CN102639102B - Surface modified pigment - Google Patents
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- CN102639102B CN102639102B CN200980161296.2A CN200980161296A CN102639102B CN 102639102 B CN102639102 B CN 102639102B CN 200980161296 A CN200980161296 A CN 200980161296A CN 102639102 B CN102639102 B CN 102639102B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
- A61K2800/61—Surface treated
- A61K2800/62—Coated
- A61K2800/624—Coated by macromolecular compounds
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- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
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- Dermatology (AREA)
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- Cosmetics (AREA)
- Detergent Compositions (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
A composition comprising a pigment particle that is coaled with Polyquaternium-67. The pigment particle can be included in a cleansing composition for deposition on a surface. such as skin.
Description
Background of invention
There is the demand of brilliance increasing skin, such consumer can feel radiant, the smooth and/or gloss of their skin.Evaluate these features via consumer rating, skin glosser is also associated with skin shine detected value.When the product by adopting deposition can increase the pigment of glossiness stay skin gives skin glosser time, by adopting the Cleasing compositions comprising pigment to increase glossiness, will be worth.
The problem of Cleasing compositions is used to be that said composition implements its cleaning function by the oil on removal skin and dirt.In order to effectively, described pigment must wash away to avoid cleaned compositions to adhere to skin through modification.
Manufacture can can't help that Cleasing compositions is removed, the pigment that can adhere to skin in the urgent need to.
Invention summary
Comprise the compositions of wrapping the pigment particles of quilt with Polyquaternium-67 (Polyquaternium-67).Also have the method increasing substrate glossiness, the method comprises described compositions is applied to substrate.
Detailed Description Of The Invention
As used in the whole text, scope is used as being described in each the writing a Chinese character in simplified form with each value within the scope of this.Any value within the scope of this can be selected as the terminal of scope.In addition, all lists of references quoted are herein incorporated into herein by full text reference.As when the disclosure and the definition in the list of references quoted contradictory, based on the disclosure.
Except as otherwise noted, the percentage ratio referred to by weight should be understood to herein with all percentage ratio expressed by other places in this manual and amount.The amount provided is the weight of the activating agent based on raw material.
The present invention relates to the pigment particles with Polyquaternium-67 bag quilt.
Pigment particles can be any particle giving glossiness.The example of pigment particles includes, but are not limited to Muscovitum/titanium dioxide, Muscovitum/ferrum oxide, Muscovitum, titanium dioxide, zinc oxide, ferrum oxide, chromium oxide, silicon dioxide, Pulvis Talci, Kaolin, and combination.In one embodiment, pigment particles is Muscovitum/titanium dioxide.Particle diameter can be selected as any size providing detectable glossiness.The particle diameter of particle uses cation raw material or other encrusting substance bag any by particle diameter before.In one embodiment, particle diameter is 1 to 1000 micron.In other embodiments, particle diameter is at least 10,20,30,40,50,60,60,80,90,100 or 150 microns.In other embodiments, particle diameter is maximum to 100,150,250,300,350,400,450,500,600,700,800,900 or 1000 microns.Any aforesaid minimum can be combined with any maximum with forming range.In one embodiment, particle diameter is 50 to 100 microns.
Polyquaternium-67 is the general purpose I NCI title of the polymeric quaternary ammonium salts of the epoxide reactive hydroxyethyl-cellulose that the epoxide that replaces with trimethyl ammonium and lauryl dimethyl ammonium (dimethyl dodecyl base) replace.Polyquaternium-67 can obtain from the Amerchol subsidiary of Dow Chemical Company with the trade name of SoftCAT.In one embodiment, Polyquaternium-67 is SoftCAT SK-MH.
In one embodiment, the amount of Polyquaternium-67 in the gross weight of pigment particles is 0.1 to 5 % by weight.In other embodiments, the amount of cation raw material is at least 0.1,0.2,0.3,0.4,0.5,0.6,0.7,0.8,0.9,1,1.5,2,2.5,3,3.5,4 or 4.5 % by weight.In other embodiments, the amount of cation raw material is less than 1,1.5,2,2.5,3,3.5,4,4.5 or 5 % by weight.Any aforesaid minimum can merge forming range with any maximum.In another embodiment, the particle diameter of pigment particles is 50 to 100 microns, and cation raw material can be any aforementioned quantities based on the amount of these particles.
In one embodiment, pigment particles is pre-coated (pre-coated).Described pre-coated, meaning this pigment particles is the pigment particles using cation raw material packet quilt before being added into the compositions containing the raw material except itself.
In another embodiment, pigment particles also can comprise isopropyl three isostearic acid titanium (isopropyl titanium triisostearate, ITT).Before or after cation raw material being applied to pigment particles, isopropyl three isostearic acid titanium can be added in pigment particles.In one embodiment, ITT is 0.1 to 5 % by weight based on the amount of pigment particles gross weight.In other embodiments, the amount of ITT is at least 0.1,0.5,1,1.5,2,2.5,3,3.5,4 or 4.5 % by weight.In other embodiments, the amount of ITT is less than 1,2,3,4 or 5 % by weight.Any aforesaid minimum can with any maximum in conjunction with forming range.In another embodiment, the particle diameter of pigment particles is 50 to 100 microns, and ITT can be any aforementioned quantities based on the amount of these particles.
Following technique Polyquaternium-67 can be adopted to prepare pigment particles.
I Polyquaternium-67, there is enough water to dissolve in the container of Polyquaternium-67 under heating, adds in water by () under mixing.
(ii) Polyquaternium-67/water heated and mix until Polyquaternium-67 dissolves.
(iii) pigment is mixed in this mixture.
(iv) by this mixture in 105 DEG C of dryings until fully dry (about 3 hours).
V the cooling of this raw material also grinds by () gently.
(vi) raw material is sieved (such as, with in No. 40 sieves) to remove grumeleuse.
Following technique can be adopted to prepare the particle containing Polyquaternium-67, its ITT added after being included in and using Polyquaternium-67.
I Polyquaternium-67, there is enough water to dissolve in the container of Polyquaternium-67 under heating, adds in water by () under mixing.
(ii) Polyquaternium-67/water heated and mix until Polyquaternium-67 dissolves.
(iii) pigment is mixed in this mixture.
(iv) by this mixture in 105 DEG C of dryings until fully dry (about 3 hours).
V the cooling of this raw material also grinds by () gently.
(vi) raw material is sieved (such as, with in No. 40 sieves) to remove grumeleuse.
(vii) isopropyl three isostearic acid titanium is dissolved in ISOPAR C solvent with 1: 2 ratio.
(viii) under the mixing of blender, solution is added in the powder obtained in step (ix).
(ix) by solution in 85 DEG C of dryings 1 hour.
X the cooling of this raw material also grinds by () gently.
Following technique can be adopted to prepare the particle containing Polyquaternium-67, its ITT added before being included in and using Polyquaternium-67.
I isopropyl three isostearic acid titanium is dissolved in ISOPAR C solvent with 1: 2 ratio by ().
(ii) under the mixing of blender, solution is added in pigment particles.
(iii) by solution in 85 DEG C of dryings 1 hour.
(iv) cooling of this raw material is also ground gently.
V Polyquaternium-67, there is enough water to dissolve in the container of Polyquaternium-67 under heating, adds in water by () under mixing.
(vi) Polyquaternium-67/water heated and mix until Polyquaternium-67 dissolves.
(vii) pigment deriving from step (iv) is mixed in this mixture.
(viii) by this mixture in 105 DEG C of dryings until fully dry (about 3 hours).
(ix) cooling of this raw material is also ground gently.
X raw material sieves by () (such as, with in No. 40 sieves) to remove grumeleuse.
Pigment particles can be included in Cleasing compositions, in such as bath gel (body wash), gluey bath oil (shower gel), soap lye of washing one's hands (liquid hand soap) or soap slab.The amount of the particle in cleaning systems can be any amount being generally used for particle.In certain embodiments, this amount is 0.01 to 20 % by weight of compositions, 0.1 to 10 % by weight or 0.15 to 2 % by weight.In other embodiments, this amount is at least 0.1,0.15,0.2,0.3,0.4,0.5,0.6,0.7,0.8,0.9,1,1.2,1.2,1.3,1.4,1.5 or 2 % by weight, most as many as 20 % by weight.Particle adds in Cleasing compositions by the standard adding technology by any interpolation pigment.
Multiple anion surfactant can be used in Cleasing compositions, comprise, such as, chain alkyl (C
6-C
22) material, such as long chain alkyl sulfates, long chain alkyl sulphonates, chain alkyl phosphate, chain alkyl ether sulfate, chain alkyl alhpa olefin sulfonate, chain alkyl taurate, chain alkyl isethionate (SCI), chain alkyl glycerylether sulfonates (AGES), sulfosuccinate, Stepan-Mild
tMpCL methyl-2 sulfolauric acid sodium and 2-sulfolauric acid disodium and lauryl sulfoacetate sodium mixture etc.These anion surfactants can be oxyalkylated, and such as, ethoxylation, although alkoxylate is optional.These surfactants typically are high water soluble, and this is the salt form containing sodium, potassium, alkyl and ammonium or alkanol ammonium due to them, and can provide the clean dirt ability of highly foaming.The anion surfactant of other equivalence can be used.In one embodiment, anion surfactant comprises sodium lauryl sulphate, alkanol polyethers sodium sulfate (sodium parethsulfate), and combination.The anion surfactant of the amount of any needs can be comprised.In one embodiment, anion surfactant is present in compositions with the amount of 0 to about 15% by weight.In one embodiment, anion surfactant exists with the amount of about 6 to about 8% by weight.
Amphoteric surfactant also can comprise in the composition.These surfactants are combined as feature typically with height surfactant activity, formation of foam and gentleness.Amphoteric surfactant comprises, but be not limited to the derivant of aliphatic secondary amine and tertiary amine, wherein said aliphatic group can be straight or branched, and one of them aliphatic substituent group contains anionic water solubilizing group containing about 8 to about 18 carbon atoms and one, as, carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.The example of such compound comprises 3-sodium dodecyl aminopropionitrile, 3-dodecylamino propanesulfonate, N-alkyl taurine and N-higher alkyl aspartic acids.The amphoteric surfactant of other equivalence can be used.The example of amphoteric surfactant comprises, but be not limited to a series of betanin, comprise, such as, higher alkyl betaines, such as coco dimethyl carboxymethyl group betanin, lauryl dimethyl carboxy-methyl betaine, lauryl dimethyl α-carboxy ethyl betanin, hexadecyldimethyl benzyl ammonium carboxymethyl group betanin, lauryl two-(2-hydroxyethyl) carboxymethyl group betanin, stearyl two-(2-hydroxypropyl) carboxymethyl group betanin, oleyl dimethyl γ-Carboxypropylbetaine and lauryl two-(2-hydroxypropyl) α-carboxy ethyl betanin, sulfobetaines, such as coco dimethyl sulfopropyl betaine, stearyl dimethyl sulfopropyl betanin, amido betaine, amidosulfobetaines etc.Have chain alkyl, particularly the betanin of cocoyl (coco), can be useful especially, as comprised amide groups, and those of such as cocamide base propyl group and cocamide base ethyl betanin.The amphoteric surfactant of the amount of any needs can be comprised.In one embodiment, amphoteric surfactant is present in compositions with the amount of 0 to about 15% by weight.In one embodiment, amphoteric surfactant is present in compositions with the amount of about 4 to about 6% by weight.
The example of non-ionic surface active agent includes, but are not limited to polysorbate20, has C
8-C
22the long chain alkyl glucosides of alkyl; Coconut fatty acid single ethanol amide, such as coconut oleoyl amine (cocamide) MEA; Coconut fatty acid diglycollic amide, alcohol ethoxylate (alkyl Polyethylene Glycol); Alkylphenol Polyethylene Glycol; Alkyl hydrosulfide Polyethylene Glycol; Amine ethoxylates (alkyl amino Polyethylene Glycol); Fatty acid ethoxylate (acyl group Polyethylene Glycol); Polypropylene glycol ethoxylate is (such as by the commercially available PLURONIC of BASF
tMblock copolymer); Fatty acid alkyl alcohol amide, (fatty acid amide Polyethylene Glycol); N-alkyl-, N-alkoxyl polyhydroxy fatty acid amide; Sucrose ester; Sorbitol ester; Polyglycol ether; And combination.The non-ionic surface active agent of the amount of any needs can be comprised.In one embodiment, non-ionic surface active agent is present in compositions with the amount of 0 to about 3% by weight.In one embodiment, non-ionic surface active agent is present in compositions with the amount of about 0.5 to about 1.5% by weight.
Cationic surfactant also can comprise in the composition.The example of cationic surfactant includes, but are not limited to any quaternary ammonium salt or polyquaternium compounds.The cationic surfactant of the level of any needs can be comprised.In one embodiment, cationic surfactant is present in compositions with the amount of 0 to about 2% by weight.In one embodiment, cationic surfactant is present in compositions with the amount of about 0.1 to about 0.3% by weight.
Many other surfactants are described in other reference material that McCUTCHEON ' S DETERGENTS and EMULSIFIERS (1989) and those of ordinary skill in the art know.
In addition, suspending agent can be comprised to form surfactant to help particle suspension.Suspending agent is any raw material increasing the ability that compositions makes raw material suspend.The example of suspending agent includes, but are not limited to composite structure agent, polymeric gel, polysaccharide, pectic substance, alginate, arabinogalactan, carrageenin, gellan gum, xanthan gum, guar gum, La Mushan glue (rhamsan gum), furcellaran (furcellaran gum) and other natural gum.In one embodiment, composite structure agent is polyacrylate.For the formation of a kind of acrylate aqueous solution of the suspension of stable solids by Lu Borun (Lubrizol) company as CARBOPOL
tMproduction of resins, it is also referred to as CARBOMER
tM, be hydrophilic macromolecule amount, crosslinked acrylic acid polymer.In one embodiment, this polymer is CARBOPOL
tMaqua SF-1.Other polymer spendable includes, but are not limited to CARBOPOL
tMaqua30, there is molecular weight about 4, the CARBOPOL of 000,000
tM940 and there is molecular weight about 3, the CARBOPOL of 000,000
tM934.
May be used alone or in combination suspending agent.The amount of suspending agent can be any amount of the level of the suspending ability providing needs.In one embodiment, suspending agent exists with the amount of the weighing scale by compositions about 0.01 to about 15%.In another embodiment, the amount of suspending agent is about 1% to about 10%.
Cleasing compositions can oil-containing and/or vaseline.Spendable oils can be any vegetable oil, such as Oleum Helianthi, soybean oil, Semen Ricini wet goods.
Also can pigment particles be comprised in oral care composition, for making pigment particles be delivered to oral surfaces, such as tooth.
Home care compositions, also can comprise pigment particles in such as hard surface cleaner, dishwasher detergent compositions, softening agent for fibres or laundry detergent compositions.
Compositions can be used in the method for the glossiness increasing substrate.Compositions is applied on substrate.Particle used is the particle that can provide glossiness.After using, compositions can stay for some time, and is then removed.Described a period of time can be time period of any needs, such as 5,10,15,20,30,45 or 60 seconds, or 1,2,3,4,5,10,15,30,60 minute, or any persistent period.
The application can carry out self-cleaning composition, wherein compositions is applied to skin with washed skin.After said composition being used and spreads upon on skin, compositions can be made to rest on skin the preceding paragraph time, wash soap bubble and dry skin afterwards.
Specific embodiment of the invention scheme
Further describe the present invention below in an example.Described embodiment be only exemplary and and never in any form described by restriction with the scope of the present invention of claim.
The embodiment of the pigment particles of preparation.
The SoftCAT SK-MH of 0.5g is added in the distilled water of the 50g in beaker.Heat and mix until SoftCAT SK-MH all dissolves.This solution is added to the KTZ of the 98g under the mixing of agitator
in Shimmer white mica/titania powder.After completing liquid feeding, by mixture in 105 DEG C of dry 3h.Make it cooling and break into pieces gently in agitator.Powder through No. 40 sieved sieves to remove grumeleuse.
The isopropyl three isostearic acid titanium of 2g is dissolved in the Isopar C solvent of 4g.Under mixing, this dropwise is added in 100g powder in agitator, that prepare in [0031].After completing liquid feeding, by mixture in 85 DEG C of dry 1h.Make it cooling and grind gently to remove grumeleuse in agitator.
The isopropyl three isostearic acid titanium of 2g is dissolved in the Isopar C solvent of 4g.Under mixing, this dropwise is added to the 100g KTZ in agitator
in Shimmer white mica/titania powder.After completing liquid feeding, by mixture in 85 DEG C of dryings 1 hour.Make it cooling and grind gently to remove grumeleuse in agitator.Then this raw material can be used for replacing the KTZ in paragraph [0031]
shimmer white mica/titania powder.
Following base composition is used to prepare shower cream composition described below.Shower cream composition is mixed with by making all compositions.
| Raw material | % by weight (activity) |
| C10-16 alcohol ethoxylate sodium sulfate salt (2EO is average) | 9.5 |
| Carbopol TMAqua SF-1 acrylate thickening polymer | 2.7 |
| Cocamido propyl betaine | 1.7 |
| Water, antiseptic and submember (minors) | Q.S. |
With there is no pigment and do not have the matched group bath gel of the pigment processed to contrast, test three kinds of particles, to detect in the glossiness with bath gel washing skin afterwards.Formula in the following table.Formula A comprises the Muscovitum/TiO 2 particles with Polyquaternium-67 bag quilt.Formula B comprises first with Polyquaternium-67 bag quilt, then uses the Muscovitum/TiO 2 particles of isopropyl three isostearic acid titanium bag quilt.Formula C comprises and first uses isopropyl three isostearic acid titanium bag quilt, then with the Muscovitum/TiO 2 particles of Polyquaternium-67 bag quilt.Bath gel is mixed with by making all compositions.In the following table, described amount is the gross weight based on raw material.
| Raw material | Contrast | Untreated | A | B | C |
| Substrate | 96.99 | 96.19 | 96.19 | 96.19 | 96.19 |
| There is no the Muscovitum/TiO 2 pigment processed | 0 | 0.8 | 0 | 0 | 0 |
| Pigment A | 0 | 0 | 0.8 | 0 | 0 |
| Pigment B | 0 | 0 | 0 | 0.8 | 0 |
| Pigment C | 0 | 0 | 0 | 0 | 0.8 |
| Spice | 1 | 1 | 1 | 1 | 1 |
| 25 % by weight saline solution | 2 | 2 | 2 | 2 | 2 |
| 50 % by weight citric acid solutions | 0.01 | 0.01 | 0.01 | 0.01 | 0.01 |
The forearm of selected membership group (panelists) tests bath gel.Forearm is prepared by following program:
I () drenches forearm with flowing warm water,
(ii) with palmolive (Palmolive) soap slab (greenvariant) the prewashing forearm from Colgate-Palmolive Company,
(iii) rinsing and dry forearm,
(iv) with the moistening forearm of flowing warm water,
V () uses 1ml syringe, wherein with the compositions that will test, the center of moistening side is used the compositions of 0.5ml,
(vi) smear (Lathering) compositions 15 seconds at test position, then allow soap bubble stay test position 30 seconds,
(vii) this position is rinsed 15 seconds with warm flowing water by the form making water and flow only through forearm,
(viii) pat dry dorsal forearm gently with napkin, pat dry the region (9the) that palm forearm (volar forearm) uses compositions subsequently,
(ix) use as napkin same in (viii), apply 5 times and bounce using region (palm forearm), dry effect to simulate.
With the Samba Arm systems axiol-ogy skin shine prepared by Bossa Nova technologies, LLC (Venice, CA) and be on sale throughout.Its forearm is inserted by instrument opening by selected membership group.Injection polarized light source, and catch polarized reflection light by Samba polaroid camera and change into glossiness by the software of instrument.This instrument is provided as provided in supplier.Arrange without the need to regulating.After step (iii) drying on forearm examinations to obtain background detection.Again forearm is detected after step (ix) drying.Detection subtracting background afterwards detects the effect namely showing deposition.
The gloss results of following table display bath gel.
Result shows, and surface treated Muscovitum/TiO 2 particles increases the glossiness of skin.In theory, because surface is treated, surface treated Muscovitum/titanium dioxide is rested on skin.Muscovitum/TiO 2 particles then provides extra reflectance to increase glossiness.
Also can by selected membership group assess performance, they assess its skin of forearm voluntarily after using the bath gel containing particle.The following problem of the selected membership group of inquiry is to describe their observation:
Has i how bright () your skin looked? (5 points of gradings)
1=is bright not at all, and 2=is bright a little, and some light of 3=, 4=is very bright, and 5=is very bright
(ii) the measuring of glossiness on your skin is ... (5 points of gradings)
1=is far from enough lights, and 2=is very brightless, and just in time, some is too bright for 4=, and 5=is too bright for 3=brightness
Has (iii) your skin looked honorable? (3 points of gradings)
1=is honorable not at all, and 2=notices that on my skin some is honorable, and 3=notices much brilliance on my skin
(iv) skin lightening (5 points of gradings) is made
1=does not describe at all, and 2=does not describe well, and 3=describes some, and 4=describes well, and 5=ideally describes
V () allows skin look (5 points of gradings) radiant
1=does not describe at all, and 2=does not describe well, and 3=describes some, and 4=describes well, and 5=ideally describes
Bath gel described below is prepared by mixing all compositions.Untreated sample uses the Muscovitum/titanium dioxide not wrapping quilt.Each other comprising of example first uses isopropyl three isostearic acid titanium bag quilt, then with the Muscovitum/titanium dioxide of Polyquaternium-67 bag quilt.Substrate is identical with above substrate.In the following table, described amount is based on the gross weight of raw material.
Ranking method described above is adopted to evaluate above compositions by selected membership group.Use the matched group of 7 selected members, with the Irish Spring that can be purchased from Colgate-Palmolive Company
tMoriginal bath gel not containing any pigment particles implements controlled trial.Following table shows the average grading provided by selected member.
This table shows, and compared to the bath gel containing particle of the bath gel and surface free process that do not have particle, the particle prepared according to the present invention gives higher light and brilliance.
Claims (14)
1. one kind comprises the Cleasing compositions of the pigment particles only using Polyquaternium-67 pre-coated.
2. the compositions of claim 1, particle is wherein for being selected from Muscovitum/titanium dioxide, Muscovitum/ferrum oxide, Muscovitum, titanium dioxide, zinc oxide, ferrum oxide, chromium oxide, silicon dioxide, Pulvis Talci and kaolinic at least one raw material.
3. the compositions of claim 1, particle is wherein Muscovitum/titanium dioxide.
4. the compositions of claim 1, pigment particles wherein also comprises isopropyl three isostearic acid titanium.
5. the compositions of claim 1, its also comprises surfactant.
6. the compositions of claim 5, compositions is wherein bath gel.
7. the compositions of claim 5, it also comprises at least one raw material being selected from oil and vaseline.
8. increase a method for surface gloss, the method comprises the compositions of claim 1 is applied to surface.
9. the method for claim 8, it also comprises from compositions described in surface clean.
10. the method for claim 8, particle is wherein for being selected from Muscovitum/titanium dioxide, Muscovitum/ferrum oxide, Muscovitum, titanium dioxide, zinc oxide, ferrum oxide, chromium oxide, silicon dioxide, Pulvis Talci and kaolinic at least one raw material.
The method of 11. claim 8, pigment particles is wherein Muscovitum/titanium dioxide.
The method of 12. claim 8, compositions also comprises surfactant wherein.
The method of 13. claim 12, compositions wherein also comprises at least one raw material being selected from oil and vaseline.
The method of 14. claim 12, pigment particles is wherein Muscovitum/titanium dioxide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2009/055510 WO2011025503A1 (en) | 2009-08-31 | 2009-08-31 | Surface modified pigment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102639102A CN102639102A (en) | 2012-08-15 |
| CN102639102B true CN102639102B (en) | 2015-03-25 |
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ID=42358674
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200980161296.2A Active CN102639102B (en) | 2009-08-31 | 2009-08-31 | Surface modified pigment |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20120145172A1 (en) |
| EP (1) | EP2473153B1 (en) |
| KR (1) | KR20120050506A (en) |
| CN (1) | CN102639102B (en) |
| AU (1) | AU2009351621B2 (en) |
| BR (1) | BR112012004332A2 (en) |
| CA (1) | CA2769908C (en) |
| MX (1) | MX2012001942A (en) |
| RU (1) | RU2488381C1 (en) |
| WO (1) | WO2011025503A1 (en) |
| ZA (1) | ZA201201293B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011025504A1 (en) | 2009-08-31 | 2011-03-03 | Colgate-Palmolive Company | Surface modified pigment |
| JP2015209380A (en) | 2014-04-24 | 2015-11-24 | ロレアル | Cosmetic composition |
| US9717674B1 (en) | 2016-04-06 | 2017-08-01 | The Procter & Gamble Company | Skin cleansing compositions comprising biodegradable abrasive particles |
| CN105860593B (en) * | 2016-04-08 | 2018-07-27 | 佛山中科欧泊科技有限公司 | A kind of composition, preparation method and application improving pearlescent pigment pearlescent effect |
| PL3235792T3 (en) | 2016-04-18 | 2020-07-13 | Arkema B.V. | Coating apparatus for containers |
| US10806692B2 (en) | 2016-10-03 | 2020-10-20 | The Procter & Gamble Company | Skin cleansing compositions comprising color stable abrasive particles |
| JP2022507476A (en) * | 2018-11-14 | 2022-01-18 | グレイスミンク・インコーポレイテッド | Cosmetic formulations with enhanced dye fixing power and methods and systems for their preparation and use |
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| US3761418A (en) * | 1967-09-27 | 1973-09-25 | Procter & Gamble | Detergent compositions containing particle deposition enhancing agents |
| FR2673838B1 (en) * | 1991-03-14 | 1995-03-03 | Oreal | COSMETIC COMPOSITIONS CONTAINING A DISPERSION OF SOLID PARTICLES WITH A SURFACE COATED WITH A CATIONIC POLYMER. |
| FR2695559B1 (en) * | 1992-09-11 | 1994-10-21 | Oreal | Cosmetic composition containing organic solid particles coated with a cationic polymer. |
| EP0771670B1 (en) * | 1995-11-03 | 2002-02-20 | Iris Graphics, Inc. | Mordanting substrates and agents |
| US6132739A (en) * | 1998-09-01 | 2000-10-17 | Amway Corporation | Makeup compositions and methods of making same |
| US6797382B2 (en) * | 1999-12-01 | 2004-09-28 | Honeywell International Inc. | Thermal interface materials |
| US6566313B1 (en) * | 2000-09-15 | 2003-05-20 | Henkel Corporation | Shampoo and body wash composition and method of use thereof |
| WO2002100652A1 (en) * | 2001-06-12 | 2002-12-19 | Kansai Paint Co., Ltd. | Ink-jet printing |
| JP2004203788A (en) | 2002-12-25 | 2004-07-22 | Kose Corp | Solid water-in-oil type emulsified cosmetic |
| US20040234613A1 (en) * | 2003-02-28 | 2004-11-25 | David Schlossman | Hybrid coated cosmetic powders and methods of making and using same |
| US20040234565A1 (en) * | 2003-05-08 | 2004-11-25 | The Procter & Gamble Company | Method for using personal care compositions containing shiny particles |
| EP1639016B1 (en) * | 2003-06-17 | 2011-03-09 | Union Carbide Chemicals & Plastics Technology LLC | Cellulose ethers |
| US20050079190A1 (en) * | 2003-10-09 | 2005-04-14 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Skin radiance cosmetic compositions |
| US20050142084A1 (en) * | 2003-12-29 | 2005-06-30 | Sanjoy Ganguly | Cosmetic compositions containing nacreous pigments of large sized synthetic mica |
| US7677714B2 (en) * | 2004-10-01 | 2010-03-16 | Hewlett-Packard Development Company, L.P. | Inkjet inks providing improved wet smudge on porous print media |
| US7977288B2 (en) | 2005-01-12 | 2011-07-12 | Amcol International Corporation | Compositions containing cationically surface-modified microparticulate carrier for benefit agents |
| US7473673B2 (en) * | 2006-03-07 | 2009-01-06 | Conopco, Inc. | Hydrophilic structured bar compositions comprising individually coated flat platy particles, each having surface deposition chemistry mechanism |
| US20090013481A1 (en) * | 2007-07-12 | 2009-01-15 | Allwyn Colaco | Composition to impart benefit agents to anionic substrates and methods of its use |
| US20100255044A1 (en) * | 2009-03-30 | 2010-10-07 | Susan Daly | Method of depositing particulate benefit agents on keratin-containing substrates |
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- 2009-08-31 RU RU2012112603/15A patent/RU2488381C1/en not_active IP Right Cessation
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| WO2011025503A1 (en) | 2011-03-03 |
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| AU2009351621A1 (en) | 2012-02-23 |
| CN102639102A (en) | 2012-08-15 |
| KR20120050506A (en) | 2012-05-18 |
| CA2769908A1 (en) | 2011-03-03 |
| RU2488381C1 (en) | 2013-07-27 |
| ZA201201293B (en) | 2014-07-30 |
| EP2473153B1 (en) | 2017-10-25 |
| AU2009351621B2 (en) | 2013-02-07 |
| US20120145172A1 (en) | 2012-06-14 |
| BR112012004332A2 (en) | 2016-03-15 |
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