is mixed, get mixing powder and obtain the regulation granularity by fully effective stirring and processing, packing is preserved, warehouse-in.
Technical parameter
pH 8;
Non-volatile matter (m/m) % 40;
Moisture≤1.0%.
Embodiment 3
The glass powder lubricant is formed by the feedstock production of following weight part: 40 parts in glass powder, 10 parts of boron nitride, 30 parts of boraxs, 10 parts of glycerin fatty acid esters.
The preparation method of glass powder lubricant is: above-mentioned each component materials is mixed, get mixing powder and obtain the regulation granularity by fully effective stirring and processing, packing is preserved, warehouse-in.
Technical parameter
pH 9;
Non-volatile matter (m/m) % 30;
Moisture≤1.0%.
Embodiment 4
The glass powder lubricant is formed by the feedstock production of following weight part: 25 parts in glass powder, 5 parts of boron nitride, 10 parts of boraxs, 5 parts of glycerin fatty acid esters.
The preparation method of glass powder lubricant is: above-mentioned each component materials is mixed, get mixing powder and obtain the regulation granularity by fully effective stirring and processing, packing is preserved, warehouse-in.
Technical parameter
pH 10;
Non-volatile matter (m/m) % 30;
Moisture≤1.5%.
Embodiment 5
The glass powder lubricant is formed by the feedstock production of following weight part: 35 parts in glass powder, 6 parts of boron nitride, 20 parts of boraxs, 6 parts of glycerin fatty acid esters.
The preparation method of glass powder lubricant is: above-mentioned each component materials is mixed, get mixing powder and obtain the regulation granularity by fully effective stirring and processing, packing is preserved, warehouse-in.
Technical parameter
pH 8;
Non-volatile matter (m/m) % 35;
Moisture≤1.0%.
Embodiment 6
The glass powder lubricant is formed by the feedstock production of following weight part: 30 parts in glass powder, 5 parts of boron nitride, 10 parts of boraxs, 5 parts of glycerin fatty acid esters.
The preparation method of glass powder lubricant is: above-mentioned each component materials is mixed, get mixing powder and obtain the regulation granularity by fully effective stirring and processing, packing is preserved, warehouse-in.
Technical parameter
pH 7;
Non-volatile matter (m/m) % 35;
Moisture≤1.5%.
Embodiment 7
The glass powder lubricant is formed by the feedstock production of following weight part: 30 parts in glass powder, 10 parts of boron nitride, 30 parts of boraxs, 10 parts of glycerin fatty acid esters.
The preparation method of glass powder lubricant is: above-mentioned each component materials is mixed, get mixing powder and obtain the regulation granularity by fully effective stirring and processing, packing is preserved, warehouse-in.
Technical parameter
pH 10;
Non-volatile matter (m/m) % 30;
Moisture≤1.5%.
Comparative Examples 1
The glass powder lubricant is prepared from by following raw materials by weight percent: the glass powder of 35% weight, the white solid lubricant agent boron nitride of 10% weight, the borax of 20% weight, the anhydrous sodium sulphate of 25% weight, the glycerin fatty acid ester of 10% weight.
The autonomous strong lubricant film of anti-extreme pressure ability that generates of glass powder in this glass powder lubricant and boron nitride melting attitude and borax melting attitude mixing energy.This film is the liquid jelly that mixes, and when friction couple relative sliding velocity is no matter large or small when 1000~1200 ℃ of following tube rollings, good lubricity is arranged, and can play heat radiation and heat insulation effect.But the sodium sulfate of molten state does not mix mutually, and this moment, there was limitation in the polishing to steel pipe internal-surface.
Comparative Examples 2
The glass powder lubricant is prepared from by following raw materials by weight percent: the glass powder of 40% weight, the sodium metaaluminate of 25% weight, the Borax pentahydrate of 25% weight, the stearic acid of 5% weight, the aluminum oxide of 5% weight
This glass powder lubricant at first generates the liquid inertia oxide film of a kind of inclined to one side borax salt and meta-aluminate after Borax pentahydrate and sodium metaaluminate and the aluminum oxide fusion, mixes with stearic acid with glass powder to have good current lubrication performance under molten state.Restraint tooth bar current of electric load 140A, lubricity is with poor.
Comparative Examples 3
The glass powder lubricant is prepared from by following raw materials by weight percent: the glass powder of 35% weight, the sodium metaaluminate of 25% weight, the Borax pentahydrate of 25% weight, the aluminum oxide of 5% weight, the glycerin fatty acid ester of 10% weight.
Generate the liquid inertia oxide film of a kind of inclined to one side borax salt and meta-aluminate after the Borax pentahydrate of this glass powder lubricant kind and sodium metaaluminate and the aluminum oxide fusion, though under molten state with glass powder mix with promoting agent have certain mobile, lubricity.But can't satisfy the tube rolling demand.Restraint tooth bar current of electric load 153A, lubricity is with poor.
Claims (1)
1. the glass powder lubricant is characterized in that, is formed by the feedstock production of following weight part: 20~40 parts in glass powder, 5~20 parts of boron nitride, 10~30 parts of boraxs, 5~10 parts of glycerin fatty acid esters.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 201210167028 CN102703180B (en) | 2012-05-25 | 2012-05-25 | Glass powder lubricant used for hot-rolling of seamless steel pipes |
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Application Number | Priority Date | Filing Date | Title |
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CN 201210167028 CN102703180B (en) | 2012-05-25 | 2012-05-25 | Glass powder lubricant used for hot-rolling of seamless steel pipes |
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CN102703180A CN102703180A (en) | 2012-10-03 |
CN102703180B true CN102703180B (en) | 2013-10-02 |
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CN 201210167028 Expired - Fee Related CN102703180B (en) | 2012-05-25 | 2012-05-25 | Glass powder lubricant used for hot-rolling of seamless steel pipes |
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Families Citing this family (2)
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CN112658033B (en) * | 2021-01-15 | 2023-02-10 | 北京天力创玻璃科技开发有限公司 | Metal hot-punching glass lubricant and metal hot-punching method |
CN114891553B (en) * | 2022-05-26 | 2023-01-10 | 西安建筑科技大学 | Preparation method of glass lubricant for titanium alloy profile extrusion and glass lubricant |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU696047A1 (en) * | 1977-10-10 | 1979-11-05 | Предприятие П/Я В-8173 | Lubricant for hot metal pressing |
CN1143107A (en) * | 1995-05-16 | 1997-02-19 | 梯姆考而有限公司 | Lubricating agent composition for metal heat working parts |
CN101376142A (en) * | 2008-10-08 | 2009-03-04 | 常荣波 | Technique of using powdered glass as special lubricant for squeezing titanium and titanium alloy sectional material |
-
2012
- 2012-05-25 CN CN 201210167028 patent/CN102703180B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU696047A1 (en) * | 1977-10-10 | 1979-11-05 | Предприятие П/Я В-8173 | Lubricant for hot metal pressing |
CN1143107A (en) * | 1995-05-16 | 1997-02-19 | 梯姆考而有限公司 | Lubricating agent composition for metal heat working parts |
CN101376142A (en) * | 2008-10-08 | 2009-03-04 | 常荣波 | Technique of using powdered glass as special lubricant for squeezing titanium and titanium alloy sectional material |
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