CN1025349C - Hard-surface cleaning compositions - Google Patents

Hard-surface cleaning compositions Download PDF

Info

Publication number
CN1025349C
CN1025349C CN90102261A CN90102261A CN1025349C CN 1025349 C CN1025349 C CN 1025349C CN 90102261 A CN90102261 A CN 90102261A CN 90102261 A CN90102261 A CN 90102261A CN 1025349 C CN1025349 C CN 1025349C
Authority
CN
China
Prior art keywords
composition
account
gross weight
mixture
ethanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN90102261A
Other languages
Chinese (zh)
Other versions
CN1046553A (en
Inventor
伊安·康恩
约翰·卡雷尔·埃马·迪韦利
艾迪·约翰·埃德蒙·沃斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of CN1046553A publication Critical patent/CN1046553A/en
Application granted granted Critical
Publication of CN1025349C publication Critical patent/CN1025349C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0043—For use with aerosol devices
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Hard surface cleaning compositions are disclosed which comprise anionic surfactants ammonium salts, monoethanolamine or diethanolamine or triethanolamine or mixtures thereof and a solvent system; the compositions herein have an alkaline pH.

Description

Hard-surface cleaning compositions
The present invention relates to provide the good clenaing effect and the hard-surface cleaning composition of brightness effect simultaneously.
Hard-surface cleaning composition is well-known on technology, and its clenaing effect has improvement greatly for many years.But in the focal attention clenaing effect, run into a new problem, that is, unless drip washing is carried out on the surface of having cleaned again during with these compositions, its brightness effect is bad.That is to say that with a kind of hard surface cleaner of not drip washing type, good brightness effect and good cleaning performance can not get both.Really, most compositions stays striped and/or residual film in use on the surface of cleaning, and the appearance that the result cleaned is bad.
The problems referred to above are especially disagreeable when cleaning window glass or mirror with hard surface cleaner, because residual film is more obvious.
With regard to window glass, once prepared the composition of formation " volatility " clean-out system, it has solved this problem effectively; But not all surface can both be cleaned with this based composition, because they usually contain the solvent that can dissolve some material.In addition, these compositions also have other shortcoming, for example inflammableness and deleterious smell.
As a kind of adoptable method, once prepared the higher composition of some ammonia contents.With regard to film forming/stripes problem, it is satisfied to contain the people with ammonia, still from the aesthetic angle of safety and product, then very undesirable.Really, the existence of ammonia makes product the smell is awful.
United States Patent (USP) 3,591, it might be the tensio-active agent of ammonium salts, a kind of mixed solvent and a kind of water soluble detergency promoter that No. 510 disclosed hard surface cleaners contain.
United States Patent (USP) 3,591, it might be the tensio-active agent of ammonium salts, a kind of mixed solvent, a kind of water soluble detergency promoter and a kind of water-soluble carboxymethyl Mierocrystalline cellulose that No. 509 disclosed compositions contain.
English Patent discloses a kind of composition No. 2160887, and it contains a kind of anion surfactant, water-soluble and water-insoluble alcohol and a kind of organic solvent.
Japanese Patent 62034998 disclosed compositions contain a kind of anionic surfactant salt, a kind of water-soluble solvent, oxychlorination sodium or potassium, and monoethanolamine.
No. 58101198 disclosed compositions of Japanese Patent contain the mixture and the polypropylene glycol of alkanolamine, a kind of negatively charged ion and nonionogenic tenside.
One of purpose of the present invention provides liquid hard-surface cleaning composition, even when using under the situation of not drip washing, they also have good clenaing effect and good brightness effect.
Another object of the present invention provides liquid hard-surface cleaning composition, and it can be used for any surface, and is especially effective to glass.
Another object of the present invention provide a kind of be applicable to any diverting device, especially be applicable to the spraying decollator hard surface cleaner.
Therefore a further object of the invention promptly, provides not contain ammonia, do not have a composition of noxious odor.
By following narration other purpose of the present invention as can be seen and advantage.
The invention provides hard-surface cleaning composition, its pH is at least 8.5, contains:
-account for the anion surfactant ammonium salt of composition total weight 0.04% to 0.6%,
-account for monoethanolamine, diethanolamine or the trolamine of composition total weight 0.2% to 2.0%, or their mixture,
-account for the solvent system of composition total weight 3% to 14%.
Composition of the present invention contains the anion surfactant ammonium salt, and its content is 0.04% to 0.6% of composition total weight, and preferably from 0.07% to 0.45%.
Here used anion surfactant comprises alkylbenzene sulfonate or vitriol, alkane sulfonate, ethylenic sulfonate, fatty acid sulfonate and fatty sulfonate, and detergent industry, in known similar substance.The kind of ethoxylation also is suitable for, for example alkyl polyethoxye vitriol and sulfosuccinate.
Be applicable to that this bright tensio-active agent preferably is C 8-C 18Alkylbenzene sulfonate and C 8-C 18Alkyl polyethoxye vitriol.
Be used to implement preferably C of the present invention 8-C 18Linear alkylbenzene sulfonate and 3 times of ethoxylation C 8-C 18The mixture of alkyl-sulphate.
All anion surfactants in the composition all exist with its ammonium salts.
Composition of the present invention also contains the monoethanolamine, diethanolamine or the trolamine that account for composition total weight 0.2% to 2.0% or their mixture, and preferably from 0.35% to 0.75%.Composition preferably contains the monoethanolamine of above-mentioned content.
Importantly, the pH of composition of the present invention is at least 8.5, and preferably 10.5.
The basicity of composition is determined by the quantity of list, two, trolamine or its mixture basically; These compounds play buffer system, make the basicity can improve composition and do not react with the ammonium salt of tensio-active agent.The result does not have ammonia to discharge, so this composition does not have noxious odor.
Composition of the present invention also contains solvent system, and its content is 3% to 14% of composition total weight, and preferably 5% to 11%.
The solvent that is suitable for has n-butoxy propyl alcohol, ethanol, Virahol, n-butoxy propoxy-propyl alcohol, diethylene glycol monobutyl ether (being 2-(2-butoxy oxyethyl group) ethanol), hexylene glycol, hexyl Trivalin SF (being 2-(2-hexyloxy oxyethyl group) ethanol), reach their mixture.
Preferred solvent system is made of the mixture of n-butoxy propyl alcohol and ethanol or Virahol, and its ratio is 1: 20 to 1: 2.The optimum solvent system is made of n-butoxy propyl alcohol and 1: 3 mixture of alcoholic acid.
In addition, composition can contain a spot of washing assistant, nitrilotriacetate for example, polycarboxylate, nitrate, water-soluble phosphate, silicate, edetate (EDTA), amino polyphosphonates, phosphoric acid ester, and their mixture.
Composition of the present invention mixes all components and obtains; The hard surface cleaner that obtains like this is applicable to any diverting device that is used for this technical field at present, but preferably uses in the mode of spray cleaning agent.These compositions are applicable to any surface, especially window glass or any glass material.
Composition of the present invention also can contain other optional, materials, for example spices, dyestuff, white dyes, soil-suspending agent, enzyme, freeze-thaw stablizer, sterilant and sanitas.
Example
The following present composition makes by all components (percentage ratio is the percentage ratio that accounts for the composition gross weight) is mixed mutually:
0.07% linear alkyl benzene sulphonic acid ammonium salt
0.10% 3 times of ethoxylated alkyl ammonium sulfate salt
2% n-butoxy propyl alcohol
6% ethanol
0.5% monoethanolamine ammonium
Water up to 100% and other material
The pH of the present composition is 10.5
This composition is compared with the reference group compound of representing as prior art, prescription is following:
0.013% 3 times of ethoxylated alkyl sulfate salt
9.0% butyl Cellosolve
0.2% ammonia
Water up to 100% and other material
The pH of this composition is 11
The brightness effect (on mirror and window glass) and their clenaing effect that compare two kinds of compositions.
Clenaing effect judges by following involutory one-tenth dirt:
HBTS dirt: form by 250 milliliters of Virahols, 75 gram calcium stearate powder and 0.5 gram carbon black.Paint cylinder and it is coated in one is being coated with on the enamelled metal sheet (washing with alcohol earlier), plate was baked 20 minutes at 180 ℃ with washing composition, back.
KD dirt: HSW by 25%
Figure 901022616_IMG1
Dirt and carbon black (2), 37.5% Grisco
Figure 901022616_IMG2
Oil (1), 37.5% Puritan
Figure 901022616_IMG3
Oil (1)Form.Paint cylinder with its roll extrusion on stainless steel plate (earlier with washing composition, then wash) with alcohol.Need to form very thin uniform coating, because this dirt is difficult to remove.Plate is placed in the baking oven in 115 ℃ (" soft dirts ") or 170 ℃ of (" hard dirts ") bakings 2 hours, aging at least one then day.
Annotate: (1) Procter﹠amp; The commodity cooking oil that Gamble company sells
(2) the commodity dirt of U.S. Chem Pack Inc. sale.
Test conditions is as follows:
All tests are all undertaken by an Erichsen washability tester.Use a size to be about 9.5 * 5 * 4 centimetres sponge, in advance it is carefully cleaned under mobile hot water and extract with the exsiccant cylinder.The clean-out system of the not diluted of 5 gram desires tests is topped on the one side of sponge.Write down cleaning machine for cleaning the number of times of the required action of plate face.
Brightness effect goes up evaluation at clean mirror or window glass (indoor and outdoor); Use the degree of 0-4 scoring method visual assessment film forming/striped independently by three identifiers, 0=indifference wherein, 4=is big difference very.
The result is as follows:
The clean minute surface window glass of HBTS KD
(action frequency) (PSU) indoor and outdoor
（PSU）
With reference to sample＞200 10 0(reference) the 0(reference) the 0(reference)
Sample of the present invention＞200 16+1.8+1.1 0
This appraisal group shows that composition of the present invention has clenaing effect and the better brightness effect same good with the reference group compound.

Claims (9)

1, a kind of pH is at least 8.5 hard-surface cleaning composition, and it contains:
Account for the anion surfactant ammonium salt of composition gross weight 0.04% to 0.6%,
Account for monoethanolamine, diethanolamine or the trolamine of composition gross weight 0.2% to 2.0%, or their mixture,
Account for a kind of solvent system of composition gross weight 3% to 14%, this solvent system is selected from n-butoxy propyl alcohol, ethanol, Virahol, n-butoxy propoxy-propyl alcohol, 2-(2-butoxy oxyethyl group) ethanol, hexylene glycol, 2-(2-is the oxygen base oxethyl) ethanol and their mixture.
According to the composition of claim 1, it is characterized in that 2, it contains:
Account for the anion surfactant ammonium salt of composition gross weight 0.07% to 0.45%,
Account for 0.35% to 0.75% monoethanolamine of composition gross weight,
Account for 5% to 11% described solvent system of composition gross weight.
According to the composition of aforementioned any one claim, it is characterized in that 3, solvent system is n-butoxy propyl alcohol and alcoholic acid mixture.
According to the composition of claim 3, it is characterized in that 4, solvent mixture is wherein pressed 1: 20 to 1: 2 composition of proportions by n-butoxy propyl alcohol and ethanol.
5, according to claim 1,2 or 4 composition, it is characterized in that the pH of composition is 8.5 to 11.
6,, it is characterized in that the pH value is about 10.5 according to the composition of claim 5.
According to the composition of claim 3, it is characterized in that 7, the pH of composition is 8.5 to 11.
8,, it is characterized in that the pH value is about 10.5 according to the composition of claim 7.
9,, it is characterized in that it is suitable as the spraying cleaning combination and uses according to the composition of claim 4.
CN90102261A 1989-04-21 1990-04-21 Hard-surface cleaning compositions Expired - Lifetime CN1025349C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8909157.3 1989-04-21
GB898909157A GB8909157D0 (en) 1989-04-21 1989-04-21 Hard-surface cleaning compositions

Publications (2)

Publication Number Publication Date
CN1046553A CN1046553A (en) 1990-10-31
CN1025349C true CN1025349C (en) 1994-07-06

Family

ID=10655508

Family Applications (1)

Application Number Title Priority Date Filing Date
CN90102261A Expired - Lifetime CN1025349C (en) 1989-04-21 1990-04-21 Hard-surface cleaning compositions

Country Status (13)

Country Link
EP (1) EP0393772A3 (en)
JP (1) JPH0341200A (en)
CN (1) CN1025349C (en)
AR (1) AR245496A1 (en)
AU (1) AU641643B2 (en)
BR (1) BR9001845A (en)
CA (1) CA2013976A1 (en)
GB (1) GB8909157D0 (en)
IE (1) IE901423L (en)
MX (1) MX171350B (en)
MY (1) MY106340A (en)
NZ (1) NZ233397A (en)
PE (1) PE27691A1 (en)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0503219A1 (en) * 1991-03-11 1992-09-16 THE PROCTER & GAMBLE COMPANY Method and diluted cleaning composition for the cleaning of hard surfaces
ES2089792T3 (en) * 1992-01-23 1996-10-01 Procter & Gamble LIQUID DETERGENT COMPOSITIONS FOR HARD SURFACES CONTAINING HYBRID AND CATIONAL SURFACES AND MONOETHANOLAMINE AND / OR BETA-AMINOALCANOL.
US5468423A (en) * 1992-02-07 1995-11-21 The Clorox Company Reduced residue hard surface cleaner
US5817615A (en) * 1992-02-07 1998-10-06 The Clorox Company Reduced residue hard surface cleaner
US5252245A (en) * 1992-02-07 1993-10-12 The Clorox Company Reduced residue hard surface cleaner
US5585342A (en) * 1995-03-24 1996-12-17 The Clorox Company Reduced residue hard surface cleaner
US5523024A (en) * 1992-02-07 1996-06-04 The Clorox Company Reduced residue hard surface cleaner
DE4210364B4 (en) * 1992-03-30 2006-05-18 Henkel Kgaa Cleaning agents for hard surfaces, in particular glass
JPH08510770A (en) * 1993-06-01 1996-11-12 エコラブ， インコーポレイテッド Foam surface cleaner
CN1046137C (en) * 1994-06-29 1999-11-03 首钢总公司 General-purpose hard surface detergent
ATE278757T1 (en) 1994-07-07 2004-10-15 Clorox Co ANTIMICROBIAL CLEANER FOR HARD SURFACES
US6399553B1 (en) * 1997-06-05 2002-06-04 The Clorox Company Reduced residue hard surface cleaner
US6432897B1 (en) * 1997-06-05 2002-08-13 The Clorox Company Reduced residue hard surface cleaner
DE19811387A1 (en) 1998-03-16 1999-09-23 Henkel Kgaa Liquid, multiphase, chlorofluorocarbon-free detergent forming temporary emulsion on shaking and used especially on glass
DE19856529A1 (en) * 1998-12-08 2000-06-15 Henkel Kgaa Detergent for hard surfaces
DE19859778A1 (en) 1998-12-23 2000-06-29 Henkel Kgaa Multi-phase cleaning agent with naphthalenesulfonic acid-formaldehyde condensate
DE19859640A1 (en) 1998-12-23 2000-06-29 Henkel Kgaa Detergent for hard surfaces
DE19859808A1 (en) 1998-12-23 2000-06-29 Henkel Kgaa Multi-phase cleaning agent with lignin sulfonate
JP2002226898A (en) * 1999-01-13 2002-08-14 Nisshin Kagaku Kk Cleaning agent for spray
EP1292664A2 (en) 2000-06-20 2003-03-19 The Procter & Gamble Company Multi-phase fabric care composition for delivering multiple fabric care benefits
CN103060824B (en) * 2013-01-21 2015-06-03 陕西理工学院 Universal metal surface cleaning agent
CA3077837A1 (en) 2020-04-03 2021-10-03 Fluid Energy Group Ltd. Hard surface cleaner
CA3113508A1 (en) 2021-03-30 2022-09-30 Fluid Energy Group Ltd. Hard surface cleaning composition

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3839234A (en) * 1973-01-26 1974-10-01 C Roscoe Multi-purpose cleaning concentrate
US4077896A (en) * 1975-01-15 1978-03-07 Minnesota Mining And Manufacturing Company Wax-stripping cleaning composition
AU575399B2 (en) * 1984-06-21 1988-07-28 S.C. Johnson & Son, Inc. Hard surface cleaning composition
JPS62252499A (en) * 1986-04-25 1987-11-04 ライオン株式会社 Liquid detergent composition
NZ224148A (en) * 1987-04-10 1991-02-26 Colgate Palmolive Co Pre-spotting composition for food residue removal
AU4702289A (en) * 1989-01-19 1990-07-26 Sterling Drug Inc. Hard surface cleaning composition

Also Published As

Publication number Publication date
GB8909157D0 (en) 1989-06-07
BR9001845A (en) 1991-06-18
AR245496A1 (en) 1994-01-31
AU641643B2 (en) 1993-09-30
MX171350B (en) 1993-10-20
AU5369890A (en) 1990-10-25
EP0393772A2 (en) 1990-10-24
JPH0341200A (en) 1991-02-21
PE27691A1 (en) 1991-09-27
EP0393772A3 (en) 1991-09-11
CN1046553A (en) 1990-10-31
CA2013976A1 (en) 1990-10-21
NZ233397A (en) 1993-05-26
IE901423L (en) 1990-10-21
MY106340A (en) 1995-05-30

Similar Documents

Publication Publication Date Title
CN1025349C (en) Hard-surface cleaning compositions
DE3686676T2 (en) ENZYME-BASED DETERGENT.
DE69024510T2 (en) Liquid enzymatic detergents
CN1087343C (en) Liquid dishwashing detergent
WO1997009407A1 (en) Fully diluted hard surface cleaners containing small amounts of certain acids
JPS62109898A (en) Creamy tooth-brushing composition
EP0261718B1 (en) Creamy scouring compositions
EP3243895A1 (en) Cleaning composition
CN1121952A (en) High actives cleaning compositions and methods of use
CN1055721C (en) Detergent composition for hard surface
JPH11504045A (en) Hard surface cleaner with little fringe (line) formation and film formation
DE69706285T2 (en) LESS FOAMING AND LOW STRIP AND FILM-MAKING CLEANER FOR HARD SURFACES
EP0428816A1 (en) Hard-surface cleaning compositions
JP2801829B2 (en) Liquid detergent composition
CN1284846C (en) Aqueous cleaning and disinfecting compositions based on quarternary ammonium compounds and alkylpolyglycoside surfactants
JPH11152497A (en) Detergent composition for washing car
JPH07504704A (en) Compositions and methods for dilute cleaning of hard surfaces
JP2608256B2 (en) Liquid detergent composition
CN1107509A (en) Acid microemulsion composition
EP0442251A1 (en) Hard surface cleaning compositions
CN1057791C (en) Manual dishwashing compositions
JPS62106999A (en) Liquid detergent composition
CN1207762A (en) Liquid hard surface detergent compositions contg. specific concentration of tartaric acid detergent builder
JP3250981B2 (en) Concentrated liquid detergent composition for kitchen
WO1996019555A1 (en) Liquid detergent composition

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant