CN102623752A - Tubular polar plate lead acid storage battery of container formation colloid electrolyte - Google Patents
Tubular polar plate lead acid storage battery of container formation colloid electrolyte Download PDFInfo
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- CN102623752A CN102623752A CN2012101031489A CN201210103148A CN102623752A CN 102623752 A CN102623752 A CN 102623752A CN 2012101031489 A CN2012101031489 A CN 2012101031489A CN 201210103148 A CN201210103148 A CN 201210103148A CN 102623752 A CN102623752 A CN 102623752A
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- lead acid
- storage battery
- plate lead
- polar plate
- acid storage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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Abstract
The invention relates to a tubular polar plate lead acid storage battery of a container formation colloid electrolyte, and belongs to the field of power batteries. The tubular polar plate lead acid storage battery of the container formation colloid electrolyte is characterized in that the components of a positive pole and a negative pole are respectively as follows: the positive pole comprises the following components in percentage by weight: 0.5%-1% of teflon, 1%-3% of amorphous carbon, 0.5%-3% of kieselguhr and the balance of lead; and the negative pole comprises the following components in percentage by weight: 0.5%-1% of barium sulfate, 0.2%-0.8% of humic acid, 0.2%-2% of carbon black, 0.1%-0.2% of lignin sodium sulfonate, 0.02%-0.1% of short fiber and the balance of lead. The service life of the tubular polar plate lead acid storage battery is prolonged, the generation of acid mist is prevented, and meanwhile the loss of acid is reduced.
Description
Technical field
The present invention relates to a kind of tubular plate lead acid accumulator that is internalized into colloidal electrolyte, belong to the electrokinetic cell field.
Background technology
In the existing gelled lead acid battery; The main component of colloidal electrolyte is gel and sulfuric acid, and colloidal electrolyte has thixotropy after becoming glue, and gel forms hydroxyl bond through the hydroxyl on surface; In the middle of system, form tridimensional network, sulfuric acid and water are wrapped in the cryptomere space of colloid.Therefore colloidal electrolyte is solid, shaped when transfixion, and when receiving certain shearing force, its tridimensional network disintegrates rapidly, and it is water-soluble aqueous that colloidal electrolyte becomes, and when shearing force was eliminated, colloidal electrolyte returned to original tridimensional network again.This thixotropy of colloidal electrolyte makes that the useful life of gelled lead acid battery is elongated.
The tubular plate lead acid accumulator is the first-selection of producing batteries of electric automobile.The cycle life of tubular plate battery doubles than the cycle life of board-like pole plate battery.And, because the characteristic of above-mentioned colloidal electrolyte can make the cycle life of storage battery increase by 20%.Therefore; In order to obtain having the more lead acid accumulator of long circulation life; The characteristic of above-mentioned colloidal electrolyte and the characteristic that has extended cycle life of tubular plate lead acid accumulator are combined, and utilize being internalized into of colloidal electrolyte to replace the outer method of using at present in the industry that changes into.Following four procedures have been saved in being internalized into of affiliated colloidal electrolyte: 1. the outer dress pole plate operation that changes into 2. goes out the pole plate operation, 3. washing pole plate operation, 4. drying process.
Summary of the invention
The technical problem that the present invention will solve is: a kind of tubular plate lead acid accumulator that is internalized into colloidal electrolyte is provided, increases the life-span of tubular plate lead acid accumulator.
The technical solution adopted for the present invention to solve the technical problems is: a kind of tubular plate lead acid accumulator that is internalized into colloidal electrolyte is provided, it is characterized in that the composition of anodal and negative pole is distinguished as follows:
The mass percent of each component is in the positive pole:
Polytetrafluoroethylene 0.5%～1%,
Amorphous carbon 1%～3%,
Diatomite 0.5%～3%,
Surplus is plumbous;
The mass percent of each component is in the negative pole:
Barium sulfate 0.5%～1%,
Humic acid 0.2%～0.8%,
Carbon black 0.2%～2%,
Lignosulphonic acid receives 0.1%～0.2%,
Short fiber 0.02%～0.1%,
Surplus is plumbous.
Described staple length is 1-6mm.
The invention has the beneficial effects as follows: increased the life-span of tubular plate lead acid accumulator, avoided the generation of acid mist, reduced sour loss simultaneously.
Embodiment
Below in conjunction with embodiment the present invention is done and to further describe.
Embodiment 1:
Produce a kind of tubular plate lead acid accumulator that is internalized into colloidal electrolyte, its positive pole and negative pole are formed as follows:
The mass percent of each component is in the positive pole:
Polytetrafluoroethylene 0.5%,
Amorphous carbon 1%,
Diatomite 0.5%,
Surplus is a lead powder;
The mass percent of each component is in the negative pole:
Barium sulfate 0.5%,
Humic acid 0.2%,
Lignosulphonic acid receives 0.1%,
Carbon black 0.2%,
Short fiber 0.02%,
Surplus is a lead powder.
Staple length is 1-6mm.
The lead acid accumulator cycle life of producing reaches 550 circulations.
Embodiment 2:
Produce a kind of tubular plate lead acid accumulator that is internalized into colloidal electrolyte, its positive pole and negative pole are formed as follows:
Each constituent mass percentage is in the positive pole:
Polytetrafluoroethylene 1%,
Amorphous carbon 3%,
Diatomite 0.3%,
Surplus is plumbous;
Each constituent mass percentage is in the negative pole:
Barium sulfate 1%,
Humic acid 0.8%,
Lignosulphonic acid receives 02,
Carbon black 2%,
Short fiber 0.1%,
Surplus is plumbous.
Staple length is 1-6mm.
The lead acid accumulator cycle life of producing reaches 650 circulations.
Embodiment 3:
Produce a kind of tubular plate lead acid accumulator that is internalized into colloidal electrolyte, its positive pole and negative pole are formed as follows:
Each constituent mass percentage is in the positive pole:
Polytetrafluoroethylene 0.75%,
Amorphous carbon 2%,
Diatomite 1%,
Surplus is plumbous;
Each constituent mass percentage is in the negative pole:
Barium sulfate 0.7%,
Humic acid 0.5%,
Lignosulphonic acid receives 0.15%,
Carbon black 0.8%,
Short fiber 0.07%,
Surplus is plumbous.
Staple length is 1-6mm.
The lead acid accumulator cycle life of producing reaches 600 circulations.
Claims (2)
1. a tubular plate lead acid accumulator that is internalized into colloidal electrolyte is characterized in that, the positive pole of said storage battery and the composition of negative pole are distinguished as follows:
The mass percent of each component is in the positive pole:
Polytetrafluoroethylene 0.5%～1%,
Amorphous carbon 1%～3%,
Diatomite 0.5%～3%,
Surplus is plumbous;
The mass percent of each component is in the negative pole:
Barium sulfate 0.5%～1%,
Humic acid 0.2%～0.8%,
Carbon black 0.2%～2%,
Lignosulphonic acid receives 0.1%～0.2%,
Short fiber 0.02%～0.1%,
Surplus is plumbous.
2. the electrokinetic cell that is internalized into tubular colloidal according to claim 1 is characterized in that, the length of said short fiber is 1-6mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101031489A CN102623752A (en) | 2012-04-11 | 2012-04-11 | Tubular polar plate lead acid storage battery of container formation colloid electrolyte |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101031489A CN102623752A (en) | 2012-04-11 | 2012-04-11 | Tubular polar plate lead acid storage battery of container formation colloid electrolyte |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102623752A true CN102623752A (en) | 2012-08-01 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101031489A Pending CN102623752A (en) | 2012-04-11 | 2012-04-11 | Tubular polar plate lead acid storage battery of container formation colloid electrolyte |
Country Status (1)
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| CN (1) | CN102623752A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104466190A (en) * | 2014-12-05 | 2015-03-25 | 淄博明泰电器科技有限公司 | Optimized thin-type and electrode-tube-type seal power lead-acid storage battery and manufacturing method thereof |
| CN108878992A (en) * | 2017-05-10 | 2018-11-23 | 中国电力科学研究院 | A kind of lead carbon battery anode composite additive |
| CN114094100A (en) * | 2021-10-19 | 2022-02-25 | 广东奥克莱集团有限公司 | Lead paste additive for lead-carbon battery and lead-carbon battery |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101847718A (en) * | 2010-05-31 | 2010-09-29 | 张天任 | Negative pole lead plaster for enhancing charging receptivity of lead-acid battery and preparation method thereof |
| CN101853958A (en) * | 2010-06-04 | 2010-10-06 | 山东圣阳电源股份有限公司 | Tubular colloidal battery and manufacturing technology thereof |
| CN101882681A (en) * | 2010-06-21 | 2010-11-10 | 冯家齐 | Positive and negative plate additive of lead-acid accumulator and preparation method thereof |
| CN101958417A (en) * | 2010-07-26 | 2011-01-26 | 武汉银泰科技电源股份有限公司 | Anode additive of lead acid storage battery |
-
2012
- 2012-04-11 CN CN2012101031489A patent/CN102623752A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101847718A (en) * | 2010-05-31 | 2010-09-29 | 张天任 | Negative pole lead plaster for enhancing charging receptivity of lead-acid battery and preparation method thereof |
| CN101853958A (en) * | 2010-06-04 | 2010-10-06 | 山东圣阳电源股份有限公司 | Tubular colloidal battery and manufacturing technology thereof |
| CN101882681A (en) * | 2010-06-21 | 2010-11-10 | 冯家齐 | Positive and negative plate additive of lead-acid accumulator and preparation method thereof |
| CN101958417A (en) * | 2010-07-26 | 2011-01-26 | 武汉银泰科技电源股份有限公司 | Anode additive of lead acid storage battery |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104466190A (en) * | 2014-12-05 | 2015-03-25 | 淄博明泰电器科技有限公司 | Optimized thin-type and electrode-tube-type seal power lead-acid storage battery and manufacturing method thereof |
| CN108878992A (en) * | 2017-05-10 | 2018-11-23 | 中国电力科学研究院 | A kind of lead carbon battery anode composite additive |
| CN108878992B (en) * | 2017-05-10 | 2021-09-21 | 中国电力科学研究院 | Composite additive composition for positive electrode of lead-carbon battery |
| CN114094100A (en) * | 2021-10-19 | 2022-02-25 | 广东奥克莱集团有限公司 | Lead paste additive for lead-carbon battery and lead-carbon battery |
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Application publication date: 20120801 |