CN102543972A - Solar battery module - Google Patents

Solar battery module Download PDF

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Publication number
CN102543972A
CN102543972A CN2011104012606A CN201110401260A CN102543972A CN 102543972 A CN102543972 A CN 102543972A CN 2011104012606 A CN2011104012606 A CN 2011104012606A CN 201110401260 A CN201110401260 A CN 201110401260A CN 102543972 A CN102543972 A CN 102543972A
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CN
China
Prior art keywords
solar energy
solar
solar module
monocell
module according
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Pending
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CN2011104012606A
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Chinese (zh)
Inventor
朴薰
朴宰莹
朴柱玉
尹汉镐
李恩暻
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Corning Precision Materials Co Ltd
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Samsung Corning Precision Materials Co Ltd
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Publication of CN102543972A publication Critical patent/CN102543972A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20Light-sensitive devices
    • H01G9/2068Panels or arrays of photoelectrochemical cells, e.g. photovoltaic modules based on photoelectrochemical cells
    • H01G9/2072Panels or arrays of photoelectrochemical cells, e.g. photovoltaic modules based on photoelectrochemical cells comprising two or more photoelectrodes sensible to different parts of the solar spectrum, e.g. tandem cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/043Mechanically stacked PV cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/05Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
    • H01L31/0504Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module
    • H01L31/0508Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module the interconnection means having a particular shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/0001Technical content checked by a classifier
    • H01L2924/0002Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/542Dye sensitized solar cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Sustainable Development (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical & Material Sciences (AREA)
  • Photovoltaic Devices (AREA)
  • Hybrid Cells (AREA)

Abstract

The present invention relates to a film type solar battery module, and particularly to a solar battery module which maximizes electricity productivity through accommodating a plurality of solar cells that are successively laminated. For this purpose, the solar battery module comprises a plurality of transparent solar cells; a cathode connector which is electrically connected with the cathodes of the solar cells; and an anode connector which is electrically connected with the anodes of the solar cells.

Description

Solar module
Technical field
The present invention relates to solar module, relate in particular to through taking in a plurality of solar energy monocells of lamination successively, thereby make the maximized solar module of electrical production rate.
Background technology
Recently, the research and development that development potentiality caused by solar cell are increasing rapidly.
Especially for the extensive commercialization of solar cell, very active about the research of the high efficiency of element and cheapization.
Thereby commercial high efficiency is as improving a kind of method that battery performance reduces the generating unit price, relatively is fit to crystal silicon solar batteries and uses CIGS (CIGS, CuIn xGa (1-x)Se 2) wait the solar cell of compound semiconductor.
In addition, dye-sensitized solar cell (Dye-sensitized solar cell) be by Switzerland Glan Ze Er (Gratzel) teach in 1991, through at ceramic semiconductors TiO 2The battery that absorption sensitising agent Ru (II) type complex compound is developed on the nano-porous films is compared with existing solar cell, and its photoelectric efficiency is low, becomes current business-like stumbling-block.
The high optoelectronic conversion ratio of dye-sensitized solar monocell is 10% level, and this level is compared low with compound semiconductor and a-Si thin film solar cell.But because cheap manufacturing equipment and technology makes it compare the generating unit price that can reduce quite a few with existing crystal silicon solar batteries, and the same with other thin film solar cell, have the advantage that can on flexible (flexible) substrate, form.
In order to obtain high efficiency dye-sensitized solar cell, research is divided into TiO 2The improvement of the improvement of film, the improvement of nesa coating, electrolyte and dyestuff etc.But basic truth is: the research to the light absorption of dye-sensitized solar cell is so not active.There is the inefficient problem that incident light can not thoroughly be absorbed by dye-sensitized solar cell, luminous energy runs off in the prior art.
In addition; Though can connect and composition module with cascaded structure by a plurality of existing solar energy monocells; Improve output voltage with this, but need be, in case the loss of function of one of monocell that connects by lead with the distribution operation that connects each monocell; Then might cause solar module general loss function, and have the problem of maintenance complicacy, the high-leveled and difficult operation of palpus process.
Summary of the invention
The present invention proposes in order to solve aforesaid the problems of the prior art.The object of the present invention is to provide a kind of solar module, this solar module especially through connect a plurality of solar energy monocells and lamination successively with parallel way, carries out effective maintenance management and increases electrical production of the same area.
For this reason, solar module of the present invention comprises: a plurality of solar energy monocells; The negative electrode connector is connected with the negative pole part of said monocell; And the anode connector, be connected with the anode portion of said monocell.
The preferred mutual lamination of said a plurality of solar energy monocells is also taken in.
Preferred said a plurality of solar energy monocells are electrically connected with parallel way.
Preferred said negative pole part comprises and is used for first protuberance that is connected with said negative electrode connector.
Preferred said anode portion comprises and is used for second protuberance that is electrically connected with said anode connector.
In addition, preferably be coated with the big metal of conductivity than the nesa coating of said negative pole part and anode portion at the terminal of said first protuberance and said second protuberance.
And the electrode of preferred said negative pole part and/or anode portion has the structure that is formed by the two or more at least different nesa coating laminations among ITO, IZO, AZO, GZO, GAZO (zinc oxide codope gallium aluminium) and the FTO (tin oxide codope fluorine).
Preferably, said solar energy monocell comprises the dye-sensitized solar monocell, but also can comprise in organic solar monocell, a-Si solar energy monocell, CIGS solar energy monocell and CdTe (cadmium telluride) the solar energy monocell at least any.
Preferred said solar module further comprises: sintered glass (frit glass), be positioned at the top of said a plurality of solar energy monocells, and have the ultraviolet function of prevention; Reach specular reverberation, be positioned at the bottom of said module.
A plurality of external members by said a plurality of solar energy monocells, said negative electrode connector and said anode connector are formed can be arranged along the arbitrary at least direction ways of connecting in directions X and the Y direction.
Said negative electrode connector and said anode connector comprise the connecting portion that is connected with other adjacent negative electrode connector or anode connector, and said connecting portion can prolong along the arbitrary at least direction in directions X, Y direction and the Z direction and form.
Preferred said negative electrode connector further comprises first connecting portion that can be electrically connected with other anode connector of outside.
Preferred said anode connector further comprises second connecting portion that can be electrically connected with other negative electrode connector of outside.
In addition, the section of preferred said first connecting portion and second connecting portion is trapezoidal, and interlaced configuration, thereby can dismounting.
The present invention makes the sunlight maximizing efficiency on equal area through taking in the solar energy monocell successively, thereby makes the electrical production maximization.
In addition, the present invention has and utilizes unabsorbed sunlight to make the maximized advantage of electrical production through taking in the identical or different solar energy monocell that absorbs different-waveband successively.
And the present invention has the advantage that can realize high voltage, high power power through connecting solar module with series connection and parallel way.
In addition, the present invention is expected to economy is produced tremendous influence through a large amount of environmental protection energies of producing.
According to the present invention, because solar module is the basis to be connected in parallel, even therefore there is a monocell to damage, whole solar module is still worked, so be easy to keep in repair.
In addition, the present invention is not owing to require the distribution of the complicacy between the solar energy monocell, can be with very simple box structure composition module, and therefore simple in structure.
Description of drawings
Fig. 1 is the cutaway view of the solar module of expression one embodiment of the invention.
Fig. 2 is the cutaway view of the solar energy monocell in the presentation graphs 1.
Fig. 3 and Fig. 4 are the illustrated view of the solar module of expression another embodiment of the present invention.
Symbol description
Figure BDA0000116573930000041
Embodiment
Solar module to the embodiment of the invention carries out detailed explanation with reference to the accompanying drawings.
Basic principle of the present invention is: with a plurality of solar energy monocells lamination successively and be accommodated in the solar module, thereby be easy to replace bad monocell, and improve electrical production rate of the same area.
At first, the employed solar module of embodiments of the invention is defined as: with equidistantly a plurality of solar energy monocells of lamination and the cassette module taken in successively.
And, in explanation of the present invention, if to relevant known function or structure to specify the explanation that is judged as aim of the present invention be unnecessary, then omit its detailed description.
Fig. 1 is the structural representation of the solar module 100 of the expression embodiment of the invention.
With reference to Fig. 1, solar module 100 of the present invention comprises a plurality of solar energy monocells 110; Negative electrode connector 130, its negative pole part with monocell 110 is connected; And anode connector 120, it is connected with the anode portion of monocell.
In solar module 100, equidistantly lamination and quilt are taken in (directions X, Y direction and Z direction are as the criterion with Fig. 4) to a plurality of solar energy monocells 110 up and down along Z direction quilt.
That is, monocell is taken in the boxlike mode in the solar module 100 of the embodiment of the invention.
Next with reference to Fig. 2 the structure and the function of the solar energy monocell 110 of the embodiment of the invention are described.
Fig. 2 is equipped on the structural representation of the solar energy monocell 110 in the solar module 100 of the embodiment of the invention for expression.
With reference to Fig. 2, solar energy monocell 110 comprises: negative pole part (front electrode base board) 111, and it is coated with nesa coating (electrode) on transparency carrier; Oxide skin(coating) 112, it contains light absorbing dyestuff; Dielectric substrate 113, it is used for to oxidized dyestuff electronics being provided; Sealing 114, it is used for the outside of sealing (Sealing) oxide skin(coating) 112 and dielectric substrate 113; And anode portion (backplate substrate) 115.
The operation principle of solar energy monocell 110 is explained as follows.
At first natural sunlight incides solar energy monocell 110, photon transmission negative pole part 111.
So, dyestuff macromolecule (not shown) in the following oxide skin(coating) 112 absorbs so by the photon of the light of transmission and transition is an excitation state, and generates electronics.The electron transfer that is generated is to loose structure TiO 2The conduction band of (not shown), and pass through negative pole part 111 to external circuit (not shown) electric energy transmitting.
Then, dielectric substrate 113 is to the oxide skin(coating) supplies electrons, so that the reduction of the fuel of oxide skin(coating) 112.
Replenished anode portion 115 from the electronics of dielectric substrate 113 supplies.
Sealing 114 contains electrolytical dielectric substrate 113 of liquid condition and the oxide skin(coating) 112 that contains dyestuff from outside seal.
In addition, solar energy monocell 110 also need be used for making its at solar module 100 by equidistant lamination and the device taken in.
Promptly with reference to Fig. 2, negative pole part 111 has the first outstanding protuberance a to the right, and anode portion 115 has the second outstanding protuberance b left.
The first protuberance a is connected to negative electrode connector 130, the second protuberance b and is connected to anode connector 120.
And, because the first protuberance a and the second protuberance b are electrically connected to negative electrode connector 130 and anode connector 120 respectively, therefore preferred on the terminal the high metallics of coated with conductive property.
The a plurality of solar energy monocells 110 that so constitute are also taken in by equidistant lamination in solar module 100.
Preferred a plurality of solar energy monocell 110 is laminated to two to four layers.
Need to prove that if a plurality of solar energy monocell 110 is laminated to more than five layers, the transmissivity of photon (Pho ton) significantly descends, the generating efficiency that causes being positioned at solar energy monocell bottom is practically negligible.
For example, when the 550nm wavelength light incided the solar module that is formed by five solar energy monocell laminations, the generating efficiency from the superiors' solar energy monocell to orlop solar energy monocell can be 10-8-3-1-0 successively.
Thus, practically negligible because of the generating efficiency of the 5th solar energy monocell of orlop, a plurality of solar energy monocells of the embodiment of the invention are defined as level Four.
Can know this moment, a plurality of solar energy monocells 110 electrically connect as parallel-connection structure.
In addition, form on the transparency carrier that the negative pole part 111 of preferred a plurality of solar energy monocells 110 and anode portion 115 are easy to transmission at natural sunlight.
The natural daylight transmission process is described for ease, to a plurality of solar energy monocell 110 mark Reference numeral 110a~110d.
The sunlight of first solar energy monocell of transmission 110a has only transmission in order by the solar energy monocell 110b~110d of lamination, could keep normal electrical production.
And, since solar energy monocell 110a~110d electrically connect as parallel connection, even if there is one to be removed because of error running or generation problem, solar module 100 still can operate as normal.
Therefore can guarantee the stability of solar module 100 of the present invention.
At this moment, in order to stop the ultraviolet ray in the incident sunlight and to improve transmittance, the top of solar module 100 is made up of sintered glass 140.
And in order utilize to see through the sunlight of solar energy monocell 110a~110d again, reverberation 150 endings of mirror for example etc. are used in the bottom of solar module 100.
Therefore can further improve solar module 100 of the present invention the electrical production rate.
In order to improve the electrical production rate of solar module 100, the solar energy monocell of the identical or different kind that absorbing wavelength that can lamination light is different.
Solar energy monocell 110a~110d can have the oxide skin(coating) 112 that contains light absorbing dyestuff, and this light absorbing dyestuff absorbs the light that absorbing wavelength has nothing in common with each other.
Because the sunlight wavelength that each solar energy monocell 110a~110d absorbs is different, therefore can be absorbed in the sunlight of the unabsorbed wave band in upper strata, and produces electric power.
Thus, the electrical production rate of solar module 100 can further increase.
In addition, the solar module among Fig. 1 has the dye-sensitized solar monocell, also can comprise at least a in organic solar monocell, a-Si solar energy monocell, CIGS solar energy monocell and the CdTe solar energy monocell simultaneously.At this moment, being positioned at bottom, the kind of the solar energy monocell of one deck is preferably CIGS solar energy monocell.
Fig. 3 is the sketch map of the solar module of expression another embodiment of the present invention; Solar module among a plurality of Fig. 1 (external member that is made up of a plurality of solar energy monocells, negative electrode connector and anode connector among Fig. 1 is shown; For with Fig. 3 and Fig. 4 in solar module differentiate, below the solar module among Fig. 1 is called the unit solar module) state to arrange along the directions X ways of connecting.
At this, negative electrode connector 130 has first connecting portion 131,132 that is used for being electrically connected with other anode connectors.
Likewise, anode connector 120 has second connecting portion 121 that is used for being electrically connected with other negative electrode connectors.
Therefore, the unit solar module 100 among Fig. 1 connects with series system respectively, can export higher voltage.
At this, the section of first connecting portion 131,132 and second connecting portion 121 is trapezoidal, and interlaced configuration, thereby can dismounting.Therefore, the contact area between the connector increases, and can improve bonding strength, and can reduce contact resistance.
Negative electrode connector in Fig. 3 (or anode connector) forms along the Y direction of negative pole part (or anode portion) on one side, has along the Y direction to prolong and the connecting portion of formation.Therefore, adjacent negative electrode connector can adopt sliding type to be connected along the Y direction with the anode connector.
Fig. 4 is the cutaway view of the solar module of expression further embodiment of this invention and the sketch map of vertical view, is that illustration unit's solar module is with the state diagram along directions X and the arrangement of Y direction ways of connecting.
The unit solar module connects with series system along directions X in Fig. 4, and connects with parallel way along Y direction unit solar cell.
Prolonging and connecting portion that forms and the connecting portion that forms along the prolongation of Z direction along the Y direction shown in Fig. 4.The connecting portion that forms along the prolongation of Z direction adopts sliding type to realize connecting along the Z direction.
But, the present invention is not limited to the closure that Fig. 3 and Fig. 4 represent.
As stated, though the present invention is illustrated according to the embodiment and the accompanying drawing that limit, the present invention is not limited to the foregoing description, and the people who under the present invention, has common knowledge in the field can carry out multiple modification and distortion from these records.
So the embodiment that scope of the present invention can not be confined to describe confirms thus that also the content that fibrous root is put down in writing according to claims reaches the content that is equal to it and confirms.

Claims (16)

1. a solar module is characterized in that, comprising:
A plurality of solar energy monocells;
The negative electrode connector is connected with the negative pole part of said a plurality of solar energy monocells; And
The anode connector is connected with the anode portion of said a plurality of solar energy monocells.
2. solar module according to claim 1 is characterized in that,
Said a plurality of solar energy monocell is along Z direction lamination and being incorporated between said negative electrode connector and the said anode connector up and down.
3. solar module according to claim 2 is characterized in that,
A plurality of external members of being made up of said a plurality of solar energy monocells, said negative electrode connector and said anode connector are to arrange along the arbitrary at least direction ways of connecting in directions X and the Y direction.
4. solar module according to claim 3 is characterized in that, said a plurality of external members are electrically connected with series system along directions X.
5. solar module according to claim 4 is characterized in that, said a plurality of external members are electrically connected with parallel way along the Y direction.
6. solar module according to claim 3 is characterized in that, said negative electrode connector and said anode connector comprise the connecting portion of trapezoidal shape, and said connecting portion is connected with adjacent negative electrode connector or anode connector.
7. solar module according to claim 6 is characterized in that,
Said connecting portion prolongs and forms along the arbitrary at least direction in said directions X, said Y direction and the said Z direction.
8. solar module according to claim 2 is characterized in that, the identical type that the absorbing wavelength that said a plurality of solar energy monocells comprise light is different or different types of solar energy monocell.
9. solar module according to claim 2 is characterized in that, said a plurality of solar energy monocells comprise:
I) dye-sensitized solar monocell; And
Ii) in organic solar monocell, a-Si solar energy monocell, CIGS solar energy monocell and the CdTe solar energy monocell at least any.
10. solar module according to claim 9 is characterized in that, said a plurality of solar energy monocells have CIGS solar energy monocell at orlop.
11. solar module according to claim 2 is characterized in that, said a plurality of solar energy monocells are laminated to two-layer above and below four layers.
12. solar module according to claim 2 is characterized in that, said solar module further comprises:
Sintered glass, be positioned at said a plurality of solar energy monocells top, have and stop ultraviolet function; And
Reverberation is positioned at the bottom of said a plurality of solar energy monocells.
13. solar module according to claim 1 is characterized in that, said a plurality of solar energy monocells are electrically connected with parallel way.
14. solar module according to claim 1 is characterized in that, in said negative pole part and the said anode portion at least any and said negative electrode connector or said anode connector between the terminal further comprise the protuberance that is coated with metal.
15., it is characterized in that the protuberance of said negative pole part and the protuberance of said anode portion are outstanding to opposite directions according to the said solar module of claim 14.
16. according to the said solar module of claim 1; It is characterized in that, in said negative pole part and the said anode portion any has the electrode that is formed by the two or more at least different nesa coating laminations among ITO, IZO, AZO, GZO, GAZO and the FTO at least.
CN2011104012606A 2010-12-06 2011-12-06 Solar battery module Pending CN102543972A (en)

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