CN102689399B - Molding technology combining PA 610 with metal embedded pieces - Google Patents

Molding technology combining PA 610 with metal embedded pieces Download PDF

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Publication number
CN102689399B
CN102689399B CN201210218038.7A CN201210218038A CN102689399B CN 102689399 B CN102689399 B CN 102689399B CN 201210218038 A CN201210218038 A CN 201210218038A CN 102689399 B CN102689399 B CN 102689399B
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metal insert
temperature
combines
protect
moulding process
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CN102689399A (en
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蒋贤志
蔡彤旻
宁凯军
王大中
叶南飚
陈大华
关安南
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Kingfa Science and Technology Co Ltd
Shanghai Kingfa Science and Technology Co Ltd
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Kingfa Science and Technology Co Ltd
Shanghai Kingfa Science and Technology Co Ltd
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Abstract

The invention discloses a molding technology combining polyamide 610 (PA 610) with metal embedded pieces, which comprises the following steps: (1) before injection molding, pre-heating the metal embedded pieces to enable surface temperature of the metal embedded pieces to be 217 DEG C to 340 DEG C; (2) putting the pre-heated metal embedding pieces into molds for injection molding, wherein the temperature of PA 610 materials is 210 DEG C to 340 DEG C; and (3) pressurizing, cooling and de-molding to obtain end products. The molding technology combining PA 610 with metal embedded pieces can be used for resolving the problems that after plastic-steel combined pieces are molded, metal embedded pieces and molded pieces are easy to fall off due to overlarge internal stress generated around the metal embedded pieces during molding.

Description

The moulding process that a kind of PA610 combines with metal insert
Technical field
The invention belongs to functional high molecule material technical field, be specifically related to the moulding process that a kind of PA610 combines with metal insert.
Background technology
PA610 also known as polyamide 610 or NYLON610, formal name used at school polyhexamethylene sebacamide, PA610 is translucent, creamy white crystals type thermoplastic polymer, and performance is between PA6 and PA66, but relative density is little, has good mechanical strength and toughness; Water imbibition is little, thus good stability of the dimension; Resistance to highly basic, more weak acid resistant, organic solvent-resistant etc., are widely used in mechanical structure parts and can the manufacture of maintenance parts.
For many years, the technique that plastic-steel combines is being used always, comprises in injection moulding process and adds metal insert, plastics carry out metal insert and heat the technique such as press-in.Because the form of the combination of metal insert and plastic is varied; current plastic-steel conjunction often there will be plastic and the stressed caducous problem of steel part in shaping or utilization process; shorten the service life of plastic-steel conjunction greatly, also limit the application of plastic-steel conjunction simultaneously.
For this reason, the plastic-steel combined process of we pin PA610 is studied, sum up PA610 and metal insert in conjunction with time a kind of technological standards.
Summary of the invention
The object of the present invention is to provide the moulding process that a kind of PA610 combines with metal insert, this technique can solve metal insert and stressed caducous problem appears in plastic after shaping.
The present invention is achieved by the following technical solutions:
The moulding process that PA610 combines with metal insert, is characterized in that, comprise the steps:
1) before injection mo(u)lding, metal insert is carried out the pre-heat treatment, make metal insert surface temperature reach 217 DEG C-340 DEG C;
2) metal insert after preheating is put into mould and carry out injection moulding, the temperature of PA610 material is 217 DEG C-340 DEG C;
3) pressurize, cooling, the demoulding and get final product.
Described metal insert is steel, copper or aluminium.
Described injection pressure is 60-80MPa ,the pressure of pressurize is 50-70 MPa, and the dwell time is 10-15s, and cool time is 25-30s.After pressurize terminates, metal insert surface temperature is 217 DEG C-336 DEG C.
Moulding process of the present invention, before injection mo(u)lding, first by clean for metal insert surface clean, afterwards metal insert is put into high temperature oven to heat, by temperature setting and the observed temperature detection of high temperature oven, management and control is carried out to the metal insert temperature in baking oven, makes metal insert surface temperature reach 217 DEG C-340 DEG C, preferably 280 DEG C-330 DEG C; When the metal insert after preheating put into mould carry out injection moulding time, the temperature of PA610 material is 217 DEG C-340 DEG C, preferably 280 DEG C-330 DEG C, surface contact is carried out with the temperature sensor be contained in mould in part surface, by the temperature sensor in mould, monitor the change of metal insert surface temperature in insert injection moulding process in real time; Then product is prepared at the known injection molding process of employing.
The present invention compared with prior art, has following beneficial effect:
The present invention is by studying technique, sum up PA610 material and metal insert in conjunction with time temperature relation, the surface temperature of metal insert is controlled all the time between 217 DEG C-340 DEG C, the temperature of PA610 material is 217 DEG C-340 DEG C time, plastic-steel combines firm, avoids and produce excessive internal stress around metal insert and cause plastic-steel conjunction to occur metal insert and the stressed caducous problem of plastic after shaping when shaping.
Accompanying drawing explanation
Fig. 1 is plastic-steel composition surface viscous force method of testing schematic diagram.
Fig. 2 is the side view of Fig. 1.
Fig. 3 is the top view of Fig. 1.
1, metal insert 2, plastic 3, fixed position 4, thrust direction.
Detailed description of the invention
Further illustrate the present invention below by detailed description of the invention, following examples are the present invention's preferably embodiment, but embodiments of the present invention are not by the restriction of following embodiment.
Plastic-steel faying face of the present invention is that semicircle engages, and the radius R of metal insert is 30mm, is highly 85mm, and the outermost radius R of plastic is 60mm, is highly 55mm.Before injection mo(u)lding, the P20 metal insert surface clean by surface roughness being Ra0.05 is clean, metal insert is put into high temperature oven heat, by temperature setting and the observed temperature detection of high temperature oven, carry out management and control to the metal insert temperature in baking oven, metal insert surface temperature is as shown in table 1; When the metal insert after preheating put into mould carry out injection moulding time, surface contact is carried out with the temperature sensor be contained in mould in metal insert surface, by the temperature sensor in mould, the in real time change of metallic surface temperature in monitoring insert injection moulding process; Namely last pressurize, cooling, the demoulding obtain product, and during pressurize, the environment temperature in the external world is room temperature, and it is as shown in table 1 that pressurize terminates rear metal insert surface temperature, injection pressure, dwell pressure dwell time, cool time.
Product after shaping is placed 24 hours, allows PA610 arrive stable, then plastic-steel conjunction is carried out thrust test.Acquired results is as shown in table 1.
Viscous force method of testing is as follows:
As Figure 1-3, after product after shaping places 24 hours, fixing plastic two ends, then promote by a power perpendicular to metal insert and inserts central plane at the upper and lower side of metal insert, come until metal insert and plastic depart from, in the process promoted the maximum thrust that is separated of plastic, thus the scope of maximum combined power that under drawing different condition, plastic-steel combines.
Table 1
Metal insert surface temperature (DEG C) PA610 material temperature (DEG C) Surface temperature (DEG C) after metal insert pressurize terminates Molding parameter: injection pressure MPa(P Note), packing pressure MPa(P Protect), dwell time S(S Protect), cool time S(S Cold Plastic-steel is in conjunction with maximum thrust (N)
Comparative example 1 Q=30 300 Q=163 P Note=72, P Protect=65, S Protect=12, S Cold=26 F=11
Comparative example 2 Q=180 280 Q=226 P Note=72, P Protect=65, S Protect=12, S Cold=26 F=22
Comparative example 3 Q=200 260 Q=227 P Note=78, P Protect=65, S Protect=12, S Cold=26 F=38
Comparative example 4 Q=210 280 Q=143 P Note=78, P Protect=65, S Protect=12, S Cold=26 F=40
Comparative example 5 Q=360 360 Q=353 P Note=68, P Protect=65, S Protect=12, S Cold=29 F=35
Comparative example 6 Q=370 340 Q=355 P Note=68, P Protect=65, S Protect=12, S Cold=29 F=33
Comparative example 7 Q=360 280 Q=318 P Note=78, P Protect=65, S Protect= 12 ,S Cold=26 F=38
Comparative example 8 Q=370 250 Q=308 P Note=78, P Protect=65, S Protect= 12 ,S Cold=26 F=40
Embodiment 1 Q=217 300 Q=256 P Note=78, P Protect=65, S Protect= 12 ,S Cold=26 F=46
Embodiment 2 Q=340 335 Q=336 P Note=78, P Protect=65, S Protect= 12 ,S Cold=26 F=47
Embodiment 3 Q=330 217 Q=272 P Note=78, P Protect=65, S Protect= 12 ,S Cold=26 F=48
Embodiment 4 Q=270 340 Q=303 P Note=68, P Protect=65, S Protect= 12, S Cold=26 F=49
Embodiment 5 Q=225 230 Q=223 P Note=78, P Protect=68, S Protect=12, S Cold=22 F=46
Embodiment 6 Q=256 267 Q=257 P Note=78, P Protect=68, S Protect=12, S Cold=22 F=48
Embodiment 7 Q=278 283 Q=278 P Note=78, P Protect=68, S Protect=12, S Cold=22 F=53
Embodiment 8 Q=280 309 Q=295 P Note=70, P Protect=68, S Protect=12, S Cold=27 F=55
Embodiment 9 Q=313 330 Q=319 P Note=70, P Protect=68, S Protect=12, S Cold=27 F=56
Embodiment 10 Q=330 280 Q=301 P Note=70, P Protect=68, S Protect=12, S Cold=27 F=53
As can be seen from the result of above-described embodiment and comparative example, when PA610 combines with metal insert, when metal insert surface temperature metal insert surface temperature between 217 DEG C-340 DEG C or in injection moulding process finally reaches between 217 DEG C-340 DEG C, the maximum combined power F > 45N that plastic-steel combines; Metal insert surface temperature remains between 280 DEG C-330 DEG C, the temperature of PA610 material 280 DEG C-330 DEG C time, plastic-steel combine maximum combined power F > 50N.

Claims (6)

1. the moulding process that combines with metal insert of PA610, is characterized in that, comprise the steps:
1) before injection mo(u)lding, metal insert is carried out the pre-heat treatment, make metal insert surface temperature reach 217 DEG C-340 DEG C;
2) metal insert after preheating is put into mould and carry out injection moulding, the temperature of PA610 material is 217 DEG C-340 DEG C;
3) pressurize, cooling, the demoulding and get final product;
Wherein, after pressurize terminates, metal insert surface temperature is 217 DEG C-336 DEG C.
2. the moulding process that combines with metal insert of PA610 according to claim 1, is characterized in that, step 2) when carrying out injection moulding, metal insert surface temperature is 280 DEG C-330 DEG C, and the temperature of PA610 material is 280 DEG C-330 DEG C.
3. the moulding process that combines with metal insert of PA610 according to claim 1, it is characterized in that, described metal insert is steel, copper or aluminium.
4. the moulding process that combines with metal insert of PA610 according to claim 1, it is characterized in that, described the pre-heat treatment metal insert is put into high temperature oven heat, by temperature setting and the observed temperature detection of high temperature oven, management and control is carried out to the metal insert temperature in baking oven.
5. the moulding process that combines with metal insert of PA610 according to claim 1, it is characterized in that, step 2) in the metal insert after preheating put into mould carry out injection moulding time, surface contact is carried out with the temperature sensor be contained in mould in metal insert surface, in real time the change of monitoring metal insert surface temperature in injection moulding process.
6. the moulding process that combines with metal insert of PA610 according to claim 1, it is characterized in that, described injection pressure is 60-80 mPa,the pressure of pressurize is 50-70 mPa, the dwell time is 10-15s, and cool time is 25-30s.
CN201210218038.7A 2012-06-28 2012-06-28 Molding technology combining PA 610 with metal embedded pieces Active CN102689399B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1107939A (en) * 1994-07-21 1995-09-06 武进县五星农机配件有限公司 Oil tank, gearbox cover, back head and top head for single-cylinder diesel engine
EP1342547A1 (en) * 2002-03-09 2003-09-10 Demag Ergotech GmbH Check valve
CN1469500A (en) * 2002-07-17 2004-01-21 山 黄 Composite leading and collecting plate for fuel cell and its manufacture

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006076483A1 (en) * 2005-01-14 2006-07-20 Tyco Electronics Corporation Insert injection-compression molding of polymeric ptc electrical devices

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1107939A (en) * 1994-07-21 1995-09-06 武进县五星农机配件有限公司 Oil tank, gearbox cover, back head and top head for single-cylinder diesel engine
EP1342547A1 (en) * 2002-03-09 2003-09-10 Demag Ergotech GmbH Check valve
CN1469500A (en) * 2002-07-17 2004-01-21 山 黄 Composite leading and collecting plate for fuel cell and its manufacture

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