CN102658016B - Method for ammonia method desulfurization of flue gas and high-purity ammonium hydrogen sulfite by-producing - Google Patents
Method for ammonia method desulfurization of flue gas and high-purity ammonium hydrogen sulfite by-producing Download PDFInfo
- Publication number
- CN102658016B CN102658016B CN201210131357.4A CN201210131357A CN102658016B CN 102658016 B CN102658016 B CN 102658016B CN 201210131357 A CN201210131357 A CN 201210131357A CN 102658016 B CN102658016 B CN 102658016B
- Authority
- CN
- China
- Prior art keywords
- flue gas
- solution
- tower
- absorption tower
- washing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 60
- 239000003546 flue gas Substances 0.000 title claims abstract description 60
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 23
- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 20
- ZETCGWYACBNPIH-UHFFFAOYSA-N azane;sulfurous acid Chemical compound N.OS(O)=O ZETCGWYACBNPIH-UHFFFAOYSA-N 0.000 title claims abstract description 11
- 238000006477 desulfuration reaction Methods 0.000 title abstract description 9
- 230000023556 desulfurization Effects 0.000 title abstract description 8
- 238000010521 absorption reaction Methods 0.000 claims abstract description 71
- 239000007789 gas Substances 0.000 claims abstract description 43
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 34
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000005406 washing Methods 0.000 claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 8
- 239000000243 solution Substances 0.000 claims description 51
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 23
- 230000003009 desulfurizing effect Effects 0.000 claims description 14
- AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 claims description 11
- 239000005864 Sulphur Substances 0.000 claims description 9
- 238000000889 atomisation Methods 0.000 claims description 8
- 239000006227 byproduct Substances 0.000 claims description 8
- 238000007872 degassing Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000012266 salt solution Substances 0.000 claims description 6
- 238000002485 combustion reaction Methods 0.000 claims description 4
- 239000000047 product Substances 0.000 claims description 4
- 239000002244 precipitate Substances 0.000 claims description 2
- 238000004062 sedimentation Methods 0.000 claims description 2
- 239000011800 void material Substances 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 abstract description 12
- 239000011593 sulfur Substances 0.000 abstract description 12
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Landscapes
- Treating Waste Gases (AREA)
Abstract
The invention discloses a method for ammonia method desulfurization of flue gas and high-purity ammonium hydrogen sulfite by-producing. The method comprises the following steps that: solid substances rich in sulfur are firstly burnt to generate the flue gas rich in high concentration sulfur dioxide gas; the flue gas enters into a cyclone separator for dedusting, and the dedusted flue gas enters into a heat exchanger for temperature reduction; then the flue gas enters into a washing and purifying tower to be washed; the flue gas respectively enters into a primary absorption tower, a secondary absorption tower and a third absorption tower for absorption, the high concentration ammonium hydrogen sulfite solution generated through reaction is taken out from a bottom groove of the primary absorption tower as a finished product for package; and the flue gas enters into a washing tower to discharge after washing. By the method, SO2 and other harmful acidic gas are highly purified; the utilization ratio of an ammonia absorption agent is effectively improved; high-purity ammonium hydrogen sulfite solution can be obtained; and the ammonium hydrogen sulfite solution has excellent special industrial use and prospect.
Description
Technical field
The present invention relates to the gas generation ammonium bisulfite technical field of utilizing rich sulfur material burning to produce, the particularly a kind of method of flue gas ammonia method desulfurizing by-product high-purity ammonium bisulfite.
Background technology
Ammonium bisulfite (NH
4hSO
3) solution is a kind of important raw material of industry, is the raw material of producing liquid sulfur dioxide, sodium hydrosulfite and sodium formaldehyde sulfoxylate, is used as reducing agent in pharmaceuticals industry.Conventional preparation method is with ammonia absorption relieving haperacidity tail gas, obtains bisulfite ammonium salt solution.Its chemical reaction formula is:
2NH
3+SO
2+H
2O→(NH
4)
2SO
3 (1) ；
(NH
4)
2SO
3+SO
2+H
2O→2NH
4HSO
3 (2) 。
The tail gas of discharge contains sulfur dioxide, in the waste gas of the tail gas of gas washing in SA production and sulfur-bearing raw ore sintering, also contains sulfur dioxide, and these sulfurous gas absorb with ammoniacal liquor conventionally, and ammonium sulfite is the byproduct of its desulfurization.Because content of sulfur dioxide in these gases is conventionally lower, therefore conventionally can react (1), it is incomplete that reaction (2) is carried out.If impurity is more in gas, or SO
2gas concentration is inadequate, and its product purity of producing is inadequate, has affected its industrial use.
Publication number is the ammonia type flue gas desulfurizing apparatus that the patent of CN201609633U discloses a kind of by-product ammonium bisulfite and ammonium sulfite, comprise two-step desulfurization tower, be specially first grade desulfurizing tower and two-grade desulfurizing tower, feed liquid in first grade desulfurizing tower and two-grade desulfurizing tower all by circulated sprinkling to absorb the sour gas in flue gas, first grade desulfurizing tower bottom is provided with slurry pool, is mainly ammonium bisulfite feed liquid in slurry pool.Can find out from the 15th section of this patent specification, the gas of the method desulfurization be plant tail gas from flue gas, conventionally sulfur dioxide in flue gas concentration is lower.When the burning such as gangue, containing sulfur minerals, SO in flue gas
2content is conventionally lower, and conventionally at 300-5000ppm, therefore the desulfurizer of secondary just can meet absorption, and discharge flue gas can meet the requirement of environmental protection.But this device is not suitable for the high concentration sulfur dioxide gas that the secondary sulfur material of burning produces.The concentration of SO 2 gas that the secondary sulfur material that burns produces is very high.For example sulfur burning, if sufficient combustion, without remaining O
2, SO in burning gases
2the ratio that gas accounts for volume of gas can reach 21%, certainly exists excess air in Actual combustion, nonetheless, and the SO of generation
2the volume ratio of gas also can reach 10% to 15%; If burning is troilite, the SO of generation
2the volume ratio of gas also can reach 7%; In activated carbon desulfurization, form the active carbon that is rich in sulphur, its sulfur content is also very high, SO in the gas producing after burning
2content is also very high.The high concentration sulfur dioxide gas that the secondary sulfur material that burns produces is by after first grade absorption tower, the sulfur dioxide concentration of residual gas is still very high, after two-level absorption tower absorbs, the concentration of SO 2 gas of discharge is difficult to reach emission request, if strengthen the concentration of the ammonia of two-level absorption tower, although sulfur dioxide can absorb completely, may have the escaping of ammonia.
Summary of the invention
The object of the present invention is to provide a kind of flue gas that is rich in high concentration sulfur dioxide that secondary sulfur material burning is produced to carry out the method for the ammonia process of desulfurization production high-purity bisulfite ammonium salt solution, make it in having compared with high desulfurization efficiency, ammonia in cleaning of off-gas, loss reduces, and reduces production costs.
For achieving the above object, the present invention proposes technical scheme and is: a kind of method of flue gas ammonia method desulfurizing by-product high-purity ammonium bisulfite, is characterized in that: the solid matter that is rich in sulphur is burnt, produce the flue gas that is rich in high concentration sulfur dioxide gas; Flue gas enters cyclone separator and carries out dedusting, and the flue gas after dedusting enters heat exchanger, cools the temperature to 60～70 DEG C; Flue gas enters washing, purifying tower, and washing, purifying tower structure and cyclone separator are similar, is just provided with shower nozzle on top, by shower nozzle ejection atomization water, the solid matter in flue gas is washed; Flue gas enters first grade absorption tower subsequently, first grade absorption tower inside at least comprises shower nozzle, several clean room and kerve from top to bottom, tower outside is provided with circulating pump, solution in kerve is constantly transported in shower nozzle by pipeline, the base plate of described clean room is with some apertures, by shower nozzle ejection atomization solution, this solution is by ammoniacal liquor and (NH
4)
2sO
3composition, the pH value of solution is controlled at 5～6, and the bisulfite ammonium salt solution of the high concentration that reaction generates falls into the kerve of first grade absorption tower, after concentration reaches requirement, from kerve, takes out and packs as finished product; Flue gas enters two-level absorption tower subsequently, and the structure of two-level absorption tower is identical with first grade absorption tower, by shower nozzle ejection atomization solution, this solution is by ammoniacal liquor and (NH
4)
2sO
3composition, the pH value of solution is controlled at 6～7; Flue gas enters three grades of absorption towers subsequently, and the structure on three grades of absorption towers is identical with first grade absorption tower, by shower nozzle ejection atomization solution, this solution is by ammoniacal liquor and (NH
4)
2sO
3composition, the pH value of solution is controlled at 6～7; Three grades of flue gas discharges after water scrubber washing that discharge on absorption tower, water scrubber structure is identical with washing, purifying tower structure.
Further, can in water scrubber, set up net demister, carry out foam removal.
Further, the solution of flue gas being washed to rear generation in washing, purifying tower enters degassing tower and carries out degassedly, and degassing tower is void tower structure, and top is provided with gas vent; The degassed solution completing enters wash cycle pond and precipitates, and again burns being rich in after solids of sedimentations such as thering is no the biochemical sulphur of completing combustion separates, and recycles; The gas that degassing tower produces is admitted to first grade absorption tower.
Further, the solution of the participation reaction in three grades of absorption towers can be transported in two-level absorption tower and react, and the solution of the participation reaction in two-level absorption tower can be transported to first grade absorption tower and react.
The invention has the beneficial effects as follows: through cyclone separator, flue gas has been carried out to dedusting, through cooling system, gas has been lowered the temperature; If when the secondary sulfur material such as sulphur can not fully burn, wherein may contain the solid impurities such as certain biochemical sulphur, through washing, purifying tower, rich sulphur gas is washed, impurity such as thering is no clean-burning biochemical sulphur can be washed out, in slag liquid accumulator tank, reclaim.The solution producing after the washing of washing, purifying tower contains certain SO
2, can in degassing tower, carry out further degassedly, reclaim SO wherein
2.With carrying out SO in three absorption towers
2absorption, wherein first grade absorption tower is mainly used to high concentration SO
2concentrating of the absorption of gas and ammonium bisulfite, due to SO
2gas concentration is very high, and participates in the ammoniacal liquor of reaction and generally lower (pure ammonia concn is 25%-33%) of concentration of ammonium sulfite solution, and the bisulfite ammonium salt solution purity therefore producing is very high.Generally at first grade absorption tower, through constantly circulation, nearly 75% SO in gas
2be absorbed.Two-level absorption tower is mainly used to absorb SO
2and for first grade desulfurizing tower provides ammonium sulfite absorption liquid, now, SO in gas
2concentration significantly reduces, and in product, main component is ammonium sulfite.Generally at two-level absorption tower, through constantly circulation, nearly 75% SO in gas
2be absorbed.In three grades of absorption towers, sulfur dioxide concentration is very low, and now the ammonia concentration in absorption liquid is also very low, reacts remaining ammonia also little; Gas after absorption is again through washing, SO in gas
2very low with the discharge capacity of ammonia, in gas, the removal efficiency of main acid contaminant can reach: SO
2:>=98%; SO
3:>=95%, can reach emission request completely.Desulfurizing tower is provided with multilayer clean room, has solved in prior art gas and has contacted insufficiently with circulation fluid, easily has dead angle, the problem that desulfuration efficiency is low.Therefore the present invention has high purification SO
2and other harmful sour gas, effectively improve the features such as ammonia absorbent utilization rate, and can obtain high concentration bisulfite ammonium salt solution, there is good special industry purposes and prospect.
Brief description of the drawings
Fig. 1 is the method for application a kind of flue gas ammonia method desulfurizing of the present invention by-product high-purity ammonium bisulfite.
Wherein: 1-sulfur furnace; 2-cyclone separating tower; 3-heat exchanger; 4-washing, purifying tower; 5-first grade absorption tower; 6-two-level absorption tower; Tri-grades of absorption towers of 7-; 8-water scrubber; 9-circulating pump; 10-shower nozzle; 11-clean room; 12-base plate; 13-kerve; 14-one-level circulating tank; 15-secondary circulation pipe; Tri-grades of circulation pipes of 16-; 17-tank; 18-ammonia water tank; 19-wash cycle pond; 20-degassing tower.
Detailed description of the invention
Experiment Introduction: at when experiment simulated flue gas of being made up of mixed air of flue gas, experiment flow is identical with Fig. 1, but flow process is from first grade absorption tower, and simulated flue gas be preheating to 60 DEG C laggard enter flow process.
Embodiment 1: simulated flue gas composition: 78% N
2, 3% O
2, 15% SO
2, 3% CO
2and steam.Flue gas flow: 1m
3/ min.In first grade absorption tower, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 5～6; In two-level absorption tower, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 6～7; In three grades of absorption towers, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 6～7.Result is as follows:
| Flue gas flow (m 3/min) | SO after purifying 2Content (ppm) | NH after purifying 3Content (ppm) | NH 4HSO 3Solution concentration |
| 1 | 58 | 32 | 75% |
Embodiment 2: simulated flue gas composition: 78% N
2, 3% O
2, 12% SO
2, 7% CO
2and steam.Flue gas flow: 1m
3/ min.In first grade absorption tower, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 5～6; In two-level absorption tower, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 6～7; In three grades of absorption towers, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 6～7.Result is as follows:
| Flue gas flow (m 3/min) | SO after purifying 2Content (ppm) | NH after purifying 3Content (ppm) | NH 4HSO 3Solution concentration |
| 1 | 65 | 28 | 70% |
Embodiment 3: simulated flue gas is formed: 78% N
2, 8 O
2sO %, 8%
2, 5% CO
2and steam.Flue gas flow: 1m
3/ min.In first grade absorption tower, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 5～6; In two-level absorption tower, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 6～7; In three grades of absorption towers, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 5～6.Result is as follows:
| Flue gas flow (m 3/min) | SO after purifying 2Content (ppm) | NH after purifying 3Content (ppm) | NH 4HSO 3Solution concentration |
| 1 | 58 | 62 | 72% |
Embodiment 4: simulated flue gas is formed: 78% N
2, 3% O
2sO %, 10%
2, 8% CO
2and steam.Flue gas flow: 1m
3/ min.In first grade absorption tower, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 5～6; In two-level absorption tower, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 6～7; In three grades of absorption towers, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 6～7.Result is as follows:
| Flue gas flow (m 3/min) | SO after purifying 2Content (ppm) | NH after purifying 3Content (ppm) | NH 4HSO 3Solution concentration |
| 1 | 62 | 27 | 73% |
Embodiment 5: simulated flue gas is formed: 78% N
2, 3% O
2sO %, 12%
2, 6% CO
2and steam.Flue gas flow: 1m
3/ min.In first grade absorption tower, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 5～6; In two-level absorption tower, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 6～7; In three grades of absorption towers, participate in the ammoniacal liquor and (NH of circulation
4)
2sO
3the pH value of solution is 6～7.Result is as follows:
| Flue gas flow (m 3/min) | SO after purifying 2Content (ppm) | NH after purifying 3Content (ppm) | NH 4HSO 3Solution concentration |
| 1 | 65 | 26 | 72% |
Claims (2)
1. the method for a flue gas ammonia method desulfurizing by-product high-purity ammonium bisulfite, it is characterized in that: the solid matter that is rich in sulphur is burnt, the flue gas of high concentration sulfur dioxide gas is rich in generation, and in described high concentration sulfur dioxide gas, the concentration of sulfur dioxide is more than 7%; Flue gas enters cyclone separator and carries out dedusting, and the flue gas after dedusting enters heat exchanger, cools the temperature to 60～70 DEG C; Flue gas enters washing, purifying tower, and washing, purifying tower structure and cyclone separator are similar, is just provided with shower nozzle on top, by shower nozzle ejection atomization water, the solid matter in flue gas is washed; Flue gas enters first grade absorption tower subsequently, first grade absorption tower inside at least comprises shower nozzle, several clean room and kerve from top to bottom, tower outside is provided with circulating pump, solution in kerve is constantly transported in shower nozzle by pipeline, the base plate of described clean room is with some apertures, by shower nozzle ejection atomization solution, this solution is by ammoniacal liquor and (NH
4)
2sO
3composition, the pH value of solution is controlled at 5～6, and the bisulfite ammonium salt solution of the high concentration that reaction generates falls into the kerve of first grade absorption tower, after concentration reaches requirement, from kerve, takes out and packs as finished product; Flue gas enters two-level absorption tower subsequently, and the structure of two-level absorption tower is identical with first grade absorption tower, by shower nozzle ejection atomization solution, this solution is by ammoniacal liquor and (NH
4)
2sO
3composition, the pH value of solution is controlled at 6～7; Flue gas enters three grades of absorption towers subsequently, and the structure on three grades of absorption towers is identical with first grade absorption tower, by shower nozzle ejection atomization solution, this solution is by ammoniacal liquor and (NH
4)
2sO
3composition, the pH value of solution is controlled at 6～7; Three grades of flue gas discharges after water scrubber washing that discharge on absorption tower, water scrubber structure is identical with washing, purifying tower structure;
The solution of flue gas being washed to rear generation in described washing, purifying tower enters degassing tower and carries out degassedly, and degassing tower is void tower structure, and top is provided with gas vent; The degassed solution completing enters wash cycle pond and precipitates, and again burns being rich in after solids of sedimentations such as thering is no the biochemical sulphur of completing combustion is collected, and recycles; The gas that degassing tower produces is admitted to first grade absorption tower.
2. the method for a kind of flue gas ammonia method desulfurizing as claimed in claim 1 by-product high-purity ammonium bisulfite, it is characterized in that: the solution of the participation reaction in three grades of absorption towers can be transported in two-level absorption tower and react, the solution of the participation reaction in two-level absorption tower can be transported to first grade absorption tower and react.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210131357.4A CN102658016B (en) | 2012-05-02 | 2012-05-02 | Method for ammonia method desulfurization of flue gas and high-purity ammonium hydrogen sulfite by-producing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210131357.4A CN102658016B (en) | 2012-05-02 | 2012-05-02 | Method for ammonia method desulfurization of flue gas and high-purity ammonium hydrogen sulfite by-producing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102658016A CN102658016A (en) | 2012-09-12 |
| CN102658016B true CN102658016B (en) | 2014-10-22 |
Family
ID=46767673
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210131357.4A Active CN102658016B (en) | 2012-05-02 | 2012-05-02 | Method for ammonia method desulfurization of flue gas and high-purity ammonium hydrogen sulfite by-producing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102658016B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103908883B (en) * | 2014-04-18 | 2016-01-20 | 中石化南京工程有限公司 | A kind of ammonia of sulfur recovery facility absorbs exhaust gas treating method |
| CN104208993A (en) * | 2014-07-31 | 2014-12-17 | 仙桃市中星电子材料有限公司 | Device and method for treatment of calcination tail gas |
| CN104474849B (en) * | 2014-12-04 | 2017-01-04 | 中国钢研科技集团有限公司 | Acid regeneration acid gas absorbs and tail gas emission system and Application way thereof |
| CN110002472A (en) * | 2019-02-21 | 2019-07-12 | 武汉青江化工黄冈有限公司 | The industrial method of by-product sodium sulphate continuous production sodium hydrogensulfite |
| CN113082959B (en) * | 2021-04-02 | 2023-07-18 | 江苏新世纪江南环保股份有限公司 | Flue gas pretreatment method and device for ammonia desulfurization |
| CN115041007A (en) * | 2022-06-23 | 2022-09-13 | 河北冀衡药业股份有限公司 | Sulfur dioxide gas recovery system and method |
| CN115006977A (en) * | 2022-06-28 | 2022-09-06 | 常州工学院 | Comprehensive treatment device for coke oven flue gas |
| CN115624851B (en) * | 2022-12-21 | 2023-03-31 | 联仕(昆山)化学材料有限公司 | Treatment process and treatment device for tail gas in electronic-grade sulfuric acid production |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6773555B1 (en) * | 1999-08-12 | 2004-08-10 | Ebara Corporation | Method for treating exhaust gas |
| CN201609633U (en) * | 2010-01-12 | 2010-10-20 | 上海洁美环保科技有限公司 | Ammonia flue gas desulfurization device of byproducts of ammonium hydrogen sulfite and ammonium sulfite |
| CN101708412B (en) * | 2009-11-16 | 2011-12-21 | 浙江大学 | Twin tower type recovering sulfur resource ammonia desulfuration equipment and method |
| CN101934192B (en) * | 2010-09-16 | 2012-01-25 | 江苏和亿昌环保工程科技有限公司 | Double-tower ammonia-method desulfurization process |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09313878A (en) * | 1996-05-24 | 1997-12-09 | Ishikawajima Harima Heavy Ind Co Ltd | Simple type ammonia flue gas desulfurization device |
-
2012
- 2012-05-02 CN CN201210131357.4A patent/CN102658016B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6773555B1 (en) * | 1999-08-12 | 2004-08-10 | Ebara Corporation | Method for treating exhaust gas |
| CN101708412B (en) * | 2009-11-16 | 2011-12-21 | 浙江大学 | Twin tower type recovering sulfur resource ammonia desulfuration equipment and method |
| CN201609633U (en) * | 2010-01-12 | 2010-10-20 | 上海洁美环保科技有限公司 | Ammonia flue gas desulfurization device of byproducts of ammonium hydrogen sulfite and ammonium sulfite |
| CN101934192B (en) * | 2010-09-16 | 2012-01-25 | 江苏和亿昌环保工程科技有限公司 | Double-tower ammonia-method desulfurization process |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102658016A (en) | 2012-09-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102658016B (en) | Method for ammonia method desulfurization of flue gas and high-purity ammonium hydrogen sulfite by-producing | |
| CN102658015B (en) | Method for ammonia method desulfurization of flue gas and high-purity solid ammonium sulfite by-producing | |
| CN101579602B (en) | Energy-saving and high-quality ammonia desulphurization process for ammonia sulfate recovery | |
| US9895661B2 (en) | Process and device for desulphurization and denitration of flue gas | |
| CN103303877B (en) | Many sources of the gas low concentration SO 2smoke comprehensive reclaims acid-making process flow process | |
| CN100531867C (en) | Method and apparatus for combined removing sulfur-dioxide and nitrogen oxide by mixed solution | |
| CN101745305B (en) | Method for removing various gaseous pollutants from smoke gas | |
| CN200998639Y (en) | Concentrated crystallization and absorbed oxidation combined type ammonia process desulfuration tower | |
| CN103007721B (en) | Ammonia circulation-based method and device for carbonating fixation of CO2 in coal-fired flue gas | |
| CN101422693A (en) | Sulphuric acid tail-gas deep desulfurization method | |
| CN201026440Y (en) | Absorption, oxidation, concentration combined desulfurizing tower | |
| CN104383798A (en) | Flue gas desulfurization and denitration purification recovery system | |
| CN203108424U (en) | Flue gas treatment apparatus performing desulfurization and denitrification simultaneously | |
| CN103977689B (en) | Device and method for removing sulfur dioxide in smoke by two-step alkalifying reproducing and sodium sulfite method | |
| CN105233647B (en) | A kind of method of ammonium sulfide solution desulphurization denitration | |
| CN201658945U (en) | Sintering smoke purifying system based on heat pipe afterheat recovery technology | |
| CN101757844A (en) | Method and device for performing flue gas desulfurization by using ammonia process | |
| CN102600710B (en) | Treatment method of high-concentration ammonia nitrogen wastewater | |
| CN109529578B (en) | Process device and process method for liquid-phase reaction desulfurization of hydrogen sulfide and sulfur dioxide | |
| CN203033778U (en) | Device for producing ammonium sulfate by using sulfate pulp and ammonia water as raw materials | |
| CN109517630B (en) | Process and system for deamination production of ammonium sulfate by coke oven gas ammonium sulfite method | |
| CN109529573B (en) | Process device and process method for liquid-phase desulfurization of hydrogen sulfide and sulfur dioxide | |
| CN202590601U (en) | Production device for ammonium bisulfate solution | |
| CN202590600U (en) | Desulfurization device for preparing ammonium bisulfite solution through ammonia process | |
| CN212881806U (en) | Flue gas desulfurization, denitrification and demercuration purification equipment |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Method for ammonia method desulfurization of flue gas and high-purity ammonium hydrogen sulfite by-producing Effective date of registration: 20180529 Granted publication date: 20141022 Pledgee: Gaotang Tsing long village bank Limited by Share Ltd Pledgor: Shandong Tiantai Steel Plastic Co., Ltd. Registration number: 2018370000098 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20180620 Granted publication date: 20141022 Pledgee: Gaotang Tsing long village bank Limited by Share Ltd Pledgor: Shandong Tiantai Steel Plastic Co., Ltd. Registration number: 2018370000098 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Method for ammonia method desulfurization of flue gas and high-purity ammonium hydrogen sulfite by-producing Effective date of registration: 20180702 Granted publication date: 20141022 Pledgee: Gaotang Tsing long village bank Limited by Share Ltd Pledgor: Shandong Tiantai Steel Plastic Co., Ltd. Registration number: 2018370000120 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20190530 Granted publication date: 20141022 Pledgee: Gaotang Tsing long village bank Limited by Share Ltd Pledgor: Shandong Tiantai Steel Plastic Co., Ltd. Registration number: 2018370000120 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190620 Address after: 457199 Grace Town 17 -108, Yumin Road and FutureRoad Intersection, Puyang County, Henan Province Patentee after: Henan Muhua Chemical Co., Ltd. Address before: 252800 Shandong Tiantai Steel Plastic Co., Ltd. Liaocheng Gaotang County, Shandong Province, Luzhuang Village, Jiangdian Township Patentee before: Shandong Tiantai Steel Plastic Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210412 Address after: 252800 Luzhuang village, Jiangdian Town, Gaotang County, Liaocheng City, Shandong Province Patentee after: Shuize Festival (Shandong) Environmental Protection Technology Co.,Ltd. Address before: 457199 Grace Town 17 -108, Yumin Road and FutureRoad Intersection, Puyang County, Henan Province Patentee before: Henan Muhua Chemical Co.,Ltd. |
|
| TR01 | Transfer of patent right |