CN102630675B - Insect-killing and disease-resistant composite and suspension seed coating agent thereof - Google Patents
Insect-killing and disease-resistant composite and suspension seed coating agent thereof Download PDFInfo
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- CN102630675B CN102630675B CN201210086157.1A CN201210086157A CN102630675B CN 102630675 B CN102630675 B CN 102630675B CN 201210086157 A CN201210086157 A CN 201210086157A CN 102630675 B CN102630675 B CN 102630675B
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Abstract
The invention relates to the field of a pesticide preparation and discloses an insect-killing and disease-resistant composite and a suspension seed coating agent thereof. The insect-killing and disease-resistant composite is composed of azoxystrobin and chlorantraniliprole with the mass ratio being 1: (4-10). The suspension seed coating agent comprises 0.5-10.0% of azoxystrobin, 1.0-30.0% of chlorantraniliprole, 1.0-8.0% of wet dispersant, 0.5-10.0% of film-forming agent, 1.0-10.0% of coloring agent, 0.1-2.0% of tackifier, 0.1-1.0% of preservative, 0.1-1.0% of de-foaming agent and the balance being distilled water. The suspension seed coating agent complexes azoxystrobin and chlorantraniliprole and advantages of azoxystrobin and chlorantraniliprole are complementary; insect killing and disease prevention can be realized by using the suspension seed coating agent for one time; and meanwhile, the pesticide effect is improved, the use amount, use types and use times of pesticides are reduced, and the suspension seed coating agent can be widely applied to agricultural fields.
Description
Technical field
The present invention relates to pesticidal preparations field, relate to specifically a kind of killing pests and preventing diseases composition and suspension seed-coating agent thereof.
Background technology
In modern agricultural production, utilize seed coat agent to seed carry out that chemicals treatment is that control soil insect and crops soil passes, one of the method for the economical and convenient of seed-borne disease.Seed coat agent be a kind of for crop or other plant seed treatment, there is the pesticidal preparations of film forming characteristics, it can solidify to form the film that is called kind of clothing at the surface of the seed.Seed coat agent imbibition and not dissolved in soil, allow normal required moisture and the air that germinate of seed to pass through, the materials such as contained agricultural chemicals and seed manure slowly discharge, can kill soil insect, seedling stage insect, there is control sprout term disease and systemic disease, improve percentage of seedgermination, promote the effects such as seedling healthy growth.
Suspension seed-coating agent is a kind of of seed coat agent, is a kind of flowable stable unit for uniform suspension of being made through wet pulverizing by pesticide original medicine, film forming agent, wetting agent, dispersant, thickener, colouring agent, filler and water.Because it is easy to use, safe, in the seed coat agent of numerous kinds, gain great popularity.
Rynaxypyr, commodity are called wide, the general honor of health, and lepidopterous Noctuidae, Pyralidae, Carposinidae, tortricid, miller Ke, diamond-back moth section, Gelechidae, Gracilariidae etc. are all had to good control effect, can also control coleoptera Culculionidae, Chrysomelidae; Diptera Agromyzidae; The multiple non-lepidoptera pest such as Bemisia tabaci.In addition, Rynaxypyr rainwater-proof rinses, and in any period of plant growth, provides at once and permanent protection, and mammal and useful arthropods, as low toxicities such as bird, fish and honeybees, to dispenser personal security, are applicable to integrated pest management very much.
But crops not only face insect pest in whole process of growth, infecting also of some germs can impact the growth of crop; especially seed germination stage; and Rynaxypyr is a kind of insecticide, can not prevent and treat harmful germ, cannot accomplish that general protection crop is not infected.Therefore, provide a kind of can insect protected again can diseases prevention suspension seed-coating agent significant.
Summary of the invention
In view of this, the object of the invention is to provide a kind of killing pests and preventing diseases composition and suspension seed-coating agent thereof, makes the pest control simultaneously of this suspension seed-coating agent and disease, and has synergistic effect.
For realizing object of the present invention, the present invention adopts following technical scheme:
A composition, is comprised of Fluoxastrobin and Rynaxypyr, and the mass ratio of described Fluoxastrobin and Rynaxypyr is 1: 4-10.
Wherein, the mass ratio of described Fluoxastrobin and Rynaxypyr is preferably 1: 6-10, more preferably 1: 8.
Rynaxypyr, chemical name is the bromo-N-[4-chloro-2-methyl-6-[(of 3-methyl-carbamoyl) benzene]-1-(3-chloropyridine-2-yl)-1-hydrogen-pyridine-5-formamide, belong to O-formammidotiazol-benzamide insecticide.Rynaxypyr can efficiently activate ryania (the blue Buddhist nun's alkali) acceptor in insect cell, thereby excessively discharges the calcium ion in smooth muscle and striated muscle cell, causes insect muscular paralysis, and finally paralysis is dead.But Rynaxypyr shows mammal and the extremely significant selective difference of insect ryanodine receptor, thereby has greatly improved mammal and other vertebrate safeties.Rynaxypyr high-efficiency broad spectrum, all has good control effect to lepidopterous Noctuidae, Pyralidae, Carposinidae, tortricid, miller Ke, diamond-back moth section, Gelechidae, Gracilariidae etc., can also control coleoptera Culculionidae, Chrysomelidae; Diptera Agromyzidae; The multiple non-lepidoptera pest such as Bemisia tabaci.
Fluoxastrobin, chemical name is (E)-[2-[6-(2-cyano-benzene oxygen) pyrimidine-4-yl oxygen] phenyl]-3-methoxy-methyl acrylate, belong to methoxy acrylic bactericide, it stops the ATP of cell synthetic by the electronics transmission of pinning between cytochrome b and c1, thereby restrains its mitochondrial respiratory and bring into play bacteriostasis.The bacterial strain that it produces resistance to 14-demethoxylation enzyme inhibitor, benzamides, dicarboxylic dihydrazides amine and benzimidazole is effective, there is protection, treat, root out, infiltration, systemic activity, and can be in plant corpus, degrade very soon in soil and water.Fluoxastrobin is efficient, wide spectrum, and nearly all fungi steel (Ascomycetes, Basidiomycetes, Oomycete and Fungi Imperfecti) disease is all had to good activity as powdery mildew, rust, glume blight, net blotch, downy mildew, rice blast etc.Can be used for cauline leaf spraying, seed treatment, also can carry out soil treatment, be mainly used in cereal, paddy rice, peanut, grape, potato, fruit tree, vegetables, coffee, lawn etc.
Different active components is mixed rear each active component due to the difference of composition, structure, physicochemical property, makes the synergy between each active component be typically expressed as synergistic effect, summation action or antagonism.So-called synergistic effect is exactly the mutual synergism between different material, and the effect of its generation is greater than the sum total of each composition effect; And the effect that summation action is exactly its generation equals the sum total of each composition effect; Antagonism refers to that when two kinds of materials act on living organism, a kind of material disturbs the effect of another kind of material, or the effect of interfering with an opponent each other, the phenomenon that general effect is declined.
The present invention, according to Sun Yunpei (Sun Y-P) method, calculates co-toxicity coefficient and evaluates Fluoxastrobin effect mixed with Rynaxypyr, and result shows that co-toxicity coefficient is all greater than 120, shows that the mixing use of the two has notable synergistic effect.
The present invention also provides a kind of suspension seed-coating agent, be calculated in mass percent, comprise Fluoxastrobin 0.5-10.0%, Rynaxypyr 1.0-30.0%, wetting dispersing agent 1.0-8.0%, film forming agent 0.5-10.0%, colouring agent 1.0-10.0%, tackifier 0.1-2.0%, preservative 0.1-1.0%, defoamer 0.1-1.0%, surplus is distilled water, the mass ratio of described Fluoxastrobin and Rynaxypyr is 1: 4-10.
As preferably, described Fluoxastrobin mass percent is 1.0-5.0%, and described Rynaxypyr mass percent is 5.0-20.0%; The mass ratio of described Fluoxastrobin and Rynaxypyr is preferably 1: 6-10, more preferably 1: 8.
In order to promote that between particles of active components, wetting dispersion prevents its phase inter coagulation, suspension seed-coating agent of the present invention also comprises wetting dispersing agent, described wetting dispersing agent can be according to the suitable wetting dispersing agent of any selection known in this field, be preferably fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene fatty acid, alkylaryl polyglycol ether, alkylsulfonate, arylsulphonate, fatty acid polyglycol ethylene glycol, dodecyl benzene sulfonate, polyoxyethylene groups phenol formaldehyde condensate, polyoxyethylene poly-oxygen propylene aether block copolymer, naphthalene or alkyl naphthalene formaldehyde condensate sulfonates, aliphatic alcohol polyoxyethylene sulfonate, alkylphenol polyoxyethylene sulfonate, lignin and derivative sulfonate thereof, fatty acid ethane additive product phosphate, alkylphenol polyoxyethylene phosphate, one or more in alkylphenol polyoxyethylene formaldehyde condensation products sulphate.
In order to guarantee that limited farm chemical ingredients is concentrated, act on seed and root, difficult drop-off and dispersing, has reduced diffusion and the contact to non-target of agricultural chemicals in environment, and described suspension seed-coating agent also needs to comprise film forming agent.Described film forming agent should guarantee that institute's ready-made clothes film is ventilative, good water permeability, and normal seed germination growth, guarantees that institute's ready-made clothes film is insoluble in water again, and in clothing film, active component can slowly discharge, and efficiency time is long.Film forming agent of the present invention can be according to the suitable film forming agent of any selection known in this field, is preferably one or more in gum Arabic, animal glue, pectin, xanthans, methylcellulose, ethyl cellulose, sodium carboxymethylcellulose, hydroxypropyl cellulose, sodium alginate, polyvinyl alcohol, polyethylene glycol, polyvinylpyrrolidone, polyacrylamide, Sodium Polyacrylate.
Colouring agent claims again alert toner, can improve the use safety of suspension seed-coating agent, wherein, described colouring agent is preferably one or more in basic rhodamine, water-based rhodo, acid scarlet, Fluorescein red (fluorescein) 5B, Red-8110, Red-131, FGR-131.
Suspension seed-coating agent of the present invention also comprises thickener, to improve the viscosity of dispersion medium, reduces the settling velocity of particle, thereby improves the stability of preparation.Thickener of the present invention can be according to the suitable kind of any selection known in this field.As preferably, described thickener is one or more in xanthans, gum Arabic, methylcellulose, carboxymethyl cellulose, hydroxyethylcellulose, hydroxypropyl cellulose, PAA, sodium alginate, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylamide, Sodium Polyacrylate, aluminium-magnesium silicate, bentonite.
In order to improve the stability of the low-temperature storage of seed coat agent, suspension seed-coating agent of the present invention can also add antifreezing agent.Preferably, described antifreezing agent is one or more in ethylene glycol, propane diols, glycerine, hexylene glycol, urea, ammonium sulfate, sodium chloride, calcium chloride.
As preferably, defoamer of the present invention is machine silicone, C
8-10fatty alcohol, C
10-20saturated fatty acid and one or more in ester class thereof; Described preservative is benzoic acid, benzaldehyde, Sodium Benzoate, Potassium Benzoate, sorbic acid, sodium salicylate, 2-xenol, parahydroxyben-zaldehyde, 1, one or more in 2-[4-morpholinodithio quinoline-3-ketone.
The preparation method of suspension seed-coating agent of the present invention is: by Fluoxastrobin and Rynaxypyr process air-flow crushing, after wetting dispersing agent, film forming agent, colouring agent, tackifier, antifreezing agent, preservative, defoamer and water dissolve completely, drop in proportion sand mill and grind 2 times, until the grain fineness of suspension reaches D
50for 2-3 μ m, D
90< 8 μ m, obtain.In actual medication process, the present invention can according to local controlling object, a situation arises determines the suitable consumption of described suspension seed-coating agent, and formulation rate is that the mass ratio of seed coat agent and seed is 1 conventionally: 50-100.
Prepared Fluoxastrobin Rynaxypyr suspension seed-coating agent outward appearance is red flowable suspension, and low temperature, heat storage stability are qualified, and heat storage resolution ratio is less than 5%, and suspensibility is greater than 90%, and wet screening test 98% is by 45 μ m standard screens, grain fineness D
50for 2-3 μ m.
Simultaneously, the test of pesticide effectiveness result of suspension seed-coating agent of the present invention shows, single use Fluoxastrobin or Rynaxypyr, can only play desinsection or disease-resistant effect, and after composite, be less than under the consumption of single use Fluoxastrobin or Rynaxypyr, suspension seed-coating agent of the present invention can desinsection, again can be disease-resistant, without cross tolerance, and preventive effect is improved, as can be seen here, this synergistic effect of composition of the present invention is not that the direct effect due to another kind of active substance produces, but both are mutually collaborative, promote self desinsection or disease-resistant effect synergy.
From above technical scheme, suspension seed-coating agent of the present invention using Fluoxastrobin and Rynaxypyr composite as active ingredient, the two mutual supplement with each other's advantages, a drug not only can pest control can also be prevented and treated disease, improve drug effect simultaneously, reduced the usage amount of agricultural chemicals and used kind, number of times, can be widely used in agriculture field.
Embodiment
The embodiment of the invention discloses a kind of killing pests and preventing diseases composition and suspension seed-coating agent thereof.Those skilled in the art can use for reference content herein, suitably improve technological parameter and realize.Special needs to be pointed out is, all similar replacements and change apparent to those skilled in the artly, they are all deemed to be included in the present invention.Product of the present invention is described by preferred embodiment, and related personnel obviously can change product as herein described or suitably change and combination within not departing from content of the present invention, spirit and scope, realizes and apply the technology of the present invention.
In order further to understand the present invention, below in conjunction with embodiment, a kind of killing pests and preventing diseases composition provided by the invention and suspension seed-coating agent thereof are elaborated.
Embodiment 1: damage by disease and insect efficiency test
Test in Earthquake of Anyang station in Henan one peasant household farmland and carry out, it is the composite seed coat agent of active component that suspension seed-coating agent be take Fluoxastrobin and Rynaxypyr, single dose is respectively Fluoxastrobin suspension seed-coating agent and Rynaxypyr suspension seed-coating agent, each suspension seed-coating agent test seed and experimental enviroment are all identical, test processing and formulation rate are in Table 1, and control efficiency is in Table 2.
Wherein, disease index, preventive effect computing formula are as follows:
Blade disease index=∑ (the disease number of sheets * relative level numerical value at different levels)/(investigating the total number of sheets * 9) * 100;
Control efficiency (%)=(blank group disease index-experimental group disease index)/disease index * 100, blank district;
Severity Scaling standard is known in this field, at this, no longer enumerates.
Insect pest preventive effect is calculated standard: regard the killed insect bite wound of thing seedling as or kill as insect pest seedling, calculating insect pest seedling ratio, then calculating preventive effect.
Table 1 test is processed and formulation rate
| Process | Reagent agent | Amount of application (active component/100kg seed) |
| 1 | Fluoxastrobin | 25g |
| 2 | Rynaxypyr | 300g |
| 3 | Fluoxastrobin+Rynaxypyr | 10g+100g |
| 4 | Fluoxastrobin+Rynaxypyr | 15g+100g |
| 5 | Fluoxastrobin+Rynaxypyr | 15g+150g |
| 6 | Fluoxastrobin+Rynaxypyr | 20g+120g |
| 7 | Fluoxastrobin+Rynaxypyr | 20g+180g |
| 8 | Fluoxastrobin+Rynaxypyr | 25g+150g |
| 9 | Fluoxastrobin+Rynaxypyr | 25g+200g |
| 10 | Clear water |
Table 2 extermination of disease and insect pest effect (%)
| Process | Wheat rust | Wheat glume blight | Mythimna separata | Cotton bollworm |
| 1 | 76.3 | 78.4 | 0 | 0 |
| 2 | 0 | 0 | 79.5 | 81.3 |
| 3 | 77.1 | 79.2 | 80.7 | 81.9 |
| 4 | 79.4 | 81.3 | 80.8 | 82.5 |
| 5 | 81.2 | 82.5 | 83.9 | 85.8 |
| 6 | 83.4 | 84.5 | 82.4 | 84.6 |
| 7 | 84.3 | 85.2 | 85.4 | 87.2 |
| 8 | 86.4 | 87.2 | 84.5 | 86.7 |
| 9 | 87.6 | 88.5 | 89.5 | 87.5 |
| 10 | 0 | 0 | 0 | 0 |
As seen from the results in Table 2, in suspension seed-coating agent of the present invention, each active ingredient is being less than under the prerequisite of each single dose consumption, and drug effect is higher than each single dose drug effect.Simultaneously, from processing 1 and 2 result of the test, this synergy result is not to directly act on disease or insect pest obtains due to another added active component, but due to two kinds of composite rear interactions of active component, has strengthened the effect of preventing and treating each other disease or insect pest.Result of the test shows in suspension seed-coating agent of the present invention that two kinds of active components are without antagonism, and has improved preventive effect, can reduce dosage and types of medicines, number of times.
Embodiment 2:5% Fluoxastrobin Rynaxypyr suspension seed-coating agent (being mass fraction)
Sodium alkyl sulfonate, alkylphenol polyoxyethylene are dissolved completely with distilled water, then add successively Fluoxastrobin, Rynaxypyr active ingredient through air-flow crushing, and other auxiliary agent, enter sand mill and grind 2 times, until the grain fineness of suspension reaches D
50for 2-3 μ m, D
90< 8 μ m obtain product.
The single dose contrast that suspension seed-coating agent prepared by the present embodiment and single-activity composition are made, take each active component consumption is criterion calculation, each active component consumption in suspension seed-coating agent of the present invention is less than under the prerequisite of each single dose active component consumption, the preventive effect of suspension seed-coating agent of the present invention is higher than the preventive effect of single dose, and without cross tolerance, can while desinsection and disease-resistant.
Embodiment 3:20% Fluoxastrobin Rynaxypyr suspension seed-coating agent (being mass fraction)
Fluoxastrobin, Rynaxypyr, through air-flow crushing, after wetting dispersing agent, film forming agent, colouring agent, thickener, antifreezing agent, preservative, defoamer and water dissolve completely, are dropped in proportion to sand mill and grind 2 times, until the grain fineness of suspension reaches D
50for 2-3 μ m, D
90< 8 μ m, obtain product.
The single dose contrast that suspension seed-coating agent prepared by the present embodiment and single-activity composition are made, take each active component consumption is criterion calculation, each active component consumption in suspension seed-coating agent of the present invention is less than under the prerequisite of each single dose active component consumption, the preventive effect of suspension seed-coating agent of the present invention is higher than the preventive effect of single dose, and without cross tolerance, can while desinsection and disease-resistant.
Embodiment 4:18% Fluoxastrobin Rynaxypyr suspension seed-coating agent (being mass fraction)
Fluoxastrobin, Rynaxypyr, through air-flow crushing, after wetting dispersing agent, film forming agent, colouring agent, thickener, antifreezing agent, preservative, defoamer and water dissolve completely, are dropped in proportion to sand mill and grind 2 times, until the grain fineness of suspension reaches D
50for 2-3 μ m, D
90< 8 μ m, obtain product.
The single dose contrast that suspension seed-coating agent prepared by the present embodiment and single-activity composition are made, take each active component consumption is criterion calculation, each active component consumption in suspension seed-coating agent of the present invention is less than under the prerequisite of each single dose active component consumption, the preventive effect of suspension seed-coating agent of the present invention is higher than the preventive effect of single dose, and without cross tolerance, can while desinsection and disease-resistant.
Embodiment 5:30% Fluoxastrobin Rynaxypyr suspension seed-coating agent (being mass fraction)
Fluoxastrobin, Rynaxypyr, through air-flow crushing, after wetting dispersing agent, film forming agent, colouring agent, thickener, antifreezing agent, preservative, defoamer and water dissolve completely, are dropped in proportion to sand mill and grind 2 times, until the grain fineness of suspension reaches D
50for 2-3 μ m, D
90< 8 μ m, obtain product.
The single dose contrast that suspension seed-coating agent prepared by the present embodiment and single-activity composition are made, take each active component consumption is criterion calculation, each active component consumption in suspension seed-coating agent of the present invention is less than under the prerequisite of each single dose active component consumption, the preventive effect of suspension seed-coating agent of the present invention is higher than the preventive effect of single dose, and without cross tolerance, can while desinsection and disease-resistant.
The explanation of above embodiment is just for helping to understand method of the present invention and core concept thereof.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improvement and modification also fall in the protection domain of the claims in the present invention.
Claims (9)
1. for preventing and treating a killing pests and preventing diseases composition for wheat rust, wheat glume blight, mythimna separata and cotton bollworm, it is characterized in that, Fluoxastrobin and Rynaxypyr, consist of, the mass ratio of described Fluoxastrobin and Rynaxypyr is 1:4-10.
2. composition according to claim 1, is characterized in that, the mass ratio of described Fluoxastrobin and Rynaxypyr is 1:6-10.
3. composition according to claim 2, is characterized in that, the mass ratio of described Fluoxastrobin and Rynaxypyr is 1:8.
4. a suspension seed-coating agent, is characterized in that, is calculated in mass percent, comprise Fluoxastrobin 0.5-10.0%, Rynaxypyr 1.0-30.0%, wetting dispersing agent 1.0-8.0%, film forming agent 0.5-10.0%, colouring agent 1.0-10.0%, tackifier 0.1-2.0%, preservative 0.1-1.0%, defoamer 0.1-1.0%, surplus is distilled water, and the mass ratio of described Fluoxastrobin and Rynaxypyr is 1:4-10.
5. suspension seed-coating agent according to claim 4, is characterized in that, described Fluoxastrobin mass percent is 1.0-5.0%.
6. suspension seed-coating agent according to claim 4, is characterized in that, described Rynaxypyr mass percent is 5.0-20.0%.
7. suspension seed-coating agent according to claim 4, is characterized in that, the mass ratio of described Fluoxastrobin and Rynaxypyr is 1:6-10.
8. suspension seed-coating agent according to claim 7, is characterized in that, the mass ratio of described Fluoxastrobin and Rynaxypyr is 1:8.
9. suspension seed-coating agent according to claim 4, is characterized in that, also comprises that mass percent is the antifreezing agent of 1.0-5.0%.
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Families Citing this family (11)
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|---|---|---|---|---|
| CN103651466B (en) * | 2013-12-10 | 2016-03-23 | 洛阳市嘉创农业开发有限公司 | A kind of suspension seed-coating agent of control of maize seedling stage diseases and pests |
| CN104304252A (en) * | 2014-09-15 | 2015-01-28 | 浙江泰达作物科技有限公司 | Pesticide composition containing picoxystrobin and ryanodine receptor and its preparation and use |
| CN105638771A (en) * | 2014-11-17 | 2016-06-08 | 武汉凌科达科技有限公司 | A water-soluble pesticide |
| CN105660731A (en) * | 2014-11-17 | 2016-06-15 | 武汉凌科达科技有限公司 | Preparation method of water-soluble pesticide |
| CN104396974B (en) * | 2014-11-18 | 2017-02-08 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Pesticide composition containing thifluzamide and chlorantraniliprole as well as application of pesticide composition |
| CN105794781A (en) * | 2016-03-31 | 2016-07-27 | 太仓市东泾农场专业合作社 | Antibacterial compound containing benzamide fungicide and coumoxystrobin |
| CN106087107B (en) * | 2016-05-28 | 2018-06-19 | 安徽广信农化股份有限公司 | The preparation method of Fluoxastrobin nanofiber with core-shell structure |
| CN106172449A (en) * | 2016-07-08 | 2016-12-07 | 广东中迅农科股份有限公司 | Containing thifluzamide and Fluoxastrobin and the seed treatment compositions of bromine cyanogen insect amide |
| WO2018224915A1 (en) | 2017-06-09 | 2018-12-13 | Upl Ltd | Novel pesticidal combinations |
| UA126202C2 (en) * | 2017-06-09 | 2022-08-31 | Юпл Лтд | Novel pesticidal combinations |
| CN109805015A (en) * | 2017-11-21 | 2019-05-28 | 唐山市农业科学研究院 | A kind of composition tablet containing flonicamid and Fluoxastrobin and its application |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101356918A (en) * | 2008-09-24 | 2009-02-04 | 中国农业科学院植物保护研究所 | Microcapsule suspension seed-coating agent |
| CN102318610A (en) * | 2011-07-25 | 2012-01-18 | 吴元林 | Chlorantraniliprole-containing seed treatment agent composition and application thereof |
| CN102351608A (en) * | 2011-07-11 | 2012-02-15 | 广西田园生化股份有限公司 | Controlled release particle fertilizer used for controlling crop insect disease |
-
2012
- 2012-03-28 CN CN201210086157.1A patent/CN102630675B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101356918A (en) * | 2008-09-24 | 2009-02-04 | 中国农业科学院植物保护研究所 | Microcapsule suspension seed-coating agent |
| CN102351608A (en) * | 2011-07-11 | 2012-02-15 | 广西田园生化股份有限公司 | Controlled release particle fertilizer used for controlling crop insect disease |
| CN102318610A (en) * | 2011-07-25 | 2012-01-18 | 吴元林 | Chlorantraniliprole-containing seed treatment agent composition and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| 冷阳.对氯虫苯甲酰胺和嘧菌酯的制剂及开发思考的分析和评价.《世界农药》.2012,第34卷(第1期),第54页3.2.2.2第1段，第51页第1.3.3.2,1.3.3.4第1段. |
| 对氯虫苯甲酰胺和嘧菌酯的制剂及开发思考的分析和评价;冷阳;《世界农药》;20120228;第34卷(第1期);第54页3.2.2.2第1段，第51页第1.3.3.2 * |
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