CN102620606A - Soft bulletproof plate - Google Patents

Soft bulletproof plate Download PDF

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Publication number
CN102620606A
CN102620606A CN2012100965797A CN201210096579A CN102620606A CN 102620606 A CN102620606 A CN 102620606A CN 2012100965797 A CN2012100965797 A CN 2012100965797A CN 201210096579 A CN201210096579 A CN 201210096579A CN 102620606 A CN102620606 A CN 102620606A
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CN
China
Prior art keywords
fabric
soft
soft armour
thermoplastic resin
armour according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012100965797A
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Chinese (zh)
Inventor
黄兴良
冯向阳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Tongyizhong Specialty Fiber Technology & Development Co Ltd
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Beijing Tongyizhong Specialty Fiber Technology & Development Co Ltd
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Application filed by Beijing Tongyizhong Specialty Fiber Technology & Development Co Ltd filed Critical Beijing Tongyizhong Specialty Fiber Technology & Development Co Ltd
Priority to CN2012100965797A priority Critical patent/CN102620606A/en
Publication of CN102620606A publication Critical patent/CN102620606A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a soft bulletproof plate, which comprises a plurality of single-layer bulletproof fabrics, wherein each single-layer bulletproof fabric comprises a reinforcement body which is made from high-performance fiber and a thermoplastic resin matrix which is coated on the reinforcement body; the thermoplastic resin matrix is a mixture of waterborne resin and a thickening acid, the mixture can be manually bent and formed after hot-pressed; and the content of the waterborne resin is 70 to 90 percent. The soft bulletproof plate has the advantages that the mixture can be manually bent and formed after hot-pressed in the proportion, so the problems of difficulty in manufacturing of the conventional bulletproof plate in a complicated shape and high cost are solved; the bulletproof plate in the complicated shape can be manually bent and formed according to a shape requirement; and by manually bending the soft bulletproof plate, a liner of a ship or an armored cash carrier can be tightly attached to a wall surface of the ship or the armored cash carrier.

Description

A kind of soft armour
Technical field
The present invention relates to the bullet resistant material technical field, particularly a kind of soft armour and preparation method thereof.
Background technology
Bullet resistant material mainly is divided into hard bullet resistant material and soft bullet resistant material; Both shellproof mechanism is different; The former mainly is a hardness of utilizing self, changes the shape of bullet or fragment, thereby reduces its kinetic energy and play shellproof effect; And the latter mainly plays cushioning effect through the deformation of soft material, thereby absorbs the bullet project on it or the kinetic energy of fragment reaches shellproof purpose.
What present soft bullet resistant material had can make flak jackets; General is the flak jackets that nylon material or other fibrous material are processed; Though this flak jackets is worn light comfortable, this flak jackets can only stop slower fractionlet, and is very limited to the effect of the light weapons of majority; Thereby need on flak jackets, increase armour and be used to the bullet or the fragment that stop that penetration power is stronger; Same in other shellproof field, simple fiber soft material still can not satisfy shellproof demand, needs the support of armour.
In case after the present soft armour moulding; Generally can only produce small elastic deformation but can not be arbitrarily crooked; And,, can only produce the soft armour of required form through the mode of mould heat pressure like the liner of naval vessels or armoured van for the armour demand that present shape becomes increasingly complex; Not only production cost is higher for this, and the applying of armour and naval vessels itself or armoured van neither be very tight.
For example with 70% acrylic acid ester and the mixture of Kraton G1650 (hydrogenated polystyrene triblock copolymer body SEBS) and 30% the abundant mixing of tackifying assistant, wherein the ratio of acrylic acid ester and SEBS is 3: 1, makes the thermoplastic resin matrix behind the mixing; Above-mentioned thermoplastic resin matrix is coated on the superhigh molecular weight polyethylene fibers of parallel arrangement, after drying, make the individual layer ballistic fabric, the content of thermoplastic matrix is 25% in this kind individual layer ballistic fabric; Two-layer this kind ballistic fabric is overlapping; And the fiber architecture direction in this two-layer ballistic fabric is vertical, under 0.5MP and 106 ℃, is hot pressed into the quadrature sheet material, and 20 layers of this quadrature sheet material are cooled to 60 ℃ of demouldings and remove burr behind 2MP and 115 ℃ of following hot pressing 15min; Process armour; Decline towards 51 formula lead for retractable pencil bullets of rifle emission though this kind armour can effectively guard against 79, it is the hard armour, can not manual brake forming; For the shellproof demand that becomes increasingly complex at present, this kind armour can't satisfy.
Therefore, how to develop a kind of can be by hand the soft armour of bending arbitrarily, with the production cost of the soft armour that reduces present complicated shape, be the technical problem that present those skilled in the art need solution badly.
Summary of the invention
The purpose of this invention is to provide a kind of soft armour,, thereby reduce the production cost of complex-shaped armour so that the soft armour of this kind can manual brake forming.
For solving the problems of the technologies described above; The present invention provides a kind of soft armour, and said soft armour comprises a plurality of individual layer ballistic fabrics, and said individual layer ballistic fabric comprises the enhancing body that high-performance fiber forms; And be brushed to the thermoplastic resin matrix on the said enhancing body; It is characterized in that said thermoplastic resin matrix is the water-base resin that can manual brake forming after the hot pressing and the amalgam of tackifying assistant, and the content of said water-base resin is 70-90%.
Preferably, water-base resin is one or more the mixture in styrenic block EVA, polyacrylate, ethylene-vinyl acetate EVA, polyurethane, the polyvinyl alcohol.
Preferably, said tackifying assistant is one or more the mixture in rosin based resin Tackified emulsion, modified rosin resin Tackified emulsion, terpenoid resin Tackified emulsion or the alicyclic petroleum resin Tackified emulsion.
Preferably, said thermoplastic resin matrix also comprises modified additive, and the percentage by weight of described modified additive in said thermoplastic resin matrix is not more than 5%.
Preferably, described modified additive is specially one or more the mixture in wetting agent, antifoaming agent, anti-oxidant, thickener, the heat stabilizer.
Preferably, said enhancing body is that superhigh molecular weight polyethylene fibers strengthens body or aramid fiber and strengthens one or more the mixture in the body.
Preferably, said individual layer ballistic fabric comprises woven fabric, knitted fabric, braid or supatex fabric.
Preferably, said supatex fabric is the superhigh molecular weight polyethylene fibers filament yarn fabric, and yarn linear density is 100-1600D; Mechanical strength is not less than 30cN/dtex; Fabric side density is 50-600g/m 2Fabric thickness is 0.10-1mm.
Preferably, said supatex fabric is the superhigh molecular weight polyethylene fibers filament yarn fabric, and yarn linear density is 100-1600D; Mechanical strength is not less than 33cN/dtex; Fabric side density is 50-200g/m 2Fabric thickness is 0.10-0.3mm.
Preferably, the woven type of said individual layer ballistic fabric is the combination of one or more weaving manners of plain weave, twill, satin weave, basket line, basket, unidirectional, three-dimensional.
Preferably, the high-performance fiber tensile strength in the said enhancing body is not less than 30cN/dtex.
Preferably, the shared mass percent of the mass percent of said enhancing body is not less than 60%.
Can find out soft armour provided by the present invention by above technical scheme; Because it adopts the multi-layer coated thermoplastic resin matrix's of having high-performance fiber to strengthen the body heat pressure and forms; And described thermoplastic resin matrix is the amalgam of water-base resin and tackifying assistant; And the content of the water-base resin in the said thermoplastic matrix is 70-90%; Because this kind amalgam can manual brake forming hot pressing after under this kind ratio, thereby solved present complex-shaped armour manufacturing difficulty and the high problem of cost, can carry out manual brake forming according to shape need for complex-shaped armour; For the liner of naval vessel or armoured van, can be by hand crooked described soft armour makes the wall joint more compact of itself and naval vessel or armoured van.
Description of drawings
Accompanying drawing 1 is the sketch map of the soft armour that the embodiment of the invention provided.
The specific embodiment
The purpose of this invention is to provide a kind of soft armour; This soft armour is that high-performance fiber that multilayer scribbles the thermoplastic resin matrix strengthens body heat and forces together and form; Described thermoplastic resin matrix is a kind of special material, adopts middle thermoplastic resin matrix can to make the manual brake forming of soft armour.
In order to make those skilled in the art person understand the present invention program better, the present invention is done further detailed description below in conjunction with accompanying drawing and embodiment.
Soft armour provided by the present invention comprises a plurality of individual layer ballistic fabrics; Said individual layer ballistic fabric comprises the enhancing body that is formed by high-performance fiber; And coating strengthens the thermoplastic resin matrix on the body to said high-performance fiber; Described thermoplastic resin matrix is the amalgam of water-base resin and tackifying assistant, and the content of described water-base resin is 70-90%, and the content of described tackifying assistant is 10-30%.
High-performance fiber among the present invention is meant the general name of the fibrous material that specific strength is high; The tensile strength of described high-performance fiber is not less than 22cN/dtex; Preferably be not less than 30cN/dtex, further preferably be not less than 38cN/dtex, density preferably is no more than 1g/cm 3, further 0.97g/cm preferably 3High-performance fiber among the present invention includes but not limited to carbon fiber, aramid fiber, superhigh molecular weight polyethylene fibers, pbo fiber, M5 fiber; Preferably aramid fiber and superhigh molecular weight polyethylene fibers; Ultra high molecular polyethylene fiber among the present invention is meant that molecular weight is not less than 1,000,000 polyethylene fibres; Preferably 100-500 ten thousand, and stretch modulus is not less than 750cN/dtex.
Thermoplastic resin matrix among the present invention is the amalgam by water-base resin and tackifying assistant; Described water-base resin is one or more assemblys in styrenic block EVA, polyacrylate, ethylene-vinyl acetate EVA, polyurethane, the polyvinyl alcohol, and said tackifying assistant is one or more the mixture in rosin based resin Tackified emulsion, modified rosin resin Tackified emulsion, terpenoid resin Tackified emulsion or the alicyclic petroleum resin Tackified emulsion.
Comprise also among the thermoplastic resin matrix among the present invention that mass percent is no more than 5% modified additive; Described modified additive is specially one or more combinations in wetting agent, antifoaming agent, anti-oxidant, thickener, the heat stabilizer, can also contain plasticizer and ageing-resistant dose among the described thermoplastic resin matrix.
The individual layer ballistic fabric comprises woven fabric, knitted fabric, braid and supatex fabric among the present invention; Said woven fabric preferably adopts the superhigh molecular weight polyethylene fibers filament yarn fabric to be made into; Said knitted fabric or braid can adopt carbon fiber, superhigh molecular weight polyethylene fibers or aramid fiber to be made into; Described non-woven fabric is the non-woven fabric of nonwoven, no latitude cloth or its mixing, described nonwoven or do not have latitude cloth and preferably adopt the superhigh molecular weight polyethylene fibers filament yarn fabric, and thread density is 100-1600D; 400-1600D more preferably; Mechanical strength is not less than 30cN/dtex, preferably is not less than 33cN/dtex, and said nonwoven or the surface density of not having latitude cloth are 50-600g/m 2, 50-200g/m preferably 2, and said nonwoven or the thickness that do not have latitude cloth is 0.10-1mm, 0.10-0.3mm preferably, further 0.15-0.25mm preferably.
The woven type of the individual layer ballistic fabric in the soft armour provided by the present invention, the woven type of the fibre reinforcement of saying so more specifically are the combination of one or more weaving manners of plain weave, twill, satin weave, basket line, basket, unidirectional, three-dimensional.
The mass percent of the enhancing body that is made up of high-performance fiber among the present invention accounts for more than 60% of soft armour overall weight, to guarantee the ballistic performance of soft armour.
Also provide a kind of method for preparing soft armour to comprise step in the embodiment of the invention:
S1: the configuration of thermoplastic matrix:
In styrenic block EVA, polyacrylate, ethene-vinyl acetate EVA, polyurethane, the polyvinyl alcohol one or more are mixed with one or more mixture in rosin based resin Tackified emulsion, modified rosin resin Tackified emulsion, terpenoid resin Tackified emulsion or the alicyclic petroleum resin Tackified emulsion of 10-30%, process thermoplastic matrix after mixing;
S2: the producing of individual layer ballistic fabric:
Sprawl superhigh molecular weight polyethylene fibers is unidirectional; Described unidirectional sprawling; Be meant that each bar fiber parallel laid puts, thread density is 100-1600D, preferred 400-1600D; Above-mentioned thermoplastic resin matrix's dip-coating to the superhigh molecular weight polyethylene fibers of parallel arrangement, can be obtained the individual layer ballistic fabric through the overbaking drying;
S3: cut out:
Said individual layer ballistic fabric is cut into suitable size;
S4: mold pressing:
The above-mentioned individual layer ballistic fabric of multilayer is overlaped; In press, at the uniform velocity be warmed up to 90-130 ℃; At pressure is to be incubated 1-15min under the 0.5-15MPa condition, and preferred, individual layer ballistic fabric fiber architecture direction of adjacent two layers in the middle of overlapping process is a quadrature;
S5: the demoulding:
In press, be cooled to below 60 ℃, the multilayer ballistic fabric demoulding that suppresses can be made soft armour blank;
S6: trimming:
The burr that soft armour edge in the pressing process produces are removed, can obtain can manual brake forming soft armour finished product.
Soft armour provided by the present invention is because it adopts the multi-layer coated thermoplastic resin matrix's of having high-performance fiber enhancing body heat pressure to form; And described thermoplastic resin matrix is the amalgam of water-base resin and tackifying assistant; And the content of the water-base resin in the said thermoplastic matrix is 70-90%; Because this kind amalgam can manual brake forming after the hot pressing under this kind ratio; Thereby solved present complex-shaped armour manufacturing difficulty and the high problem of cost, can be for complex-shaped armour according to the manual brake forming of shape need, for the liner of naval vessel or armoured van; Can be by hand crooked described soft armour makes the wall joint more compact of itself and naval vessel or armoured van; This kind armour also has excellent ballistic performance simultaneously, the 51 formula lead for retractable pencil bullets, 79 that can effectively protect the emission of 54 formula pistols, the 51 formula lead for retractable pencil bullets of tommy gun emission that decline, and its raw materials for production environmental protection, light weight, inexpensive.
Embodiment one
With processing the thermoplastic resin matrix behind the polyacrylate resin of 80kg and the abundant mixing of 20kg high stable esterified rosin resin Tackified emulsion; Perhaps add simultaneously the wetting agent of 0.5kg and the anti-oxidant of 1kg therein and form the thermoplastic resin matrix; The thermoplastic resin matrix is applied on the woven fabric of superhigh molecular weight polyethylene fibers; Superhigh molecular weight polyethylene fibers in the present embodiment adopts the inspire confidence in safe board superhigh molecular weight polyethylene fibers of Beijing with company's production in the benefit; Weaving manner adopts twill, and yarn linear density is 1600D; Mechanical strength is 33cN/dtex; Fabric side density is 100g/m 2, fabric thickness is 0.10mm; After drying, obtain the individual layer ballistic fabric.This woven is that the thermoplastic resin matrix is soaked in the superhigh molecular weight polyethylene fibers mechanism thing, is integrally formed with it, becomes single sheet, shown in accompanying drawing 1.Contain 20% thermoplastic resin matrix in this individual layer ballistic fabric; The individual layer ballistic fabric is cut into the specification of 400*400 and 30 layers of this kind individual layer ballistic fabric are overlaped; Under the condition of 2MPa and 115 ℃, in press, the hot pressing of above-mentioned individual layer ballistic fabric is cooled to 50 ℃ of demouldings after 15 minutes, and removes burr; Process the soft armour shown in accompanying drawing 1; The thermoplastic resin matrix of this soft armour is soaked in the superhigh molecular weight polyethylene fibers mechanism thing, is integrally formed with it, is fused to armour integral body.。This soft armour can manual brake forming, shown in accompanying drawing.Can effectively guard against running through of 9mmFMJ RN bullet through this armour of verification experimental verification.
Embodiment two
Polyacrylate and the mixture of Kraton D1161 (polystyrene triblock copolymer body SIS) and the abundant mixing of terpene resin Tackified emulsion of 30kg with 70kg; Wherein the ratio of polyacrylate and polystyrene triblock copolymer body is 3: 1; Make the thermoplastic resin matrix behind the mixing; Above-mentioned thermoplastic resin matrix is coated on the superhigh molecular weight polyethylene fibers of parallel arrangement, yarn linear density is 1000D; Mechanical strength is 35cN/dtex; Fabric side density is 55g/m 2Fabric thickness is 0.15mm.After drying, make the individual layer ballistic fabric; The content of thermoplastic matrix is 25% in this kind individual layer ballistic fabric, and two-layer this kind ballistic fabric is overlapping, and the fiber architecture direction in this two-layer ballistic fabric is vertical; Under 0.5MPa and 106 ℃, be hot pressed into the quadrature sheet material; 20 layers of this quadrature sheet material are cooled to 60 ℃ of demouldings and remove burr behind 2MPa and 115 ℃ of following hot pressing 15min, process the soft armour shown in accompanying drawing 1, the thermoplastic resin matrix of this soft armour is soaked in the superhigh molecular weight polyethylene fibers; Be integrally formed with it; Be fused to armour integral body, this soft armour can manual brake forming, and can effectively guard against 79 through this armour of test and decline towards 51 formula lead for retractable pencil bullets of rifle emission.
Embodiment three
The polyurethane of 90kg is fully mixed with the abietic resin Tackified emulsion of 10kg and adds the wetting agent of 1.5kg and the mixture of anti-oxidant; Obtain the thermoplastic resin matrix after mixing; Above-mentioned thermoplastic resin matrix is coated on the knitted fabric of aramid fiber; The weaving manner of this aramid fiber adopts plain weave, and yarn linear density is 1500D; Mechanical strength is 30cN/dtex; Fabric side density is 120g/m 2Fabric thickness is 1mm, and the content that after super-dry, makes the thermoplastic resin matrix of this individual layer ballistic fabric of individual layer ballistic fabric is 20%, the individual layer ballistic fabric is cut into the specification of 400*400; And with 25 layers of this kind individual layer ballistic fabric under condition 2MPa and 115 ℃; In press, the hot pressing of above-mentioned individual layer ballistic fabric is cooled to 50 ℃ of demouldings after 15 minutes, and removes burr, process the soft armour shown in accompanying drawing 1; The thermoplastic resin matrix of this soft armour is soaked in the knitted fabric of aramid fiber; Be integrally formed with it, being fused to whole this soft armour of armour can manual brake forming, shown in accompanying drawing 1.Through test, can effectively guard against 51 formula lead for retractable pencil bullets of 54 formula pistols emission.
Can find out by above embodiment; Soft shellproof version provided by the present invention not only can effectively be guarded against running through of all kinds of bullets; Simultaneously all right manual brake forming for the demand of complex-shaped armour, only needs get final product through bending to required armour shape by hand.
More than soft armour provided by the present invention has been carried out detailed introduction.Used concrete example among this paper principle of the present invention and embodiment are set forth, the explanation of above embodiment just is used for helping to understand method of the present invention and core concept thereof.Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention, can also carry out some improvement and modification to the present invention, these improvement and modification also fall in the protection domain of claim of the present invention.

Claims (12)

1. soft armour; Said soft armour comprises a plurality of individual layer ballistic fabrics; Said individual layer ballistic fabric comprises the enhancing body that is formed by high-performance fiber, and is brushed to the thermoplastic resin matrix on the said enhancing body, it is characterized in that; Said thermoplastic resin matrix is the water-base resin that can manual brake forming after the hot pressing and the amalgam of tackifying assistant, and the content of said water-base resin is 70-90%.
2. soft armour according to claim 1 is characterized in that, described water-base resin is one or more the mixture in styrenic block EVA, polyacrylate, ethylene-vinyl acetate EVA, polyurethane, the polyvinyl alcohol.
3. soft armour according to claim 1; It is characterized in that said tackifying assistant is one or more the mixture in rosin based resin Tackified emulsion, modified rosin resin Tackified emulsion, terpenoid resin Tackified emulsion or the alicyclic petroleum resin Tackified emulsion.
4. soft armour according to claim 1 is characterized in that said thermoplastic resin matrix also comprises modified additive, and the percentage by weight of described modified additive in said thermoplastic resin matrix is not more than 5%.
5. soft armour according to claim 4 is characterized in that, described modified additive is specially one or more the mixture in wetting agent, antifoaming agent, anti-oxidant, thickener, the heat stabilizer.
6. soft armour according to claim 1 is characterized in that, said enhancing body is that superhigh molecular weight polyethylene fibers strengthens body or aramid fiber and strengthens one or more the mixture in the body.
7. soft armour according to claim 1 is characterized in that, said individual layer ballistic fabric comprises woven fabric, knitted fabric, braid or supatex fabric.
8. soft armour according to claim 7 is characterized in that, said supatex fabric is the superhigh molecular weight polyethylene fibers filament yarn fabric, and yarn linear density is 100-1600D; Mechanical strength is not less than 30cN/dtex; Fabric side density is 50-600g/m 2Fabric thickness is 0.10-1mm.
9. soft armour according to claim 8 is characterized in that, said supatex fabric is the superhigh molecular weight polyethylene fibers filament yarn fabric, and yarn linear density is 100-1600D; Mechanical strength is not less than 33cN/dtex; Fabric side density is 50-200g/m 2Fabric thickness is 0.10-0.3mm.
10. soft armour according to claim 1 is characterized in that, the woven type of said woven is the combination of one or more weaving manners of plain weave, twill, satin weave, basket line, basket, unidirectional, three-dimensional.
11. soft armour according to claim 1 is characterized in that, the high-performance fiber tensile strength in the said enhancing body is not less than 30cN/dtex.
12. soft armour according to claim 1 is characterized in that, the shared mass percent of the mass percent of said enhancing body is not less than 60%.
CN2012100965797A 2012-04-01 2012-04-01 Soft bulletproof plate Pending CN102620606A (en)

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Cited By (7)

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Publication number Priority date Publication date Assignee Title
CN105157479A (en) * 2015-08-05 2015-12-16 北京普凡防护科技有限公司 Soft burster block and manufacturing method thereof
CN106905652A (en) * 2017-04-27 2017-06-30 武汉理工大学 A kind of ballistic composite and preparation method thereof
CN109667152A (en) * 2019-01-02 2019-04-23 北京普凡防护科技有限公司 A kind of modified aqueous polyurethane elastomer resin part infiltrates aramid fiber material prepreg
CN112013719A (en) * 2020-07-23 2020-12-01 北京理工大学 Impact-resistant composite structure based on UHMWPE secondary hybrid weaving
CN112304161A (en) * 2020-11-23 2021-02-02 上海斯瑞科技有限公司 Bendable bulletproof plate and preparation method thereof
CN112549711A (en) * 2020-09-28 2021-03-26 中化高性能纤维材料有限公司 Aramid nanofiber composite unidirectional cloth and preparation method thereof
CN115096139A (en) * 2022-07-15 2022-09-23 北京航天凯恩新材料有限公司 High-adaptability bulletproof plate and manufacturing method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105157479A (en) * 2015-08-05 2015-12-16 北京普凡防护科技有限公司 Soft burster block and manufacturing method thereof
CN106905652A (en) * 2017-04-27 2017-06-30 武汉理工大学 A kind of ballistic composite and preparation method thereof
CN109667152A (en) * 2019-01-02 2019-04-23 北京普凡防护科技有限公司 A kind of modified aqueous polyurethane elastomer resin part infiltrates aramid fiber material prepreg
CN112013719A (en) * 2020-07-23 2020-12-01 北京理工大学 Impact-resistant composite structure based on UHMWPE secondary hybrid weaving
CN112013719B (en) * 2020-07-23 2021-12-31 北京理工大学 Impact-resistant composite structure based on UHMWPE secondary hybrid weaving
CN112549711A (en) * 2020-09-28 2021-03-26 中化高性能纤维材料有限公司 Aramid nanofiber composite unidirectional cloth and preparation method thereof
WO2022063286A1 (en) * 2020-09-28 2022-03-31 中化高性能纤维材料有限公司 Aramid nanofiber composite unidirectional fabric and preparation method therefor
CN112304161A (en) * 2020-11-23 2021-02-02 上海斯瑞科技有限公司 Bendable bulletproof plate and preparation method thereof
CN115096139A (en) * 2022-07-15 2022-09-23 北京航天凯恩新材料有限公司 High-adaptability bulletproof plate and manufacturing method thereof

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Application publication date: 20120801