CN102644528A - CO2 catching device - Google Patents

CO2 catching device Download PDF

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Publication number
CN102644528A
CN102644528A CN2012101194683A CN201210119468A CN102644528A CN 102644528 A CN102644528 A CN 102644528A CN 2012101194683 A CN2012101194683 A CN 2012101194683A CN 201210119468 A CN201210119468 A CN 201210119468A CN 102644528 A CN102644528 A CN 102644528A
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China
Prior art keywords
sieve
liquid oxygen
layer
inlet
oxygen
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CN2012101194683A
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CN102644528B (en
Inventor
刘永峰
陈红兵
李德英
秦建军
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Beijing University of Civil Engineering and Architecture
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Beijing University of Civil Engineering and Architecture
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Priority to CN201210119468.3A priority Critical patent/CN102644528B/en
Publication of CN102644528A publication Critical patent/CN102644528A/en
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Publication of CN102644528B publication Critical patent/CN102644528B/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

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  • Treating Waste Gases (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention relates to a CO2 catching device, which not only can meet oxygen enrichment combustion, but also can catch CO2 exhausted from an internal combustion engine by the aid of a heat absorption effect of liquid oxygen vaporization, so that zero emission of the engine is realized. The CO2 catching device comprises a shell, an inlet (1), a condensate tube (2), a first CO2 condensing sieve (3), a first dry ice collector (4), a second CO2 condensing sieve (5), a second dry ice collector (6), a gas outlet (7), a liquid oxygen inlet (8) and a liquid oxygen guiding block (9). Liquid oxygen is vaporized into oxygen gas, the oxygen gas and a part of uncondensed CO2 jointly enter the internal combustion machine to realize oxygen enrichment combustion, and CH and CO are eliminated. After being used with the device, the internal combustion engine can work in narrow spaces needing zero emission, such as military adit construction vehicles, tunnel excavators, drilling generators, submarine generators, military missile launching vehicles and the like.

Description

A kind of CO 2Seizure device
Technical field
The present invention relates to a kind of novel CO 2Seizure device relates in particular to the liquid oxygen that is complementary with oxygen-enriched combusting zero-emission internal-combustion engine system and solidifies CO 2Device.
Background technique
Require strict day by day today in energy-conservation and environmental protection etc., the energy-conservation and environmental protection research of motor becomes the focus of current research.Oxygen-enriched combusting is one of main mode of energy saving, and oxygen-enriched combusting can make fuel combustion more abundant, eliminates the generation of pollutants such as CH, CO, obtains higher pressure peak, thereby the acting ability of motor is improved.But contain nitrogen in the common air, the coal hydrogen fuel can produce CO 2And NO xTherefore the problem of pollutant starts with from engine combustion-supporting gas, and the research internal-combustion engine solidifies CO with liquid oxygen 2And having suitable realistic meaning with the combustion-supporting new method of liquid oxygen, the realization of this method can thoroughly solve engine producing CO 2And NO xThe problem of pollutant.Utility model patent (ZL201020576059.2) has provided a kind of overall plan of the solid carbon zero-emission internal-combustion engine of liquid oxygen, but not to CO 2Seizure device study; Application for a patent for invention (CN201010171423.1) has designed the solid carbon device of a kind of ammonia process, with the CO of chemical raw material recovery boiler generation 2, but can not be to the CO of engine exhaust 2Catch.The present invention is for the CO that catches in the exhaust gases of internal combustion engines 2Device has carried out system research.
Summary of the invention
In order to realize catching CO 2, need utilize vaporization of liquid oxygen to absorb heat and make CO 2Become dry ice, the device of the present invention's design both can satisfy the vaporization of liquid oxygen oxygen-enriched combusting, can also utilize vaporization of liquid oxygen to absorb heat simultaneously and catch the CO of engine emission 2, make motor realize zero-emission.
The present invention makes the tail gas CO that produces behind the liquid oxygen oxygen enrichment combustion in IC engine 2Be reduced near 50 ℃ through condensed water, pass through this device then,, liquid oxygen is heated is vaporized into oxygen, a part of CO with the liquid oxygen convection heat exchange 2Be condensed into dry ice, it is combustion-supporting that the oxygen mix after a part and the vaporization gets into internal-combustion engine, realizes oxygen-enriched combusting.
Adopt the present invention can make internal-combustion engine realize catching CO 2The time eliminated NO again xGeneration, be oxygen with vaporization of liquid oxygen, with the CO that does not sublimate 2The common internal-combustion engine that gets into carries out oxygen-enriched combusting, has eliminated the generation of CH and CO.Both improve the efficiency of internal combustion engine, realized the zero-emission of internal-combustion engine again.Internal-combustion engine and this device are used; Can make internal combustion engine in narrow space; Simultaneously need can be applied to the occasion of zero-emission, such as military tunnel construction vehicle, tunnel excavator, drilling well generator, submarine generator, occasions such as ordnance missile emission vehicle.
Description of drawings
Fig. 1 is CO 2Seizure device figure.
Among the figure: 1-inlet, 2-condensate pipe, the 3-first layer sieve of sublimating, first dry ice trap of 4-, the 5-second layer sieve of sublimating, second dry ice trap of 6-, the 7-air outlet, the 8-liquid oxygen enters the mouth, 9-liquid oxygen baffle.
Embodiment
Below in conjunction with accompanying drawing the present invention is described in further detail:
Concrete technological scheme of the present invention is: like Fig. 1, and CO 2Seizure device has shell, and inlet 1 is arranged on the shell side bottom, and air outlet 7 is arranged on shell upper, and sublimate sieve 3 and the second layer of first layer sublimates that 7 direction is set in turn in said enclosure to sieve 5 to the air outlet along inlet 1.
Progressive below narration CO 2The principle of seizure device.(overwhelming majority is CO to the tail gas that produces behind the combustion-supporting internal-combustion engine oxygen-enriched combusting of liquid oxygen 2) through condensate pipe 2 condensations of outlet pipe tail end, temperature is reduced near 50 ℃, through 1 this seizure device of entering that enters the mouth.Simultaneously liquid oxygen gets into through the liquid oxygen inlet 8 at device top, arrives liquid oxygen baffle 9, and liquid oxygen flows to first layer the sublimate surface of sieve 5 of sieve 3 and the second layer of sublimating respectively along baffle 9, forms liquid film attached on the sieve aperture.At this moment, through CO 2The CO that inlet 1 gets into 2The arrival first layer is sublimated and is sieved 3, and with the liquid oxygen convection heat exchange that adheres to above that, liquid oxygen is heated and is vaporizated into oxygen, CO 2Sublimating is dry ice particles, because action of gravity, dry ice falls and arrives sublimate first dry ice trap 4 of sieve 3 bottoms of first layer.Do not sublimate and be the CO of dry ice 2Gas arrives the sublimate surface of sieve 5 of the second layers through the first layer sieve 3 of sublimating, and proceeds convection heat exchange with the liquid oxygen that adheres on it, this moment vaporization of liquid oxygen, CO 2The particle arrival second layer after gas is sublimated is sublimated and is sieved second dry ice trap 6 of 5 bottoms.Oxygen behind the vaporization of liquid oxygen and the CO that does not also sublimate 2Gas is mixed into new gas, through the air outlet 7 of this device, discharges this device, gets into induction system of internal combustion engine.The second layer of this device design sieve 5 of sublimating is finer and closely woven than the first layer sieve 3 of sublimating, and sieve plate makes most of CO because first layer is sublimated 2Gas is all sublimated into dry ice, and remaining have only a small amount of CO 2Gas is not sublimated, in order to make CO still less 2Gas is not sublimated and 7 discharges along the air outlet, needs finer and closely woven sieve aperture.In order to prevent and heat exchange with outside, adopt the insulation heat insulation layer that device is carried out thermal insulation.
The internal-combustion engine of using system of the present invention can be operated in need zero-emission, in the narrow space; Such as military tunnel construction vehicle, tunnel excavator, drilling well generator, submarine generator; Occasions such as ordnance missile emission vehicle simultaneously; The dry ice that reclaims can carry out recycle, is used for refrigeration, senior Dry ice cleaning agent, plant nutrient ingredient etc.
The invention is not restricted to above description to embodiment; The content that those skilled in the art disclose according to the present invention; On basis of the present invention, needn't pass through improvement and the modification that creative work carries out; Selection such as suction tude supercharging device and dry ice mothballed plant is provided with etc., all should be within protection scope of the present invention.

Claims (10)

1. CO 2Seizure device comprises shell, inlet (1), condensate pipe (2), first layer sublimate sieve (3), first dry ice trap (4), the second layer sublimate sieve (5), second dry ice trap (6), air outlet (7), liquid oxygen inlet (8), liquid oxygen baffle (9); Wherein, said inlet (1) is arranged on said shell side bottom, and said air outlet (7) are arranged on said shell upper, and said liquid oxygen inlet (8) is arranged at the top of said housing; It is characterized in that: sublimate sieve (3) and said the layer of sieve (5) of sublimating of said first layer is set in turn in said enclosure along the direction of said inlet (1) to said air outlet (7).
2. a kind of CO as claimed in claim 1 2Seizure device is characterized in that: said liquid oxygen baffle (9) is arranged at said liquid oxygen inlet (8) inboard, makes liquid oxygen can flow to said first layer the sublimate surface of sieve (5) of sieve (3) and the said second layer of sublimating respectively along said liquid oxygen stream piece (9).
3. according to claim 1 or claim 2 a kind of CO 2Seizure device is characterized in that: said first dry ice trap (4) be positioned at said first layer sublimate sieve (3) the bottom, said second dry ice trap (6) be positioned at the said second layer sublimate sieve (5) the bottom.
4. according to claim 1 or claim 2 a kind of CO 2Seizure device is characterized in that: said two layers of sieve (5) of sublimating are finer and closely woven than said layer of sieve (3) of sublimating.
5. a kind of CO as claimed in claim 3 2Seizure device is characterized in that: said two layers of sieve (5) of sublimating are finer and closely woven than the said first layer sieve (3) of sublimating.
6. like claim 1 or 2 or 5 described kinds of CO 2Seizure device is characterized in that: said condensate pipe (2) is arranged on the outside of said inlet (1).
7. a kind of CO as claimed in claim 3 2Seizure device is characterized in that: said condensate pipe (2) is arranged on the outside of said inlet (1).
8. a kind of CO as claimed in claim 4 2Seizure device is characterized in that: said condensate pipe (2) is arranged on the outside of said inlet (1).
9. according to claim 1 or claim 2 a kind of CO 2Seizure device is characterized in that: adopt the insulation heat insulation layer that said seizure device is carried out thermal insulation.
10. like claim 5 or 7 or 8 described a kind of CO 2Seizure device is characterized in that: adopt the insulation heat insulation layer that said seizure device is carried out thermal insulation.
CN201210119468.3A 2012-04-23 2012-04-23 CO2 catching device Expired - Fee Related CN102644528B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210119468.3A CN102644528B (en) 2012-04-23 2012-04-23 CO2 catching device

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CN201210119468.3A CN102644528B (en) 2012-04-23 2012-04-23 CO2 catching device

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CN102644528B CN102644528B (en) 2014-11-05

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114371257A (en) * 2022-01-12 2022-04-19 成都汇能恒源科技有限公司 Indoor evaluation method for carbon dioxide pollution of drilling fluid

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100860020B1 (en) * 2007-12-21 2008-09-25 한국에너지기술연구원 Oxy-fuel combustion boiler system having liquid-oxygen vaporizer exchanging heat with flue gas for carbon capture
CN102003305A (en) * 2010-10-19 2011-04-06 清华大学 Liquid-oxygen carbon-fixation and zero-emission internal combustion engine
CN102213162A (en) * 2010-09-13 2011-10-12 靳北彪 Nitrogen liquefaction carbon dioxide closed engine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100860020B1 (en) * 2007-12-21 2008-09-25 한국에너지기술연구원 Oxy-fuel combustion boiler system having liquid-oxygen vaporizer exchanging heat with flue gas for carbon capture
CN102213162A (en) * 2010-09-13 2011-10-12 靳北彪 Nitrogen liquefaction carbon dioxide closed engine
CN102003305A (en) * 2010-10-19 2011-04-06 清华大学 Liquid-oxygen carbon-fixation and zero-emission internal combustion engine

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114371257A (en) * 2022-01-12 2022-04-19 成都汇能恒源科技有限公司 Indoor evaluation method for carbon dioxide pollution of drilling fluid
CN114371257B (en) * 2022-01-12 2023-11-24 成都汇能恒源科技有限公司 Indoor evaluation method for pollution of drilling fluid by carbon dioxide

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