CN102618188A - Adhesive sticker for rubber products and rubber non-drying tape - Google Patents
Adhesive sticker for rubber products and rubber non-drying tape Download PDFInfo
- Publication number
- CN102618188A CN102618188A CN2012100981569A CN201210098156A CN102618188A CN 102618188 A CN102618188 A CN 102618188A CN 2012100981569 A CN2012100981569 A CN 2012100981569A CN 201210098156 A CN201210098156 A CN 201210098156A CN 102618188 A CN102618188 A CN 102618188A
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- rubber
- setting adhesive
- resin
- applique
- adhesive sticker
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Abstract
The invention relates to an adhesive sticker for bonding rubber products. The adhesive sticker mainly comprises 100 parts of rubber, 5-20 parts of tackfying resin, 2-5 parts of accelerating agent, 5-10 parts of activating agent and a right amount of solvent. The adhesive sticker does not contain a vulcanized agent, can be stored for long term and can be used for conveniently and firmly bonding the rubber products. The invention also relates to a rubber type non-drying tape containing the adhesive sticker.
Description
Technical field
The present invention relates to a kind of polymeric composition, be specifically related to a kind of non-setting adhesive.
Background technology
Rubber item often need be enclosed some literal or pattern identification, for example manufacturer, product type, registered trademark or the like.And under many circumstances, hope that these signs have eye-catching color.CN1067205 discloses a kind of working method with the pattern forming goods, and CN1060430 discloses a kind of method of producing patterned shaped article, all is that the method through die casting is attached to sign on the tire, the operation more complicated.Another kind method is to use applique, needs the sign of transfer printing to be made into applique, is attached on the rubber item with sticker then.The initial bonding strength of sticker is little, so also need the step of a sintering or thermofixation usually.In addition, owing to contain linking agent (solidifying agent) in the sticker,, after storing certain hour, promptly lost efficacy so sticker all has the restriction of storage period.For the non-setting adhesive that does not contain linking agent, then exist sticking power little, the defective that applique comes off easily.
Summary of the invention
The present invention provides a kind of to have new rubber item and uses non-setting adhesive, with the rubber item that overcomes prior art with non-setting adhesive can not vulcanize, the complicated defective of rubber item sign transfer operation.
Non-setting adhesive of the present invention does not contain vulcanizing agent, mainly is made up of 100 parts of rubber, 5-20 part tackifying resin, 2-5 part promotor, 5-10 part acvator and proper amount of solvent by weight.
The invention still further relates to not dry doubling of a kind of rubber; Comprise applique, be coated in the non-drying glue layer of this applique one side and the protective membrane that covers this non-drying glue layer; Said applique is processed by elastomeric material, and said non-drying glue layer is mainly processed by 100 parts rubber, the tackifying resin of 5-20 part, the promotor of 2-5 part, the acvator and the proper amount of solvent of 5-10 part.
Perhaps dry doubling is not long storage period for non-setting adhesive of the present invention, behind the adhesive rubber goods, utilizes the spontaneous sulfuration of vulcanizing agent in the rubber item, not only bonding convenience, and also very firm.Be particluarly suitable for rubber article and make colored marking.
Embodiment
Non-setting adhesive of the present invention comprises 100 parts rubber, the tackifying resin of 5-20 part, the promotor of 2-5 part, the acvator and the proper amount of solvent of 5-10 part in weight part.
Be applicable to that rubber of the present invention comprises tree elastomer, styrene-butadiene rubber(SBR), paracril, X 050, ethylene-propylene rubber(EPR), butyl rubber; Viton, Zylox etc.; The preferred compounded rubber that uses tree elastomer and styrene-butadiene rubber(SBR); Use this compounded rubber can be suitable for most of rubber item, and have advantage easy to make.In a kind of embodiment of the present invention, tree elastomer and styrene-butadiene rubber(SBR) are used, the ratio of the two is 10: 1-10: between 4, be preferably 10: 3.The non-setting adhesive that adopts this rubber to process is highly suitable for the tire identification transfer printing, rubber rain boots, and have good workability.
Tackifying resin of the present invention be can be used for and resol, acrylate resin, terpine resin, coumarone indene resin, rosin comprised; Preferred terpine resin or the rosin of using; Or, use terpine resin and rosiny non-setting adhesive to have good, the not allochroic advantage of tack with the two mixing use.The consumption of resin is preferably per 100 parts by weight of rubber 10-20 part resins.
The example that can be used for acvator of the present invention includes but not limited to Triple Pressed Stearic Acid, zinc oxide.The example of vulcanization accelerator comprises and includes but not limited to vulkacit D, DETU, DPG, M, TMTD, BZ, PZ, ZDC, CZ.
Some neutral industrial solvents commonly used all can be used for the present invention; These solvents comprise arenes such as benzene,toluene,xylene, fat hydrocarbons such as pentane, hexane, octane, hexanaphthene, halogenated hydrocarbons such as chlorobenzene, dichlorobenzene, methylene dichloride; Alcohols such as methyl alcohol, ethanol, Virahol; Ethers such as ether, propylene oxide, ester classes such as ritalin, vinyl acetic monomer, propyl acetate, ketones such as acetone, espeleton, mibk, pimelinketone, toluene pimelinketone; Diol, derivatives such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether preferably use environmental protection, nontoxic solvent.The consumption of solvent can be held according to the selection situation and the mobile needs of other compositions flexibly, non-setting adhesive is processed gel or paste.
It is obvious that, and non-setting adhesive of the present invention can also be introduced other complementary composition, to give the non-setting adhesive augmented performance, for example can introduce a spot of protective agent, inhibitor etc.Therefore, though above mentioned several kinds of compositions, its physical meaning is that non-setting adhesive of the present invention mainly is by rubber, tackifying resin, promotor, acvator and solvent composition.But this non-setting adhesive does not contain vulcanizing agent.
The preparation non-setting adhesive of the present invention step following: 1, with rubber plastic steelmaking to plasticity number greater than 0.5.Preferably adopt mill to carry out three sections and plasticate, the every period end back storage period of plasticating carries out hypomere again and plasticates more than 8 hours; 2, under the situation of using compounded rubber, each rubber constituent after plasticating is rehearsed, all the other components, banburying 5-10 minute are added in the rehearsal back; 3, with the sizing material slice after the banburying, film was parked 2-4 hour; 4, film heat refining on warm-up mill, stripping and slicing; 5, on hollander, beat film and solvent in proportion 8-12 hour; 6, filter with 200 purpose filtering nets.
Non-setting adhesive of the present invention can be processed independent product; Can non-setting adhesive directly be spread upon the surface of treating the adhesive rubber goods during use; With the tire is example, can glue be spread upon the position of treating that decals is known, and the applique (pattern or literal) that then elastomeric material is formed is attached to this position and gets final product.
As another kind of mode, non-setting adhesive and above-mentioned rubber applique are processed not dry doubling together, be about to non-setting adhesive attached on the rubber applique, with the protective membrane covering protection.Tear this protective membrane during use off, applique is sticked on the predetermined position of rubber tyre.
Non-setting adhesive of the present invention is exclusively used in bonding between rubber item, is particularly useful for transfer printing rubber sign on rubber tyre.Contain a large amount of tackifying resins in the non-setting adhesive, make non-setting adhesive have higher preliminary bonding force.Owing to do not contain vulcanizing agent in the non-setting adhesive,, under the intact condition of sealing, can store more than at least 2 years so this non-setting adhesive can long storage and do not lose efficacy.After the rubber applique was attached, the vulcanizing agent in the rubber item had in a small amount of immersion non-drying glue layer, thus the sulfuration non-drying glue layer, and vulcanized non-drying glue layer is bonding very firm.
Embodiment 1
Composite formula: tree elastomer 70g, styrene-butadiene rubber(SBR) 30g, Gum Rosin 20g, Triple Pressed Stearic Acid 3g, zinc oxide 3g, TM monex TD 4g, YLENE 80ml.
Respectively tree elastomer and styrene-butadiene rubber(SBR) are carried out three sections with mill and plasticate, plasticate for every section and finish the back storage period and carry out next section more than 8 hours again and plasticate.Each rubber constituent after plasticating is rehearsed, and all the other components, banburying 5-10 minute are added in the rehearsal back.With the sizing material slice after the banburying, film was parked 2-4 hour; Heat refining on warm-up mill then, stripping and slicing.On hollander, beat film and vinyl acetic monomer 8-12 hour, filter with 200 purpose filtering nets at last.Opened afterwards in 30 months with the plastic tank sealing, this non-setting adhesive does not solidify, and has flowability.
Embodiment 2
Get a doughnut material, wipe surperficial dust and dirt, spread the non-setting adhesive that embodiment 1 makes after air-dry with wet cloth.A clean bicycle inner tube material is also spread non-setting adhesive, and keep an angle and do not have non-setting adhesive.Then this bicycle inner tube material is attached on the doughnut material, places after 72 hours with exhausted air with hand pressed several times around mediad, clamp above-mentioned not bonding angle with plyers and firmly draw back, the original bonding plane of result is destroyed.
The explanation of the embodiment of front can disclose general feature of the present invention fully; So that other people are easily concrete application by existing knowledge these embodiments are adjusted and/or adaptations; These all do not depart from scope of the present invention, so these adjustment and revise and to be regarded as the replacement that is equal to embodiment disclosed in the present invention.
Claims (6)
1. a rubber item is used non-setting adhesive, mainly is grouped into by following one-tenth by weight, and does not contain vulcanizing agent:
Rubber, 100 parts;
Tackifying resin, 5-20 part;
Promotor, 2-5 part;
Acvator, 5-10 part; With
An amount of solvent.
2. non-setting adhesive according to claim 1, wherein, said rubber is selected from tree elastomer, styrene-butadiene rubber(SBR) or its mixture.
3. non-setting adhesive according to claim 1, wherein, said rubber is the mixture of tree elastomer and styrene-butadiene rubber(SBR), the two ratio is 10: 1-10: between 4.
4. non-setting adhesive according to claim 1, wherein, said tackifying resin is selected from resol, acrylate resin, terpine resin, coumarone indene resin, rosin or its mixture.
5. non-setting adhesive according to claim 1, wherein, said tackifying resin is terpine resin or rosin.
6. rubber dry doubling not; Comprise applique, be coated in the non-drying glue layer of this applique one side and the protective membrane that covers this non-drying glue layer; It is characterized in that; Said applique is processed by elastomeric material, and said non-drying glue layer does not contain vulcanizing agent, and is mainly processed by 100 parts rubber, the tackifying resin of 5-20 part, the promotor of 2-5 part, the acvator and the proper amount of solvent of 5-10 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012100981569A CN102618188A (en) | 2012-04-06 | 2012-04-06 | Adhesive sticker for rubber products and rubber non-drying tape |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012100981569A CN102618188A (en) | 2012-04-06 | 2012-04-06 | Adhesive sticker for rubber products and rubber non-drying tape |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310738730.7A Division CN103740298A (en) | 2012-04-06 | 2012-04-06 | Method for attaching mark in rubber product and application of adhesive sticker to manufacturing tyre |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102618188A true CN102618188A (en) | 2012-08-01 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012100981569A Pending CN102618188A (en) | 2012-04-06 | 2012-04-06 | Adhesive sticker for rubber products and rubber non-drying tape |
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| CN (1) | CN102618188A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265908A (en) * | 2012-06-19 | 2013-08-28 | 东莞光群雷射科技有限公司 | Transparent glue for hard plastic, and preparation method thereof |
| CN103709755A (en) * | 2013-12-16 | 2014-04-09 | 芜湖万润机械有限责任公司 | High-temperature-resistant composite rubber material for leather rings |
| CN104371634A (en) * | 2014-10-30 | 2015-02-25 | 田琳琳 | Anti-aging pressure-sensitive adhesive |
| CN106148923A (en) * | 2016-08-16 | 2016-11-23 | 无锡益联机械有限公司 | A kind of surface treatment method of radial tyre bead steel wire |
| CN106916545A (en) * | 2017-04-01 | 2017-07-04 | 合肥梦飞电器有限公司 | A kind of corrosion-resisting aluminium foil belt |
| CN111978919A (en) * | 2020-08-25 | 2020-11-24 | 福建佳通轮胎有限公司 | Formula and preparation process of glue oil for light rail tire molding drum brush |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1635040A (en) * | 2004-08-24 | 2005-07-06 | 葛林刚 | Pressure-sensitive adhesive for adhesive tape and method for preparation |
| CN101580678A (en) * | 2009-06-17 | 2009-11-18 | 佛山市畅通交通新材料发展有限公司 | Non-setting adhesive cement for coiled material for reflecting mark of traffic road and production method thereof |
| CN102086354A (en) * | 2009-12-07 | 2011-06-08 | 戚冬梅 | Rubber adhesive |
-
2012
- 2012-04-06 CN CN2012100981569A patent/CN102618188A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1635040A (en) * | 2004-08-24 | 2005-07-06 | 葛林刚 | Pressure-sensitive adhesive for adhesive tape and method for preparation |
| CN101580678A (en) * | 2009-06-17 | 2009-11-18 | 佛山市畅通交通新材料发展有限公司 | Non-setting adhesive cement for coiled material for reflecting mark of traffic road and production method thereof |
| CN102086354A (en) * | 2009-12-07 | 2011-06-08 | 戚冬梅 | Rubber adhesive |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265908A (en) * | 2012-06-19 | 2013-08-28 | 东莞光群雷射科技有限公司 | Transparent glue for hard plastic, and preparation method thereof |
| CN103709755A (en) * | 2013-12-16 | 2014-04-09 | 芜湖万润机械有限责任公司 | High-temperature-resistant composite rubber material for leather rings |
| CN104371634A (en) * | 2014-10-30 | 2015-02-25 | 田琳琳 | Anti-aging pressure-sensitive adhesive |
| CN106148923A (en) * | 2016-08-16 | 2016-11-23 | 无锡益联机械有限公司 | A kind of surface treatment method of radial tyre bead steel wire |
| CN106148923B (en) * | 2016-08-16 | 2018-12-11 | 无锡益联机械有限公司 | A kind of surface treatment method of radial tyre bead steel wire |
| CN106916545A (en) * | 2017-04-01 | 2017-07-04 | 合肥梦飞电器有限公司 | A kind of corrosion-resisting aluminium foil belt |
| CN111978919A (en) * | 2020-08-25 | 2020-11-24 | 福建佳通轮胎有限公司 | Formula and preparation process of glue oil for light rail tire molding drum brush |
| CN111978919B (en) * | 2020-08-25 | 2022-04-01 | 福建佳通轮胎有限公司 | Formula and preparation process of glue oil for light rail tire molding drum brush |
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Application publication date: 20120801 |