CN102634228A - Method for producing high color ratio double-strength caramel using cane molasses - Google Patents
Method for producing high color ratio double-strength caramel using cane molasses Download PDFInfo
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Abstract
The invention provides a method for producing high color ratio double-strength caramel using cane molasses, which includes: a, pretreating cane molasses to remove gum, and filtering the molasses solution after neutralizing PH value; b, concentrating the pretreated molasses till the molasses accounts for 60%-80% of total molasses in weight percentage; c, adding solid catalysts, namely sodium pyrosulfite and ammonium bicarbonate; d, adding phosphoric acid to adjust the PH value to 5.5; e, heating and controlling temperature, and performing Maillard reaction; f, cooling caramel; g, blending, metering, and canning to obtain the finished product. The method overcomes a plurality of technical bottlenecks, and implements production of the high color ratio double-strength caramel using the cane molasses to replace white granulated sugar or glucose as material, and accordingly material cost is reduced greatly, and the molasses is turned into wealth. The color ratio of the double-strength caramel can be up to 120000EBC, and liquid catalysts such as traditional liquid ammonia, liquid sulfur dioxide and the like are replaced with the solid catalysts such as the sodium pyrosulfite and the like.
Description
Technical field
The present invention relates to the working method of caramel colour in the foodstuff production, be specially the method that cane molasses is produced the double caramel colour of high luminance relay rate.
Background technology
Caramel colour is commonly called as dark reddish brown, is a kind of natural food colour that obtains through caramelize or Maillard reaction with glucide, and Application Areas is extensive.At present, the caramel colour industry mainly is that employing white sugar or glucose are raw material, produces caramel colour through Maillard reaction.It is different to press finished product look rate, and caramel colour can be divided into two big types of single times of caramel colour, double caramel colours.Double caramel colour is mainly used in cola, tea drink, candy production etc. at present, because its look rate is high, low-consuming, at the unit product addition, improve on the product quality to compare with single times of caramel colour and have clear superiority.But problem such as more single times of caramel colour complicacy of the technology of double caramel colour, production cost are higher has all limited the popularization and the application of double caramel colour.Present sugar wholesale price goes up over the same period last year and reaches 70%; Domestic sugar short supply; Price continues to skyrocket, and the caramel colour industry has been caused enormous impact, and the production cost of double caramel colour is also along with the rise of sugar price is constantly risen violently; When the double caramel colour of influence is promoted, used, seriously restrict the development of tinting material industry, be badly in need of the production cost that cheap alternative materials reduces double caramel colour.
Molasses are by products of sugar industry, and its total sugar content can reach 45%-50%, also contain a large amount of colloidalmaterials simultaneously.Because it is cheap, in chemical industry, light industry, food, medicine and building material industry, there is very big exploitation to be worth.At present, the utilization to molasses both at home and abroad mainly divides two types: the one, and direct utilization, just molasses pass through simple process or do not handle, and directly are used as raw material or auxiliary material, for example make fodder additives or concrete admixture.Though this approach technology is simple, the value of molasses is difficult to excavated fully.The 2nd, degree of depth utilization, i.e. extracting effective components therefrom, or as the fermented product and the biological products of fermentation raw material production high added value, like caramel colour, alcohol, lactic acid etc.Present domestic molasses are mainly used in production alcohol, but waste water that gives off in its production process and waste residue are difficult for processing, and finished product alcohol is inappropriate for problems such as remote transportation and sale, has seriously limited the digestion amount of molasses in grain distillery.
The research that utilizes molasses to produce caramel colour also has report at home, and its technology mainly contains following shortcoming: carry out the cane molasses pre-treatment with technology such as acid adjustment, ultrafiltration, at first complicated operation, cost are higher, and unsafe factor increases in the production process; Secondly, colloid is handled not thorough, and impurity is residual to influence product quality and security, and product look rate is difficult to improve, and most cane molasses are produced the product look rate of caramel colours report all at 20,000 to 30,000 EBC, and the highest only have 60,000 EBC, can't satisfy customer requirements, surpasses; In addition, reaction requires HTHP, and unit consumption of energy is big, complex process, and complex steps is difficult to drop into industrial production.In sum, the caramel colour industry is healthy in order to make, sustainable development, is badly in need of novel process and solves above-mentioned difficulties, reduces the production cost of double caramel colour, and improving with the cane molasses is the quality of the caramel colour of raw material production.
The difficult point that cane molasses is produced the double caramel colour of high luminance relay rate mainly contains two: the one, only contain the total reducing sugar of 45%-50% in the cane molasses; Wherein glucose and fructose account for 50% of total reducing sugar; Sucrose accounts for 50% of total reducing sugar; And sucrose can not directly carry out Maillard reaction; Must be transformed into the monose (fructose and glucose) with reductibility to sucrose and just can carry out Maillard reaction, comprise half can not to participate in the sucrose of reaction directly be one of difficult point of doing high luminance relay rate caramel colour so total reducing sugar is low.The 2nd, contain a large amount of colloidalmaterials in the cane molasses, colloid can very fast sex change form water-fast particle in the process of heating that heats up, and makes solution muddy, forms the false color valency, has lost the due function of caramel colour.
Caramel colorant is as a kind of tinting material; The look rate is an important indicator, and its regulation is that 0.1% liquor sacchari usti (W/V) adopts accurate spectrophotometer under the wavelength of 610nm, measures its optical density(OD) through the cuvette of 1cm; Again through formula convert outstanding rate, unit is EBC.Optical density(OD) is big more, and the expression tinting strength is strong more, and we surpass 2EBC with the look rate usually and are called the high luminance relay rate, and it is 10,000 that single times of caramel colour refers to caramel colorant---and 20,000 EBC, surpassing becomes double caramel colour more than 60,000 EBC.
Summary of the invention
The present invention is just to above technical problem; Provide can be cheap cane molasses substitute white sugar or glucose is the production that raw material carries out the double caramel colour of high luminance relay rate; Reduced raw materials cost and safe in utilization; Metering easily, is accurately produced the method that more manageable cane molasses is produced the double caramel colour of high luminance relay rate.
Concrete technical scheme of the present invention is following:
Cane molasses is produced the method for the double caramel colour of high luminance relay rate, may further comprise the steps:
A, molasses pre-treatment: cane molasses is carried out pre-treatment removes glue, in pH value after-filtration molasses solution;
B, concentrated: will pass through the pretreated molasses of molasses and concentrate, concentrating the device that adopts is the triple effect concentrating unit, is concentrated into the 60%-80% that the quality percentage composition is total molasses;
C, batching: add solid catalyst Sodium Pyrosulfite and bicarbonate of ammonia, the ratio of two kinds of catalyzer of adding is 1:25, adopts solid catalyst to substitute the traditional liquid catalyzer, make produce safer, metering more accurately, quality product is more stable;
D, accent PH, adding phosphoric acid adjusting Ph value is 5.5;
E, Maillard reaction: heat up also controlled temperature carries out Maillard reaction, termination reaction after temperature reaction to the look rate that requires in the time of 120 ℃;
F, cooling: in the reaction kettle coil pipe, feed water coolant, be cooled to 60-70 ℃ to caramel colour;
G, allotment according to customer demand, are allocated indexs such as Baume to acceptability limit, measure canned, finished product.
The step of removing glue in the step (a) comprises: carry out hydrolysis earlier, water is regulated the quality percentage composition of molasses butt to 40%--45%, and adding acid adjusting pH value is 3-2.7; Be warming up to the boiling shape then; The boiling temperature here is 98 ℃, keeps 30 minutes, is cooled to 50 ℃ again; Neutralize then, add alkali and regulate pH value to 4.0--4.5; Filter at last: add flocculating aids, filter through pressure filter, obtain clarifying molasses liquid, clarifying molasses liquid under the 3500R/M centrifugation centrifugal 20 minutes makes centrifugal sediment content less than 0.1%.
Regulate pH value except that adding acid in the glue in the step (a), added acid is phosphoric acid, and its concentration is 85%;
Add alkali and regulate pH value, the alkali of employing is sodium hydroxide, and concentration sodium hydroxide is 98%.
Accurately measure the total solid of cane molasses in the step (c); And adding catalyzer in proportion according to total solid, the solid catalyst Sodium Pyrosulfite of adding is in the quality percentage composition; The 0.2%-0.5% that presses the molasses butt adds, and the add-on of bicarbonate of ammonia is 0.5-1.2%.
Removing the flocculating aids that adopts in the glue step is perlite, and the colloidalmaterial in the molasses is warming up under acidic conditions and boils, and colloid is destroyed; Colloid after the sex change is that 4.0--4.5 produces flocculation at pH value; The cake layer interception that is formed by perlite then filters out, and obtains clarifying molasses liquid, removes the glue step and can the colloidalmaterial in the molasses be removed clean; Prevent cane molasses coking and resinifying in reaction, increased the content of reducing sugar in the molasses.
It is described that to remove the flocculating aids that adopts in the glue step be perlite; Colloidalmaterial in the molasses is warming up under acidic conditions and boils, and colloid is destroyed, and the colloid after the sex change is that 4.0--4.5 produces flocculation at pH value; The cake layer interception that is formed by perlite then filters out, and obtains clarifying molasses liquid.
Use cane molasses to be raw material among the present invention; Adopt unique pre-treatment to remove the glue technology,, reduce the look rate and form necessary temperature of reaction and pressure through the optimization of catalyst formulation; Maillard reaction can be carried out under comparatively gentle condition; When reducing unit consumption of energy, avoid the formation of caramel colour false color valency, reaction is developed towards the direction of high luminance relay rate more, finally obtain high luminance relay rate---the double caramel colour of 120,000 EBC in the market.
Replaced expensive glucose and white sugar with cheap cane molasses, the main raw material cost reduces significantly.Need 600 kilograms of sugar to calculate to produce double caramel colour per ton, the main raw material cost of white sugar is 4200 yuan, and the main raw material cost of glucose is 2100 yuan, and the main raw material cost of molasses is merely 720 yuan.If annual produce 20,000 tons of double caramel colours, with molasses raw material than with 6,960 ten thousand yuan of white sugar raw material savings, than using glucose to be 2,760 ten thousand yuan of raw material savings.
Positively effect of the present invention is embodied in:
(1), many technical bottlenecks have been overcome; Realized that with alternative white sugar of cane molasses or glucose be the production that raw material carries out the double caramel colour of high luminance relay rate; Reduced raw materials cost significantly; Evaded sugar price and gone up, fully realized its value for cane molasses and looked for a better outlet, molasses are turned waste into wealth the pining down of caramel colour raw materials cost;
(2), the look rate of the double caramel colour of finished product produced of novel process can reach 120,000 EBC; Be general producer with 2 times of the double caramel colour look rate of white sugar or glucose production; And best in quality, each item index meets national requirements, possesses the powerful market competitiveness;
(3), replaced liquid catalysts such as traditional liquefied ammonia and sulfur dioxide liquid, measure easyly, accurate, made and produce saferly, more easy to control, quality of finished is stable with solid catalysts such as Sodium Pyrosulfites.
(4), the technology that generally adopts of other producers is much lower relatively at present for the temperature and pressure that needs of novel process; Reduced requirement so on the one hand to equipment; Demand to vapor temperature, pressure also reduces simultaneously, the principles and policies that meet national energy-saving and emission-reduction, cut down the consumption of energy.
Description of drawings
Fig. 1 is the process flow diagram among the present invention.
Embodiment
In order to make the object of the invention, technical scheme and advantage clearer, below in conjunction with embodiment the present invention is made further detailed description, but should this be interpreted as that the scope of the above-mentioned theme of the present invention only limits to following embodiment.
Embodiment 1:
Water is regulated cane molasses 50kg, and the mass percent of water accounts for 78% of solution total amount, cane molasses butt to 40%; Adding concentration then is 85% phosphoric acid, regulates pH to 2.7, is warming up to 98 ℃; Kept 30 minutes; Be cooled to 50 ℃, adopt concentration 98% sodium hydroxide to regulate the pH value, regulate pH value to 4.0.
With the perlite is flocculating aids, filters through pressure filter, obtains clarifying molasses liquid, and this moment, the quality percentage composition of molasses butt was 45%, 78kg altogether, the clear liquid after the filtration under the 3500R/M centrifugation centrifugal 20 minutes, and centrifugal sediment content is less than 0.1%; Pretreated molasses are calculated as 75% through the mass percent that triple effect is concentrated into butt, 46.8kg; Accurately contents on dry basis is 35.1kg in the total solid of metering molasses, and adds catalyzer in proportion according to total solid.Add I catalyzer Sodium Pyrosulfite 3.86 kg, the consumption 6.318kg of II catalyzer carbonic acid hydrogen ammonium; Termination reaction after Maillard reaction to the look rate that requires is carried out in intensification, and temperature of reaction is 120 ℃, in the reaction kettle coil pipe, feeds water coolant, is cooled to 60 ℃ to caramel colour; Allocate according to customer demand, allocate indexs such as Baume to acceptability limit.According to 30 kilograms of/barrel quantitative fillings.Quality control department is finished product after being up to the standards according to GB8817-2001 and inner quality standard, the warehouse-in keeping.The Interventions Requested tabulation is:
Annotate: the index of band * project be the desired value of absorbancy when being 0.10 absorbance units (when colourity is not equal to 0.10, after must each relevant index determining result being converted, again with this table relatively, judgement).
Embodiment 2:
Water is regulated cane molasses 50kg, and the mass percent of water accounts for 78% of solution total amount, cane molasses butt to 40%; Adding concentration then is 85% phosphoric acid, and regulating the pH value is 3, is warming up to 98 ℃; Kept 30 minutes; Be cooled to 50 ℃, adopt concentration 98% sodium hydroxide to regulate the pH value, regulate pH value to 4.5.
With the perlite is flocculating aids, filters through pressure filter, obtains clarifying molasses liquid, and this moment, the quality percentage composition of molasses butt was 45%, 78kg altogether, the clear liquid after the filtration under the 3500R/M centrifugation centrifugal 20 minutes, and centrifugal sediment content is less than 0.1%; Pretreated molasses are calculated as 75% through the mass percent that triple effect is concentrated into butt, 46.8kg; Accurately contents on dry basis is 35.1kg in the total solid of metering molasses, and adds catalyzer in proportion according to total solid.Add I catalyzer Sodium Pyrosulfite 3.86 kg, the consumption 6.318kg of II catalyzer carbonic acid hydrogen ammonium; Termination reaction after Maillard reaction to the look rate that requires is carried out in intensification, and temperature of reaction is 120 ℃, in the reaction kettle coil pipe, feeds water coolant, is cooled to 70 ℃ to caramel colour; Allocate according to customer demand, allocate indexs such as Baume to acceptability limit.According to 30 kilograms of/barrel quantitative fillings.Quality control department is finished product after being up to the standards according to GB8817-2001 and inner quality standard; The warehouse-in keeping, this technology not only can realize that the colloidal impurity clearance reaches more than 98%, can be fructose and glucose with the sucrose inversion in the molasses also simultaneously; Improving reducing sugar content reaches about 173%; Realize the degraded and the conversion of organic macromolecule, reduce the viscosity of molasses, improve the efficient of reaction.
If to produce 20,000 tons of double caramel colours every year, 600 kilograms of sugar of needs per ton calculate, the main raw material cost of white sugar is 4200 yuan, and the main raw material cost of glucose is 2100 yuan, and the main raw material cost of molasses is merely 720 yuan.Substitute white sugar with molasses and can save 6,960 ten thousand yuan, can save 2,760 ten thousand yuan, can practice thrift 600,000 yuan steam expense with the molasses place of glucose.
Because the relative traditional technology of temperature and pressure of this arts demand is much lower, reduced requirement on the one hand to production unit, reduced demand on the other hand to vapor temperature and pressure, its energy consumption significantly is lower than traditional technology.It is thus clear that cane molasses is produced the double caramel colour novel process of high luminance relay rate and significantly is being superior to traditional technology aspect production cost control and the quality of finished.
Claims (5)
1. cane molasses is produced the method for the double caramel colour of high luminance relay rate, it is characterized in that may further comprise the steps:
A, molasses pre-treatment: cane molasses is carried out pre-treatment removes glue, in pH value after-filtration molasses solution;
B, concentrated: will pass through the pretreated molasses of molasses and concentrate, concentrating the device that adopts is the triple effect concentrating unit, is concentrated into the 60%-80% that the quality percentage composition is total molasses;
C, batching: add solid catalyst Sodium Pyrosulfite and bicarbonate of ammonia, the ratio of two kinds of catalyzer of adding is 1:25;
It is 5.5 that d, adjust pH add the phosphorus acid for adjusting pH value;
E, Maillard reaction: heat up also controlled temperature carries out Maillard reaction in the time of 120 ℃;
F, cooling: in the reaction kettle coil pipe, feed water coolant, be cooled to 60-70 ℃ to caramel colour;
G, allotment, canned, the finished product of metering.
2. cane molasses according to claim 1 is produced the method for the double caramel colour of high luminance relay rate; It is characterized in that: the step of removing glue in the described step (a) comprises: carry out hydrolysis earlier; Water is regulated the quality percentage composition of molasses butt to 40%--45%, and adding acid for adjusting pH value is 2.7-3, is warming up to then and boils; Kept 30 minutes, and be cooled to 50 ℃ again; Neutralize then, add alkali and regulate the pH value to 4.0--4.5; Filter at last: add flocculating aids, filter through pressure filter, obtain clarifying molasses liquid, clarifying molasses liquid under the 3500R/M centrifugation centrifugal 20 minutes makes centrifugal sediment content less than 0.1%.
3. cane molasses according to claim 2 is produced the method for the double caramel colour of high luminance relay rate, it is characterized in that: add acid for adjusting pH value except that in the glue in the described step (a), added acid is phosphoric acid, and its concentration is 85%;
Add alkali and regulate the pH value, the alkali of employing is sodium hydroxide, and concentration sodium hydroxide is 98%.
4. cane molasses according to claim 1 is produced the method for the double caramel colour of high luminance relay rate; It is characterized in that: the solid catalyst Sodium Pyrosulfite that adds in the described step (c); In the quality percentage composition; The 0.2%-0.5% that presses the molasses butt adds, and the add-on of bicarbonate of ammonia is 0.5-1.2%.
5. cane molasses according to claim 6 is produced the method for the double caramel colour of high luminance relay rate; It is characterized in that: described to remove the flocculating aids that adopts in the glue step be perlite; Colloidalmaterial in the molasses is warming up under acidic conditions and boils, and colloid is destroyed, and the colloid after the sex change produces flocculation in the pH value for 4.0--4.5; The cake layer interception that is formed by perlite then filters out, and obtains clarifying molasses liquid.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102977629A (en) * | 2012-11-30 | 2013-03-20 | 广西崇左市湘桂糖业有限公司 | Method for preparing caramel pigment from molasses |
| CN102993767A (en) * | 2012-12-13 | 2013-03-27 | 广州双桥股份有限公司 | Process for continuous preparation of caramel pigment by ammonium sulfite method |
| CN103695567A (en) * | 2013-12-12 | 2014-04-02 | 广西轻工业科学技术研究院 | Process for producing brown sugar from low-purity material |
| CN104152265A (en) * | 2014-08-13 | 2014-11-19 | 河南中烟工业有限责任公司 | Sugar cane juice Maillard reaction product, preparation method thereof and application thereof to cigarettes |
| CN105295433A (en) * | 2015-11-16 | 2016-02-03 | 广西宣达食品有限公司 | Method and equipment thereof for producing caramel pigment |
| CN105295432A (en) * | 2015-11-16 | 2016-02-03 | 广西宣达食品有限公司 | Method and equipment thereof for producing caramel pigment special for mature vinegar |
| CN105440733A (en) * | 2015-11-16 | 2016-03-30 | 广西宣达食品有限公司 | Method and equipment for producing caramel pigment specially used for soybean sauce |
| CN105925011A (en) * | 2016-05-19 | 2016-09-07 | 千禾味业食品股份有限公司 | Caustic sulfite process caramel color production technology |
| CN106455644A (en) * | 2014-06-18 | 2017-02-22 | 可口可乐公司 | Method for reducing low molecular weight species in caramel |
| CN106957537A (en) * | 2017-04-20 | 2017-07-18 | 千禾味业食品股份有限公司 | A kind of one of double caramel pigment production technology |
| CN107668492A (en) * | 2017-08-02 | 2018-02-09 | 刘启华 | A kind of production method of liquid caramel pigment |
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| CN109662241A (en) * | 2019-02-01 | 2019-04-23 | 桂林红星食品配料有限责任公司 | A kind of preparation method and applications of one of double caramel pigment |
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| CN113136113A (en) * | 2021-04-23 | 2021-07-20 | 上海爱普食品工业有限公司 | Method for improving oxidation resistance of caramel color by gradient reaction |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101693903A (en) * | 2009-10-14 | 2010-04-14 | 安徽工程科技学院 | Process for producing caramel pigment |
| CN101864190A (en) * | 2010-06-13 | 2010-10-20 | 华南理工大学 | Method for preparing caramel colorant by using multistage membrane separation |
-
2012
- 2012-04-05 CN CN 201210096400 patent/CN102634228B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101693903A (en) * | 2009-10-14 | 2010-04-14 | 安徽工程科技学院 | Process for producing caramel pigment |
| CN101864190A (en) * | 2010-06-13 | 2010-10-20 | 华南理工大学 | Method for preparing caramel colorant by using multistage membrane separation |
Non-Patent Citations (1)
| Title |
|---|
| 汤兴俊等: "甘蔗糖蜜生产焦糖色素的研究", 《广州食品工业科技》 * |
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| CN102993767B (en) * | 2012-12-13 | 2015-05-20 | 广州双桥股份有限公司 | Process for continuous preparation of caramel pigment by ammonium sulfite method |
| CN102993767A (en) * | 2012-12-13 | 2013-03-27 | 广州双桥股份有限公司 | Process for continuous preparation of caramel pigment by ammonium sulfite method |
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