CN104661636A - Mild foaming make-up remover composition - Google Patents
Mild foaming make-up remover composition Download PDFInfo
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- CN104661636A CN104661636A CN201380044248.1A CN201380044248A CN104661636A CN 104661636 A CN104661636 A CN 104661636A CN 201380044248 A CN201380044248 A CN 201380044248A CN 104661636 A CN104661636 A CN 104661636A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
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- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
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- Birds (AREA)
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- Dispersion Chemistry (AREA)
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Abstract
A make-up remover composition suitable for dispensing from a mechanical pump foamer is provided for abundant and long-lasting foam properties on wet skin as well as on dry waxy makeup. The foam remains stable at -5 C. The inventive make-up remover composition also is expected to provide an enhanced moisturizing feeling to the skin after rinsing compared to comparative products. The composition includes a specific minimum ratio of C10-C14 acyl argininate to C10-C14 acyl glycinate in an aqueous polyol surfactant matrix.
Description
Background of invention
2,
background technology
An important component part of Cosmetic Market is the product for removing ornaments and formal dress.The removal of the pigment of eye shadow, mascara, rouge, lip pomade and sweet powder (face powder) is the everyday problem of many women.This problem is resolved by comprising by solvent action or the preparation of material that worked by emulsification, such as, can obtain the product form of O/W emulsifiable paste, gel, oil or flap-type.Recently, the cleansing composition used by pump foam maker allotter is come into the market, and it can allow people in shower or shower, namely uses easily with wet hands, and the form of foam allocated product of not dripping with snap action on skin.
The people such as Kobayashi WO2008052956 disclosed in 8 days Mays in 2008 describes a kind of Cleasing compositions, it comprise one or more non-saccharide polyol fatty acid three esters and one or more sugar alcohol fatty acid four esters with the admixture of specific ratios and with oily fusion, it in a wetted condition, such as with wet hands makeup removing, and the problem impaired with makeup removal efficiency that be not separated.
Astoundingly; discovery comprises one or more acylglycine salt and one or more acyl group arginine (acyl argininate) with the admixture of specific ratios scope and the preparation of one or more polynary alcohol and waters of fusion; compared with contrast makeup removal products; produce a large amount of with lasting foam when being assigned on wet skin, and clean and expection moistening skin.In addition, product of the present invention under the low temperature of-5C not for contrast product with prior art products is visible is separated and the problem of foam volume deficiency.
Preferably, product of the present invention adopts adverse current (countertop) mechanical pump upwards to use, and is directly assigned on hand to make foam.Preferably, pump is positioned at a stable position, can be used for Pressing pump allocated product to make hands or forearm.This causes much cleaner cleaning course.Foam in addition, do not need to use water Initial dilution, because can easily be distributed on skin before flushing.Product of the present invention is preferably transparent.Transparency is defined as the turbidity having and be less than or equal to 105NTU (nephelometric turbidity unit) in this article.
1,
invention field
The present invention relates to cosmetic composition for removing makeup, it is assigned as lasting foam advantageous by non-aerosol pump foam maker allotter.
Summary of the invention
An aspect of of the present present invention is moisture for cleaning skin, preferably clear, the fluid composition of preferably foaming, and described compositions includes but not limited to:
A. total concentration scope is one or more C8 to C18 soaps of about 0.1 to 10wt.%;
B. total concentration scope is one or more C10 to C14 acylglycine salt of about 5 to 25wt.%;
C. total concentration scope is one or more C10 to C14 acyl group arginine of about 0.01 to 0.1wt.%;
D. the water of about 30wt.% is greater than;
E. wherein the ratio of one or more acyl group arginine and one or more acylglycine salt is less than about 0.008; With
F. concentration is one or more polyhydric alcohol of about 20 to 40.0wt.%.
Another preferred embodiment is the packaging product comprising above-mentioned composition for cleaning skin, and wherein said compositions is included in mechanical pump foam dispenser, dispense foam in this mechanical pump foam dispenser.
Another preferred embodiment is clean and gets on except the method for wax-like cosmetics from user skin, and described method includes but not limited to following steps:
A. with form of foam be assigned effective amount for getting on except the above-mentioned composition of oil-based cosmetic preparation from wet skin;
B. foam is applied to wet skin;
C. foam is massaged on wet skin time enough to disperse the oil-based cosmetic preparation remained on skin; With
D. the oil-based cosmetic preparation of foam compositions and dispersion is rinsed from skin.
Detailed Description Of The Invention
The all publications mentioned herein and patent application, patent and other lists of references are incorporated herein by reference with its entirety.
An aspect of of the present present invention is moisture for cleaning skin, preferably clear, the fluid composition of preferably foaming, and described compositions includes but not limited to:
A. total concentration scope is about 0.1 to 10wt.%; Preferably 0.1 to 5.0 and more preferably 0.1 to 1.0 one or more C8 to C18 soaps;
B. total concentration scope is about 5 to 25wt.%; Preferably 5.0 to 15.0 and more preferably 10.0 to 15.0 one or more C10 to C14 acylglycine salt;
C. total concentration scope is about 0.01 to 0.1wt.%; Preferably 0.01 to 0.08 and more preferably 0.02 to 0.08 one or more C10 to C14 acyl group arginine;
D. the water of about 30wt.% is greater than; Be preferably greater than 40.0 and more preferably greater than 50.0;
E. wherein the ratio of one or more acyl group arginine and one or more acylglycine salt is less than about 0.008; Preferably be less than 0.007 and be more preferably less than 0.005; With
F. concentration is about 20 to 40.0wt.%, preferably about 20.0 to 35.0 and more preferably from about 25.0 to 35.0 one or more polyhydric alcohol.
In a preferred embodiment, the ratio of one or more acyl group arginine and one or more acylglycine salt is greater than 0.0004 and is preferably greater than 0.002.Advantageously, the minimum rate of one or more acyl group arginine and one or more acylglycine salt is in 0.002 to 0.0004 scope and preferably in 0.002 to 0.005 scope.
Described compositions is preferably the moisture transparent liquid foamable composition for cleaning skin.
Advantageously, compositions of the present invention comprises total concentration further for about 1 to 5wt.%, preferably about 1.0 to 4.0 and more preferably from about 1.0 to 3.0 one or more C8 to C12 glucosides.Preferably also comprise total concentration for about 1 to 5wt.%, preferably about 1.0 to 4.0 and more preferably from about 1.0 to 3.0 one or more C8 to C12 hydroxyl sulfo betaines (hydroxysultaine).More preferably, the viscosity of compositions of the present invention under 25C is less than 40.0mPas, is preferably less than 35.0mPas and is more preferably less than 30.0mPas.
Another preferred embodiment is the packaging product comprising above-mentioned composition for cleaning skin, and wherein said compositions is included in mechanical pump foam dispenser, dispense foam in this mechanical pump foam dispenser.
Another preferred embodiment is clean and gets on except the method for wax-like cosmetics from user skin, and described method includes but not limited to following steps:
A. with form of foam be assigned effective amount for getting on except the above-mentioned composition of oil-based cosmetic preparation from wet skin;
B. foam is applied to wet skin;
C. foam is massaged on wet skin time enough to disperse the oil-based cosmetic preparation remained on skin; With
D. the oil-based cosmetic preparation of foam compositions and dispersion is rinsed from skin.
soap
General C8-C18 alkyl carboxylic acid soap can be used for the present invention.Preferably, one or more carboxylic soaps, such as lauric acid (C12) soap, myristic acid (C14) soap, Palmic acid (C16) soap or stearic acid (C18) soap, be used alone or in combination.Advantageously, be low to moderate the concentration of 0.1wt.% and height to 1,5 or the concentration of 10wt.% use one or more soaps.
the anion surfactant of synthesis
Use one or more C10-C14 acylglycine salt in the present compositions.Its preferably be low to moderate the concentration of 5 or 10wt.% and height to 15,20 or the concentration of 25wt.% use.Compositions of the present invention also comprises one or more acyl group arginine with following formula (acyl arginate), and wherein R can have the value of 10 to 14 and the unbranched alkyl chain (lauroyl arginine (lauroyl arginate)) of preferred expression 11 carbon
Other anionic detersive active matters used in the present invention can be aliphatic sulfonates, and such as primary alkyl is (as C
8-C
22) sulfonate, primary alkyl is (as C
8-C
22) disulfonate, C
8-C
22alkene sulfonate, C
8-C
22hydroxy alkyl sulfonic acid salt or alkyl glyceryl ether sulfonate (AGS); Or aromatic sulphonate, such as alkylbenzenesulfonate.Anion surfactant also can be alkyl sulfate (such as C
12-C
18alkyl sulfate) or alkyl ether sulfate (comprising alkyl glyceryl ether sulfates).Alkyl ether sulfate comprises those with following formula:
RO(CH
2CH
2O)
nSO
3M
Wherein R is for having 8 to 18 carbon, preferably the alkyl or alkenyl of 12 to 18 carbon, and n has and is greater than 1.0, is preferably greater than the meansigma methods of 3; And M is solubilising cation, the ammonium of such as sodium, potassium, ammonium or replacement.Preferred Zetesol AP and sodium laureth sulfate.
Anion surfactant may also be alkyl sulfosuccinates salt and (comprises list-and dialkyl group, such as C
6-C
22sulfosuccinate ester salt); Alkyl and acyl taurine salt, alkyl and acyl sarcosinates, sulfosalicylic acetate, C
8-C
22alkyl phosphate salt and phosphate ester salt, alkyl phosphate and alkoxyalkyl phosphate ester, acyl-lactate, C
8-C
22mono-alkyl succinic acid ester salt and maleate salt, sulfosalicylic acetate, alkyl androstanediol and acyl-hydroxyethyl sulfonate etc.
Sulfosuccinate ester salt can be the monoalkyl sulfosuccinate ester salt of following formula:
R
4o
2cCH
2cH (SO
3m) CO
2m; With
Amide-MEA the sulfosuccinate ester salt of following formula:
R
4CONHCH
2CH
2O
2CCH
2CH(SO
3M)CO
2M，
Wherein R
4for C
8-C
22alkyl and M is solubilising cation.
Sarcosinate is generally expressed from the next:
R
1CON(CH
3)CH
2CO
2M，
Wherein R
1for C
8-C
20alkyl and M is solubilising cation.
Taurate is generally expressed from the next:
R
2CONR
3CH
2CH
2SO
3M，
Wherein R
2for C
8-C
20alkyl, R
3for C
1-C
4alkyl and M is solubilising cation.
polyhydric alcohol
There are one or more polyhydric alcohol in compositions of the present invention.These polyhydric alcohol can be monomer or polymerization.Monomeric polyols can have 1 to 20 carbon atom and 2 to 10 hydroxyls.The monomeric polyols that can exemplify comprises glycerol, propylene glycol, BDO, 1,3 butylene glycol, 1,2-butanediol, 1,6-hexanediol, 1,2-hexanediol, 3-methyl isophthalic acid, 3-butanediol, 2-methyl isophthalic acid, ammediol, Sorbitol and composition thereof etc.Particularly preferably be glycerol, propylene glycol and 1,3 butylene glycol.
The polyhydric alcohol of the polymerization that can exemplify is polypropylene glycol, Polyethylene Glycol, dipropylene glycol, diglycerol, polyglycereol, 1,3-PD, dipentaerythritol and combination thereof etc.
non-ionic surface active agent and amphoteric surfactant
Multiple non-ionic surface active agent and amphoteric surfactant can be used as other component optionally of the present invention.Non-ionic surface active agent normally based on hydrophobe unit, such as, has fatty alcohol or the fatty acid of about 10 to about 22 carbon atoms, has the alkyl phenol of about 6 to about 12 carbon atoms, anhydro sorbitol and composition thereof in alkyl chain.These hydrophobes usually and hydrophilic unit, particularly with 1 to about 50, preferably about 10 to about 30 moles oxirane, expoxy propane, epoxy butane or its mixture condensation.The material that can exemplify is POE-20 Arlacel-20, POE-20 cetyl ether, POE-7 glyceryl cocoate, POE-15 stearyl ether, POE-10 stearyl ether, POE-15 palmityl ether and combination thereof etc.Other useful non-ionic surface active agent is that the APG that can obtain from BASF AG and Kao Corp. is as lauryl poly glucoside.Another kind of nonionic emulsifier is long chain tertiary amine oxides.Example comprises dimethyl dodecylamine oxide, dimethyl hexadecyl amine oxide, two (2-hydroxyl) tetradecylamine oxide, dimethyldecylamine oxide and combination thereof etc.
Amphoteric surfactant, such as betaines (betaines) and sulfobetaines bases (sultaines) also can adopt.Suitable example comprises C8-C12 hydroxyl sulfo betaine class, such as lauryl hydroxyl sulfo betaine, cocoamidopropyl, cocoamido sulfobetaines, dodecyldimethylammonium hydroxide inner salt, Cetyl dimethyl betaine and combination thereof etc.
The amount of non-ionic surface active agent can be about 0.1 of composition weight to about 10% separately, preferably about 0.2 to about 5%, be preferably about 0.3 to about 7%.The amount of amphoteric surfactant can be about 0.1 of composition weight to about 10% separately, preferably about 0.2 to about 5%, be preferably about 0.3 to about 7%.
other components
Water, preferably to be greater than about 30wt.%, is preferably greater than 40.0wt.% and amount more preferably greater than 50.0wt.% exists.The amount of water is preferably less than 75wt.%.Preferably, the amount of water is 30wt.% to 75wt.%.
Antiseptic also can mix in preparation of the present invention usually.Representational material comprises phenyl phenol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate, ethylenediaminetetraacetic acid (EDTA) salt, benzylalcohol, iodopropynyl butylcarbamate, DMDM Hydantoin, caprylyl glycol (caprylyl glycol) and combination thereof etc.These amount of substances can be any value in about 0.0001 to about 1% of composition weight.
Optional accessory constituent can comprising toner, spice, promotion composition (promotional ingredients), separately for its effective dose is to realize its respective function.Typical promotion composition comprises vitamin, such as retinyl palmitate (retynyl palmitate), tocopherol acetate and nicotiamide.Other promotes that composition comprises conjugated linoleic acid, ceramide, pentapeptide and combination thereof.
Compositions of the present invention preferably not containing any oil phase, does not especially contain water-insoluble emollient.Term " not containing " refers to and is less than 0.05%, and be preferably less than the emollient of 0.01%, water-insoluble refers to that the dissolubility of arbitrary emollient when 25C in distilled water is less than the every 100mL of about 1gm, is more preferably less than the every 100mL of about 0.1gm.The disappearance of water-insoluble emollient makes compositions can be transparent and has the foaminess of improvement.
The viscosity of the present composition is under 25C preferably in 1 to 50mPas scope, and preferably 1 to 40mPas, is measured by Brookfield Model LVDV-II+, Spindle NoLV1 as used 60rmp and 1 minute Measuring Time.
non-aerosol foaming dispenser
A preferred embodiment according to cleaning product of the present invention is the non-aerosol foaming dispenser comprising the present composition.Compositions of the present invention is distributed with form of foam, and producing lasting and abundant foam with during wet contact skin.
Suitable allotter be machinery and general features for for the container (preferably clear container) of storage composition, the dispensing head that limited by the shell containing pump, and for compositions being sent to from container the dip-tube of dispensing head.Foam is by requiring that compositions is through can be that the screen material of porous material such as sintered material, silk thread (plastics or metal) gauze or similar structures produces.Preferred use two screen clothes.
Suitable mechanical dirstributor is described in U.S. Patent No. 3,709,437 (Wright), U.S. Patent No. 3,937,364 (Wright), U.S. Patent No. 4,022,351 (Wright), U.S. Patent No. 4,147,306 (Bennett), U.S. Patent No. 4,184,615 (Wright), U.S. Patent No. 4,598,862 (Rice), U.S. Patent No. 4,615,467 (people such as Grogan) and U.S. Patent No. 5, in 364,031 (people such as Tamiguchi).All these patents are hereby incorporated by.
The F5L pump foam maker head that preferred foam maker manufactures for the Daiwa company being positioned at (Tokyo, Japan).This foam maker is for carrying out foam stabilization Journal of Sex Research and the research of pumping simplification of discussion in embodiment 1.F5L device has following characteristics:
Sieve size: 255 orders (top)/200 (bottom)
Gas/liquid ratio: 9.5/1
Often push away volume once: 0.95g.
Other suitable foaming dispenser can comprise extruding foaming device.Extruding foaming device packaging is well-known, and as illustrated in the disclosure by patent below, these patents are hereby incorporated by.U.S. Patent No. 3,709,437, Wright, on January 9th, 1973 authorizes; 3,937,364, Wright, on February 10th, 1976 authorizes; 4,022,351, Wright, on May 10th, 1977 authorizes; 4,147,306, Bennett, on April 3rd, 1979 authorizes; 4,184,615, Wright, on January 22nd, 1980 authorizes; 4,598,862, Rice, on July 8th, 1986 authorizes; And the people such as 4,615,467, Grogan, on October 7th, 1986 authorizes; With French Patent (FRP) 2,604,622, Verhulst, on April 8th, 1988 announces.
When using extruding foaming device, compositions is placed in container device (plastic extrusion bottle).Impel compositions by foam maker head with hands squeeze receptacle, or other foam generating devices, wherein compositions mixes with air and then through homogenizer, makes foam evenly and control the denseness of foam.Then foam is discharged with uniform non-pressurised aerated foam form.
Now, will by nonrestrictive embodiment more detailed description the present invention below.These embodiments are only exemplary purposes, are not intended to limit the present invention by any way.Physical test method is described below:
except in operation embodiment and comparative example, or outside other clearly indicates in addition, in this description
the amount of indicator substance or ratio or reaction condition, the physical property of material and/or all numerical value of purposes should be understood
for being modified by word " about ".
The term used in this description " comprises " existence that expection comprises indication feature, entirety (integer), step, component, but does not get rid of one or more features, entirety (integer), step, component or its existence of combining or interpolation.
Except as otherwise noted, in this description and embodiment, all percentage ratio expections are by weight.
embodiment 1
According to table 1, use program described below to prepare a series of embodiments of the invention and comparative example, under-5C, assess clarity, simplification with foam stability during wet substrate contact and on dry cosmetic foundation and pumping foam to use above-described F5L foam maker pump.
Based on the result reported in Table 1, it is evident that, when comparing with comparative sample, sample of the present invention has foam stability best under both wet and dry conditions and usual better pumping simplification.
Test method:
(1) dissolubility
Amisafe is joined in Amilite GCK-12K under 20C (room temperature), is under agitation heated to 80C subsequently.If it dissolves after 10 minutes under 80C, so deciding grade and level is " good ".If there is visible insoluble matter to remain after 10 minutes, so deciding grade and level is " NG ".
(2) foam stability on wet surface
1. with water moistening napkin but not hydrops (pooling the water) equably.
2. on wet paper towel, distribute the about 0.7g sample from F5L pump foam maker.
3. at ambient conditions, about 20C (room temperature) and 50%RH observes foam property after lower 15 minutes in atmosphere.
4. carry out the classification of foam stability as follows:
+ all lather collapses
++ some lather collapses
+++ seldom lather collapse
(3) foam stability on dry cosmetic foundation
1. on polypropylene plastics flitch, (Shiseido MAQUILLAGE Lasting Liquid UV, Ochre 10 All Season Type, can purchased from Shiseido to use the foundation cream of 0.2g with the even square pattern of 1.5cm × 1.5cm, Tokyo, Japan).
2. at ambient conditions, make its dry 10 minutes in atmosphere under about 20C (room temperature) and 50%RH.
3. on the foundation cream of drying, distribute the about 0.7g sample from F5L pump foam maker.
4. at ambient conditions, about 20C (room temperature) and 50%RH observes foam stability after lower 15 minutes in atmosphere.
5. carry out the classification of foam stability as follows:
+ all lather collapses
++ some lather collapses
+++ seldom lather collapse
(4) simplification of dispense foam from pump
Use liquid cleaning product filling containers, leave air space simultaneously.With the F5L pump foam maker head sealing that Daiwa Corporation (Tokyo, Japan) manufactures.Whether Pressing pump is also observed foam and is assigned with.If foam is assigned with, then from pump, the simplification grade of dispense foam is " good ".If foam is not assigned with (such as only liquid is assigned with), then from pump, the simplification grade of dispense foam is " NG ".
(5) moisture-keeping function test
1. gather one group of trained people.
2. on the right forearm of each group member, place a kind of test specimen of about 3g.
3. use tap water a few minutes at ambient temperature.
4. towel, then each group member feels classification, then by whole classification adduction with best result 5 points to moisturizing.
5. on the left forearm of each group member, use the contrast test sample repeated trials of about 3g.
6. or the skin moisture-keeping effect that suitable instrumental method can be utilized to come between comparative sample.All Instrument Evaluations are undertaken after the laundering period of 30 minutes.Recording room humidity and temperature data, and be included in last report.Apparatus measures can be carried out in some or all of following time point: 0,1,2,4,6,8 and 24 hour after products applied.The instrument that can use together with this scheme includes but not limited to ServoMed Evaporimeter (the SeroMed AB with EP1 or EP2 probe, Stockholm, Sweden), Comeometer CM820 (COURAGE+KHAZAKA electronic GmbH, Cologne, Germany), there is Skicon Skin Hygrometer (the I.B.S CO. of MT-8C probe, LTD., Shizuoka-ken, and Moisture Checker (STR-School & Science TechnologyResources Japan), Scotts Valley, Ca).Room temperature remains on 68 ° to 77 °F and relative humidity is 30% to 40%.Moisture-keeping function is defined as the mean change from (vision drying or skin hydration) baseline.
(6) program of illustrative embodiment in preparation table 1:
1. under 80C, Amisafe is dissolved in (mutually 1) in Amilite GCK-12K, until solution clarification.
2. under 80C, water and glycerol are mixed to evenly (mutually 2).
3. will mutually 1 join and mix in 2 mutually under 80C.
4. under 80C, add NONSOUL LK-30 and mix.
5. add Amphitol, Mydol 12 and fully mixing.
6. be cooled to 35C.
(7) turbidity
For purposes of the present invention, the acceptability of preparation transparency or clarity can be measured with the ocular estimate of turbidimetric analysis turbidimetry and scopometer respectively with carrying out quantitative and qualitative analysis.Briefly, ocular estimate comprises by determining that the preparation of path is observed sensation target and determines that whether described sensation target is clearly or discernible.This target can be the straight line be imprinted on blank sheet of paper, one group of parallel lines, digital or alphabetical.Test preparation is placed in glass beaker, makes the height from the bottom of beaker to the end face of preparation be four inches.Guarantee preparation not bubbles.The a piece of paper with sensation target is placed under beaker.Sensation target is seen by preparation end face.If sensation target seems that preparation has acceptable clarity and obtains the grading of " passing through " with original similar.If sensation target seems obviously fuzzy compared to original object, or out of focus, then preparation has unacceptable clarity, and obtains the grading of " failure ".
Turbidity can pass through scopometer (model DRT-100D is manufactured by Shaban Manufacturing Inc, H.F.Instruments Division) use diameter 28mm, the flat article colorimetric ware of long 91mm carrys out quantitative assay.The sample of being graded by ocular estimate acquisition " passing through " expects to have the turbidity measurement being less than or equal to 105NTU ' s (nephelometric turbidity unit).The sample of being graded by ocular estimate acquisition " failure " has the turbidity measurement being greater than 105NTU ' s.
Aforementioned specification and embodiment illustrate selected embodiment of the present invention.Accordingly, those skilled in the art can expect variation and amendment, and all these is within scope and spirit of the present invention.
Claims (9)
1., for the moisture fluid composition of cleaning skin, described compositions comprises:
A. total concentration scope is one or more C8 to C18 soaps of about 0.1 to 10wt.%;
B. total concentration scope is one or more C10 to C14 acylglycine salt of about 5 to 25wt.%;
C. total concentration scope is one or more C10 to C14 acyl group arginine of about 0.01 to 0.1wt.%;
D. the water of about 30wt.% is greater than;
E. wherein the ratio of one or more acyl group arginine and one or more acylglycine salt is less than about 0.008; With
F. concentration is one or more polyhydric alcohol of about 20 to 40.0wt.%.
2. compositions according to claim 1, wherein said compositions is transparent.
3., according to the compositions of claim 1 or 2, wherein said compositions is composition, foam.
4., according to the compositions of aforementioned any one of claim, comprise one or more C8 to C12 glucosides that total concentration is about 1 to 5wt.% further.
5., according to the compositions of aforementioned any one of claim, comprise one or more C8 to C12 hydroxyl sulfo betaines that total concentration is about 1 to 5wt.% further.
6., according to the compositions of aforementioned any one of claim, the viscosity wherein under 25C is less than 40.0mPas.
7. for the packaging product comprising the compositions of aforementioned any one of claim of cleaning skin, wherein said compositions is included in mechanical pump foam dispenser, dispense foam in this mechanical pump foam dispenser.
8. clean and get on except the method for wax-like cosmetics from user skin, said method comprising the steps of:
A. with form of foam be assigned effective amount for getting on except the compositions any one of claim 1 to 6 of oil-based cosmetic preparation from wet skin;
B. foam is applied to wet skin;
C. foam is massaged on wet skin time enough to disperse the oil-based cosmetic preparation remained on skin; With
D. the oil-based cosmetic preparation of foam compositions and dispersion is rinsed from skin.
9. method according to claim 8, wherein said foam is by distributing containing the non-aerosol foaming dispenser of the compositions any one of with good grounds claim 1 to 6.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1215054.6 | 2012-08-23 | ||
| GB201215054A GB201215054D0 (en) | 2012-08-23 | 2012-08-23 | Mild foaming make-up remover composition |
| PCT/EP2013/067191 WO2014029711A2 (en) | 2012-08-23 | 2013-08-16 | Mild foaming make-up remover composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104661636A true CN104661636A (en) | 2015-05-27 |
| CN104661636B CN104661636B (en) | 2017-05-10 |
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ID=47045303
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380044248.1A Active CN104661636B (en) | 2012-08-23 | 2013-08-16 | Mild foaming make-up remover composition |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JP6333253B2 (en) |
| CN (1) | CN104661636B (en) |
| BR (1) | BR112015003693A2 (en) |
| EA (1) | EA027395B1 (en) |
| GB (1) | GB201215054D0 (en) |
| MX (1) | MX352365B (en) |
| TW (1) | TWI586372B (en) |
| WO (1) | WO2014029711A2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110621289A (en) * | 2017-05-10 | 2019-12-27 | 荷兰联合利华有限公司 | Low viscosity, high polyol self-foaming compositions |
| CN113226268A (en) * | 2019-02-15 | 2021-08-06 | 拜尔斯道夫日化（武汉）有限公司 | Cleansing composition capable of releasing in form of stable foam |
| WO2023065258A1 (en) * | 2021-10-22 | 2023-04-27 | Beiersdorf Ag | A mild cleansing composition distributable from a pump foamer |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102015217502A1 (en) * | 2015-09-14 | 2017-03-16 | Henkel Ag & Co. Kgaa | Cleaning compositions with biosurfactants in a foam dispenser |
| WO2020164087A1 (en) * | 2019-02-15 | 2020-08-20 | Beiersdorf Daily Chemical (Wuhan) Co. Ltd. | A cleansing composition releasable as a shapeable foam |
| WO2021100812A1 (en) | 2019-11-20 | 2021-05-27 | 味の素株式会社 | Detergent composition for foamer |
| WO2024208675A1 (en) * | 2023-04-05 | 2024-10-10 | Surfactgreen | Surfactant composition based on a mixture of dibasic amino acid ester and glycine betaine ester, and uses thereof |
Citations (4)
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|---|---|---|---|---|
| EP1151743A2 (en) * | 2000-04-27 | 2001-11-07 | Kao Corporation | Cosmetic emulsion |
| US20030224955A1 (en) * | 2002-03-28 | 2003-12-04 | Delphine Ribery | Foaming cosmetic compositions, uses for cleansing or make-up removal |
| WO2009112432A2 (en) * | 2008-03-12 | 2009-09-17 | Unilever Plc | Make-up removal composition which provides good foam |
| DE102011107503A1 (en) * | 2011-07-15 | 2012-03-01 | Clariant International Ltd. | Preparing acylglycinate compound useful in a composition, which is used as a surfactant in a cosmetic preparation, comprises reacting glycine with fatty acid chloride in water and in the presence of a basic alkali metal compound |
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| US4022351A (en) | 1975-04-03 | 1977-05-10 | Hershel Earl Wright | Foam dispenser |
| US4184615A (en) | 1975-04-03 | 1980-01-22 | Wright Hershel E | Foam dispensing device |
| US3937364A (en) | 1975-04-03 | 1976-02-10 | Hershel Earl Wright | Foam dispensing device |
| US4147306A (en) | 1977-09-28 | 1979-04-03 | Bennett Robert S | Foam producing apparatus |
| US4598862A (en) | 1983-05-31 | 1986-07-08 | The Dow Chemical Company | Foam generating device and process |
| US4615467A (en) | 1985-07-24 | 1986-10-07 | Calmar, Inc. | Liquid foam dispenser |
| JPH0246639B2 (en) * | 1985-12-12 | 1990-10-16 | Kao Corp | SENJOZAISOSEIBUTSU |
| FR2604622B1 (en) | 1986-10-06 | 1990-12-14 | Applied Chemical Research Corp | LIQUID COMPOSITION FOR SHAVING FOAM FOR USE WITHOUT PROPELLANT GAS IN A BOTTLE OF COMPRESSIBLE PLASTIC MATERIAL |
| US5364031A (en) | 1993-06-10 | 1994-11-15 | The Procter & Gamble Company | Foam dispensing nozzles and dispensers employing said nozzles |
| JP3556755B2 (en) * | 1996-01-09 | 2004-08-25 | 株式会社ノエビア | Makeup removal fee |
| JP3662513B2 (en) * | 2000-04-27 | 2005-06-22 | 花王株式会社 | Emulsified cosmetics |
| JP4551557B2 (en) * | 2000-12-08 | 2010-09-29 | 阪本薬品工業株式会社 | Skin cleanser composition |
| JP2003055131A (en) * | 2001-06-06 | 2003-02-26 | Ajinomoto Co Inc | Cosmetic composition |
| JP2003267836A (en) * | 2002-03-18 | 2003-09-25 | Rohto Pharmaceut Co Ltd | Gel-like cleansing cosmetic |
| JP4527655B2 (en) * | 2004-11-30 | 2010-08-18 | ライオン株式会社 | Cleaner composition in former container |
| GB0621993D0 (en) | 2006-11-04 | 2006-12-13 | Unilever Plc | Make-up remover cosmetic compositions |
| DE102009034115A1 (en) * | 2009-07-20 | 2011-01-27 | Beiersdorf Ag | Cosmetic preparation containing acylarginates |
| EP2523649B1 (en) * | 2010-01-15 | 2016-11-30 | Ajinomoto Co., Inc. | N-acyl basic amino acid dispersion |
| DE102010007958A1 (en) * | 2010-02-12 | 2011-08-18 | Beiersdorf AG, 20253 | Active ingredient combinations of acylarginates and quaternary ammonium compounds |
| JP2014218475A (en) * | 2013-05-10 | 2014-11-20 | ライオン株式会社 | Antiperspirant composition |
| JP6337729B2 (en) * | 2014-10-01 | 2018-06-06 | 日油株式会社 | Hair cleaning composition |
-
2012
- 2012-08-23 GB GB201215054A patent/GB201215054D0/en not_active Ceased
-
2013
- 2013-08-14 TW TW102129168A patent/TWI586372B/en not_active IP Right Cessation
- 2013-08-16 BR BR112015003693A patent/BR112015003693A2/en not_active Application Discontinuation
- 2013-08-16 JP JP2015527873A patent/JP6333253B2/en active Active
- 2013-08-16 CN CN201380044248.1A patent/CN104661636B/en active Active
- 2013-08-16 EA EA201590177A patent/EA027395B1/en not_active IP Right Cessation
- 2013-08-16 WO PCT/EP2013/067191 patent/WO2014029711A2/en active Application Filing
- 2013-08-16 MX MX2015002280A patent/MX352365B/en active IP Right Grant
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1151743A2 (en) * | 2000-04-27 | 2001-11-07 | Kao Corporation | Cosmetic emulsion |
| US20030224955A1 (en) * | 2002-03-28 | 2003-12-04 | Delphine Ribery | Foaming cosmetic compositions, uses for cleansing or make-up removal |
| WO2009112432A2 (en) * | 2008-03-12 | 2009-09-17 | Unilever Plc | Make-up removal composition which provides good foam |
| DE102011107503A1 (en) * | 2011-07-15 | 2012-03-01 | Clariant International Ltd. | Preparing acylglycinate compound useful in a composition, which is used as a surfactant in a cosmetic preparation, comprises reacting glycine with fatty acid chloride in water and in the presence of a basic alkali metal compound |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110621289A (en) * | 2017-05-10 | 2019-12-27 | 荷兰联合利华有限公司 | Low viscosity, high polyol self-foaming compositions |
| CN113226268A (en) * | 2019-02-15 | 2021-08-06 | 拜尔斯道夫日化（武汉）有限公司 | Cleansing composition capable of releasing in form of stable foam |
| WO2023065258A1 (en) * | 2021-10-22 | 2023-04-27 | Beiersdorf Ag | A mild cleansing composition distributable from a pump foamer |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2015526451A (en) | 2015-09-10 |
| JP6333253B2 (en) | 2018-05-30 |
| EA027395B1 (en) | 2017-07-31 |
| MX2015002280A (en) | 2015-08-20 |
| TW201408331A (en) | 2014-03-01 |
| GB201215054D0 (en) | 2012-10-10 |
| EA201590177A1 (en) | 2015-07-30 |
| TWI586372B (en) | 2017-06-11 |
| CN104661636B (en) | 2017-05-10 |
| BR112015003693A2 (en) | 2017-07-04 |
| WO2014029711A2 (en) | 2014-02-27 |
| WO2014029711A3 (en) | 2014-09-12 |
| MX352365B (en) | 2017-11-22 |
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