CN102575417B - Water-soluble adhesive compound coating for water-soluble interlining materials - Google Patents

Water-soluble adhesive compound coating for water-soluble interlining materials Download PDF

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Publication number
CN102575417B
CN102575417B CN201080043390.0A CN201080043390A CN102575417B CN 102575417 B CN102575417 B CN 102575417B CN 201080043390 A CN201080043390 A CN 201080043390A CN 102575417 B CN102575417 B CN 102575417B
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CN
China
Prior art keywords
water
adhesive
soluble
carrier material
liner
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201080043390.0A
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Chinese (zh)
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CN102575417A (en
Inventor
P·格雷内乌斯
H·库恩雷恩
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Freudenberg SAS
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Freudenberg SAS
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Publication of CN102575417A publication Critical patent/CN102575417A/en
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Publication of CN102575417B publication Critical patent/CN102575417B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00Producing multi-layer textile fabrics
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4266Natural fibres not provided for in group D04H1/425
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282Addition polymers
    • D04H1/4309Polyvinyl alcohol
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • DTEXTILES; PAPER
    • D05SEWING; EMBROIDERING; TUFTING
    • D05CEMBROIDERING; TUFTING
    • D05C17/00Embroidered or tufted products; Base fabrics specially adapted for embroidered work; Inserts for producing surface irregularities in embroidered products
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00Producing multi-layer textile fabrics
    • D06M17/04Producing multi-layer textile fabrics by applying synthetic resins as adhesives
    • D06M17/06Polymers of vinyl compounds

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Details Of Garments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Manufacturing Of Multi-Layer Textile Fabrics (AREA)
  • Automatic Embroidering For Embroidered Or Tufted Products (AREA)
  • Laminated Bodies (AREA)

Abstract

In order to achieve the aim of designing and further developing the adhesive compounds known from the prior art such that they can easily be used for water-soluble interlinings, in particular for non-woven fabrics, an interlining for use as a fixing interlining for embroidery, consisting of a textile carrier material coated with an adhesive compound, the adhesive compound containing a water-soluble, thermoplastic polymer, is characterised in that the adhesive compound is designed as an aqueous polymer dispersion and/or as a polymer solution.

Description

For the water-soluble adhesive coating of water-soluble inner lining material
Technical field
The present invention relates to a kind of liner being used as embroidery secure liner, it is made up of the fabric carrier material applied with adhesive, and wherein said adhesive has water-soluble, thermoplastic polymer.
Prior art
Mention that for introductory song the water-soluble adhesive of the water-soluble embroidery secure liner of type is known by DE 100 32 769 A1 already.In addition, fixable water-soluble adhesive is known, its at inner lining material particularly on nonwoven fabric, temporary fixed for tissue layer.
Herein before treatment or during process, inner lining material or nonwoven fabric and be laminated together in bonder as the tissue layer that skin-material designs.Then, reinforcing and unguyed part are bonded together, sew up also shaping by sizing flatiron when needed.
After washing process subsequently, described adhesive is washed off.The layer be bonded together thus unclamps again, and clothing is therefore and more pliable and tough and soft.
Same various shrinkage material also can be bonded together like this, makes not occur that bubble is formed after nursing process.
Be applied on water miscible nonwoven fabric (Vliesstoff) by the direct spray silk of the scatter coated of water-soluble hot melt bonded nonwoven, heat seeling coating, gummed (Auflaminieren) or melt spraying non-woven fabrics by the known adhesive of DE 100 32 769 A1.
By DE 100 32 769 A1 known with (being total to) polyamide, the polymer for adhesive based on polyvinyl alcohol and/or (being total to) polyester is not printed on water miscible nonwoven fabric by rotary screen-printing method with the form of water-borne dispersions, because the water in adhesive causes the pointwise of soluble non-woven fabrics to be dissolved.
Soluble non-woven fabrics dissolve or printing position cause with adhesive coating nonwoven fabric unsightly, irregular surface.
This out-of-flatness is passed to by the fixing tissue layer of described liner.Mentioned surface irregularity causes adverse effect on the visual appearance of finished product.
The position of dissolving in nonwoven fabric or hole are unacceptable, and eliminate the purposes of material for clothing or embroidery.
Invention describes
Therefore the object of the invention is to, so design and improving by the known adhesive of prior art, make it can without difficulty for water miscible liner, especially for nonwoven fabric.
The present invention solves above-mentioned object by the feature of claim 1.
Thus, the feature of the liner mentioned by introductory song is, described adhesive is configured to the polymeric dispersions of water-based and/or is configured to polymer solution.
Find surprisingly, aqueous polymer dispersions concentrated enough to heavens and/or polymer solution can be printed on carrier material soluble in water, particularly nonwoven fabric, and without above-mentioned adverse effect.Have realized that the system of water-based can be printed on the nonwoven fabric of cold-water-soluble according to the present invention.Herein, " cold water " is interpreted as that temperature is the highest 40 DEG C.
Therefore, achieve introductory song and mention object.
The template specification of CP5-CP250 can be used when printing.
Described adhesive can have the solids content more than 50%.The swelling of cold-water-soluble carrier material is avoided by this concentration or higher concentration.
Described adhesive can have the vinyl pyrrolidone of vinyl pyrrolidone or modification.Prove that particularly vinyl pyrrolidone and copolymer are suitable for preparing polymeric dispersions and/or the polymer solution of water-based.Vinyl pyrrolidone is soluble in cold water, but very hygroscopic and becoming sticky along with the increase of air humidity.The vinyl pyrrolidone with polyvinyl acetate part is at room temperature weak than the hygroscopicity of unmodified vinyl pyrrolidone.Therefore, the liner through coating can not bond in a rolled-up condition.
Described adhesive can have polyalcohol or polyglycols.Can be changed by interpolation polyalcohol and/or polyglycols, particularly reduce the melting range of polymer (particularly vinyl pyrrolidone), or the melt flows of telomerized polymer be to adapt to the purposes in various situation.Described water-soluble adhesive is by polyglycols plasticising.Preferred polyethylene glycol (PEG) uses as plasticizer.
Particularly preferably working concentration is the PEG 400 of 0-20%, and particularly preferably concentration is 2-10%.
In addition, described adhesive can be mixed with the printing auxiliary agent of 0-10 % by weight as dispersant or thickener.
Described fabric carrier material can be water miscible.Therefore described carrier material can dissolve.
Described fabric carrier material can be made up of polyvinyl alcohol.The polyvinyl alcohol of described carrier material can carry out modification by the ethoxylation of polymer or by the saponification that saponification degree is greater than 95%.Polyvinyl alcohol through modification is soluble in cold water, and namely temperature is the water of 10 to 40 DEG C.Particularly described fabric carrier material can be configured to nonwoven fabric.Described nonwoven fabric can have 20 to 120g/m 2weight per unit area.
Not only described fabric carrier material but also described adhesive are water-soluble when the temperature of 10 to 40 DEG C.
The object that introductory song is mentioned also is realized by the adhesive for coated fabric carrier material.
Mentioned adhesive is also applicable to the printing of non aqueous carrier material.Non-water-soluble fabric carrier material also can be coated with the coating that can well fix be made up of mentioned adhesive, and this adhesive can be washed off after treatment easily.In this context, the solids content of described adhesive can lower than 50%.
Liner described herein is fixable, that is to say, it can engage without difficulty with the textile surface element of any kind in thermal process process.Described thermal process process, namely fixing or laminated, carry out at the temperature of 80 to 140 DEG C.
Adhesive described herein preferably can be used for liner nonwoven fabric, especially for water miscible liner and/or embroidery nonwoven fabric.
Method for the preparation of the liner of kind as described herein can comprise the following steps: provide fabric carrier material and with the adhesive coated fabric carrier material with aqueous polymer dispersions and/or polymer solution.Thus, first liner can be produced as intermediate products, and it is use polymeric dispersions and/or polymer solution coating.Then this intermediate products lose the water of aqueous polymer dispersions and/or polymer solution and become finished product, namely required here liner.
There is now various possibility, instruction of the present invention to be implemented in an advantageous manner and perfect further.For this reason, on the one hand with reference to following claim, on the other hand with reference to the explanation of following preferred embodiment.
Be associated with the explanation of preferred embodiment, also explain the perfect further of generally preferred embodiment and instruction.
Working of an invention
The change of fusion temperature scope and melt flows is shown in following table 1.
Table 1
Preferably use the mixture of Luvitec VA 64 and 0-20% PEG 400, particularly preferably 3-15% PEG 400.Other PEG can use equally.
Embodiment
Embodiment 1
Be 80g/m by weight per unit area 2the spunlace non-woven cloth adhesive printing be made up of the aqueous polymer dispersions of solids content 45% of making of 100% cotton.
Described polymeric dispersions is by 400g/l Luvitec VA 64,40g/l PEG400 with by dispersant, and the mixture of the 5g/l of thickener and paste glidant composition (Pastenlaufhilfsmitteln) is formed.
Described printing is undertaken by rotary screen-printing technology.Use the printing stencil CP 110 being equivalent to the open area of 20%, coating 25g/m 2adhesive coating.Described drying is carried out at 145 DEG C.
Embodiment 2
Weight per unit area that use heat bonding as the carrier material for secure liner of embroidering, that prepared by polyvinyl alcohol (PVAL) artificial fibre of cold-water-soluble is about 40g/m 2nonwoven fabric.
Described vinal-artificial fibre is prepared with gel spinning and is had the intensity of 4g/den (denier).This nonwoven fabric uses adhesive (i.e. dispersion or the solution) printing of solids content 60%.
Described adhesive is made up of 600g/l Luvitec VA 64,45g/l PEG 400 and the mixture of 5g/l that is made up of dispersant, thickener and paste glidant.
Described printing is undertaken by rotary screen-printing technology.Use the printing stencil CP 52 being equivalent to the open area of 15%, coating 15g/m 2adhesive coating.Described drying is carried out at 145 DEG C.
Difficulty is had no surprisingly with mentioned adhesive printing.The bonding of layer is not observed after drying yet.
List in following table 2, the adhesion value obtained when the liner of kind described herein engages with shirting poplin test material.
Table 2
(mod.) PA (polyamide) of modification mentioned in table 2 corresponds to the polyamide according to the embodiment 1 of DE100 32 769 A1.VA represents vinylacetate, and wherein said product uses Luvitec VA 64.PEG represents polyethylene glycol.
Advantage:
When sintering cold-water-soluble with copolyesters ( 699 types) based on polymer powder time, higher than the sintering conditions of 150 DEG C be carrier material start shrink boundary.Huge amplitude loss is there is when firing (Ansintern).
This is no longer insoluble with mixture according to the present invention and method described herein.Be easy to realize lower than the baking temperatures of 150 DEG C.Firing of the point printed is very good.
The spun-bonded non-woven fabrics (Spinnvliesstoff) formed with water-soluble polymer separately spray spins, and then by complicated approach laminated to itself and soluble non-woven fabrics, greatly simplifies by method described herein.
The polymeric blends of mentioned kind also can fuse together.In this case, there is browning look.This polymeric blends can be coated with using hot-melt object or under grinding state as powder point.This extra process makes method more expensive, and wherein said variable color is undesirable additional attribute.
Method described herein is easy to realize, because described component can be stirred in together.Micro-albescent dispersion or limpid solution is produced after deaeration.Viscosity needed for the mixture that can regulate for printing with the 1-3% thickener be made up of the cellulose of modification.Other printing auxiliary agents can also be mixed on a small quantity according to different demands.
In order to can good print in the carrier material of cold-water-soluble, printable adhesive should have the solids content more than 50%.Solids content more than 75% provides the mixture of high viscosity, and it can only be used for printing in relative difficulty ground.On non aqueous carrier material, also can print the mixture had compared with low solid content.
About other favourable embodiments and the improvement further of instruction according to the present invention, on the one hand with reference to the main part of description, on the other hand with reference to the claim of adding.
Finally ben, before selected embodiment be only used as according to instruction of the present invention discussion, but be not limited to these embodiments.

Claims (7)

1. one kind is used as the liner of embroidery secure liner, it is made up of the fabric carrier material applied with adhesive, wherein said adhesive has water-soluble, thermoplastic polymer, it is characterized in that, described adhesive is configured to aqueous polymer dispersions and/or is configured to polymer solution, not only described fabric carrier material but also described adhesive are water miscible the temperature of 10 to 40 DEG C, described adhesive has the solids content more than 50%, with described adhesive, there is vinyl pyrrolidone, described vinyl pyrrolidone is the vinyl pyrrolidone with polyvinyl acetate part.
2. liner according to claim 1, is characterized in that, described adhesive has polyalcohol or polyglycols.
3. according to the liner of claim 1 or 2, it is characterized in that, described fabric carrier material from polyethylene alcohol is made.
4. according to the liner of claim 1 or 2, it is characterized in that, described fabric carrier material structure is the nonwoven fabric of cold-water-soluble.
5. liner according to claim 3, is characterized in that, described fabric carrier material structure is the nonwoven fabric of cold-water-soluble.
6. for the adhesive of coated fabric carrier material, described fabric carrier material is used for the liner according to one of the claims, this adhesive comprises aqueous polymer dispersions and/or polymer solution, and described aqueous polymer dispersions and/or polymer solution have the solids content more than 50%.
7., for the preparation of the method for the liner according to one of claim 1 to 5, comprise the steps: to provide fabric carrier material and with the adhesive coated fabric carrier material with aqueous polymer dispersions and/or polymer solution.
CN201080043390.0A 2009-10-16 2010-10-12 Water-soluble adhesive compound coating for water-soluble interlining materials Expired - Fee Related CN102575417B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102009049802.8 2009-10-16
DE102009049802A DE102009049802A1 (en) 2009-10-16 2009-10-16 Water-soluble adhesive coating for water-soluble interlinings
PCT/EP2010/006206 WO2011045017A2 (en) 2009-10-16 2010-10-12 Water-soluble adhesive compound coating for water-soluble interlining materials

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CN102575417A CN102575417A (en) 2012-07-11
CN102575417B true CN102575417B (en) 2015-04-08

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CN201080043390.0A Expired - Fee Related CN102575417B (en) 2009-10-16 2010-10-12 Water-soluble adhesive compound coating for water-soluble interlining materials

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EP (1) EP2488691A2 (en)
JP (1) JP5625204B2 (en)
KR (1) KR101482948B1 (en)
CN (1) CN102575417B (en)
AR (1) AR078642A1 (en)
BR (1) BR112012008738A2 (en)
DE (1) DE102009049802A1 (en)
TW (1) TWI424110B (en)
WO (1) WO2011045017A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010046386A1 (en) * 2010-09-24 2012-03-29 Carl Freudenberg Kg Thermally fixable interlining material and use
CN104074000B (en) * 2014-06-27 2017-01-11 昆山胜昱无纺布有限公司 Water-soluble fabric assembly line
CN104073999B (en) * 2014-06-27 2016-04-06 昆山胜昱无纺布有限公司 The composite of water-soluble fabric and water-soluble fabric streamline
CN104088102A (en) * 2014-07-02 2014-10-08 苏州市叶绣工艺厂 Embroidery cloth suitable for public
US20230002966A1 (en) * 2021-06-30 2023-01-05 CreateMe Technologies LLC Stabilizer coating for machine embroidering

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3961125A (en) * 1972-12-18 1976-06-01 Kurashiki Boseki Kabushiki Kaisha Temporary interlining coated with foamed adhesive
US4570311A (en) * 1981-12-07 1986-02-18 Firma Carl Freudenberg Method for manufacturing water soluble fabric for chemical laces
GB2188566A (en) * 1986-04-02 1987-10-07 Clark & Sons Ltd William Interlining materials

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JPS60162850A (en) * 1984-01-30 1985-08-24 金井 宏之 Water-soluble fiber sheet
JPH03146759A (en) * 1989-10-30 1991-06-21 Reiko Co Ltd Steric embroidery product and steric embroidering
JP3128326B2 (en) * 1992-05-11 2001-01-29 株式会社クラレ Water-soluble sheet and method for producing the same
WO1997002376A1 (en) * 1995-06-30 1997-01-23 Kimberly-Clark Worldwide, Inc. Water-dispersible fibrous nonwoven coform composites
ATE282733T1 (en) * 1999-08-26 2004-12-15 Siber Hegner & Co Ltd METHOD FOR PRODUCING A BACKING METHOD FOR SUBSEQUENT EMBROIDERY
DE10032769C2 (en) * 2000-07-05 2003-12-04 Freudenberg Carl Kg Water soluble embroidery fixer and process for making it
US6443081B1 (en) * 2000-10-13 2002-09-03 Laura J. Quint Applique art kit assembly and method of creating an applique art object
DE10344573A1 (en) * 2002-10-01 2004-04-15 Textilforschungsinstitut Thüringen-Vogtland e.V. Embroidery process carried out on large industrial machines is for embroidering elastic textiles or non-textiles and requires no major adaptation of machinery
JPWO2006129744A1 (en) * 2005-06-03 2009-01-08 株式会社クラレ Masking fabric used for post-transfer dyeing of embroidery parts

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3961125A (en) * 1972-12-18 1976-06-01 Kurashiki Boseki Kabushiki Kaisha Temporary interlining coated with foamed adhesive
US4570311A (en) * 1981-12-07 1986-02-18 Firma Carl Freudenberg Method for manufacturing water soluble fabric for chemical laces
GB2188566A (en) * 1986-04-02 1987-10-07 Clark & Sons Ltd William Interlining materials

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Publication number Publication date
WO2011045017A2 (en) 2011-04-21
TWI424110B (en) 2014-01-21
CN102575417A (en) 2012-07-11
EP2488691A2 (en) 2012-08-22
JP2013507538A (en) 2013-03-04
KR20120089724A (en) 2012-08-13
DE102009049802A1 (en) 2011-04-21
AR078642A1 (en) 2011-11-23
BR112012008738A2 (en) 2016-05-10
TW201120276A (en) 2011-06-16
WO2011045017A3 (en) 2011-07-14
KR101482948B1 (en) 2015-01-15
JP5625204B2 (en) 2014-11-19

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