CN102660190A - Ultraviolet (UV) metal decorating base oil - Google Patents
Ultraviolet (UV) metal decorating base oil Download PDFInfo
- Publication number
- CN102660190A CN102660190A CN201210161676XA CN201210161676A CN102660190A CN 102660190 A CN102660190 A CN 102660190A CN 201210161676X A CN201210161676X A CN 201210161676XA CN 201210161676 A CN201210161676 A CN 201210161676A CN 102660190 A CN102660190 A CN 102660190A
- Authority
- CN
- China
- Prior art keywords
- oil
- percent
- mixture
- tin graphed
- graphed sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Wrappers (AREA)
Abstract
The invention discloses ultraviolet (UV) metal decorating base oil. The UV metal decorating base oil consists of the following components in percentage by weight: 30 to 60 percent of modified acrylic ester, 5 to 10 percent of photoinitiator, 0 to 40 percent of rutile type titanium dioxide, 0 to 2 percent of dispersing agent, and 15 to 35 percent of functional monomer, wherein the total weight percentage of all the components is 100 percent, the modified acrylic ester is aliphatic polyurethane acrylate, and the photoinitiator is 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-propanone, and acyl phosphonates or a mixture thereof. The UV metal decorating base oil has the advantages of high flexibility, adhesion, impact resistance, boiling resistance, no mobility, capacity of meeting the requirement of metal post-processing, high production efficiency, and obvious energy-saving and emission-reducing effect, and can be used for outer coating of food and beverage cans and industry packaging barrels and cans.
Description
Technical field
The present invention relates to a kind of UV curing metal coating, a kind of specifically snappiness is good, sticking power is good, good impact resistance, boiling resistance are good, oil at the bottom of the UV tin graphed sheet of no transport property.
Background technology
The metallic surface printing is commonly called as tin graphed sheet, generally comprises following several kinds of modes: oil, ink printing, oil polish at the bottom of the primary coat.What primary coat was at present used is solvent based coating, need in the environment more than 150 ℃, could solidify through high bake, and energy consumption is high, pollutes big.
Summary of the invention
High in order to overcome at the bottom of the conventional solvent type tin graphed sheet oil energy consumption; Heavy-polluted problem; The purpose of this invention is to provide oil at the bottom of a kind of UV tin graphed sheet; This oil snappiness good end, sticking power is good, good impact resistance, good, the no transport property of boiling resistance, can adapt to the needs of metal post-treatment, can be used for the outer application of food and beverage, industrial packaging barrel cage; And production efficiency is high, and effects of energy saving and emission reduction is obvious.
The objective of the invention is to realize through following technical scheme:
Oil at the bottom of a kind of UV tin graphed sheet; It is characterized in that: oil is made up of following components in weight percentage at the bottom of this tin graphed sheet: modification acrylate 30%～60%, light trigger 5%～10%, Rutile type Titanium Dioxide 0%～40%, dispersion agent 0%～2%, functional monomer 15%～35%, and said modification acrylate is an aliphatic urethane acrylate; Said light trigger is 1-methylol cyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, acylphosphanes thing or their mixture; More than each percentages of ingredients sum be 100%.
Said modification acrylate is aliphatic urethane acrylate (PUA), can adopt CYTEC company, SARTOMER company, Changxing chemistry, three lignify workers or their mixture.
Said functional monomer is CYTEC company, SARTOMER company, Changxing chemistry, three lignify workers or their mixture; As: IBOA, HEA, PETA etc.
Said Rutile type Titanium Dioxide is E.I.Du Pont Company, Te Nuo company, the Sichuan dragon is big or their mixture, as: R906, CR828, R996 etc.
Said dispersion agent is copolymer solution, block copolymer solution or their mixture that contains acidic-group, as: BYK103, BYK110, BYK111, tego685, tego655 etc.
Said light trigger is 1-methylol cyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, acylphosphanes thing or their mixture, as: 1173,184,819, TPO etc.
Advantage of the present invention is that snappiness is good, sticking power is good, good impact resistance, good, the no transport property of boiling resistance, can adapt to the needs of metal post-treatment, and production efficiency is high, and effects of energy saving and emission reduction is obvious.The present invention adapts to the needs of metal post-treatment, can be used for the outer application of food and beverage, industrial packaging barrel cage; And production efficiency is high, and effects of energy saving and emission reduction is obvious.
Embodiment
Embodiment 1
Oil at the bottom of the described UV tin graphed sheet of one invention, the oil component weight proportion is at the bottom of this UV tin graphed sheet: modification acrylate 50%, light trigger 10%, Rutile type Titanium Dioxide 10%, dispersion agent 2%, functional monomer 28%.More than each percentages of ingredients sum be 100%.Said modification acrylate is aliphatic urethane acrylate (PUA), adopts CYTEC company, SARTOMER company, Changxing chemistry, three lignify workers or their mixture.Said functional monomer is CYTEC company, SARTOMER company, Changxing chemistry, three lignify workers or their mixture; As: IBOA, HEA, PETA etc.Said Rutile type Titanium Dioxide is E.I.Du Pont Company, Te Nuo company, the Sichuan dragon is big or their mixture, as: R906, CR828, R996 etc.Said dispersion agent is copolymer solution, block copolymer solution or their mixture that contains acidic-group, as: BYK103, BYK110, BYK111, tego685, tego655 etc.Said light trigger is 1-methylol cyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, acylphosphanes thing or their mixture, as: 1173,184,819, TPO etc.
The preparation method of oil is at the bottom of the UV tin graphed sheet of the present invention: after earlier UV resin, partial function property monomer, dispersion agent, light trigger being uniformly dispersed, add and be ground to certain fineness after Rutile type Titanium Dioxide fully disperses, add the surplus monomer again and be uniformly dispersed and get final product.
During coating decoration, can control coating coating temperature or add suitable monomer and regulate viscosity as the case may be, it is coated with and the metallic surface through roll coating model.
Through detecting oil main performance index such as table 1 at the bottom of the UV tin graphed sheet of the present invention:
Table 1:
| Test event | Testing method | Test result |
| Gloss | GB 1743-79 | ≥80° |
| Sticking power | GB/T 1720-1989 | The I level |
| Shock resistance | GB/T 1732-1993 | Qualified |
| Cup is protruding | GB 9753-88 | Qualified |
| Anti-boiling | The face-to-face 180 ° of doublings of paint film were 121 ℃ of airtight poach 30 minutes | Well |
Snappiness of the present invention is good, sticking power is good, good impact resistance, good, the no transport property of boiling resistance, can adapt to the needs of metal post-treatment, and production efficiency is high, and effects of energy saving and emission reduction is obvious.
Embodiment 2
Oil is compared with embodiment 1 at the bottom of the described UV tin graphed sheet of another invention, only is the composition change with oil at the bottom of the UV tin graphed sheet; The oil component weight proportion is at the bottom of this UV tin graphed sheet: modification acrylate 60%, functional monomer 35%, Rutile type Titanium Dioxide 0%; Dispersion agent 0%, light trigger 5%.Through detecting, oil meets the demands at the bottom of the UV tin graphed sheet that obtains.
Embodiment 3
Oil is compared with embodiment 1 at the bottom of the described UV tin graphed sheet of another invention, only is the composition change with oil at the bottom of the UV tin graphed sheet; The oil component weight proportion is at the bottom of this UV tin graphed sheet: modification acrylate 45%, functional monomer 27%, Rutile type Titanium Dioxide 20%; Dispersion agent 1%, light trigger 7%.Through detecting, oil meets the demands at the bottom of the UV tin graphed sheet that obtains.
Embodiment 4
Oil is compared with embodiment 1 at the bottom of the described UV tin graphed sheet of another invention, only is the composition change with oil at the bottom of the UV tin graphed sheet; The oil component weight proportion is at the bottom of this UV tin graphed sheet: modification acrylate 30%, functional monomer 18%, Rutile type Titanium Dioxide 40%; Dispersion agent 2%, light trigger 10%.Through detecting, oil meets the demands at the bottom of the UV tin graphed sheet that obtains.
Claims (5)
1. oil at the bottom of the UV tin graphed sheet; It is characterized in that: oil is made up of following components in weight percentage at the bottom of this tin graphed sheet: modification acrylate 30%～60%, light trigger 5%～10%, Rutile type Titanium Dioxide 0%～40%, dispersion agent 0%～2%, functional monomer 15%～35%, more than each percentages of ingredients sum be 100%; Said modification acrylate is an aliphatic urethane acrylate; Said light trigger is 1-methylol cyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, acylphosphanes thing or their mixture.
2. oil at the bottom of the UV tin graphed sheet according to claim 1 is characterized in that: said modification acrylate is to adopt CYTEC company, SARTOMER company, Changxing chemistry, three lignify workers' product or the mixture of their products.
3. oil at the bottom of the UV tin graphed sheet according to claim 1 is characterized in that: said functional monomer is CYTEC company, SARTOMER company, Changxing chemistry, three lignify workers' product or their mixture.
4. oil at the bottom of the UV tin graphed sheet according to claim 1 is characterized in that: said Rutile type Titanium Dioxide is E.I.Du Pont Company, Te Nuo company, the Sichuan dragon is big or their mixture.
5. oil at the bottom of the UV tin graphed sheet according to claim 1, it is characterized in that: said dispersion agent is copolymer solution, block copolymer solution or their mixture that contains acidic-group.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210161676XA CN102660190A (en) | 2012-05-23 | 2012-05-23 | Ultraviolet (UV) metal decorating base oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210161676XA CN102660190A (en) | 2012-05-23 | 2012-05-23 | Ultraviolet (UV) metal decorating base oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102660190A true CN102660190A (en) | 2012-09-12 |
Family
ID=46769778
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210161676XA Pending CN102660190A (en) | 2012-05-23 | 2012-05-23 | Ultraviolet (UV) metal decorating base oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102660190A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102825935A (en) * | 2012-09-21 | 2012-12-19 | 郑州金泰制罐有限公司 | Polishing-free metal decorating process for partially printing characters or small patterns |
| CN103909754A (en) * | 2013-01-04 | 2014-07-09 | 上海宝钢包装股份有限公司 | Ultraviolet (UV) base oil metal tank UV printing and coating method |
| CN114736557A (en) * | 2022-05-17 | 2022-07-12 | 广东希贵光固化材料有限公司 | Offset printing LED tin printing ink capable of being processed by deep drawing and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6057380A (en) * | 1997-08-22 | 2000-05-02 | Ciba Specialty Chemicals Corporation | Photogeneration of amines from α-aminoacetophenones |
| CN1415682A (en) * | 2002-09-20 | 2003-05-07 | 中国化工建设总公司常州涂料化工研究院 | Polyester paint of high solid for coiled material and lithographed sheet |
| CN101050325A (en) * | 2007-03-12 | 2007-10-10 | 佛山市儒林化工有限公司 | Environmental protection type tin printing ink solidified by ultraviolet light |
-
2012
- 2012-05-23 CN CN201210161676XA patent/CN102660190A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6057380A (en) * | 1997-08-22 | 2000-05-02 | Ciba Specialty Chemicals Corporation | Photogeneration of amines from α-aminoacetophenones |
| CN1415682A (en) * | 2002-09-20 | 2003-05-07 | 中国化工建设总公司常州涂料化工研究院 | Polyester paint of high solid for coiled material and lithographed sheet |
| CN101050325A (en) * | 2007-03-12 | 2007-10-10 | 佛山市儒林化工有限公司 | Environmental protection type tin printing ink solidified by ultraviolet light |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102825935A (en) * | 2012-09-21 | 2012-12-19 | 郑州金泰制罐有限公司 | Polishing-free metal decorating process for partially printing characters or small patterns |
| CN103909754A (en) * | 2013-01-04 | 2014-07-09 | 上海宝钢包装股份有限公司 | Ultraviolet (UV) base oil metal tank UV printing and coating method |
| CN103909754B (en) * | 2013-01-04 | 2016-08-24 | 上海宝钢包装股份有限公司 | The UV of a kind of UV base oil canister prints coating method |
| CN114736557A (en) * | 2022-05-17 | 2022-07-12 | 广东希贵光固化材料有限公司 | Offset printing LED tin printing ink capable of being processed by deep drawing and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102504668B (en) | Water-based primer-topcoat synthetic anti-corrosive paint for coating automobile spare parts and preparation method thereof | |
| CN102206462B (en) | Metal UV (Ultraviolet) coating | |
| CN102533063B (en) | Ultraviolet ray-curable low-gloss flow-coating paint and preparation method thereof | |
| CN102329558A (en) | Low-odor high-wear-resistance UV (ultraviolet) metal printing oil polish | |
| CN101935425B (en) | Modified polyurethane (PU) acrylic resin and preparation method thereof | |
| CN102977760B (en) | A kind of Thick film type polyurethane finish paint | |
| CN101429402A (en) | Watersoluble metal self-drying antirusting paint | |
| CN102408827B (en) | Aqueous ultraviolet-curing transparent prime coat and preparation method thereof | |
| CN104927620B (en) | A kind of solid wood board solidifies painting design with crack resistence ultraviolet light | |
| CN102977748A (en) | UV furniture spray-coating gloss topcoat without volatile organic solvent | |
| CN102660190A (en) | Ultraviolet (UV) metal decorating base oil | |
| CN103773151A (en) | High temperature resistance acid-proof alkali-proof coating | |
| CN102658738A (en) | Printing iron coating process | |
| CN103146280A (en) | Water-soluble antirust nano composite coating and preparation method thereof | |
| US10316195B2 (en) | Zinc-based composite material and use thereof | |
| CN101993654A (en) | Ultraviolet (UV) high elasticity primer | |
| CN105038489A (en) | Modified acrylic resin energy-conservation and environmental-friendly coating for product packing metal box | |
| CN102977763A (en) | UV varnish topcoat used for preventing rust at welds of paint iron drum or iron can | |
| CN103589295A (en) | Leveling-free ultraviolet curing primer | |
| CN101173144B (en) | UV paint | |
| CN105038344A (en) | Modified acrylic resin energy conservation and environment protection coating for back plate of refrigerator | |
| CN101451043A (en) | Novel acrylic resin bottom face synthetic lacquer | |
| CN104250460A (en) | Wear-resistant paint used for metal components, and preparation method of wear-resistant paint | |
| CN105038352A (en) | Energy-saving environment-friendly coating adopting modified acrylic resin and used for knurled decoration plate | |
| CN102952464A (en) | UV (Ultraviolet) curing spraying melamine adhesion-enhanced transparent primer coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120912 |