CN102660416B - Solid detergent for automotive windshield and preparation method for solid detergent - Google Patents
Solid detergent for automotive windshield and preparation method for solid detergent Download PDFInfo
- Publication number
- CN102660416B CN102660416B CN 201210131394 CN201210131394A CN102660416B CN 102660416 B CN102660416 B CN 102660416B CN 201210131394 CN201210131394 CN 201210131394 CN 201210131394 A CN201210131394 A CN 201210131394A CN 102660416 B CN102660416 B CN 102660416B
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- CN
- China
- Prior art keywords
- parts
- sodium
- solid detergent
- windshield
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000013042 solid detergent Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 28
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims abstract description 17
- COHYTHOBJLSHDF-UHFFFAOYSA-N Indigo Chemical compound N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 15
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 15
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 15
- 239000011734 sodium Substances 0.000 claims abstract description 15
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims abstract description 3
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims description 14
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 14
- 229940097275 indigo Drugs 0.000 claims description 14
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 14
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 14
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 12
- 239000012467 final product Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 7
- -1 olefin sulfonate Chemical class 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 239000011521 glass Substances 0.000 abstract description 9
- 239000012459 cleaning agent Substances 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract 1
- 230000003373 anti-fouling effect Effects 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
- 235000015165 citric acid Nutrition 0.000 description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to a technology for preparing a cleaning agent and discloses a convenient-to-transport solid detergent for an automotive windshield and a preparation method for the solid detergent. The detergent comprises the following components in part by weight: 30 to 60 parts of sodium alpha-olefin sulfonate, 5 to 15 parts of sodium dodecyl sulfate, 20 to 30 parts of sodium bicarbonate, 5 to 15 parts of citric acid, 0.1 to 0.5 part of titanium isopropoxide, 0.2 to 1 part of polyvinyl alcohol and 0.01 to 0.05 part of indigo blue. The solid detergent has the advantages of low cost and convenience in transport, and ensures that automotive glass has high antifouling capacity and has a self-cleaning function, and the transportation cost is greatly reduced.
Description
Technical field
The present invention relates to a kind of clean-out system technology of preparing, relate in particular to a kind of convenient transportation solid type windshield washing composition and preparation method.
Background technology
Vehicle glass is easily dirty, is infected with dust, oil stain, animal excrement, worm ant corpse etc., not only affects sight line and attractive in appearance, but also might cause serious accident.In addition, winter, frost, summer rainwater directly affected officer's the visual field especially, and potential safety hazard can not be ignored.Various glass cleaners (automobile windscreen cleaning agent, CN101921663 have been developed for the many people of the problems referred to above; Antistatic automobile glass cleaning agent, CN 101798550 etc.).Then existing automobile glass cleaning agent overwhelming majority composition is pure water, pack very large, cause retailer, human consumer energy, manpower in transportation to waste huge, transportation, operation cost have greatly been increased, in exit procedure, the actual effective constituent of the glass cleaner of a freight container only has the amount of a luggage especially.Therefore, demand the glass cleaner of development of new urgently.
Summary of the invention
The purpose of this invention is to provide a kind of with low costly, convenient transportation realizes that transportation cost significantly descends, and makes the vehicle glass stain resistance high, and has windshield solid detergent of self-cleaning function and preparation method thereof.
In order to solve the problems of the technologies described above, the present invention is solved by following technical proposals:
The windshield solid detergent, contain the component of following weight part:
α-sodium olefin sulfonate 30-60 part;
Sodium laurylsulfonate 5-15 part;
Sodium bicarbonate 20-30 part;
Citric acid 5-15 part;
Titanium isopropylate 0.1-0.5 part;
Polyvinyl alcohol 0.2-1 part;
Indigo 0.01-0.05 part.
The preparation method of above-mentioned windshield solid detergent is as follows:
Stirred 1-5 minute after the titanium isopropylate of above-mentioned weight part is added polyvinyl alcohol, add successively α-sodium olefin sulfonate, sodium laurylsulfonate, sodium bicarbonate, citric acid, the indigo continuation of corresponding weight part to stir after 5-10 minute, get final product with die stamping.
The present invention has significant technique effect owing to having adopted above technical scheme:
1, windshield solid detergent of the present invention is high concentrated, solid, and compared with prior art packing, convenient transportation, reduced transport energy, the waste of manpower and the use of packaging bottle;
2, windshield solid detergent of the present invention is owing to containing titanium isopropylate, this material can be decomposed into titanium dioxide under the effect of citric acid, can form the layer of titanium dioxide film before windshield, can realize self-cleaning function, the frost that is not easy in the winter time to freeze, summer not allow to be subject to the misty rain impact;
3, windshield solid detergent of the present invention environmental protection, the nonirritant composition can delay wiper blade rubbers aging.
4, windshield solid detergent of the present invention is with low cost, directly puts into the wiper sanitising agent groove before automobile in the time of use, then fills water and get final product, uses afterwards without solid residue.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail:
Embodiment 1
A kind of windshield solid detergent is made of by weight following component:
30 parts of α-sodium olefin sulfonates;
15 parts of sodium laurylsulfonates;
20 parts of sodium bicarbonates;
5 parts of citric acids;
0.1 part of titanium isopropylate;
0.2 part of polyvinyl alcohol;
Indigo 0.01 part
Its preparation method is as follows:
After being added 0.2 part of polyvinyl alcohol, stirred 1 minute 0.1 part of titanium isopropylate, add successively 30 parts of α-sodium olefin sulfonates, 15 parts of sodium laurylsulfonates, 20 parts of sodium bicarbonates, 5 parts of citric acids, 0.01 part of indigo rear continuation to stir after 5 minutes, get final product with die stamping.
Mold shape used is right cylinder.
Embodiment 2
A kind of windshield solid detergent is made of by weight following component:
60 parts of α-sodium olefin sulfonates;
5 parts of sodium laurylsulfonates;
30 parts of sodium bicarbonates;
15 parts of citric acids;
0.5 part of titanium isopropylate;
1 part of polyvinyl alcohol;
Indigo 0.05 part
Its preparation method is as follows:
Stirred 5 minutes after 0.5 part of titanium isopropylate is added 1 part of polyvinyl alcohol, add successively 60 parts of α-sodium olefin sulfonates, 5 parts of sodium laurylsulfonates, 30 parts of sodium bicarbonates, 15 parts of citric acids, 0.05 part of indigo continuation to stir after 10 minutes, get final product with die stamping.
Mould therefor is shaped as rectangular parallelepiped.
Embodiment 3
A kind of windshield solid detergent is made of by weight following component:
45 parts of α-sodium olefin sulfonates;
10 parts of sodium laurylsulfonates;
25 parts of sodium bicarbonates;
10 parts of citric acids;
0.3 part of titanium isopropylate;
0.6 part of polyvinyl alcohol;
Indigo 0.03 part
Its preparation method is as follows:
Stirred 3 minutes after 0.3 part of titanium isopropylate is added 0.6 part of polyvinyl alcohol, add successively 45 parts of α-sodium olefin sulfonates, 10 parts of sodium laurylsulfonates, 25 parts of sodium bicarbonates, 10 parts of citric acids, 0.03 part of indigo continuation to stir after 8 minutes, get final product with die stamping.
Mould therefor is shaped as spherosome.
Embodiment 4
A kind of windshield solid detergent is made of by weight following component:
30 parts of α-sodium olefin sulfonates;
5 parts of sodium laurylsulfonates;
20 parts of sodium bicarbonates;
5 parts of citric acids;
0.1 part of titanium isopropylate;
0.2 part of polyvinyl alcohol;
Indigo 0.01 part
Its preparation method is as follows:
Stirred 1 minute after 0.1 part of titanium isopropylate is added 0.2 part of polyvinyl alcohol, add successively 30 parts of α-sodium olefin sulfonates, 5 parts of sodium laurylsulfonates, 20 parts of sodium bicarbonates, 5 parts of citric acids, 0.01 part of indigo rear continuation to stir after 3 minutes, get final product with die stamping.
Mold shape used is rectangular parallelepiped.
Embodiment 5
A kind of windshield solid detergent is made of by weight following component:
60 parts of α-sodium olefin sulfonates;
15 parts of sodium laurylsulfonates;
30 parts of sodium bicarbonates;
15 parts of citric acids;
0.5 part of titanium isopropylate;
1 part of polyvinyl alcohol;
Indigo 0.05 part
Its preparation method is as follows:
Stirred 1 minute after 0.5 part of titanium isopropylate is added 1 part of polyvinyl alcohol, add successively 60 parts of α-sodium olefin sulfonates, 15 parts of sodium laurylsulfonates, 30 parts of sodium bicarbonates, 15 parts of citric acids, 0.05 part of indigo rear continuation to stir after 5 minutes, get final product with die stamping.
Mold shape used is spherosome.
Use the product of above-mentioned 5 embodiment gained, glass surface is transparent, and without hanging the globule, fog, frost phenomenon, the bead of more crucial an is 10g can be converted the pure water more than 5L, has reduced transportation cost, and is easy to carry.
In a word, the above is only preferred embodiment of the present invention, and all equalizations of doing according to the present patent application the scope of the claims change and modify, and all should belong to the covering scope of patent of the present invention.
Claims (2)
1. the windshield solid detergent, is characterized in that, is comprised of the component of following weight part:
α-sodium olefin sulfonate 30-60 part;
Sodium laurylsulfonate 5-15 part;
Sodium bicarbonate 20-30 part;
Citric acid 5-15 part;
Titanium isopropylate 0.1-0.5 part;
Polyvinyl alcohol 0.2-1 part;
Indigo 0.01-0.05 part.
2. the preparation method of windshield solid detergent according to claim 1, is characterized in that, described method is as follows:
Stirred 1-5 minute after the titanium isopropylate of above-mentioned weight part is added polyvinyl alcohol, add successively α-sodium olefin sulfonate, sodium laurylsulfonate, sodium bicarbonate, citric acid, the indigo continuation of corresponding weight part to stir after 5-10 minute, get final product with die stamping.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210131394 CN102660416B (en) | 2012-05-02 | 2012-05-02 | Solid detergent for automotive windshield and preparation method for solid detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210131394 CN102660416B (en) | 2012-05-02 | 2012-05-02 | Solid detergent for automotive windshield and preparation method for solid detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102660416A CN102660416A (en) | 2012-09-12 |
| CN102660416B true CN102660416B (en) | 2013-06-12 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201210131394 Expired - Fee Related CN102660416B (en) | 2012-05-02 | 2012-05-02 | Solid detergent for automotive windshield and preparation method for solid detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102660416B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103897888A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Residue-free detergent |
| CN103087858B (en) * | 2013-02-06 | 2014-05-21 | 厦门富可汽车配件有限公司 | Solid glass cleaner and processing method thereof |
| CN103820228B (en) * | 2014-02-20 | 2016-04-06 | 苏州龙腾万里化工科技有限公司 | A kind of glass cleaner composition |
| CN107805552A (en) * | 2017-11-14 | 2018-03-16 | 广州沿江科技有限公司 | A kind of windshield solid cleaning agent and preparation method thereof |
| CN108373948A (en) * | 2018-02-05 | 2018-08-07 | 安阳工学院 | A kind of full efficiency vehicle glass water |
| CN110846139A (en) * | 2019-12-07 | 2020-02-28 | 安徽克菱保健科技有限公司 | Solid glass water |
| CN111088116A (en) * | 2019-12-20 | 2020-05-01 | 佛山科学技术学院 | Cleaning agent for automobile windshield and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100395324C (en) * | 2006-09-01 | 2008-06-18 | 王涛 | Synthetic detergent and its preparation method |
| CN102181326A (en) * | 2011-04-01 | 2011-09-14 | 中国铁道科学研究院金属及化学研究所 | Glass cleaner and application thereof |
-
2012
- 2012-05-02 CN CN 201210131394 patent/CN102660416B/en not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| CN102660416A (en) | 2012-09-12 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: ZHEJIANG SOUTHEAST RUBBER CORPORATION Free format text: FORMER NAME: ZHEJIANG DONGNAN RUBBER MACHINE BELT CO., LTD. |
|
| CP03 | Change of name, title or address |
Address after: 317100, No. 9, Zhujiang East Road, pearl Ao Town, three counties, Taizhou, Zhejiang Patentee after: ZHEJIANG SOUTHEAST RUBBER Corp. Address before: 317101, No. 9, Zhujiang East Road, pearl Ao Town, three counties, Taizhou, Zhejiang Patentee before: Zhejiang Dongnan Rubber Belt Co.,Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130612 |