CN102597766A - In-borehole gas monitor apparatus and method comprising a VOC concentration analyser and a VOC collector - Google Patents

In-borehole gas monitor apparatus and method comprising a VOC concentration analyser and a VOC collector Download PDF

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Publication number
CN102597766A
CN102597766A CN2010800482771A CN201080048277A CN102597766A CN 102597766 A CN102597766 A CN 102597766A CN 2010800482771 A CN2010800482771 A CN 2010800482771A CN 201080048277 A CN201080048277 A CN 201080048277A CN 102597766 A CN102597766 A CN 102597766A
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voc
pump
igm
gas
borehole
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史蒂夫·鲍尔特
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Intelisys Ltd
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Intelisys Ltd
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B49/00Testing the nature of borehole walls; Formation testing; Methods or apparatus for obtaining samples of soil or well fluids, specially adapted to earth drilling or wells
    • E21B49/08Obtaining fluid samples or testing fluids, in boreholes or wells
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/22Devices for withdrawing samples in the gaseous state
    • G01N1/2202Devices for withdrawing samples in the gaseous state involving separation of sample components during sampling
    • G01N1/2205Devices for withdrawing samples in the gaseous state involving separation of sample components during sampling with filters
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/22Devices for withdrawing samples in the gaseous state
    • G01N1/26Devices for withdrawing samples in the gaseous state with provision for intake from several spaces
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
    • G01N33/004CO or CO2
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
    • G01N33/0047Organic compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Biomedical Technology (AREA)
  • Immunology (AREA)
  • Mining & Mineral Resources (AREA)
  • Pathology (AREA)
  • Geology (AREA)
  • General Physics & Mathematics (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Sampling And Sample Adjustment (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Abstract

In-borehole gas monitor apparatus and method. An in-borehole gas monitor (IGM) apparatus comprising a VOC concentration analyser and a VOC collector.

Description

The in-borehole gas monitor apparatus and the method that comprise VOC concentration analysis device and VOC gatherer
Invention field
The present invention relates to in-borehole gas monitor (IGM) apparatus and method.
Background of invention
The monitoring of the gas concentration that produces by landfill and relevant place; The particularly monitoring of methane and gas concentration lwevel; Because the potential problems that these gases exist,, and become more common legislation requirement gradually such as the risk of blast with as the influence of greenhouse gases.At present, the gas analysis of most landfill is to realize through spot sampling or through the monitoring station, fixed position of using large-scale costliness.Recently, have recognized that the generation of gas and migration response environment factor are such as atmospheric pressure and ground water movement, and the reality of following is that spot sampling can be ignored such variation usually.
From WO2007/141512 is known a kind of self contained (self-contained) IGM is provided device, this integrated IGM device comprises that the detecting device that is used for the measurement gas variable automatically periodically uses detecting device to come the controller of measurement gas variable with being configured to.
Yet disclosed apparatus and method are not handled VOC (VOC) in WO2007/141512.
The purpose of preferred implementation of the present invention is the deficiency that solves, overcomes or eliminate prior art, and no matter whether this prior art or deficiency are related in this article or otherwise.
Summary of the invention
According to the present invention, in first aspect, in-borehole gas monitor (IGM) device is provided, it comprises VOC concentration analysis device and VOC gatherer.
Compatibly, VOC concentration analysis device is configured to provide the unspecific real-time concentration of VOC.Compatibly, VOC concentration analysis device comprises photoionization detector.
Compatibly, the VOC gatherer is configured to provide specific concentration by volume.Compatibly, the VOC gatherer comprises sorbent material.
Compatibly, device also comprises the pressure transducer that is configured to measure atmospheric pressure.
Compatibly, device also comprises timer.
Compatibly; Device comprises and being used on downstream direction the pump of gas pump through VOC concentration analysis device and VOC gatherer; And device is configured; VOC concentration analysis device continues one section pump cycles with the borehole gases pumping through VOC concentration analysis device and VOC gatherer through pump thus, and the VOC concentration under confirming at the fixed time.Compatibly, device is configured, and writes down pump cycles, Measuring Time and the atmospheric pressure under Measuring Time thus.
Compatibly; Device comprises pump and filtrator; Pump is used on downstream direction, gas pump being passed through VOC concentration analysis device and VOC gatherer, and filtrator is used for removing any particulate or moisture from the gas access, and wherein VOC concentration analysis device and VOC gatherer are positioned at the upper reaches of filtrator.
Compatibly, device comprises and being used on downstream direction the pump of gas pump through VOC concentration analysis device and VOC gatherer, and has the gas flow paths of first valve at the upper reaches that comprise gas access, pressure transducer and be positioned at pump; Wherein device configuration; Thus when first valve cuts out, the pumping one section predetermined period of living, and if in predetermined period; The predetermined pressure that is measured by pressure transducer is not exceeded, and then generates the failure of pump signal.Compatibly, predetermined period is between 8 seconds and 12 seconds, and predetermined pressure is 100mb.
Compatibly, device comprises and being used on downstream direction the pump of gas pump through VOC concentration analysis device and VOC gatherer, and has the gas flow paths of first valve, pressure transducer and the filtrator at the upper reaches that comprise the gas access, are positioned at pump; Wherein device is configured; When first valve was opened, first pressure sensor readings was obtained thus, the pump one section predetermined period that is activated; After pump is activated one section predetermined period; Second pressure sensor readings is obtained, and if the difference amount between first pressure sensor readings and second pressure sensor readings greater than predetermined value, then generate the filtrator fault-signal.Suitably, predetermined period is between 2 seconds and 6 seconds.Compatibly, predetermined value is 250mb.
Compatibly, sensing time and pump operated time span are by record.
Compatibly, device comprises gas vent and second valve that is positioned at the downstream of first valve.
Compatibly, device is configured to have boring side and atmospheric side, wherein has boring side of leading to equipment and the gas vent that leads to the atmospheric side of equipment.
Compatibly, VOC concentration analysis device and VOC gatherer are connected with gas tester in gas flow paths.Compatibly, gas tester is analyzed one or more in hydrocarbon, carbon dioxide, oxygen and the sulfuretted hydrogen.
According to a second aspect of the invention, the method for operating of in-borehole gas monitor apparatus is provided, this method comprises the use of in-borehole gas monitor apparatus in boring according to a first aspect of the invention.
Compatibly, quantitative through the VOC quilt of VOC gatherer collection.
Compatibly, device comprises and is used for gas is crossed the pump of VOC gatherer and VOC analyzer from the bore hole pump warp let-off that wherein sensing time and pump operated time span are write down to confirm to pass the gas volume of device.This makes it possible to confirm VOC concentration.
Description of drawings
To only with reference to following accompanying drawing the present invention be described simultaneously now through the mode of example; In the accompanying drawing:
Fig. 1 is the indicative icon that has according to the bore position of in-borehole gas monitor of the present invention.
Fig. 2 is the schematic sectional front view according to in-borehole gas monitor apparatus of the present invention.
Fig. 3 is the indicative flowchart that illustrates according to the method for operating of in-borehole gas monitor apparatus of the present invention.
The description of preferred implementation
With reference to Fig. 1 of accompanying drawing, shown the boring 2 in the ground that is constituted by the garbage loading embeading district.Boring 2 is supported by lining 4, and a plurality of side openings 6 are arranged in lining 4 to allow sampling.
With reference to Fig. 2 of accompanying drawing, shown in-borehole gas monitor (IGM) device 8 that comprises cover 10.Cover 10 comprises the endoporus 12 that is used to receive IGM device 8.Cover 10 comprise be used for lining 4 on the external thread 14 of corresponding internal thread (not shown) engagement.Optionally, cover can be used as the part of shell and processes.Seal 16 is not set for when having available suitable screw thread to be used by cover 10 IGM device 8 is installed in the boring.
IGM device 8 is made up of main part 17, and main part is to satisfy the i.e. self contained unit of waterproof basically of environmental rating IP-68.IGM device 8 comprises top 30 and outer tube 32.In this embodiment, the external diameter of pipe 32 is about 40mm, allows it to be inserted in the general boring lining.In this embodiment of the present invention, the length of pipe 32 is 800mm, but can be littler.
IGM device 8 also comprises the gas access 36 that is connected to first inlet valve 38; VOC (" VOC ") detecting device 40 is led in this gas access; Detecting device 40 is connected to VOC gatherer 42, and VOC gatherer 42 is connected to and is used for removing any excessive moisture and/or the moisture and the particulate filter 44 of particulate from getting into gas.Filtrator 44 is connected to first pressure transducer, 46, the first pressure transducers 46 and is connected to pump 48, and pump 48 is connected to the detector 50 that comprises a plurality of gas testers, and a plurality of gas testers in this example are H 2S and CO sensor 52, CO 2Sensor 52, CH 4Sensor 56 and O 2Sensor 58.Detecting device is connected to second valve 60; Second valve 60 is connected to return line (first outlet) 62 and the branch that turn back to boring and is connected to the 3rd valve 64; The 3rd valve 64 is connected to second pressure transducer 66, is extended with second outlet 68 from second pressure transducer 66, leads to atmosphere specifically.
Suitable filtrator 44 is particulate and moisture filtrators of orthoscopic (in-line), such as the filtrator that can obtain from the Geotechnical Engineering technology instrument (Geotechnical Instruments) of the Sovereign House in queen main road, Britain Li Mingdun mineral spring city (Queensway).
VOC detecting device 40 detects existence and the concentration of the VOC of certain limit, but does not distinguish various VOC.Suitable VOC sampling thief 40 is photoionization detectors.VOC gatherer 42 is adsorbent and absorption (that is, receive (adsorb) or absorb (absorb)) VOC from its process.Suitable VOC sampling thief 40 can be GORESorb (trade mark) pipe that wherein has a plurality of little adsorbent balls.
Can in detecting device 50, measure the gas variable of any appropriate, analyzer is generally used for monitoring hydrocarbon (especially methane) concentration, gas concentration lwevel, oxygen concentration, carbonomonoxide concentration and concentration of hydrogen sulfide.
IGM device 8 also comprises battery (electric battery) 72 and the combined type controller and the storer 70 that are used for the operation of control device 8, and the operation that makes device 8 is self contained, does not promptly rely on the data communication of external source or from the power of external source.Controller 70 comprises timer.
Gas outlet 74 is configured to pass the top 30 (atmosphere end of device) of leading to atmosphere and through-going device 8 from the boring end to outlet 76.For gas outlet 64 provide blow off valve 78 with control its whether with atmosphere.
Also shown water content detection device 80, it detects the existence or the vicinity of the aqueous water in equipment, and transfers signals to controller 70 based on such detection.Use conductivity sensor to confirm existing of aqueous water.
In addition, the level switch (not shown) can be connected to the bottom of IGM device, and in use is suspended in the following entering boring of bottom.As the pressure converter (wired pressure transducer) of distribution can be used.
Top 30 comprises that permission and remote equipment and unit activating carry out the connector 82 of data communication.In addition, pressure transducer can be connected to here, is used to monitor the water level of boring.
IGM device 8 is installed in the boring 2, wherein hole 2 be positioned at through cover 10 gas tight seal is provided the boring liner.
As time goes on, gas will be assembled in boring 2.The IGM device 8 particularly programming through controller 70 is configured to automatically and periodically detects self-drilling gaseous sample.Now the process that this test is adopted is carried out in description.
At first (step 100) carried out the test of pump.When first valve 38 cuts out, start the pump 48 and first pressure transducer 46 and in 10 seconds, must read 100bm, otherwise can produce failure warning, because pump 48 possibly break down through controller 70.
Secondly (step 102) carried out the test of filtrator.After first valve 38 was opened 4 seconds, first pressure transducer 46 read pressure reading BH.Then, the pump one section predetermined period of 48 operations and the first pressure transmission power sensor 46 read another pressure reading BHP.If BHP-BH>250mb then can produce failure warning through controller 70, because filtrator 44 possibly stop up.
Any failure warning is as appearing significantly from the part of device data downloaded.
Open first valve 38 and second valve 60 (step 104) and activate pump 48 (step 106), have the self-drilling up-to-date gaseous sample of coming to guarantee sensor so that gas is passed above-mentioned gas flow paths from the boring pumping.VOC detecting device 40 and VOC gatherer 42 are positioned at the front of filtrator 44, otherwise filtrator 44 will be removed VOC from gas flow.Can be through the collected VOC of VOC gatherer through removing the VOC gatherer and making VOC be eluted to instrument such as in the gas chromatograph and by quantitatively.The measurement (step 108) of VOC concentration is carried out through VOC detecting device 40.Remove moisture and particulate through filtrator 44.
Then, borehole gases is passed detecting device 50, analyzes (step 110) in detecting device 50 place's borehole gases through gas tester 57,54,56 and 58.
Simultaneous gas pressure measurement (step 112) carries out through first pressure transducer 38, and the atmospheric pressure force measurement of reference carries out through second pressure transducer 66.Record sensing time and pump operated time span (step 114).Rule of thumb measure or through calculating, can confirm that when pump 48 operations time per unit passes the gas volume of device 8.Therefore, can confirm how many gas volumes that in given arbitrarily test period, passes device is.This data storing is in controller/storer 70.Then, can obtain the measured value of VOC concentration divided by the gas volume that passes gatherer through the amount of the collected VOC of VOC gatherer.
Then, close first valve 38 and second valve 60 (step 116).Come self-drilling gas to circulate and turn back to boring through the boring end of device.
Through gas tester 52,54,56 and 58, carry out the measurement of gas variable.Can monitor any suitable variable, comprise in existence or shortage, gas concentration level, the gaseous tension of specific gas, the moisture content in the gas etc. one or more.Be stored in controller/storer 70 from the gas variable data measured.
Reset the timer in the controller 70, make and to carry out periodic measurement subsequently.
The data that are stored in controller/storer 70 can be downloaded from hardwired connects via connector 82 or through wireless transmission.This connection also can be used for programmable controller 70, to come operating means 8 according to required.For example, the frequency of variable such as sampling can be set also, no matter sample regular or irregular, whether should regularly be disposed to atmosphere or the like.
Is the basis with above-mentioned, if water content detection device 80 detects the existence of moisture in device, then the detection of moisture signal is sent to and can takes appropriate steps in the controller 70 of (such as stopping device 8, transmit caution signal, light emergency warning lamp or the like).But this protective device 8 is without prejudice and avoids reading the reading of pollution.
Because gas is assembled a period of time in boring, therefore making boring and atmosphere is favourable with the pressure that reduces the there, but also through allowing boring and atmospheric equilibrium to offer an opportunity for restarting sampling operation effectively.Therefore, the reconfigurable mutation analysis that is used for the baseline of monitoring arbitrarily and can carries out the gas variable of a period of time.Installing 8 configurable one-tenth periodically or according to instruction ventilates to atmosphere boring.
Therefore, portable self contained IGM device is provided, it can be deployed in the boring to read the periodic data reading of the gas variable in the boring expediently.
Particularly, of the present inventionly preferred embodiment make it possible to monitor VOC.VOC detecting device and VOC controller make that with the combination of confirming of the gas volume that passes device calculating can be realizing of how changing through absolute concentration and the absolute concentration of the specific VOC in the boring together in a period of time.Through the result of time mark, the variation of VOC in a period of time can be monitored, for example make can with other time-the variable phenomenon compares such as atmospheric pressure or weather conditions.
With notice guide into submit to or submit to this instructions that is relevant to the application prior to this instructions and be open all publications and file with this instructions for public's inspection, and the content of all these publications and file mode is by reference incorporated this paper into.
The institute of disclosed all characteristics and/or disclosed so any method or process can merge with combination arbitrarily in steps in this instructions (comprising any additional claim, summary and accompanying drawing), except the combination that wherein at least some such characteristics and/or step are repelled each other.
Only if explanation is arranged clearly in addition, otherwise disclosed each characteristic can be reached selectional feature replacement identical, that equate or similarly purpose in this instructions (comprising any additional claim, summary and accompanying drawing).Therefore, only if explanation is arranged clearly in addition, otherwise disclosed each characteristic is an instance of general a series of equivalent characteristics or similar characteristics.
The invention is not restricted to the details of the embodiment of preceding text.The present invention extends to any novel characteristics in the disclosed characteristic or novel arbitrarily combination in this instructions (comprising any additional claim, summary and accompanying drawing), or extends to method or the process or the novel arbitrarily combination of any novelty of disclosed so any method or process.

Claims (23)

1. an in-borehole gas monitor (IGM) installs, and it comprises VOC concentration analysis device and VOC gatherer.
2. in-borehole gas monitor as claimed in claim 1 (IGM) device, wherein said VOC concentration analysis device is configured to provide the unspecific real-time concentration of VOC.
3. like claim 1 or the described in-borehole gas monitor of claim 2 (IGM) device, wherein said VOC concentration analysis device comprises photoionization detector.
4. like each described in-borehole gas monitor (IGM) device in the above-mentioned claim, wherein said VOC gatherer is configured to provide specific concentration by volume.
5. like each described in-borehole gas monitor (IGM) device in the above-mentioned claim, wherein said VOC gatherer comprises sorbent material.
6. like each described in-borehole gas monitor (IGM) device in the above-mentioned claim, wherein said device also comprises the pressure transducer that is configured to measure atmospheric pressure.
7. like each described in-borehole gas monitor (IGM) device in the above-mentioned claim, wherein said device also comprises timer.
8. like each described in-borehole gas monitor (IGM) device in the above-mentioned claim; Wherein said device comprises and being used on downstream direction the pump of gas pump through said VOC concentration analysis device and said VOC gatherer; And said device is configured; Said thus VOC concentration analysis device continues one section pump cycles with the borehole gases pumping through said VOC concentration analysis device and said VOC gatherer through said pump, and the VOC concentration under confirming at the fixed time.
9. in-borehole gas monitor as claimed in claim 8 (IGM) device, wherein said device is configured, and said thus pump cycles, Measuring Time and the atmospheric pressure under said Measuring Time are by record.
10. install like the described in-borehole gas monitor of claim 1-7 (IGM); Wherein said device comprises pump and filtrator; Said pump is used on downstream direction gas pump said VOC concentration analysis device of process and said VOC gatherer; Said filtrator is used for removing any particulate or moisture from the gas access, and wherein said VOC concentration analysis device and said VOC gatherer are positioned at the upper reaches of said filtrator.
11. install like the described in-borehole gas monitor of claim 1-7 (IGM); Wherein said device comprises and being used on downstream direction the pump of gas pump through said VOC concentration analysis device and said VOC gatherer; And have the gas flow paths of first valve at the upper reaches that comprise gas access, pressure transducer and be positioned at said pump, wherein said device is configured, thus when said first valve cuts out; The said pump one section predetermined period that is activated; And if in said predetermined period, the predetermined pressure that is measured by said pressure transducer is not exceeded, and then generates the failure of pump signal.
12. in-borehole gas monitor as claimed in claim 11 (IGM) device, wherein said predetermined period is between 8 seconds and 12 seconds, and said predetermined pressure is 100mb.
13. install like the described in-borehole gas monitor of claim 1-7 (IGM); Wherein said device comprises and being used on downstream direction the pump of gas pump through said VOC concentration analysis device and said VOC gatherer; And have the gas flow paths of first valve at the upper reaches that comprise gas access, pressure transducer, filtrator and be positioned at said pump, wherein said device is configured, thus when said first valve is opened; First pressure sensor readings is obtained; The said pump one section predetermined period that is activated, after said pump was activated one section predetermined period, second pressure sensor readings was obtained; And if the difference amount between said first pressure sensor readings and said second pressure sensor readings then generates the filtrator fault-signal greater than predetermined value.
14. in-borehole gas monitor as claimed in claim 13 (IGM) device, wherein said predetermined period is between 2 seconds and 6 seconds.
15. like claim 13 or the described in-borehole gas monitor of claim 14 (IGM) device, wherein said predetermined value is 250mb.
16. like the described in-borehole gas monitor of claim 8-15 (IGM) device, wherein sensing time and said pump operated time span are by record.
17. like the described in-borehole gas monitor of claim 11-15 (IGM) device, wherein said device comprises gas vent and second valve that is positioned at the downstream of said first valve.
18. as each described in-borehole gas monitor (IGM) device in the above-mentioned claim; Wherein said device is configured to have boring side and atmospheric side, wherein has said boring side of leading to said equipment and the gas vent that leads to the said atmospheric side of said equipment.
19. as each described in-borehole gas monitor (IGM) installs in the above-mentioned claim, wherein said VOC concentration analysis device and said VOC gatherer are connected with gas tester in gas flow paths.
20. in-borehole gas monitor as claimed in claim 19 (IGM) device, wherein said gas tester is analyzed one or more in hydrocarbon, carbon dioxide, oxygen and the sulfuretted hydrogen.
21. the method for operating of an in-borehole gas monitor apparatus, this method comprise the use according to each described in-borehole gas monitor apparatus among the claim 1-20.
22. the method for operating of in-borehole gas monitor apparatus as claimed in claim 21 is wherein quantitative through the VOC quilt that said VOC gatherer is collected.
23. method of operating like claim 21 or the described in-borehole gas monitor apparatus of claim 22; Wherein said device comprises the pump that is used for gas is crossed from the bore hole pump warp let-off said VOC gatherer and said VOC analyzer; Wherein sensing time and said pump operated time span are write down to confirm to pass the gas volume of said device, and this volume makes it possible to confirm VOC concentration.
CN2010800482771A 2009-09-01 2010-08-03 In-borehole gas monitor apparatus and method comprising a VOC concentration analyser and a VOC collector Pending CN102597766A (en)

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GB0915150.7 2009-09-01
GBGB0915150.7A GB0915150D0 (en) 2009-09-01 2009-09-01 In-borehole gas monitor apparatus and method
PCT/GB2010/051282 WO2011027137A1 (en) 2009-09-01 2010-08-03 In-borehole gas monitor apparatus and method comprising a voc concentration analyser and a voc collector

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US (1) US20130036811A1 (en)
EP (1) EP2473843A1 (en)
JP (1) JP2013504035A (en)
CN (1) CN102597766A (en)
AU (1) AU2010290994A1 (en)
BR (1) BR112012004245A2 (en)
CA (1) CA2772744A1 (en)
GB (1) GB0915150D0 (en)
IN (1) IN2012DN02476A (en)
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