CN102520480A - Multi-medium-coupling three-dimensional photonic crystal and method for designing and manufacturing multi-medium-coupling three-dimensional photonic crystal - Google Patents
Multi-medium-coupling three-dimensional photonic crystal and method for designing and manufacturing multi-medium-coupling three-dimensional photonic crystal Download PDFInfo
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Abstract
本发明公开了一种多介质耦合三维光子晶体及其设计制造方法,在较宽频率内具有超宽带隙并且容易制造的多介质耦合三维光子晶体。根据本发明的多介质耦合三维光子晶体中周期性包含了多种不同介电常数的介质材料。所述光子晶体中包括周期性层叠和交叉两种形式,采用快速成型结合多步注模法来制备,本发明中的光子晶体包含两种以上的介质材料,多种介质材料之间的介电常数比(折射率比)加强了布拉格散射,得到了比单一介质材料光子晶体更宽的带隙。The invention discloses a multi-medium coupled three-dimensional photonic crystal and a design and manufacture method thereof, which is a multi-medium coupled three-dimensional photonic crystal which has an ultra-wide bandgap within a wide frequency and is easy to manufacture. The multi-medium coupling three-dimensional photonic crystal according to the present invention periodically includes a variety of dielectric materials with different dielectric constants. The photonic crystal includes two forms of periodic stacking and crossing, and is prepared by rapid prototyping combined with multi-step injection molding. The photonic crystal in the present invention contains more than two dielectric materials, and the dielectric between multiple dielectric materials The constant ratio (refractive index ratio) strengthens the Bragg scattering and obtains a wider band gap than that of a single dielectric material photonic crystal.
Description
技术领域 technical field
本发明涉及一种多介质耦合三维光子晶体及其设计制造方法。具体是指同时包含两种以上介质材料的三维光子晶体。The invention relates to a multi-media coupled three-dimensional photonic crystal and a design and manufacture method thereof. Specifically, it refers to a three-dimensional photonic crystal containing two or more dielectric materials.
背景技术 Background technique
光子晶体是指介电常数(或折射率)在三维空间上呈三维排列的一种复合结构材料。Yablornovitch和John在1987年分别研究抑制原子的自发辐射和光局域时独立提出光子晶体的概念。与传统的晶体材料类似,当介电常数在三维空间中受到调制时,就会呈现出与固态电子晶体相似的能带结构,能量处于带隙之中的电磁波将不能在此结构中传播。当工作的电磁波频率在光波段时,习惯称之为光子晶体或光子带隙结构。当工作的电磁波频率处于微波频段范围时,习惯称之为电磁带隙结构。为研究方便,统一沿用“光子晶体”这一概念。Photonic crystal refers to a composite structural material whose dielectric constant (or refractive index) is three-dimensionally arranged in three-dimensional space. Yablornovitch and John independently proposed the concept of photonic crystals in 1987 when they studied the suppression of atomic spontaneous emission and light localization respectively. Similar to traditional crystal materials, when the dielectric constant is modulated in three-dimensional space, it will present an energy band structure similar to that of solid-state electronic crystals, and electromagnetic waves with energy in the band gap will not be able to propagate in this structure. When the working electromagnetic wave frequency is in the optical band, it is customary to call it a photonic crystal or a photonic bandgap structure. When the working electromagnetic wave frequency is in the microwave frequency range, it is customary to call it an electromagnetic bandgap structure. For the convenience of research, the concept of "photonic crystal" is uniformly used.
光子晶体最基本的特性是光子禁带和光子局域。除此之外,研究人员还在光子晶体发现了慢波和超慢波传输及负折射现象。光子晶体的各种新型应用都是基于光子晶体结构本身的这些新颖奇特的性质。反射镜、光学波导和谐振腔是光子晶体应用的几个基本领域。由于光子晶体具有带隙特性,因此通过合理设计就可以得到反射率接近100%的反射镜。基于反射镜的设计,很容易就可以获得各种各样高效率的滤波器(如低通滤波器、高通滤波器、带通滤波器、极窄带滤波器等)。从反射器出发,利用光子晶体中TE和TM极化的不同带隙特点就可以获得各种偏振器。通过在反射镜设计中引入恰当的线缺陷,就可以获得优异的光学波导。而通过在反射镜设计中引入恰当的点缺陷,就可以获得高品质因子的谐振腔。对实现光子晶体的这些特性来说,越宽的带隙越有利于在更宽的范围内控制电磁波的传输。The most basic characteristics of photonic crystals are photonic band gap and photonic localization. In addition, the researchers also discovered slow-wave and ultra-slow-wave transmission and negative refraction in photonic crystals. Various new applications of photonic crystals are based on these novel and peculiar properties of the photonic crystal structure itself. Mirrors, optical waveguides, and resonant cavities are a few fundamental areas of application of photonic crystals. Since the photonic crystal has a band gap characteristic, a reflective mirror with a reflectivity close to 100% can be obtained through reasonable design. Based on the mirror design, it is easy to obtain a variety of high-efficiency filters (such as low-pass filters, high-pass filters, band-pass filters, extremely narrow-band filters, etc.). Starting from the reflector, various polarizers can be obtained by utilizing the different bandgap characteristics of TE and TM polarization in photonic crystals. Excellent optical waveguides can be obtained by introducing appropriate line defects in the mirror design. By introducing appropriate point defects into the mirror design, resonators with high quality factors can be obtained. For the realization of these properties of photonic crystals, a wider band gap is more conducive to controlling the transmission of electromagnetic waves in a wider range.
光子晶体的带隙可以通过改变结构、填充率和高低介电比来控制。关于不同三维结构,如木堆结构、金刚石结构光子晶体已经有不少研究报道。而Kirihara等的文章“通过改变电磁晶体的周期控制电磁波的传输”(SolidState Communications,124期,2002年,135-139页)研究了将金刚石结构周期拉伸对光子晶体带隙的影响,实质是通过改变光子晶体结构的填充率来控制电磁带隙,拉伸后得到了更宽带隙的光子晶体。吕雪松等的文章“用微波介质粉末制备毫米波电磁带隙晶体”(Joural of American CeramicsSociety,9期2009年,第371-378页)研究了不同介电常数微波介质材料各自对电磁带隙的影响。但是基于制造技术的限制,以上这些研究中光子晶体都是只包含高低介两种介质材料,同时包含两种以上介质材料的光子晶体至今没有研究报道。这是由于三维结构的复杂性,加上同时包含的多种介质材料在成型、干燥和烧结过程中的不一致性都使其制造非常困难。The bandgap of photonic crystals can be controlled by changing the structure, filling ratio, and high-low dielectric ratio. There have been many research reports on different three-dimensional structures, such as wood pile structure and diamond structure photonic crystal. And Kirihara et al.'s article "Controlling the Transmission of Electromagnetic Waves by Changing the Period of Electromagnetic Crystals" (SolidState Communications, 124, 2002, pages 135-139) studied the effect of stretching the diamond structure period on the bandgap of photonic crystals. The essence is By changing the filling rate of the photonic crystal structure to control the electromagnetic bandgap, a photonic crystal with a wider bandgap is obtained after stretching. The article "Preparation of Millimeter Wave Electromagnetic Bandgap Crystals Using Microwave Dielectric Powder" (Joural of American Ceramics Society, Issue 9, 2009, pp. 371-378) studied the effects of microwave dielectric materials with different dielectric constants on the electromagnetic bandgap. Influence. However, based on the limitation of manufacturing technology, the photonic crystals in the above studies only contain two kinds of dielectric materials, high and low, and there are no research reports on photonic crystals containing more than two kinds of dielectric materials. This is due to the complexity of the three-dimensional structure, coupled with the inconsistencies in the molding, drying, and sintering processes of multiple dielectric materials included at the same time, making it very difficult to manufacture.
发明内容 Contents of the invention
本发明的目的在于提供一种多介质耦合三维光子晶体及其设计制造方法。The purpose of the present invention is to provide a multi-medium coupling three-dimensional photonic crystal and its design and manufacture method.
本发明的技术方案是这样实现的:Technical scheme of the present invention is realized like this:
多介质耦合三维光子晶体中周期性包含了多种不同介电常数的介质材料,所述光子晶体中包括周期性层叠和交叉两种形式:Multi-medium coupling three-dimensional photonic crystals periodically include a variety of dielectric materials with different dielectric constants, and the photonic crystals include two forms of periodic stacking and crossing:
周期性层叠的多介质耦合三维光子晶体是指:将三维光子晶体结构平均分为两部分或更多部分,在每一部分中分别填充不同介电常数的介质,最后形成同时含有多种不同介电常数介质的光子晶体;Periodically stacked multi-medium coupled three-dimensional photonic crystal refers to: divide the three-dimensional photonic crystal structure into two or more parts on average, fill each part with media with different dielectric constants, and finally form Photonic crystals with constant media;
周期性交叉的多介质三维光子晶体是指:将具有周期性三维结构的光子晶体中,第一层填充第一种介质,第二层填充第二种介质,第三层再填充第一种介质,第四层再填充第二种介质,以此类推;或者是每一层中交叉填充不同介质;或者两种介质相互嵌套填充形成多介质光子晶体。Periodically intersecting multi-medium three-dimensional photonic crystal refers to: in the photonic crystal with periodic three-dimensional structure, the first layer is filled with the first medium, the second layer is filled with the second medium, and the third layer is filled with the first medium , the fourth layer is filled with the second medium, and so on; or each layer is cross-filled with different media; or two media are nested and filled to form a multi-media photonic crystal.
所述三维结构包括三维柱状金刚石结构和球状金刚石结构以及金刚石结构的衍生体,木堆结构。The three-dimensional structure includes a three-dimensional columnar diamond structure, a spherical diamond structure, a derivative of the diamond structure, and a wood pile structure.
所用介质材料包含所有陶瓷材料,液体材料和超低温金属材料;所述多介质耦合是指陶瓷材料之间、液体材料之间或超低温金属材料之间多种不同介电常数的介质各自耦合,或者是陶瓷材料、液体材料和超低温金属材料之间多种介质相互耦合。The dielectric materials used include all ceramic materials, liquid materials and ultra-low temperature metal materials; the multi-media coupling refers to the respective coupling of a variety of media with different dielectric constants between ceramic materials, between liquid materials or between ultra-low temperature metal materials, or ceramics Various media are coupled between materials, liquid materials and ultra-low temperature metal materials.
一种多介质耦合三维光子晶体的制造方法,包括以下步骤:A method for manufacturing a multi-media coupled three-dimensional photonic crystal, comprising the following steps:
首先根据电磁理论采用CAD软件进行结构设计和利用光固化快速成型制造树脂模型,并制备陶瓷浆料或液体材料、超低温金属材料;First, CAD software is used for structural design based on electromagnetic theory, and resin models are manufactured by light-curing rapid prototyping, and ceramic slurry or liquid materials and ultra-low temperature metal materials are prepared;
其次,采用多步注模法制备多介质耦合三维光子晶体;Secondly, the multi-media coupling three-dimensional photonic crystal was prepared by multi-step injection molding method;
针对于周期性层叠的光子晶体,将注模用外壳进行连通式设计,每种介质材料对应的结构有一个注浆口和一个连通口,连通口的高度与对应介质所占结构的最高点平行。将一种介质浆料注模后,用橡皮泥封好注浆口和连通口,然后进行第二种介质的注模,以此类推,最终得到多介质三维光子晶体。For periodically stacked photonic crystals, the casing for injection molding is designed in a connected manner. The structure corresponding to each dielectric material has a grouting port and a communication port. The height of the communication port is parallel to the highest point of the structure occupied by the corresponding medium. . After injecting one kind of medium slurry, seal the grouting port and the connecting port with plasticine, then carry out the injection molding of the second medium, and so on, finally obtain the multi-media three-dimensional photonic crystal.
针对与相互嵌套结构的光子晶体,将注模外壳的结构上方中间按介质种类用隔板分开,一边用于第一种介质对应结构的注模,另一边用于第二种介质对应结构的注模,最终得到多介质耦合三维光子晶体。For photonic crystals with nested structures, the upper middle of the injection molded shell is separated by a partition according to the type of medium, one side is used for the injection molding of the structure corresponding to the first medium, and the other side is used for the structure corresponding to the second medium. Injection molding, and finally obtain a multi-medium coupled three-dimensional photonic crystal.
本发明与传统的三维光子晶体相比,具有以下特点:Compared with the traditional three-dimensional photonic crystal, the present invention has the following characteristics:
①本发明中的光子晶体包含两种以上的介质材料,多种介质材料之间的介电常数比(折射率比)加强了布拉格散射,得到了比单一介质材料光子晶体更宽的带隙;1. the photonic crystal among the present invention comprises two or more dielectric materials, and the dielectric constant ratio (refractive index ratio) between multiple dielectric materials strengthens Bragg scattering, obtains the bandgap wider than single dielectric material photonic crystal;
②采用快速原型模具结合多步注模法解决了多介质耦合光子晶体的成形问题,充分发挥了光固化快速成型在设计和制造上的优势,为光子晶体向器件化发展奠定了坚实的基础。②Using rapid prototyping mold combined with multi-step injection molding method to solve the forming problem of multi-medium coupling photonic crystal, give full play to the advantages of light-cured rapid prototyping in design and manufacturing, and lay a solid foundation for the development of photonic crystal to device.
通过下面附图和具体实施方式的描述,将更清晰的展示本发明的特征。The features of the present invention will be more clearly shown through the following descriptions of the accompanying drawings and specific embodiments.
附图说明 Description of drawings
图1是周期性层叠金刚石结构三种介质光子晶体Figure 1 shows three dielectric photonic crystals with periodically stacked diamond structures
图2是周期性交叉金刚石结构三种介质光子晶体Figure 2 is three kinds of dielectric photonic crystals with periodic cross diamond structure
图3周期性嵌套金刚石结构三种介质光子晶体Figure 3 Three dielectric photonic crystals with periodically nested diamond structures
图4周期性交叉木堆结构多种介质光子晶体Figure 4 Periodic cross wood pile structure of multiple dielectric photonic crystals
图5根据实施例1制造多介质耦合光子晶体的方法示意图Fig. 5 is a schematic diagram of a method for manufacturing a multi-media coupling photonic crystal according to Embodiment 1
图6根据实施例3制造多介质耦合光子晶体的方法示意图Fig. 6 is a schematic diagram of a method for manufacturing a multi-media coupling photonic crystal according to Embodiment 3
具体实施方式 Detailed ways
实施例1Example 1
附图1是周期性层叠金刚石结构多种介质光子晶体。选取多种合适的介质材料(介电常数分别为ε1、ε2、ε3……),利用快速成型和多步凝胶注模法制备多介质耦合光子晶体。附图1中第一周期层是介电常数为ε1的第一种介质,在第一种介质即将固化的时候往第二周期层注入第二种介质ε2,在第二种介质快要固化的时候向第三周期层注入第三种介质ε3,以此类推,可制备如附图1的同时包含多种介质的光子晶体。所制备的多介质耦合光子晶体可以是包含树脂结构的多介质耦合光子晶体,也可以是经过干燥、脱脂和烧结处理后的纯陶瓷光子晶体。
实施例2Example 2
附图2是周期性交叉金刚石结构三种介质光子晶体。选取两种合适的介质材料(介电常数分别为ε1、ε2),利用快速成型和多步凝胶注模法制备多介质耦合光子晶体。附图2中第一周期层是介电常数为ε1的第一种介质,在第一种介质即将固化的时候往第二周期层注入第二种介质ε2,在第二种介质快要固化的时候向第三周期层注入第一种介质ε1,在第三周期层介质即将固化时向第四周期层重新注入第二种介质ε2,以此类推,可制备如附图2的同时包含三种介质的周期性交叉金刚石结构光子晶体。所制备的多介质光子晶体可以是包含树脂结构和两种介质的多介质耦合光子晶体,也可以是经过干燥、脱脂和烧结处理后的包含两种陶瓷和空气的纯陶瓷光子晶体。Accompanying drawing 2 is three kinds of dielectric photonic crystals with periodic intersecting diamond structure. Select two suitable dielectric materials (dielectric constants ε 1 , ε 2 ), and use rapid prototyping and multi-step gel injection molding to prepare multi-media coupled photonic crystals. In Figure 2, the first periodic layer is the first medium with a dielectric constant of ε 1. When the first medium is about to solidify, inject the second medium ε 2 into the second periodic layer. When the second medium is about to solidify When the third periodic layer is injected with the first medium ε 1 , when the third periodic layer medium is about to solidify, the second medium ε 2 is re-injected into the fourth periodic layer, and so on. Periodically crossed diamond-structured photonic crystals containing three media. The prepared multi-medium photonic crystal can be a multi-medium coupled photonic crystal containing a resin structure and two media, or a pure ceramic photonic crystal containing two kinds of ceramics and air after drying, degreasing and sintering.
实施例3Example 3
附图3是周期性嵌套金刚石结构三种介质光子晶体。选取两种合适的介质材料(介电常数分别为ε1、ε2),利用快速成型和多步凝胶注模法制备多介质耦合光子晶体。所述金刚石结构通过CAD软件抽壳处理,得到空气金刚石结构、树脂金刚石结构、空气反金刚石结构相互嵌套组成的多介质金刚石结构模型。向附图3中的空气金刚石结构中注入第一种介质ε1,然后向空气反金刚石结构中注入第二种介质ε2,经过真空冷冻干燥后得到由介质ε1、树脂和介质ε2组成的包含三种介质的周期性嵌套金刚石结构三种介质耦合光子晶体Accompanying drawing 3 is three kinds of dielectric photonic crystals with periodically nested diamond structures. Select two suitable dielectric materials (dielectric constants ε 1 , ε 2 ), and use rapid prototyping and multi-step gel injection molding to prepare multi-media coupled photonic crystals. The diamond structure is shelled by CAD software to obtain a multi-media diamond structure model composed of an air diamond structure, a resin diamond structure, and an air anti-diamond structure nested with each other. Inject the first medium ε 1 into the air diamond structure in Figure 3, and then inject the second medium ε 2 into the air anti-diamond structure, and after vacuum freeze-drying, it is composed of medium ε 1 , resin and medium ε 2 A Periodically Nested Diamond Structure Containing Three Dielectrics Three Dielectric Coupling Photonic Crystals
实施例4Example 4
附图4是周期性交叉木堆结构多种介质耦合光子晶体。选取两种合适的介质材料(介电常数分别为ε1、ε2),利用快速成型和多步凝胶注模法制备多介质耦合光子晶体。每层的相邻的长柱体分别注入两种不同的介质材料ε1、ε2,上层对应的长柱体和下层对应的长柱体相互连通。所制备的多介质光子晶体可以是包含树脂结构和两种介质的多介质光子晶体,也可以是经过干燥、脱脂和烧结处理后的包含两种陶瓷和空气的纯陶瓷光子晶体。Accompanying drawing 4 is a photonic crystal coupled with multiple media with a periodic cross wood pile structure. Select two suitable dielectric materials (dielectric constants ε 1 , ε 2 ), and use rapid prototyping and multi-step gel injection molding to prepare multi-media coupled photonic crystals. Adjacent long cylinders of each layer are respectively injected with two different dielectric materials ε 1 and ε 2 , and the long cylinders corresponding to the upper layer and the long cylinders corresponding to the lower layer are connected to each other. The prepared multimedia photonic crystal may be a multimedia photonic crystal containing a resin structure and two media, or may be a pure ceramic photonic crystal containing two ceramics and air after drying, degreasing and sintering.
实施例5Example 5
根据实施例1制造多介质耦合光子晶体的方法。附图5中所示的1是第一种介质注浆口;2是连通口,作用是保证第一种介质只能达到设计的结构高度;3、4分别是第一种和第二种介质,5是树脂模型,6是注浆用外壳。具体实施方法为将准备好的第一种介质浆料从1注入,当浆料高度达到2连通口的高度时,多余的浆料会从2流出,此时用橡皮泥将1和2口堵住,从模型顶端将事先准备好的浆料2快速注入。上部的外壳较宽,这个设计的作用是有两个,一是在注入第一种介质浆料时,浆料到达中间高度后,多余的浆料会流向旁边的空隙,最终从2口流出,避免流入上部的结构中;二是从模型顶端注入第二种介质浆料时,浆料会从四周流出,尽量使浆料均匀向下,避免第二种介质浆料集中某一点向下挤压第一种介质,从而引起两种介质相互混合在一起,注浆完成后经固化、冷冻干燥后得到包含树脂结构和两种介质的多介质耦合光子晶体,也可以经过脱脂和烧结处理后的包含两种陶瓷和空气的纯陶瓷光子晶体。The method for manufacturing a multi-media coupling photonic crystal according to
实施例6Example 6
根据实施例3制造多介质耦合光子晶体的方法。附图6中所示的结构是图3结构加上外壳,中间用隔板将金刚石结构和反金刚石结构隔开。首先将第一种介质ε1的浆料注入空气金刚石结构中;然后将第二种介质ε2注入反金刚石结构中,两种介质浆料经固化、冷冻干燥后得到同时包含介质ε1、介质ε2和树脂三种介质的多介质耦合三维光子晶体。The method for manufacturing a multi-media coupling photonic crystal according to
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