CN102613294A - Oligosaccharide milk - Google Patents
Oligosaccharide milk Download PDFInfo
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- CN102613294A CN102613294A CN2011100335317A CN201110033531A CN102613294A CN 102613294 A CN102613294 A CN 102613294A CN 2011100335317 A CN2011100335317 A CN 2011100335317A CN 201110033531 A CN201110033531 A CN 201110033531A CN 102613294 A CN102613294 A CN 102613294A
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Abstract
The invention relates to oligosaccharide milk, comprising 920-990 kg of dairy products, 6-65 kg of oligosaccharide, and 1-5 kg of emulsion stabilizer, wherein the oligosaccharide is a combination of 5-55 kg of galacto-oligosaccharides (GOS) and 1-10 kg of fructo-oligosaccharide (FOS). The milk containing oligosaccharide of the present invention can be utilized by beneficial bacteria in human intestinal tract and has the effects of inhibiting the growth of harmful bacteria, especially can be effectively utilized by intestinal bifidobacteria and lactobacillus to rapidly proliferate, improve intestinal micro-environment, and raise the body immunity.
Description
Technical field
[the present invention relates to a kind of normal temperature sterile milk, more specifically say to the present invention relates to a kind of normal temperature sterile milk that contains compound sugar.
Background technology
In cow's milk, add prebiotics and be at present one of method of comparatively popular enhancing breast trophic function property both at home and abroad.According to for many years to the further investigation of dietary fiber and oligosaccharides, people confirmed FOS and galactooligosaccharide to the function of intestinal canal improvement, prevent treating constipation and effects such as diarrhea, raising body immunity remarkable.The FOS structure is unique, not by the hydrochloric acid in gastric juice of human body alimentary canal and enzymic digestion, Bifidobacterium is bred rapidly, because of it produces SCFA, makes enteron aisle pH value meta-acid, suppresses the growth of pernicious bacteria, plays the effect that improves function of intestinal canal.Galactooligosaccharide is raw material with the lactose; Through beta galactosidase catalyzing hydrolysis galactolipin glycosidic bond, generate galactolipin and glucose, and the effect through transgalactosidation; The galactoside that hydrolysis is got off is transferred to lactose molecule; Generate galactooligosaccharide, then through behind the purifying or granulation obtain, the product form that obtains is for liquid or Powdered; Galactooligosaccharide can make its rapid propagation effectively by Bifidobacterium and Bacillus acidi lactici utilization, improves the intestinal microecology environment, improves immunity of organisms.
In recent years; The various intercurrent diseases that obesity causes have caused people's abundant concern; Most of people have noted reducing the absorption of animal fat; Therefore, developing the consumption demand that the dairy products that contain compound sugar meet numerous people, also is one of developing direction that reaches in the recent period the dairy products new product foreseeable future.
CN101766226A discloses a kind of liquid diary product that contains galactooligosaccharide and dietary fiber, and it comprises milk, and the pH value is cushioning liquid or buffer salt system, dietary fiber and the stabilizing agent of the galactooligosaccharide of 6.5-7.5.
The sour milk products that does not also contain composite phosphate in the prior art.
Summary of the invention
Technical problem to be solved by this invention provides a kind of cow's milk that contains compound sugar; Compound sugar wherein is selected from the combination of FOS and galactooligosaccharide, and it not only can satisfy the human nutrition needs, and instant edible; Can help improve the human body intestinal canal function, improve body immunity.
Therefore, the present invention provides a kind of compound sugar cow's milk, and raw materials used proportioning comprises as follows: dairy products 920-990kg, os compound sugar 6-65kg, emulsion stabilizer 1-5kg.
Among the present invention, except that mentioned component, can also contain other compositions, for example moisture in the cow's milk of the present invention; The essence that is used to tart up; Be used for further increasing the thickener of denseness, like xanthans; Other flavor enhancements are like honey or the like.
In one embodiment, also contain flavoring essence 0.5-1.5kg in the compound sugar cow's milk of the present invention.Essence can be any essence commonly used in this area.For example, honey peach essence, essence for organi juice, blackberry, blueberry essence, strawberry essence, flavoring pineapple essence, flavoring apple essence, lychee flavor, mango essence, lemon extract etc.
Among the present invention, the os compound sugar is the combination of galactooligosaccharide (GOS) 5-55kg and FOS (FOS) 1-10kg.
Compound sugar, FOS and galactooligosaccharide
Generally speaking, compound sugar comprises many types, for example, and malto-oligosaccharide, oligoisomaltose, cyclodextrine, gentiobiose, coupling sugar (Coup ling sugar), fructose oligosaccharides, panose, trehalose, sucrose compound sugar, cow's milk compound sugar; The chitin compound sugar; Soyabean oligosaccharides; The wood compound sugar.
Inventor of the present invention is through further investigation, and the combination of having found to be suitable for the compound sugar in the dairy products is the combination of FOS and galactooligosaccharide.
(Fructo oligosaccharide is a kind of natural active matter FOS) to FOS, has the adjusting gut flora, and the propagation Bifidobacterium promotes the absorption of calcium, regulates blood fat, immunological regulation, health cares such as anti-carious tooth.
FOS is except that the physicochemical properties with general utility functions property compound sugar; The most noticeable physiological property is that it can obviously improve microbial population ratio in the enteron aisle; It is the activation and proliferation factor of Bifidobacterium in the intestines; Can reduce and suppress the generation of corrupt substance in the intestines, suppress the growth of harmful bacteria, regulate the enteron aisle inner equilibrium; Can promote the absorption and the utilization of trace elements iron, calcium, to prevent osteoporosis; Can reduce hepatotoxin, can in intestines, generate anticancer organic acid, significant preventing cancer function is arranged; And pure taste is fragrant and sweet good to eat, adipose fragrance of type of having and tasty and refreshing soapy feeling.
The concrete efficacy performance of FOS exists: the heat energy value is hanged down in (1), because FOS can not be absorbed by the human body direct digestion, can only be absorbed by enteric bacteria, so its calorific value is low, can not cause fat, and antiobesity action is also arranged indirectly.Also a kind of good sweetener concerning the diabetic.(2), thereby has the anti-caries effect owing to it can not be utilized by oral bacteria (phalangeal process becomes streptococcus Smutans).(3) to the proliferation function of enteron aisle benefit bacterium.FOS is to the selective proliferation function of profitable strain such as Bifidobacterium Bifidum, Bacillus acidi lactici etc. in the enteron aisle; Profitable strain is taken advantage in enteron aisle; Suppress the growth of harmful bacterium, reduce the formation of noxious material (like endotoxin, Ammonia etc.), intestinal mucosa cells and liver are had protective effect; Thereby prevent the generation of pathology intestinal cancer, enhancing body immunity.(4) can reduce the content of cholesterol in serum and triglycerides.(5) absorption of absorption, the especially calcium of promotion nutrition.(6) prevent and treat diarrhea and constipation.FOS is a kind of water-soluble dietary fiber, takes for a long time and can reduce serum cholesterol, improves lipid-metabolism.
Through animal and human's body experiment confirm, FOS has following physiological function: by beneficial bacteriums such as Bifidobacterium are utilized, have the effect of bidirectional modulation.After human body was taken in FOS, profitable strain Bifidobacterium quantity can suppress growth and breeding such as intrinsic putrefactivebacteria such as salmonella in external source pathogenic bacteria and the intestines in the body, reduced the growth and the accumulation of corrupt substance in the intestines, promoted intestines peristalsis, prevented constipation and diarrhoea.FOS is a kind of good water-soluble dietary fiber, can effectively reduce the quantity of serum cholesterol, triglyceride, free fatty, for having a better role because of a series of angiocardiopathies such as the high hypertension that causes of blood fat, artery sclerosis.FOS is generated L-lactic acid by bacterial fermentation in large intestine, can dissolving calcium, mineral matters such as magnesium, iron, promote the absorption of human body to mineral matter.Experiment confirm, FOS promote the absorptivity of calcium to reach 70.8%.Therefore, FOS can promote to grow and prevent osteoporosis.Also can promote forming naturally of vitamin B1, B2, B3, B6, B12 and folic acid simultaneously, thereby improve the human body metabolism, improve immunity and premunition.Prevention and improving because the skin diseases that the body endogenous toxic material causes can prevent face sore, blackspot, freckle, whelk, age mark, make skin beautiful, wear out and slow down.After Bifidobacterium absorbed FOS, propagation suppressed spoilage organisms such as Escherichia coli, salmonella and clostruidium and has an effect rapidly; Reduce the generation of toxic metabolites (like indoles, nitroso ammonia), rapidly toxic metabolites is excreted simultaneously, alleviate burden of liver; Play liver-protective effect; Prevent effects such as various chronic diseases, cancer obviously, FOS seldom can be decomposed by hydrochloric acid in gastric juice in the alimentary canal and enzyme, and extremely difficulty is absorbed by the body.
(Galactooligosaccharides GOS) is a kind of functional oligose with natural attribute to galactooligosaccharide.Galactooligosaccharide (GOS) and FOS (FOS) and oligoisomaltose (IMO) are compared: in three kinds of compound sugar, galactooligosaccharide is unique can both the utilization by 8 big beneficial bacteriums in the human body intestines.
? | Bacterium | GOS | IMO | FOS |
1 | Bifidobacterium adolescentis B. adolescentils | ++ | ++ | ++ |
2 | Bifidobacterium bifidum B. bifidum | ++ | - | - |
3 | Bifidobacterium infantis B. infantis | ++ | ++ | ++ |
4 | Bifidobacterium longum B. longum | ++ | + | ++ |
5 | Bifidobacterium breve B. breve | ++ | ++ | + |
6 | Lactobacillus acidophilus L. acidophilus | ++ | + | + |
7 | Lactobacillus casei L. casei | ++ | - | ? |
8 | Lactobacillus salivarius L. salivarius | ++ | - | ++ |
Galactooligosaccharide can suppress the growth and breeding of human body intestinal toxic bacterium.
? | Bacterium | GOS | IMO | FOS |
1 | Clostridium difficile C. difficile | + | - | - |
2 | ETEC E. coli | ++ | - | - |
Galactooligosaccharide has stronger acid resistance, hear resistance, can not decompose and loses the characteristic that it should have originally because of the high temperature sterilization in process and human body hydrochloric acid in gastric juice, and FOS does not then possess these characteristics.Galactooligosaccharide can be utilized by bifid bar B bacterium and lactic acid bar A bacterium effectively simultaneously.Compound sugar such as FOS FOS are then utilized by lactic acid bar A bacterium only, and are then not obvious to bifid bar B bacterium.
Because galactooligosaccharide can be by the beneficial bacterium utilization; And can suppress harmful bacterium; As main compound sugar composition, cooperate FOS as auxiliary compound sugar composition it, both make beneficial bacteria of intestinal tract propagation aspect that good enhancing, complementation arranged as prebiotics; FOS can make Bifidobacterium breed rapidly, and galactooligosaccharide can make Bifidobacterium and Bacillus acidi lactici propagation.Therefore its function benefit will better be brought into play both combinations.
Therefore, galactooligosaccharide and the FOS ratio with 5-55kg:1-10kg being made up, add in the cow's milk, is inventive point of the present invention.
Dairy products
Among the present invention, used dairy products can be selected from raw milk, for example full-cream fresh milk, and full-cream reconstituted milk, full-cream antibiotic-free milk or the like is processed the raw milk that contains compound sugar.Reconstituted milk is claimed " recombined milk " or " recombined milk " again, be meant milk concentrate, drying becomes and concentrates breast or milk powder, adds suitable quantity of water again, process and former Ru Zhongshui, emulsion that the solids ratio is suitable.Generally, reconstituted milk is exactly to blend the cow's milk that reduction forms with milk powder." antibiotic-free milk " as its name suggests, is the milk that does not contain antibiotic, only otherwise containing the milk that the raw material milk of antibiotic produces is " antibiotic-free milk ".It is not the kind of milk, but general reference does not contain the milk of antibiotic; Or the milk of " antibiotic residue does not detect ".The milk that present a lot of well-known producers dispatch from the factory can both reach " antibiotic-free milk " this standard.
Dairy products of the present invention can also be selected from low fat cow's milk, process the low fat cow's milk that contains compound sugar, and preferred, being selected from fat content is the low fat cow's milk of 1.2-1.5%.
Low fat cow's milk of the present invention can use any cow's milk that meets the fat content condition commonly used; Preferably with whole milk or full-cream reconstituted milk; Through being warming up to 43-60 ℃; Degreasing to fat content is 1.2-1.5%, and perhaps nonfat milk and whole milk being mixed to fat content is that 1.2-1.5% processes.
Emulsion stabilizer
Emulsion stabilizer is the stabilizing agent of emulsion, also claims emulsifying agent.Emulsifying agent commonly used has the emulsifying agent of Arabic gum, sodium alkyl benzene sulfonate, locust bean gum, guar gum, carrageenan, sodium alginate, sodium carboxymethylcellulose and multiple combination thereof etc.
The present invention can use this area any emulsion stabilizer commonly used or the combination of multiple emulsion stabilizer.
Preferably, be selected from microcrystalline cellulose, glycerin monostearate, natrium citricum, sodium carboxymethylcellulose, the carragheen one or more.
In a preferred scheme, emulsion stabilizer is the combination of microcrystalline cellulose 0.2-1Kg, glycerin monostearate 0.2-1Kg, natrium citricum 0.1-0.5Kg, sodium carboxymethylcellulose 0.3-2Kg, carragheen 0.2-0.5kg.
According to finding, in the cow's milk that contains compound sugar of the present invention, use the combination of above-mentioned emulsion stabilizer or emulsion stabilizer; Except that having common emulsification; Also has following function: the protein interaction in (1) and the cow's milk, the network structure of enhancement cow's milk system, enhanced toughness and drag; Make protein have elasticity, increase volume.(2) antiseized and anti-fusing becomes layer protecting film at the habit of compound sugar, prevents that air and moisture from invading, and improves the moisture resistance of goods, prevents product deformation, reduces the viscosity of system simultaneously.(3) promote the dispersion of liquid in liquid, improve product stability.(4) fatty crystal in the improvement cow's milk, fatty crystal has multiple crystalline form, and is wherein comparatively common and stable with β-crystalline form; Because crystal particles is big, fusing point is high, is inappropriate for baked product; Be easy to generate " sand grains " emulsifying agent controlled combinations body proterties size and the speed of growth; Stablize β-crystalline form, make it to be transformed into β-crystalline form, improving with the hard fat is the product institutional framework of matrix.(5) keep the emulsion balanced action, in process, add above-mentioned emulsion stabilizer, can prevent because of adding other compositions, like compound sugar, the destruction of the emulsion balance that causes has the effect that suppresses foam; (6) anti-corrupt preservation, the emulsion stabilizer agent also has certain bacteriostasis.
Compound sugar cow's milk of the present invention prepares through following method, and it comprises the steps: (1) batching; (2) preheating and homogeneous; (3) sterilization; (4) cooling;
Wherein, described (1) batching step is preferably: in cow's milk, proportionally add compound sugar, emulsion stabilizer raw material, stirring, mixing, constant volume;
Described (2) preheating and homogenizing step are preferably: preheating, preheat temperature are 65-90 ℃, homogeneous, and homogenization pressure: gross pressure is 18-25Mpa;
Described (3) sterilization steps, be preferably superhigh temperature instantaneous (UHT) sterilization: sterilising temp is 137-142 ℃, and sterilizing time is 2-4 second.The UHT sterilization can be adopted tubular type steam sterilizing, the multiple sterilization method of board-like steam sterilizing;
Described (4) cooling step is preferably: the milk of ultra high temperature short time sterilization is cooled to about 15-30 ℃.
Preparation method of the present invention can comprise aseptic jar of cooled milk entering, carry out sterile filling.
Before described batching step, the method for preparing cow's milk of the present invention can also comprise the raw milk examination; With the raw milk preliminary treatment.
Described raw milk is checked and accepted step, is preferably: be primarily aimed at acidity, fat, real milk solids, proportion, mingle (starch, alkali, salt, nitrite), antibiotic, taste smell detect, qualified high-quality milk is as raw milk.Harmful material in the strict control milk is like nitrate, residues of pesticides, antibiotic;
Described raw milk pre-treatment step is preferably: cow's milk is removed bigger foreign matter, impurity through gauze or duplex strainer coarse filtration; Through centrifugal clean breast, the breast epithelial tissue, the leucocyte that remove tiny dirt, come off, reach highly clean breast, improve the quality of products.In order to obtain the finished product that liptinite becomes component, must carry out standardization, reach the balance of index between butter oil and the non-fat solid, storage temperature is about 4 ℃;
Cow's milk of the present invention, if use low fat cow's milk, can be with whole milk or full-cream reconstituted milk, through being warming up to 43-60 ℃, degreasing to fat content is 1.2-1.5%, or nonfat milk and whole milk are mixed to fat content is 1.2-1.5%.
The cow's milk that contains compound sugar of the present invention has by beneficial bacterium utilization in the human body intestinal canal, suppresses the effect of harmful bacteria growing; Particularly can be effectively by intestinal bifidobacteria and Bacillus acidi lactici utilization; Make its rapid propagation, improve the intestinal microecology environment, improve immunity of organisms.
In the cow's milk of the present invention; Compound sugar is main compound sugar composition with galactooligosaccharide; FOS is auxiliary compound sugar composition, and both can make beneficial bacteria of intestinal tract propagation aspect that good enhancing, complementation are arranged as prebiotics, and its function benefit is better brought into play.
In addition, in the cow's milk of the present invention, preferably used the combination of specific emulsion stabilizer, except that having common emulsification, can also produce with cow's milk in protein interaction, promote the network structure of cow's milk system; Habit at compound sugar becomes layer protecting film; Promote the dispersion of liquid in liquid; Fatty crystal in the improvement cow's milk; Keep effects such as emulsion balance.
The specific embodiment
Following examples only are to illustrate of the present invention, and scope of the present invention is not limited thereto.
Embodiment 1
The batching of present embodiment is following:
Whole milk 990Kg, galactooligosaccharide 55Kg, FOS 1Kg, honey peach essence 0.6Kg.
Emulsion stabilizer is: microcrystalline cellulose 1Kg, glycerin monostearate 1Kg, natrium citricum 0.5Kg, sodium carboxymethylcellulose 2Kg, carragheen 0.5kg.
The preparation method comprises the steps:
Milk is pumped into mixing tank.Proportionally add raw material, stirring, mixing, constant volume; After material adds mixing tank, stir;
Preheating: preheat temperature is 90 ℃, homogeneous: homogenization pressure: gross pressure is 25Mpa, and first class pressure is 20Mpa, and secondary pressure is 5Mpa;
Sterilising temp is 142 ℃, and sterilizing time is 2 seconds.Board-like steam sterilizing is adopted in the UHT sterilization;
The milk of ultra high temperature short time sterilization is cooled to about 30 ℃.Milk after the sterilization gets into aseptic jar;
Sterile filling gets into warehouse for finished product to packing through the product that is up to the standards.
Embodiment 2
The batching of present embodiment is following:
Fat content is 1.5% low fat cow's milk 920Kg, galactooligosaccharide 5Kg, FOS 10Kg.
Emulsion stabilizer is: microcrystalline cellulose 0.2Kg, glycerin monostearate 0.2Kg, natrium citricum 0.1Kg, sodium carboxymethylcellulose 0.3Kg, carragheen 0.2kg.
The preparation method comprises the steps:
Milk is pumped into mixing tank.Proportionally add raw material, stir;
Preheating: preheat temperature is 65 ℃, homogeneous: homogenization pressure: gross pressure is 18Mpa, and first class pressure is 13Mpa, and secondary pressure is 5Mpa;
Sterilising temp is 137 ℃, and sterilizing time is 4 seconds.The tubular type steam sterilizing is adopted in the UHT sterilization;
The milk of ultra high temperature short time sterilization is cooled to about 15 ℃.Milk after the sterilization gets into aseptic jar.
Embodiment 3
The batching of present embodiment is following:
Full-cream reconstituted milk 950Kg, galactooligosaccharide 30Kg, FOS 5Kg, essence for organi juice 1Kg;
Emulsion stabilizer is: microcrystalline cellulose 0.6Kg, glycerin monostearate 0.6Kg, natrium citricum 0.3Kg, sodium carboxymethylcellulose 1.6Kg, carragheen 0.4kg.
The preparation method comprises the steps:
Raw milk is checked and accepted: be primarily aimed at acidity, fat, real milk solids, proportion, mingle (starch, alkali, salt, nitrite), antibiotic, taste smell detect, qualified high-quality milk is as raw milk.Harmful material in the strict control milk is like nitrate, residues of pesticides, antibiotic;
The raw milk preliminary treatment is preferably: cow's milk is removed bigger foreign matter, impurity through gauze or duplex strainer coarse filtration; Through centrifugal clean breast, the breast epithelial tissue, the leucocyte that remove tiny dirt, come off, reach highly clean breast, improve the quality of products.In order to obtain the finished product that liptinite becomes component, must carry out standardization, reach the balance of index between butter oil and the non-fat solid, storage temperature is about 4 ℃;
Pretreated milk is pumped into mixing tank.Proportionally add raw material if make, stirring, mixing, constant volume; After material adds mixing tank, stir, and keep the skin wet constant volume;
Preheating: preheat temperature is 75 ℃, homogeneous: homogenization pressure: gross pressure is 18Mpa, and first class pressure is 10Mpa, and secondary pressure is 8Mpa;
Sterilising temp is 137 ℃, and sterilizing time is 3 seconds.The tubular type steam sterilizing is adopted in the UHT sterilization;
The milk of ultra high temperature short time sterilization is cooled to about 20 ℃.Milk after the sterilization gets into aseptic jar;
Sterile filling gets into warehouse for finished product to packing through the product that is up to the standards.
Embodiment 4
The batching of present embodiment is following:
Whole milk 980Kg, galactooligosaccharide 55Kg, FOS 10Kg.
Emulsion stabilizer is: microcrystalline cellulose 1Kg, glycerin monostearate 0.3Kg, natrium citricum 0.3Kg, carragheen 0.4kg, sodium carboxymethylcellulose 2Kg.
The preparation method comprises the steps:
With full-cream fresh milk, be warming up to 60 ℃, using seperator degreasing to fat content is 1.2%,
Pretreated milk is pumped into mixing tank.Proportionally add raw material if make, stir;
Preheating: preheat temperature is 69 ℃, homogeneous: homogenization pressure: gross pressure is 18Mpa, and first class pressure is 10Mpa, and secondary pressure is 8Mpa;
Sterilising temp is 137 ℃, and sterilizing time is 3 seconds.The tubular type steam sterilizing is adopted in the UHT sterilization;
The milk of ultra high temperature short time sterilization is cooled to about 20 ℃.Milk after the sterilization gets into aseptic jar;
Sterile filling gets into warehouse for finished product to packing through the product that is up to the standards.
Though below done to elaborate according to the design and the embodiment of the object of the invention; But those of ordinary skills can recognize; Under the precondition that does not break away from the claim limited range; Still can make various improvement and conversion to the present invention, and these improve and conversion still should belong to protection scope of the present invention.
Claims (7)
1. a compound sugar cow's milk is characterized in that, raw materials used proportioning comprises as follows: dairy products 920-990kg, os compound sugar 6-65kg, emulsion stabilizer 1-5kg;
Wherein, described os compound sugar is the combination of galactooligosaccharide (GOS) 5-55kg and FOS (FOS) 1-10kg.
2. compound sugar cow's milk according to claim 1, wherein said dairy products are selected from raw milk.
3. compound sugar cow's milk according to claim 1, wherein said dairy products are selected from the low fat cow's milk that fat content is 1.2-1.5%.
4.., wherein also contain flavoring essence 0.5-1.5kg according to each compound sugar cow's milk of claim 1-3.
5. according to each described compound sugar cow's milk of claim 1-4, wherein said emulsion stabilizer is selected from: one or more in microcrystalline cellulose, glycerin monostearate, natrium citricum, sodium carboxymethylcellulose, the carragheen.
6. compound sugar cow's milk according to claim 5, wherein said emulsion stabilizer are the combinations of microcrystalline cellulose 0.2-1Kg, glycerin monostearate 0.2-1Kg, natrium citricum 0.1-0.5Kg, sodium carboxymethylcellulose 0.3-2Kg, carragheen 0.2-0.5kg.
7. compound sugar cow's milk according to claim 3; Wherein said low fat cow's milk is whole milk or full-cream reconstituted milk; Through being warming up to 43-60 ℃, degreasing to fat content is 1.2-1.5%, or nonfat milk and whole milk are mixed to fat content is 1.2-1.5%.
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CN103300144A (en) * | 2013-06-14 | 2013-09-18 | 扬州市扬大康源乳业有限公司 | Production method for low-fat raw milk and low-fat liquid milk product |
CN105265580A (en) * | 2014-07-10 | 2016-01-27 | 内蒙古伊利实业集团股份有限公司 | Organic children milk and preparation method thereof |
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