CN102604718A - Environmentally-friendly water-soluble non-oil metal rust-inhibiting lubricant - Google Patents

Environmentally-friendly water-soluble non-oil metal rust-inhibiting lubricant Download PDF

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Publication number
CN102604718A
CN102604718A CN2012100301207A CN201210030120A CN102604718A CN 102604718 A CN102604718 A CN 102604718A CN 2012100301207 A CN2012100301207 A CN 2012100301207A CN 201210030120 A CN201210030120 A CN 201210030120A CN 102604718 A CN102604718 A CN 102604718A
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China
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minutes
reaction kettle
rust
lubricant
friendly water
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CN2012100301207A
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Chinese (zh)
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CN102604718B (en
Inventor
张洪民
经纬
苗天
张雷
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Abstract

The invention relates to an environmentally-friendly water-soluble non-oil metal rust-inhibiting lubricant which is characterized by comprising the following materials in percent by weight: 30% of amine borate, 5% of sodium gluconate, 2% of sodium molybdate, 20% of monoethanolamine, 13% of polyethylene glycol, 5% of ethanol, 15% of glycerol and the balance of deionized water. An organic metal corrosion inhibitor and an inorganic metal corrosion inhibitor are compounded and blended into the rust-inhibiting lubricant, thus the modern civilization production requirements for low energy consumption, low pollution, low emission and high environment friendliness are met. The lubricant has the four functions of inhibiting rust, removing rust, lubricating and washing and is a high-efficiency maintaining agent which is used for the production, storage, maintenance and repair of a variety of mechanical equipment, precision instruments and parts and component and can be used for keeping the metal product in the optimum work state so that the service life of the metal product is prolonged. The detection of the Shenyang Disease Control Center shows that the LD50 (lethal dose, 50%) is more than 10,000mg/kg, and the fishes and shrimps can live and propagate normally in 1 per mill aqueous solution.

Description

The non-oily metal rust preventing lubricant of environment-friendly water-soluble
Technical field
The invention belongs to a kind of technology rust-inhibiting lubricant that is used for black, non-ferrous metal, the non-oily metal rust preventing lubricant of particularly a kind of environment-friendly water-soluble.
Background technology
Centuries, the home and abroad mainly is an oil at the metallic antirust material of usefulness always, promptly so-called " slushing oil ".Scientific development with facts have proved, oil unsatisfactory as rush-resisting material, shortcoming is: 1, labor high energy; 2, oil is prone to oxygenolysis, and rust-proof life is short, and damage a large amount of iron and steel because of corrosion every year; 3, follow-up oil removing difficulty; 4, the waste liquid after the oil removing is extremely hard to manage, and seriously polluted.
Summary of the invention
The invention solves the drawback of traditional slushing oil, purpose provides a kind of high-efficiency environment friendly, energy-conservation, the reduction of discharging characteristics that has, and is used for the non-oily metal rust preventing lubricant of a kind of environment-friendly water-soluble of ferrous metal, non-ferrous metal processing industry and equipment protection.
The non-oily metal rust preventing lubricant content Description of environment-friendly water-soluble of the present invention:
The non-oily metal rust preventing lubricant of environment-friendly water-soluble of the present invention is characterized in that: be made up of by mass percentage following substances: amine borate 30%, glucono-receive 5%, Sodium orthomolybdate 2%, Monoethanolamine MEA BASF 20%, polyoxyethylene glycol 13%, ethanol 5%, USP Kosher 15%, deionized water surplus.
The non-oily metal rust preventing lubricant of preparation environment-friendly water-soluble is pressed following process step:
(1), the capping still adds Monoethanolamine MEA BASF in the reaction kettle, stop to heat up behind the heat temperature raising to 65 ℃;
(2), in reaction kettle, add amine borate capping still, stirred 10 minutes, stir;
(3), with stirring 20~30 minutes in polyoxyethylene glycol, the USP Kosher adding reaction kettle;
(4), with glucono-receive, Sodium orthomolybdate fully dissolves the back with deionized water and adds in the reaction kettle and stirred 15 minutes;
(5), in reaction kettle, add ethanol and stir after 15 minutes static 20 minutes;
(6), blowing packing.
The non-oily metal rust preventing lubricant of environment-friendly water-soluble of the present invention; The organo-metallic inhibiter is incorporated in the rust-inhibiting lubricant through composite with the inorganic metal inhibiter; Overcome the defective that traditional rust-preventive agent exists, realized the requirement that the modern civilization of less energy-consumption, low pollution, low emission, high environmental protection is produced.Four large effects such as that the present invention has is antirust, separate rust, lubricated, cleaning; It is a kind of efficient maintaining agent that all kinds of mechanical means, precision instrument, component can both be suitable in links such as production, storage, maintenance, repairings; Can let metal products keep excellent working order for a long time, increase the service life.The non-oily metal rust preventing lubricant of while environment-friendly water-soluble, CDC is detected through Shenyang: LD 50>10000 milligrams of/㎏, but the procreation of 1 ‰ aqueous solution fishes and shrimps normal existences.
Embodiment
Do below the non-oily metal rust preventing lubricant of environment-friendly water-soluble of the present invention is achieved in that and specify.
Preparation environment-friendly water-soluble non-oily metal rust preventing lubricant, get: amine borate 30 ㎏, glucono-are received 5 ㎏, Sodium orthomolybdate 2 ㎏, Monoethanolamine MEA BASF 20 ㎏, polyoxyethylene glycol 13 ㎏, ethanol 5 ㎏, USP Kosher 15 ㎏, deionized water surplus.
At first the capping still adds Monoethanolamine MEA BASF 20 ㎏ in the reaction kettle, stops to heat up behind the heat temperature raising to 65 ℃; In reaction kettle, add amine borate 30 ㎏ capping stills, stirred 10 minutes, stir; With stirring 20~30 minutes in polyoxyethylene glycol 13 ㎏, the USP Kosher 15 ㎏ adding reaction kettle; Glucono-is received 5 ㎏, Sodium orthomolybdate 2 ㎏ fully to be dissolved the back with proper amount of deionized water and adds in the reaction kettle and stirred 15 minutes; In reaction kettle, add ethanol 5 ㎏ and stir after 15 minutes, static 20 minutes, the blowing packing.
The non-oily metal rust preventing lubricant of environment-friendly water-soluble of the present invention is a kind of smokeless, tasteless, nontoxic, harmless product, LD 50>10000 milligrams of/㎏, but the procreation of 1 ‰ aqueous solution fishes and shrimps normal existences.Prove through the industrialness production test: the present invention have antirust, separate four large effects such as rust, lubricated, cleaning; It is a kind of efficient maintaining agent that all kinds of mechanical means, precision instrument, component can both be suitable in links such as production, storage, maintenance, repairings; Can let metal products keep excellent working order for a long time, increase the service life.The non-oily metal rust preventing lubricant of while environment-friendly water-soluble, CDC is detected through Shenyang: LD 50>10000 milligrams of/㎏, but the procreation of 1 ‰ aqueous solution fishes and shrimps normal existences.

Claims (3)

1. non-oily metal rust preventing lubricant of environment-friendly water-soluble is characterized in that: be made up of by mass percentage following substances: amine borate 30%, glucono-receive 5%, Sodium orthomolybdate 2%, Monoethanolamine MEA BASF 20%, polyoxyethylene glycol 13%, ethanol 5%, USP Kosher 15%, deionized water surplus.
2. prepare the non-oily metal rust preventing lubricant of environment-friendly water-soluble as claimed in claim 1, it is characterized in that: press following process step:
(1), the capping still adds Monoethanolamine MEA BASF in the reaction kettle, stop to heat up behind the heat temperature raising to 65 ℃;
(2), in reaction kettle, add amine borate capping still, stirred 10 minutes, stir;
(3), with stirring 20~30 minutes in polyoxyethylene glycol, the USP Kosher adding reaction kettle;
(4), with glucono-receive, Sodium orthomolybdate fully dissolves the back with deionized water and adds in the reaction kettle and stirred 15 minutes;
(5), in reaction kettle, add ethanol and stir after 15 minutes static 20 minutes;
(6), blowing packing.
3. the non-oily metal rust preventing lubricant of environment-friendly water-soluble according to claim 1 is characterized in that: get: amine borate 30 ㎏, glucono-are received 5 ㎏, Sodium orthomolybdate 2 ㎏, Monoethanolamine MEA BASF 20 ㎏, polyoxyethylene glycol 13 ㎏, ethanol 5 ㎏, USP Kosher 15 ㎏, deionized water surplus; At first the capping still adds Monoethanolamine MEA BASF 20 ㎏ in the reaction kettle, stops to heat up behind the heat temperature raising to 65 ℃; In reaction kettle, add amine borate 30 ㎏ capping stills, stirred 10 minutes, stir; With stirring 20~30 minutes in polyoxyethylene glycol 13 ㎏, the USP Kosher 15 ㎏ adding reaction kettle; Glucono-is received 5 ㎏, Sodium orthomolybdate 2 ㎏ fully to be dissolved the back with proper amount of deionized water and adds in the reaction kettle and stirred 15 minutes; In reaction kettle, add ethanol 5 ㎏ and stir after 15 minutes, static 20 minutes, the blowing packing.
CN 201210030120 2012-02-13 2012-02-13 Environmentally-friendly water-soluble non-oil metal rust-inhibiting lubricant Expired - Fee Related CN102604718B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201210030120 CN102604718B (en) 2012-02-13 2012-02-13 Environmentally-friendly water-soluble non-oil metal rust-inhibiting lubricant

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Application Number Priority Date Filing Date Title
CN 201210030120 CN102604718B (en) 2012-02-13 2012-02-13 Environmentally-friendly water-soluble non-oil metal rust-inhibiting lubricant

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CN102604718B CN102604718B (en) 2013-05-22

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602379A (en) * 2013-10-20 2014-02-26 安徽嘉木橡塑工业有限公司 Antirust lubricant
CN108774574A (en) * 2018-04-08 2018-11-09 清华大学天津高端装备研究院 A kind of total synthesis water-base antirust complexing agent and its evaluation method and application
CN109136954A (en) * 2018-08-03 2019-01-04 天津普罗米新材料有限公司 A kind of metal Environment-friendlywater-base water-base rust inhibitor

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070015672A1 (en) * 2005-07-14 2007-01-18 Adams Christopher J Method of improving the compatibility of an overbased detergent with other additives in a lubricating oil composition
CN101712817A (en) * 2008-09-30 2010-05-26 无锡市弘育化工有限公司 Water soluble anti-rust agent
CN101812359A (en) * 2010-03-19 2010-08-25 北京天一精人石化科技有限公司 Antirust oil for high-speed railway track switch and production method thereof
CN102295976A (en) * 2011-07-13 2011-12-28 李胜 Lubricant for heavy-load machining of metals and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070015672A1 (en) * 2005-07-14 2007-01-18 Adams Christopher J Method of improving the compatibility of an overbased detergent with other additives in a lubricating oil composition
CN101712817A (en) * 2008-09-30 2010-05-26 无锡市弘育化工有限公司 Water soluble anti-rust agent
CN101812359A (en) * 2010-03-19 2010-08-25 北京天一精人石化科技有限公司 Antirust oil for high-speed railway track switch and production method thereof
CN102295976A (en) * 2011-07-13 2011-12-28 李胜 Lubricant for heavy-load machining of metals and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602379A (en) * 2013-10-20 2014-02-26 安徽嘉木橡塑工业有限公司 Antirust lubricant
CN103602379B (en) * 2013-10-20 2015-04-29 安徽嘉木橡塑工业有限公司 Antirust lubricant
CN108774574A (en) * 2018-04-08 2018-11-09 清华大学天津高端装备研究院 A kind of total synthesis water-base antirust complexing agent and its evaluation method and application
CN108774574B (en) * 2018-04-08 2022-08-19 超滑科技(佛山)有限责任公司 Fully-synthetic water-based antirust complexing agent as well as evaluation method and application thereof
CN109136954A (en) * 2018-08-03 2019-01-04 天津普罗米新材料有限公司 A kind of metal Environment-friendlywater-base water-base rust inhibitor

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Application publication date: 20120725

Assignee: Anshan nanomei Special Oil Development Co Ltd

Assignor: Zhang Hongmin

Contract record no.: 2013210000075

Denomination of invention: Environmentally-friendly water-soluble non-oil metal rust-inhibiting lubricant

Granted publication date: 20130522

License type: Exclusive License

Record date: 20130712

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