CN102560194A - Non-lead metal material and application of non-lead metal material to cord type initiating explosive devices - Google Patents

Non-lead metal material and application of non-lead metal material to cord type initiating explosive devices Download PDF

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Publication number
CN102560194A
CN102560194A CN2012100644283A CN201210064428A CN102560194A CN 102560194 A CN102560194 A CN 102560194A CN 2012100644283 A CN2012100644283 A CN 2012100644283A CN 201210064428 A CN201210064428 A CN 201210064428A CN 102560194 A CN102560194 A CN 102560194A
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CN
China
Prior art keywords
metal material
lead metal
lead
cord
tin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012100644283A
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Chinese (zh)
Inventor
黄寅生
李锦涛
刘建彬
苏辉
王文涛
黄娜
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Nanjing University of Science and Technology
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Nanjing University of Science and Technology
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Publication date
Application filed by Nanjing University of Science and Technology filed Critical Nanjing University of Science and Technology
Priority to CN2012100644283A priority Critical patent/CN102560194A/en
Publication of CN102560194A publication Critical patent/CN102560194A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a metal material, in particular to a non-lead metal material for cord type initiating explosive devices. The non-lead metal material is alloy in which tin is used as a main component and comprises the following components in percentage by weight: 80 to 100 percent of tin and 0 to 20 percent of copper or antimony. Due to the application of tin alloy to the cord type initiating explosive devices, compared with the conventional cord type initiating explosive devices, the non-lead metal material has the advantages that: (1) lead pollution is avoided, and the development direction of environment friendliness is met; (2) the conventional process for manufacturing the cord type initiating explosive devices is not needed to be changed in the application process; and (3) the manufactured metal delay cord has excellent combustion performance, and the manufactured detonating cord has stable explosive performance.

Description

A kind of non-lead metal material and the application in explosive fuze cord thereof
Technical field
The present invention relates to the application of a kind of metallic substance in explosive fuze cord, the application of particularly a kind of non-lead metal material in explosive fuze cord belongs to the explosive fuze cord field.
Background technology
The metal explosive fuze cord mainly comprises extension rope, primacord fuse and safety fuse.The metal explosive fuze cord passes fire, propagation of explosion is stable, and reliable, because of tight-closed, environmental resistance is good, and particularly humidity resistance is good.Because plumbous is functional, handling ease is cheap.Therefore, at present most enterprise and research unit except adopting the argent at metal explosive fuze cord in the space flight, all adopt with the lead metal material as housing, and relevant production technique is comparative maturity.Yet there is serious Lead contamination in lead in production and use, and particularly lead forms a large amount of lead steam and lead dust after the blast of detonator and explosive, is absorbed by the body to form chronic poisoning, and this does not meet the developing direction of current environmental protection.In addition, be the metal explosive fuze cord of main body with lead, in some use occasion, because plumbous intensity is relatively poor, easy quilt is broken, and causes afunction; Moreover, because plumbous fusing point is lower, in some cases,, cause burning medicament end face to separate owing to the thawing of lead is expanded, make combustion reactions appearance interruption, this high section delay electric detonator often occur miss-firing and obtain checking in China.So studying non-plumbous explosive fuze cord is very urgently to reach the technical issues that need to address.People such as Huang Yinsheng had once studied the aluminum hull primacord fuse, found that its performance is better than plumbous shell, also can be used in the microsecond arming delay device; People such as Ma Honghao have studied a kind of unleaded detonator system, have substituted traditional lead extension body with aluminium extension body, but need to increase production process.
Summary of the invention
The objective of the invention is to exist to metal explosive fuze cord in the prior art problem of serious Lead contamination, a kind of non-lead metal material of suitable drawing explosive fuze cord is provided, this material is main body with tin, adds the tin alloy that other an amount of metals are formed.The metal extension rope and the stable performance of metal primacord fuse that utilize tin alloy to make, no Lead contamination, and making processes need not to change existing manufacturing technique.
A kind of non-lead metal material that is used for explosive fuze cord is the alloy of main body with tin, and its composition is: tin content is 80%-100%, and copper or antimony content are 0%-20%.
The preparation of metal explosive fuze cord: utilize tin alloy to make the tin alloy pipe earlier; In the tin alloy pipe, pack into explosive or pyrotechnics composition; Through drawing process repeatedly, process metal explosive fuze cord with 1mm-10mm external diameter, cutting is used to transmit detonation and flame as required again.
The present invention compared with prior art has following advantage:
(1) no Lead contamination meets the developing direction of environmental protection;
(2) in application process, need not to change existing explosive fuze cord ME;
(3) the metal extension rope combustionproperty that makes is good, and the primacord fuse blast performance is stable.
Embodiment
Metal proportioning by technical scheme is processed base material, processes metal tube then, and the various firer's medicaments of packing into utilize existing technology to carry out drawing, make the metal explosive fuze cord.
Instance one: tin content 100%, process external diameter 18mm, internal diameter 16mm metal tube, the tungsten of packing into are the extension rope that delay powder is drawn into the 4mm external diameter, on average fire fast 1.67mm/s, relative error 2%.
Instance two: tin content 95%, copper content 5% is processed external diameter 18mm, and internal diameter 16mm metal tube, the tungsten of packing into are the extension rope that delay powder is drawn into the 4mm external diameter, on average fire fast 1.75mm/s, relative error 1%.
Instance three: tin content 90%, copper content 10% is processed external diameter 18mm, and internal diameter 16mm metal tube, the tungsten of packing into are that delay powder is drawn into 4mm external diameter extension rope, on average fire fast 1.92mm/s, relative error 1.1%.
Instance four: tin content 80%, antimony content 20% is processed external diameter 18mm, and internal diameter 16mm metal tube, the tungsten of packing into are the extension rope that delay powder is drawn into the 4mm external diameter, on average fire fast 1.98mm/s, relative error 1.8%.
Instance five: tin content 95%, copper content 5% is processed external diameter 18mm, internal diameter 16mm metal tube, the paraffin desensitized hexogen of packing into is drawn into external diameter 3mm primacord fuse, explosion velocity 6700m/s, explosion velocity is stable.
Instance six: tin content 90%, antimony content 10% is processed external diameter 18mm, internal diameter 16mm metal tube, the paraffin desensitized hexogen of packing into is drawn into external diameter 2mm primacord fuse, explosion velocity 6500m/s, explosion velocity is stable.

Claims (2)

1. a non-lead metal material is characterized in that described non-lead metal material is a tin alloy, and wherein, tin content is 80%-100%, and copper or antimony content are 0%-20%.
2. the application of a non-lead metal material in explosive fuze cord; It is characterized in that utilizing the described non-lead metal material prepn explosive fuze cord of claim 1; Its concrete technology may further comprise the steps: make the tin alloy pipe earlier with tin alloy, in the tin alloy pipe, pack into explosive or pyrotechnics composition are through drawing process repeatedly; Process the metal explosive fuze cord with 1mm-10mm external diameter, cutting is used to transmit detonation and flame as required again.
CN2012100644283A 2012-03-13 2012-03-13 Non-lead metal material and application of non-lead metal material to cord type initiating explosive devices Pending CN102560194A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012100644283A CN102560194A (en) 2012-03-13 2012-03-13 Non-lead metal material and application of non-lead metal material to cord type initiating explosive devices

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012100644283A CN102560194A (en) 2012-03-13 2012-03-13 Non-lead metal material and application of non-lead metal material to cord type initiating explosive devices

Publications (1)

Publication Number Publication Date
CN102560194A true CN102560194A (en) 2012-07-11

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104045496A (en) * 2014-07-03 2014-09-17 广东明华机械有限公司 Tungsten-based delay powder for detonator and use of tungsten-based delay powder

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995035477A1 (en) * 1994-06-20 1995-12-28 The Ensign-Bickford Company Tin and tin alloy liners and sheaths for explosive, deflagrating and pyrotechnic products
US5827995A (en) * 1994-06-20 1998-10-27 The Ensign-Bickford Company Reactive products having tin and tin alloy liners and sheaths
WO2003091184A2 (en) * 2002-04-23 2003-11-06 Universal Propulsion Company, Inc. Tin alloy sheathed explosive device
CN1482266A (en) * 2003-07-02 2004-03-17 中国科学院金属研究所 Industrial pure tin with resistance to liquid surface oxidizing and application
CN1681618A (en) * 2002-09-18 2005-10-12 国际商业机器公司 Solder hierarchy for lead free solder joint
CN1883832A (en) * 2005-06-23 2006-12-27 中国科学技术大学 Primacord rolling method and primacord rolling machine
CN101556130A (en) * 2009-05-14 2009-10-14 中国科学技术大学 Method for producing detonating fuse or detonator delay line with small diameter and low charge linear density

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995035477A1 (en) * 1994-06-20 1995-12-28 The Ensign-Bickford Company Tin and tin alloy liners and sheaths for explosive, deflagrating and pyrotechnic products
US5827995A (en) * 1994-06-20 1998-10-27 The Ensign-Bickford Company Reactive products having tin and tin alloy liners and sheaths
WO2003091184A2 (en) * 2002-04-23 2003-11-06 Universal Propulsion Company, Inc. Tin alloy sheathed explosive device
CN1681618A (en) * 2002-09-18 2005-10-12 国际商业机器公司 Solder hierarchy for lead free solder joint
CN1482266A (en) * 2003-07-02 2004-03-17 中国科学院金属研究所 Industrial pure tin with resistance to liquid surface oxidizing and application
CN1883832A (en) * 2005-06-23 2006-12-27 中国科学技术大学 Primacord rolling method and primacord rolling machine
CN101556130A (en) * 2009-05-14 2009-10-14 中国科学技术大学 Method for producing detonating fuse or detonator delay line with small diameter and low charge linear density

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104045496A (en) * 2014-07-03 2014-09-17 广东明华机械有限公司 Tungsten-based delay powder for detonator and use of tungsten-based delay powder

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Application publication date: 20120711