CN1026503C - 一种油田缓蚀剂 - Google Patents
一种油田缓蚀剂 Download PDFInfo
- Publication number
- CN1026503C CN1026503C CN 89108825 CN89108825A CN1026503C CN 1026503 C CN1026503 C CN 1026503C CN 89108825 CN89108825 CN 89108825 CN 89108825 A CN89108825 A CN 89108825A CN 1026503 C CN1026503 C CN 1026503C
- Authority
- CN
- China
- Prior art keywords
- oil field
- hydroxyethyl
- corrosion inhibitor
- imidazoline
- field corrosion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 230000007797 corrosion Effects 0.000 title claims abstract description 11
- 238000005260 corrosion Methods 0.000 title claims abstract description 11
- 239000003112 inhibitor Substances 0.000 title claims abstract description 8
- -1 (N-hydroxyethyl-N ', N' -dicarboxymethyl ethylenediamine) octadecanamide sodium salt Chemical compound 0.000 claims abstract description 7
- HPRBJMCIUYVZOW-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)[NH-].[Na+] Chemical compound C(CCCCCCCCCCCCCCCCC)[NH-].[Na+] HPRBJMCIUYVZOW-UHFFFAOYSA-N 0.000 claims description 2
- KFIGICHILYTCJF-UHFFFAOYSA-N n'-methylethane-1,2-diamine Chemical compound CNCCN KFIGICHILYTCJF-UHFFFAOYSA-N 0.000 claims 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 abstract description 2
- RWCPWWUBUCTSKX-UHFFFAOYSA-L [Na+].C(=O)([O-])C(N1CNCC1)C(=O)[O-].[Na+] Chemical compound [Na+].C(=O)([O-])C(N1CNCC1)C(=O)[O-].[Na+] RWCPWWUBUCTSKX-UHFFFAOYSA-L 0.000 abstract 1
- 230000005764 inhibitory process Effects 0.000 abstract 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000002461 imidazolidines Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
一种咪唑啉油田缓蚀剂，它由(N-羟乙基-N′-羟乙基-N′，N′-二羧甲基乙二胺)十八酰胺钠盐15-30%、1-羟乙基-2-十七烯基-3，3-二羧甲基咪唑啉钠盐70-85%组成。经在油田试用，其缓蚀效果优良。
Description
本发明涉及一种油田缓蚀剂。
咪唑啉两性表面活性剂自1940年被开发以来，在合成洗发香波、纤维防静电剂和柔软剂、玻璃纤维的润滑剂、油漆颜料的分散剂、金属处理的缓蚀剂、油田杀菌缓蚀剂等方面得到广泛的应用。美国在油田使用的各种有机缓蚀剂中，以咪唑啉系用量最大。国外已在油田应用的有效咪唑啉衍生物有：1-（2-羟乙基）-1-苄基-2-十三烷基咪唑啉;烷基咪唑啉;咪唑啉的季胺盐;1-乙胺-2-烷基咪唑啉等。适合我国油田情况的缓蚀剂，仍有待进一步开发。
为开发适于我国油田使用的油田缓蚀剂，本发明选择以下配方：
组分A：（N-羟乙基-N′-羟乙基-N′，N′-＝羧甲基乙二胺）十八酰胺钠盐 15-30%
组分B：1-羟乙基-2-十七烯基-3，3-二羧甲基咪唑啉钠盐 70-85%
前者结构式为：
后者结构式为：
经在胜利、华北、二连、新疆油田试用，缓蚀效果优良，平均腐蚀率（MPY）为8.81，平均点蚀率为21.67。
实施例：
组分A：20%
组分B：80%
平均腐蚀率（MPY）：12.82
平均点蚀率（MPY）：30.28
Claims (1)
1、一种油田缓蚀剂，其特征在于它由：
结构式(Ⅰ)占15-30%重量的(N-羟乙基-N′-羟乙基-N′，N′-二羧甲基乙二胺)十八酰胺钠和结构式为(Ⅱ)的占70-85%重量的1-羟乙基-2-十七烯基-3，3-二羧甲基咪唑啉钠组成；
A的结构式(Ⅰ)为：
B的结构式(Ⅱ)为：
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89108825 CN1026503C (zh) | 1989-11-21 | 1989-11-21 | 一种油田缓蚀剂 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89108825 CN1026503C (zh) | 1989-11-21 | 1989-11-21 | 一种油田缓蚀剂 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1052151A CN1052151A (zh) | 1991-06-12 |
| CN1026503C true CN1026503C (zh) | 1994-11-09 |
Family
ID=4857749
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 89108825 Expired - Fee Related CN1026503C (zh) | 1989-11-21 | 1989-11-21 | 一种油田缓蚀剂 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1026503C (zh) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2792653B1 (fr) * | 1999-04-21 | 2001-05-18 | Ceca Sa | Inhibition de la corrosion carbonique ou sulfhydrique du fer et des metaux ferreux par des n,n'- [imino (polyethyleneimino) diethylene] bis-alkylamides oxyethyles a l'azote |
| CN100453704C (zh) * | 2003-09-08 | 2009-01-21 | 成都孚吉科技有限责任公司 | 固体缓蚀剂及其制备方法 |
| CN100453703C (zh) * | 2005-02-07 | 2009-01-21 | 长江大学 | 一种控制二氧化碳腐蚀的缓蚀剂及其制备方法 |
| US7682526B2 (en) * | 2005-12-22 | 2010-03-23 | Afton Chemical Corporation | Stable imidazoline solutions |
| GB201018916D0 (en) * | 2010-11-09 | 2010-12-22 | Champion Technologies Ltd | Corrosion inhibition |
| CN104215189A (zh) * | 2014-08-28 | 2014-12-17 | 昆山勃盛电子有限公司 | 一种电缆外径在线spc检测和数据采集方法 |
| CN108863967A (zh) * | 2018-09-11 | 2018-11-23 | 四川格鑫拓科技有限公司 | 一种三嗪环多季铵盐抗氧缓蚀剂及其制备方法和应用 |
-
1989
- 1989-11-21 CN CN 89108825 patent/CN1026503C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1052151A (zh) | 1991-06-12 |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |