CN102617838B - Natural and environment friendly resin used for decorating paint - Google Patents
Natural and environment friendly resin used for decorating paint Download PDFInfo
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- CN102617838B CN102617838B CN 201110425764 CN201110425764A CN102617838B CN 102617838 B CN102617838 B CN 102617838B CN 201110425764 CN201110425764 CN 201110425764 CN 201110425764 A CN201110425764 A CN 201110425764A CN 102617838 B CN102617838 B CN 102617838B
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Abstract
The invention provides a natural and environment friendly resin used for a decorating paint. The resin is composed of soybean oil, castor oil, dimethylbenzene, an antioxidant, benzoic anhydride, pentaerythritol, phthalic anhydride, ethylene glycol and butyl ester. The resin adopts natural soybean oil and castor oil as raw materials to synthesize a natural and environment friendly resin, which canbe used for decorating paint blending and has environmental protection property. As the soybean oil and the castor oil are renewable resources, the resin provided in the invention is conducive to thesustainable development of society.
Description
Technical field
The present invention relates to a kind of natural environmental-protective resin, especially a kind of decorations natural environmental-protective resin and production method thereof.
Background technology
Present prior art, resin is the chief component of coating, is directly determining the quality of coating property.Conventional resin is to be formed by the petroleum cracking monomer polymerization, and oil belongs to Nonrenewable resources, will certainly affect the Sustainable development of society to the long-term exploitation of oil.
Summary of the invention
The objective of the invention is: a kind of fitment paint natural environmental-protective resin is provided, it adopts crude soya bean oil and Viscotrol C is starting material, synthetic a kind of natural environmental-protective resin, this resin can be used for the allotment of fitment paint, has environmental protection, because soybean oil and Viscotrol C are renewable resources, be conducive to the Sustainable development of society.
The present invention is achieved in that the said a kind of natural environmental-protective resin of the present invention, and its weight percent is:
Soybean oil 20%-30%,
Viscotrol C 10%-20%,
Dimethylbenzene 2%-6%,
Oxidation inhibitor 0.1%-0.5%,
Benzoyl oxide 1.0%-2.0%,
Tetramethylolmethane 10%-16%,
Phthalic anhydride 15%-25%,
Ethylene glycol 2%-2.6%,
Butyl ester 17.5%-22.5%.
Its making method comprises the steps:
(1) check whether reactor is clean, and whether bottom valve closes, whether each cooling water system of inspection on probation is normal, and whether equipment is normal;
(2) in order with in soybean oil, Viscotrol C, the dimethylbenzene suction reactor, deserve to be called at little pound with plastic tank and accurately to weigh up oxidation inhibitor, add and be uniformly dispersed (not splashing on the still wall when attention adds oxidation inhibitor) from manhole after the dilution;
(3) successively benzoyl oxide, tetramethylolmethane, phthalic anhydride, ethylene glycol are dropped into reactor, build manhole, logical CO2 5L/min opens heating system and heats up after ten minutes;
(4) open horizontal water coolant and continue to heat up, be warming up to 100 ± 2 ℃, runin is stirred, and continues directly to be warming up to 220 ℃ of insulations;
(5) 225 ± 2 ℃ of insulation insulation esterifications.Begin middle control after the insulation.Per hour detect once, when viscosity behind 10s, detected once in per 0.5 hour, until acid number, viscosity are qualified;
(6) acid number, viscosity quality inspection are cooled to below 100 ℃ after qualified, with the butyl ester latting drown, transfer sticking, discharging.
Embodiment
Embodiment 1
A kind of fitment paint natural environmental-protective resin, its weight percent is:
Its manufacture method comprises the steps:
(1) check whether reactor is clean, and whether bottom valve closes, whether each cooling water system of inspection on probation is normal, and whether equipment is normal;
(2) in order with in soybean oil, Viscotrol C, the dimethylbenzene suction reactor, deserve to be called at little pound with plastic tank and accurately to weigh up oxidation inhibitor, add and be uniformly dispersed from manhole after the dilution; Do not splash on the still wall when noting adding oxidation inhibitor;
(3) then successively benzoyl oxide, tetramethylolmethane, phthalic anhydride, ethylene glycol are dropped into reactor, build manhole, logical CO2 5L/min opens heating system and heats up after ten minutes;
(4) open horizontal water coolant and continue to heat up, be warming up to 100 ± 2 ℃, runin is stirred, and continues directly to be warming up to 220 ℃ of insulations;
(5) 225 ± 2 ℃ of insulation insulation esterifications.Begin middle control after the insulation.Per hour detect once, when viscosity detected once behind the 10s in per 0.5 hour, until acid number, viscosity are qualified;
(6) acid number, viscosity quality inspection are cooled to below 100 ℃ after qualified, with the butyl ester latting drown, transfer sticking, discharging.
The solvent-borne type dimethylbenzene of dimethylbenzene PetroChina Company Limited.;
The P-3050 oxidation inhibitor of oxidation inhibitor Paasche holder company.
The purified soyabean oil of the permanent chemical industry far away of soybean oil Shen county of Shandong;
The emerging refining castor oil in sky, Viscotrol C Shandong;
The organic benzoyl oxide in benzoyl oxide Wuhan;
The tetramethylolmethane that tetramethylolmethane Hubei should be changed;
The phthalic anhydride Dongguan contain and phthalic anhydride;
The ethylene glycol of the fast petrochemical industry in ethylene glycol east;
The butyl ester of the modest letter in butyl ester Jiangmen.
Embodiment 2
A kind of fitment paint natural environmental-protective resin, its weight percent is:
Soybean oil 30%, Viscotrol C 10%
Dimethylbenzene 2% oxidation inhibitor 0.1%
Benzoyl oxide 2.0%, tetramethylolmethane 10%
Phthalic anhydride 20.8 ethylene glycol 2.6%
Butyl ester 22.5%.
Embodiment 3
A kind of fitment paint natural environmental-protective resin, its weight percent is:
Soybean oil 23% Viscotrol C 14.4%
Dimethylbenzene 3% oxidation inhibitor 0.3%
Benzoyl oxide 1.5%, tetramethylolmethane 13%
Phthalic anhydride 25% ethylene glycol 2.3%
Butyl ester 17.5%.
Replace the compound of petroleum cracking with natural compounds, saved Nonrenewable resources, be conducive to the Sustainable development of society,
Above-described only is preferential embodiment of the present invention.Should be pointed out that for the person of ordinary skill of the art, in the situation that do not break away from the principle of the invention, can also make some improvement and modification, this also is considered as protection scope of the present invention.
Claims (1)
1. a fitment paint is with the manufacture method of natural environmental-protective resin, and it is characterized in that: its described fitment paint with the weight percent of natural environmental-protective resin composition is:
Described fitment paint comprises the steps: with the manufacture method of natural environmental-protective resin
(1) check whether reactor is clean, and whether bottom valve closes, whether each cooling water system of inspection on probation is normal, and whether equipment is normal;
(2) in order with in soybean oil, Viscotrol C, the dimethylbenzene suction reactor, deserve to be called at little pound with plastic tank and accurately to weigh up oxidation inhibitor, add and be uniformly dispersed from manhole after the dilution;
(3) successively benzoyl oxide, tetramethylolmethane, phthalic anhydride, ethylene glycol are dropped into reactor, build manhole, logical CO
25L/min opens heating system and heats up after ten minutes;
(4) open horizontal water coolant and continue to heat up, be warming up to 100 ± 2 ℃, runin is stirred, and continues directly to be warming up to 220 ℃ of insulations;
(5) 225 ± 2 ℃ of insulation esterifications, begin middle control after the insulation, per hour detect once, when viscosity behind 10s, detected once in per 0.5 hour, until acid number, viscosity are qualified;
(6) acid number, viscosity quality inspection qualified after, be cooled to below 100 ℃, with the butyl ester latting drown, transfer sticking, discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110425764 CN102617838B (en) | 2011-12-19 | 2011-12-19 | Natural and environment friendly resin used for decorating paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110425764 CN102617838B (en) | 2011-12-19 | 2011-12-19 | Natural and environment friendly resin used for decorating paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102617838A CN102617838A (en) | 2012-08-01 |
| CN102617838B true CN102617838B (en) | 2013-09-18 |
Family
ID=46558079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110425764 Expired - Fee Related CN102617838B (en) | 2011-12-19 | 2011-12-19 | Natural and environment friendly resin used for decorating paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102617838B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103435791B (en) * | 2013-08-07 | 2015-09-09 | 山东奔腾漆业股份有限公司 | A kind of low taste coating alkyd resin and preparation method thereof |
| CN104397991A (en) * | 2014-11-07 | 2015-03-11 | 成都三鑫鼎高家具有限公司 | Office table with embossing effect and manufacturing method of office table |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1483777A (en) * | 2003-07-21 | 2004-03-24 | 深圳市飞扬实业有限公司 | High-fullness high-resolution environment protection polyureshane sublight uarnish |
| CN101259990A (en) * | 2008-04-10 | 2008-09-10 | 上海交通大学 | Mirror back lacquer resin and mirror back lacquer |
| CN101845274A (en) * | 2009-11-18 | 2010-09-29 | 嘉汉林业(广州)有限公司 | Coating combination for pure natural woodenware |
| CN101942063A (en) * | 2010-08-17 | 2011-01-12 | 华南理工大学 | Water-borne epoxy ester modified alkyd resin emulsion and preparation method thereof |
| CN102051110A (en) * | 2010-12-14 | 2011-05-11 | 惠州市长润发涂料有限公司 | Alkyd resin for wood lacquer and preparation method thereof |
-
2011
- 2011-12-19 CN CN 201110425764 patent/CN102617838B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1483777A (en) * | 2003-07-21 | 2004-03-24 | 深圳市飞扬实业有限公司 | High-fullness high-resolution environment protection polyureshane sublight uarnish |
| CN101259990A (en) * | 2008-04-10 | 2008-09-10 | 上海交通大学 | Mirror back lacquer resin and mirror back lacquer |
| CN101845274A (en) * | 2009-11-18 | 2010-09-29 | 嘉汉林业(广州)有限公司 | Coating combination for pure natural woodenware |
| CN101942063A (en) * | 2010-08-17 | 2011-01-12 | 华南理工大学 | Water-borne epoxy ester modified alkyd resin emulsion and preparation method thereof |
| CN102051110A (en) * | 2010-12-14 | 2011-05-11 | 惠州市长润发涂料有限公司 | Alkyd resin for wood lacquer and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN102617838A (en) | 2012-08-01 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 611330 Chengdu badshi coating Co., Ltd., Jiazi Road, Jinyuan Town, Dayi County, Chengdu City, Sichuan Province Patentee after: Sichuan badshi New Material Co.,Ltd. Address before: 611330 Chengdu badshi coating Co., Ltd., Jiazi Road, Jinyuan Town, Dayi County, Chengdu City, Sichuan Province Patentee before: CHENGDU BADESHI PAINT Co.,Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130918 Termination date: 20211219 |