CN102689399A - Molding technology combining PA 610 with metal embedded pieces - Google Patents

Molding technology combining PA 610 with metal embedded pieces Download PDF

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Publication number
CN102689399A
CN102689399A CN2012102180387A CN201210218038A CN102689399A CN 102689399 A CN102689399 A CN 102689399A CN 2012102180387 A CN2012102180387 A CN 2012102180387A CN 201210218038 A CN201210218038 A CN 201210218038A CN 102689399 A CN102689399 A CN 102689399A
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China
Prior art keywords
metal insert
temperature
combines
moulding process
protect
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CN2012102180387A
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CN102689399B (en
Inventor
蒋贤志
蔡彤旻
宁凯军
王大中
叶南飚
陈大华
关安南
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Kingfa Science and Technology Co Ltd
Shanghai Kingfa Science and Technology Co Ltd
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Kingfa Science and Technology Co Ltd
Shanghai Kingfa Science and Technology Co Ltd
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Abstract

The invention discloses a molding technology combining polyamide 610 (PA 610) with metal embedded pieces, which comprises the following steps: (1) before injection molding, pre-heating the metal embedded pieces to enable surface temperature of the metal embedded pieces to be 217 DEG C to 340 DEG C; (2) putting the pre-heated metal embedding pieces into molds for injection molding, wherein the temperature of PA 610 materials is 210 DEG C to 340 DEG C; and (3) pressurizing, cooling and de-molding to obtain end products. The molding technology combining PA 610 with metal embedded pieces can be used for resolving the problems that after plastic-steel combined pieces are molded, metal embedded pieces and molded pieces are easy to fall off due to overlarge internal stress generated around the metal embedded pieces during molding.

Description

The moulding process that a kind of PA610 combines with metal insert
Technical field
The invention belongs to the functional high molecule material technical field, be specifically related to the moulding process that a kind of PA610 combines with metal insert.
Background technology
PA610 claims polyamide 6 10 or NYLON610 again, and formal name used at school polyhexamethylene sebacamide, PA610 are translucent, milky crystal type thermoplastic polymers, and performance is between PA6 and PA66, but relative density is little, has mechanical strength and toughness preferably; Water imbibition is little, thereby dimensional stability is good; Anti-highly basic, weak acid resistant more, organic solvent-resistant etc., but be widely used in the manufacturing of mechanical structure parts and maintenance parts.
For many years, the technology that plastic-steel combines use always, comprises that adding metal insert, plastics in the injection moulding process carries out metal insert and heat and technology such as be pressed into.Because metal insert is varied with the form that combines of plastic; Present plastic-steel conjunction plastic and the stressed caducous problem of steel part occur through regular meeting in moulding or utilization process; Shorten the service life of plastic-steel conjunction greatly, also limited the application of plastic-steel conjunction simultaneously.
For this reason, the plastic-steel combined process of we pin PA610 is studied, and sums up a kind of technological standards of PA610 when combining with metal insert.
Summary of the invention
The moulding process that the object of the present invention is to provide a kind of PA610 to combine with metal insert, this technology can solve metal insert and stressed caducous problem appears in plastic after moulding.
The present invention realizes through following technical scheme:
The moulding process that a kind of PA610 combines with metal insert is characterized in that, comprises the steps:
1) before the injection mo(u)lding, metal insert is carried out The pre-heat treatment, make the metal insert surface temperature reach 217 ℃-340 ℃;
2) put into mould to the metal insert after the preheating and carry out injection moulding, the temperature of PA610 material is 217 ℃-340 ℃;
3) pressurize, cooling, the demoulding promptly get.
Said metal insert is steel, copper or aluminium.
Said injection pressure is 60-80MPa ,The pressure of pressurize is 50-70 MPa, and the dwell time is 10-15s, and be 25-30s cool time.Finishing back metal insert surface temperature in pressurize is 217 ℃-336 ℃.
Moulding process of the present invention; Before injection mo(u)lding, earlier that the metal insert surface clean is clean, the back is put into high temperature oven to metal insert and is heated; Set and the observed temperature detection through the temperature of high temperature oven; Come the metal insert temperature in the baking oven is carried out management and control, make the metal insert surface temperature reach 217 ℃-340 ℃, preferred 280 ℃-330 ℃; When the metal insert after the preheating is put into mould and is carried out injection moulding; The temperature of PA610 material is 217 ℃-340 ℃; Preferred 280 ℃-330 ℃; The part surface temperature sensor interior with being contained in mould carries out the surface and contacts, and through the temperature sensor in the mould, monitors the variation of metal insert surface temperature in the inserts injection moulding process in real time; Adopting known injection molding process to prepare product then.
The present invention compared with prior art has following beneficial effect:
The present invention is through studying technology; Sum up the temperature relation of PA610 material when combining with metal insert; The surface temperature of metal insert is controlled between 217 ℃-340 ℃ all the time; The temperature of PA610 material is in the time of 217 ℃-340 ℃, and plastic-steel combines firmly, when moulding, has avoided producing excessive internal stress and causing the plastic-steel conjunction metal insert and the stressed caducous problem of plastic after moulding, to occur around the metal insert.
Description of drawings
Fig. 1 is a plastic-steel composition surface viscous force method of testing sketch map.
Fig. 2 is the side view of Fig. 1.
Fig. 3 is the vertical view of Fig. 1.
1, metal insert 2, plastic 3, fixed position 4, thrust direction.
The specific embodiment
Further specify the present invention through the specific embodiment below, following examples are preferred implementation of the present invention, but embodiment of the present invention does not receive the restriction of following embodiment.
Plastic-steel faying face of the present invention is that semicircle engages, and the radius R of metal insert is 30mm, highly is 85mm, and the peripheral radius R of plastic is 60mm, highly is 55mm.Before injection mo(u)lding; With surface roughness is that the P20 metal insert surface clean of Ra0.05 is clean; Putting into high temperature oven to metal insert heats; Set and the observed temperature detection through the temperature of high temperature oven, come the metal insert temperature in the baking oven is carried out management and control, the metal insert surface temperature is as shown in table 1; When the metal insert after the preheating was put into mould and carried out injection moulding, the metal insert surface temperature sensor interior with being contained in mould carried out the surface and contacts, and through the temperature sensor in the mould, monitors the variation of metallic surface temperature in the inserts injection moulding process in real time; Last pressurize, cooling, the demoulding promptly get product, and environment temperature extraneous during pressurize is a room temperature, and it is as shown in table 1 that pressurize finishes afterwards metal insert surface temperature, injection pressure, dwell pressure dwell time, cool time.
Product after the moulding was placed 24 hours, and it is stable to let PA610 arrive, and carries out the thrust test to the plastic-steel conjunction then.The gained result is as shown in table 1.
The viscous force method of testing is following:
Shown in Fig. 1-3; After the product after the moulding is placed 24 hours; Fixing plastic two ends, the upper and lower side at metal insert promotes with the power perpendicular to metal insert and inserts central plane then, breaks away from up to metal insert and plastic and comes; In the process that promotes, get the maximum thrust that plastic separates, thereby draw the scope of the maximum combined power that plastic-steel combines under the different condition.
Table 1
? The metal insert surface temperature (℃) The PA610 material temperature (℃) Surface temperature after the metal insert pressurize finishes (℃) Molding parameter: injection pressure MPa (P Annotate), packing pressure MPa (P Protect), dwell time S (S Protect), cool time S (S Cold Plastic-steel combines maximum thrust (N)
Comparative Examples 1 Q=30 300 Q=163 P Annotate=72, P Protect=65, S Protect=12, S Cold=26 ?F=11
Comparative Examples 2 Q=180 280 Q=226 P Annotate=72, P Protect=65, S Protect=12, S Cold=26 F=22
Comparative Examples 3 Q=200 260 Q=227 P Annotate=78, P Protect=65, S Protect=12, S Cold=26 F=38
Comparative Examples 4 Q=210 280 Q=143 P Annotate=78, P Protect=65, S Protect=12, S Cold=26 F=40
Comparative Examples 5 Q=360 360 Q=353 P Annotate=68, P Protect=65, S Protect=12, S Cold=29 F=35
Comparative Examples 6 Q=370 340 Q=355 P Annotate=68, P Protect=65, S Protect=12, S Cold=29 F=33
Comparative Examples 7 Q=360 280 Q=318 P Annotate=78, P Protect=65, S Protect= 12 ,S Cold=26 F=38
Comparative Examples 8 Q=370 250 Q=308 P Annotate=78, P Protect=65, S Protect= 12 ,S Cold=26 F=40
Embodiment 1 Q=217 300 Q=256 P Annotate=78, P Protect=65, S Protect= 12 ,S Cold=26 F=46
Embodiment 2 Q=340 335 Q=336 P Annotate=78, P Protect=65, S Protect= 12 ,S Cold=26 F=47
Embodiment 3 Q=330 217 Q=272 P Annotate=78, P Protect=65, S Protect= 12 ,S Cold=26 F=48
Embodiment 4 Q=270 340 Q=303 P Annotate=68, P Protect=65, S Protect= 12, S Cold=26 F=49
Embodiment 5 Q=225 230 Q=223 P Annotate=78, P Protect=68, S Protect=12, S Cold=22 F=46
Embodiment 6 Q=256 267 Q=257 P Annotate=78, P Protect=68, S Protect=12, S Cold=22 F=48
Embodiment 7 Q=278 283 Q=278 P Annotate=78, P Protect=68, S Protect=12, S Cold=22 F=53
Embodiment 8 Q=280 309 Q=295 P Annotate=70, P Protect=68, S Protect=12, S Cold=27 F=55
Embodiment 9 Q=313 330 Q=319 P Annotate=70, P Protect=68, S Protect=12, S Cold=27 F=56
Embodiment 10 Q=330 280 Q=301 P Annotate=70, P Protect=68, S Protect=12, S Cold=27 F=53
Result by the foregoing description and Comparative Examples can find out; When PA610 combines with metal insert; When the metal insert surface temperature finally reaches between 217 ℃-340 ℃ in metal insert surface temperature between 217 ℃-340 ℃ or in injection moulding process, maximum combined power F>45N that plastic-steel combines; The metal insert surface temperature remains between 280 ℃-330 ℃, the temperature of PA610 material in the time of 280 ℃-330 ℃, maximum combined power F>50N that plastic-steel combines.

Claims (7)

1. the moulding process that PA610 combines with metal insert is characterized in that, comprises the steps:
1) before the injection mo(u)lding, metal insert is carried out The pre-heat treatment, make the metal insert surface temperature reach 217 ℃-340 ℃;
2) put into mould to the metal insert after the preheating and carry out injection moulding, the temperature of PA610 material is 217 ℃-340 ℃;
3) pressurize, cooling, the demoulding promptly get.
2. the moulding process that PA610 according to claim 1 combines with metal insert is characterized in that step 2) when carrying out injection moulding, the metal insert surface temperature is 280 ℃-330 ℃, the temperature of PA610 material is 280 ℃-330 ℃.
3. the moulding process that PA610 according to claim 1 combines with metal insert is characterized in that, said metal insert is steel, copper or aluminium.
4. the moulding process that PA610 according to claim 1 combines with metal insert; It is characterized in that; Said The pre-heat treatment is to put into high temperature oven to metal insert to heat; Set and the observed temperature detection through the temperature of high temperature oven, come the metal insert temperature in the baking oven is carried out management and control.
5. the moulding process that PA610 according to claim 1 combines with metal insert; It is characterized in that; When putting into the metal insert after the preheating mould and carry out injection moulding step 2); The metal insert surface temperature sensor interior with being contained in mould carries out the surface and contacts, and monitors the variation of metal insert surface temperature in injection moulding process in real time.
6. the moulding process that PA610 according to claim 1 combines with metal insert is characterized in that, said injection pressure is 60-80MPa ,The pressure of pressurize is 50-70 MPa, and the dwell time is 10-15s, and be 25-30s cool time.
7. the moulding process that PA610 according to claim 1 combines with metal insert is characterized in that, finishing back metal insert surface temperature in pressurize is 217 ℃-336 ℃.
CN201210218038.7A 2012-06-28 2012-06-28 Molding technology combining PA 610 with metal embedded pieces Active CN102689399B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1107939A (en) * 1994-07-21 1995-09-06 武进县五星农机配件有限公司 Oil tank, gearbox cover, back head and top head for single-cylinder diesel engine
EP1342547A1 (en) * 2002-03-09 2003-09-10 Demag Ergotech GmbH Check valve
CN1469500A (en) * 2002-07-17 2004-01-21 山 黄 Composite leading and collecting plate for fuel cell and its manufacture
US20060157891A1 (en) * 2005-01-14 2006-07-20 Tyco Electronics Corporation Insert injection-compression molding of polymeric PTC electrical devices

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1107939A (en) * 1994-07-21 1995-09-06 武进县五星农机配件有限公司 Oil tank, gearbox cover, back head and top head for single-cylinder diesel engine
EP1342547A1 (en) * 2002-03-09 2003-09-10 Demag Ergotech GmbH Check valve
CN1469500A (en) * 2002-07-17 2004-01-21 山 黄 Composite leading and collecting plate for fuel cell and its manufacture
US20060157891A1 (en) * 2005-01-14 2006-07-20 Tyco Electronics Corporation Insert injection-compression molding of polymeric PTC electrical devices

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