CN102516730B - Degradable pearl zipper - Google Patents
Degradable pearl zipper Download PDFInfo
- Publication number
- CN102516730B CN102516730B CN 201110443275 CN201110443275A CN102516730B CN 102516730 B CN102516730 B CN 102516730B CN 201110443275 CN201110443275 CN 201110443275 CN 201110443275 A CN201110443275 A CN 201110443275A CN 102516730 B CN102516730 B CN 102516730B
- Authority
- CN
- China
- Prior art keywords
- parts
- pla
- slide fastener
- better
- pearly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The invention discloses a degradable pearl zipper. The zipper comprises 95 to 105 weight parts of base material and 2.0 to 8.0 weight parts of pearlescent master batch, wherein the base material comprises polylactic acid (PLA) and polyoxymethylene (POM), and the weight ratio of the PLA to the POM is (65-75):30; and the pearlescent master batch comprises PLA and 123 pearl powder, and the weight ratio of the PLA to the 123 pearl powder is (25-35):10. The zipper has a transparent pearl effect and a broad market prospect, also has the degradability, and meets development and environmental protection requirements of zipper industry; meanwhile, various properties of the zipper can also be met.
Description
Technical field
The present invention discloses a kind of slide fastener, particularly a kind of degradable pearly-lustre slide fastener.
Background technology
Slide fastener make people live in common thing, often be used in the clothes, present slide fastener is in the majority with plastic fastener, they are many to be that major ingredient is made with POM.The transparency of POM plastics itself is relatively poor, be difficult to add some special pigment, has hindered the development of slide fastener industry, how to find a kind of plastics both to have the POM chemical property, and transparency plastics have preferably again become the difficult problem of industry.And along with the proposition of environmental protection slogan, how to reduce white pollution, and having become the matter of utmost importance of plastic article industry, the degradation property of POM plastics self is poor, can not satisfy people to the demand of environmental protection.
Summary of the invention
At the above-mentioned POM plastics of mentioning of the prior art as zipper material, the slide fastener non-degradable of its production, and there are not shortcomings such as pearl effect, the invention provides a kind of new degradable pearly-lustre slide fastener, it adopts the PLA of certain proportioning and POM as base-material, and added pearlescent material, and make the slide fastener of producing both have pearl effect, can degrade again.
The technical scheme that the present invention solves its technical problem employing is: a kind of degradable pearly-lustre slide fastener, slide fastener comprises base-material and pearly-lustre Masterbatch, the weight proportion of base-material accounts for 95 parts ~ 105 parts, the weight proportion of pearly-lustre Masterbatch accounts for 2.0 parts ~ 8.0 parts, described base-material comprises PLA and POM, the weight ratio of PLA and POM is 65 ~ 75:30, and described pearly-lustre Masterbatch comprises PLA and 123 pearlescences, and the weight ratio of PLA and 123 pearlescences is 25 ~ 35:10.
The technical scheme that the present invention solves its technical problem employing further comprises:
The weight ratio of described PLA and POM is preferably 70:30.
The weight ratio of described PLA and 123 pearlescences is 30:10.
Described slide fastener also comprises transparent plastics pigment, and transparent plastics pigment accounts for 0 part ~ 1 part of gross weight.
The invention has the beneficial effects as follows: the slide fastener that the present invention produces had both had transparent pearl effect, had degradability again, simultaneously, can also satisfy the various aspects of performance of slide fastener, had vast market prospect, met development and the environmental requirement of slide fastener industry.
The present invention will be further described below in conjunction with embodiment.
Embodiment
Present embodiment is the preferred embodiment for the present invention, and other all its principles are identical with present embodiment or approximate with basic structure, all within protection domain of the present invention.
The present invention is mainly a kind of degradable pearly-lustre slide fastener, and slide fastener mainly comprises base-material and PLA pearly-lustre Masterbatch, and base-material comprises PLA and POM, the weight ratio of PLA and POM is 65 ~ 75:30, the weight ratio of PLA and POM is preferably 70:30, and in the present embodiment, PLA is polylactice acid, it is the biodegradable plastic poly(lactic acid), poly(lactic acid) is also referred to as polylactide, belongs to polyester family, and POM is Polyoxymethylene, be polyoxymethylene, PLA and POM can adopt commercially available product.Pearly-lustre Masterbatch (or being called PLA pearly-lustre Masterbatch) comprises PLA and 123 pearlescences, the weight ratio of PLA and 123 pearlescences is 25 ~ 35:10, the weight ratio of PLA and 123 pearlescences is preferably 30:10, and 123 pearlescences are the Iriodin 123 white pearlescent powder of German MERCK company.In the present embodiment, the weight proportion of base-material in material accounts for 95 parts ~ 105 parts, and the weight proportion of pearly-lustre Masterbatch in material accounts for 2.0 parts ~ 8.0 parts.Among the present invention, can also optionally in material, add transparent plastics pigment, when in material, adding transparent plastics pigment, 0 part ~ 1 part of the shared material gross weight of transparent plastics pigment, can add according to actual needs, in the present embodiment, can also optionally in material, add transparent plastics pigment, when in material, adding transparent plastics pigment, 0 part ~ 1 part of the shared material gross weight of transparent plastics pigment, can add according to actual needs, in the present embodiment, transparent plastics pigment can adopt the transparent plastics pigment of the MACROLEX series that commercially available German LANXESS Energizing Chemistry company produces, specifically select which kind of transparent plastics pigment for use, can be according to the color settings of slide fastener finished product, when the needs slide fastener was yellow, can select model for use was Yellow 3G Gran transparent plastics pigment, when the needs slide fastener is blueness, can select model for use is Blue 3R Gran transparent plastics pigment, and when the needs slide fastener took on a red color, can select model for use was Red A transparent plastics pigment etc.
Below will the present invention will be further described with several specific embodiments:
Embodiment one: in the present embodiment, add 65 parts of PLA, 30 parts of POM, 8.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment two: in the present embodiment, add 66 parts of PLA, 30 parts of POM, 8.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment three: in the present embodiment, add 67 parts of PLA, 30 parts of POM, 8.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment four: in the present embodiment, add 68 parts of PLA, 30 parts of POM, 8.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment five: in the present embodiment, add 69 parts of PLA, 30 parts of POM, 8.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment six: in the present embodiment, add 65 parts of PLA, 30 parts of POM, 7.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment seven: in the present embodiment, add 66 parts of PLA, 30 parts of POM, 7.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment eight: in the present embodiment, add 67 parts of PLA, 30 parts of POM, 7.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment nine: in the present embodiment, add 68 parts of PLA, 30 parts of POM, 7.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment ten: in the present embodiment, add 69 parts of PLA, 30 parts of POM, 7.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 11: in the present embodiment, add 65 parts of PLA, 30 parts of POM, 7.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 12: in the present embodiment, add 66 parts of PLA, 30 parts of POM, 7.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 13: in the present embodiment, add 67 parts of PLA, 30 parts of POM, 7.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 14: in the present embodiment, add 68 parts of PLA, 30 parts of POM, 7.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 15: in the present embodiment, add 69 parts of PLA, 30 parts of POM, 7.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 16: in the present embodiment, add 65 parts of PLA, 30 parts of POM, 6.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 17: in the present embodiment, add 66 parts of PLA, 30 parts of POM, 6.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 18: in the present embodiment, add 67 parts of PLA, 30 parts of POM, 6.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 19: in the present embodiment, add 68 parts of PLA, 30 parts of POM, 6.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 20: in the present embodiment, add 69 parts of PLA, 30 parts of POM, 6.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 21: in the present embodiment, add 65 parts of PLA, 30 parts of POM, 6.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 22: in the present embodiment, add 66 parts of PLA, 30 parts of POM, 6.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 23: in the present embodiment, add 67 parts of PLA, 30 parts of POM, 6.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 24: in the present embodiment, add 68 parts of PLA, 30 parts of POM, 6.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 25: in the present embodiment, add 69 parts of PLA, 30 parts of POM, 6.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 26: in the present embodiment, add 65 parts of PLA, 30 parts of POM, 5.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 27: in the present embodiment, add 66 parts of PLA, 30 parts of POM, 5.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 28: in the present embodiment, add 67 parts of PLA, 30 parts of POM, 5.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 29: in the present embodiment, add 68 parts of PLA, 30 parts of POM, 5.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 30: in the present embodiment, add 69 parts of PLA, 30 parts of POM, 5.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has very strong pearl effect.
Embodiment 31: in the present embodiment, add 65 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has stronger pearl effect.
Embodiment 32: in the present embodiment, add 66 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has stronger pearl effect.
Embodiment 33: in the present embodiment, add 67 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has stronger pearl effect.
Embodiment 34: in the present embodiment, add 68 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has stronger pearl effect.
Embodiment 35: in the present embodiment, add 69 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has stronger pearl effect.
Embodiment 40: in the present embodiment, add 65 parts of PLA, 30 parts of POM, 4.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has general pearl effect.
Embodiment 41: in the present embodiment, add 66 parts of PLA, 30 parts of POM, 4.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has general pearl effect.
Embodiment 42: in the present embodiment, add 67 parts of PLA, 30 parts of POM, 4.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has general pearl effect.
Embodiment 43: in the present embodiment, add 68 parts of PLA, 30 parts of POM, 4.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has general pearl effect.
Embodiment 44: in the present embodiment, add 69 parts of PLA, 30 parts of POM, 4.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has general pearl effect.
Embodiment 45: in the present embodiment, add 65 parts of PLA, 30 parts of POM, 4.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has general pearl effect.
Embodiment 46: in the present embodiment, add 66 parts of PLA, 30 parts of POM, 4.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has general pearl effect.
Embodiment 47: in the present embodiment, add 67 parts of PLA, 30 parts of POM, 4.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has general pearl effect.
Embodiment 48: in the present embodiment, add 68 parts of PLA, 30 parts of POM, 4.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has general pearl effect.
Embodiment 49: in the present embodiment, add 69 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has general pearl effect.
Embodiment 50: in the present embodiment, add 65 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 51: in the present embodiment, add 66 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 52: in the present embodiment, add 67 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 53: in the present embodiment, add 68 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 54: in the present embodiment, add 69 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 55: in the present embodiment, add 65 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 56: in the present embodiment, add 66 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 57: in the present embodiment, add 67 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 58: in the present embodiment, add 68 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 59: in the present embodiment, add 69 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 60: in the present embodiment, add 65 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 61: in the present embodiment, add 66 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 62: in the present embodiment, add 67 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 63: in the present embodiment, add 68 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 64: in the present embodiment, add 69 parts of PLA, 30 parts of POM, 3.5 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has soft pearl effect.
Embodiment 65: in the present embodiment, add 65 parts of PLA, 30 parts of POM, 2.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has faint pearl effect.
Embodiment 66: in the present embodiment, add 66 parts of PLA, 30 parts of POM, 2.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has faint pearl effect.
Embodiment 67: in the present embodiment, add 67 parts of PLA, 30 parts of POM, 2.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has faint pearl effect.
Embodiment 68: in the present embodiment, add 68 parts of PLA, 30 parts of POM, 2.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has faint pearl effect.
Embodiment 69: in the present embodiment, add 69 parts of PLA, 30 parts of POM, 2.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has faint pearl effect.
Embodiment 70: in the present embodiment, add 70 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has strong pearl effect.
Embodiment 71: in the present embodiment, add 71 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has strong pearl effect.
Embodiment 72: in the present embodiment, add 72 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has strong pearl effect.
Embodiment 73: in the present embodiment, add 73 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has strong pearl effect.
Embodiment 74: in the present embodiment, add 74 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener demoulding of production is better, and the slide fastener smoothness is better, and has strong pearl effect.
Embodiment 75: in the present embodiment, add 75 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, and 0.1 part of Red A transparent plastics pigment, the slide fastener smoothness of production is better, and has strong pearl effect, but demolding performace begins variation.
Among the embodiment 70 to embodiment 75, adopt 5.0 parts of PLA pearly-lustre Masterbatchs, it has stronger pearl effect, it also can adopt the PLA pearly-lustre Masterbatch as other proportioning numbers among the embodiment one to embodiment 69, and its pearl effect is identical with pearl effect among the embodiment one to embodiment 69.
The slide fastener color of producing according to the proportioning in above-described embodiment is red, during concrete production, can in the said ratio material, add transparent plastics pigment according to actual needs, make slide fastener have special color, the transparent plastics pigment that adds accounts for 0 part ~ 1 part of material gross weight, the transparent plastics specific gravity of pigment that adds is more many, the slide fastener color of producing is more dark, the transparent plastics specific gravity of pigment that adds is more few, the slide fastener color of producing is more shallow, when not adding any transparent plastics pigment, the slide fastener color of producing is white.Repeat no more herein.
Slide fastener is had relatively high expectations to the over-all properties of plastics, need possess higher physical strength, certain chemical solvent resistance energy, certain self-lubricating property.
Embodiment 76: in the present embodiment, add 80 parts of PLA, 20 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, 0.1 part of Red A transparent plastics pigment, the slide fastener of production have strong pearl effect, but the slide fastener smoothness begins variation, is difficult for the demoulding.
Embodiment 77: in the present embodiment, add 90 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, though the pearl effect of product is better, release property is relatively poor, and the slide fastener smoothness is very poor, can not use.
Embodiment 78: in the present embodiment, add 80 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, though the pearl effect of product is better, release property also makes moderate progress than embodiment nine, and the slide fastener smoothness is very poor, can not use.
Embodiment 79: in the present embodiment, add 60 parts of PLA, 30 parts of POM, 5.0 parts of PLA pearly-lustre Masterbatchs according to weight ratio, the pearl effect of product is relatively poor, and is undesirable.
The present invention provides a kind of technology that adopts above-mentioned raw materials to produce slide fastener simultaneously, and concrete technology comprises the steps:
1, get the raw materials ready: PLA and the POM of suitable proportioning number (being PLA and POM proportioning number feasible in above-described embodiment) are fully mixed the formation base-material, 123 pearlescences are fully mixed formation pearly-lustre Masterbatch with PLA, with the pearly-lustre Masterbatch, base-material and transparent plastics pigment (transparent plastics pigment is alternative to be added) mix, form the slide fastener raw material, in the present embodiment, if when directly 123 pearlescences being added in PLA and the POM mixed resin, mixed effect is bad, namely the slide fastener pearl effect of Sheng Chaning is bad, so, in the present embodiment, earlier 123 pearlescences are fully mixed with PLA and form the pearly-lustre Masterbatch, and then mix mutually with PLA and POM mixed resin, thereby can obtain good pearl effect;
2, the model that adopts Wenzhou City dragon brightness machinofacture company limited to produce is that LH123S row microphone machine device carries out zipper fabrication, and the machine parameter during manufacturing is set as follows shown in the table:
Parameter shown in the last table in one hurdle, the left side, is the slide fastener of routine, the parameter setting the when parameter setting when namely the POM slide fastener is produced, one hurdle, the right are produced for the batching among employing the present invention.
The slide fastener that the present invention produces had both had transparent pearl effect, had degradability again, simultaneously, can also satisfy the various aspects of performance of slide fastener, had vast market prospect, met development and the environmental requirement of slide fastener industry.
Claims (4)
1. degradable pearly-lustre slide fastener, it is characterized in that: described slide fastener comprises base-material and pearly-lustre Masterbatch, the weight proportion of base-material accounts for 95 parts ~ 105 parts, the weight proportion of pearly-lustre Masterbatch accounts for 2.0 parts ~ 8.0 parts, described base-material comprises PLA and POM, the weight ratio of PLA and POM is 65 ~ 75:30, and described pearly-lustre Masterbatch comprises PLA and 123 pearlescences, and the weight ratio of PLA and 123 pearlescences is 25 ~ 35:10.
2. degradable pearly-lustre slide fastener according to claim 1, it is characterized in that: the weight ratio of described PLA and POM is preferably 70:30.
3. degradable pearly-lustre slide fastener according to claim 1, it is characterized in that: the weight ratio of described PLA and 123 pearlescences is 30:10.
4. according to claim 1 or 2 or 3 described degradable pearly-lustre slide fasteners, it is characterized in that: described slide fastener also comprises transparent plastics pigment, and transparent plastics pigment accounts for 0 part ~ 1 part of gross weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110443275 CN102516730B (en) | 2011-12-27 | 2011-12-27 | Degradable pearl zipper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110443275 CN102516730B (en) | 2011-12-27 | 2011-12-27 | Degradable pearl zipper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102516730A CN102516730A (en) | 2012-06-27 |
| CN102516730B true CN102516730B (en) | 2013-07-10 |
Family
ID=46287820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110443275 Expired - Fee Related CN102516730B (en) | 2011-12-27 | 2011-12-27 | Degradable pearl zipper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102516730B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109320900B (en) * | 2018-09-11 | 2021-02-19 | 东莞市瑞翔新型材料科技有限公司 | Transparent flash polyformaldehyde POM (polyoxymethylene) zipper tooth, preparation method and zipper |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1701082A (en) * | 2003-05-13 | 2005-11-23 | 纳幕尔杜邦公司 | Toughened polyoxymethylene-poly(lactic acid) compositions |
| JP2010195872A (en) * | 2009-02-23 | 2010-09-09 | Mitsubishi Plastics Inc | Film, stretched film, heat shrinkable film, molded article using the film, stretched film or heat shrinkable film, heat shrinkable label, and container using the molded article or having the label attached thereto |
| CN102181137A (en) * | 2011-03-24 | 2011-09-14 | 山东省意可曼科技有限公司 | High-performance PHAs (polyhydroxyalkanoates)/POM (polyoxymethylene)/PLA (polylactic acid) blending alloy |
-
2011
- 2011-12-27 CN CN 201110443275 patent/CN102516730B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1701082A (en) * | 2003-05-13 | 2005-11-23 | 纳幕尔杜邦公司 | Toughened polyoxymethylene-poly(lactic acid) compositions |
| JP2010195872A (en) * | 2009-02-23 | 2010-09-09 | Mitsubishi Plastics Inc | Film, stretched film, heat shrinkable film, molded article using the film, stretched film or heat shrinkable film, heat shrinkable label, and container using the molded article or having the label attached thereto |
| CN102181137A (en) * | 2011-03-24 | 2011-09-14 | 山东省意可曼科技有限公司 | High-performance PHAs (polyhydroxyalkanoates)/POM (polyoxymethylene)/PLA (polylactic acid) blending alloy |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2010195872A 2010.09.09 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102516730A (en) | 2012-06-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104031344B (en) | The preparation method of decoration bar section moulded by a kind of wood-grain imitating PVC wood | |
| CN101597408B (en) | Composite material capable of replacing ABS and preparation method thereof | |
| CN103073829B (en) | It is material modified and preparation method thereof that one exempts from metallize texture PMMA | |
| CN105237977A (en) | Bamboo fiber reinforced degradable PLA material and preparation method thereof | |
| CN104191772B (en) | A kind of billboard ecological environment-friendly type wood-plastic composite board and preparation method thereof | |
| CN102276964A (en) | Degradable engineering plastic and preparation method thereof | |
| KR20120023589A (en) | A nonmetal material modified thermoplastic resin composite and a method for preparing products using said composite | |
| CN104004300A (en) | Color masterbatch | |
| CN103044861A (en) | Antibacterial polybutylene terephthalate composition and preparation method thereof | |
| CN102532836B (en) | Degradable noctilucent zipper | |
| CN103102607A (en) | Modifier modified hard PVC injection molded piece and its preparation method | |
| CN106589650A (en) | Fine-performance plastic material and preparation method thereof | |
| CN103254546A (en) | ABS color master batch and preparation process thereof | |
| CN102250456A (en) | Antibacterial polylactic acid dinnerware and preparation method thereof | |
| CN103571127A (en) | Modified PC/ABS (Poly Carbonate)/(Acrylonitrile Butadiene Styrene) with marble strip appearance and preparation method thereof | |
| CN104829970A (en) | Mosquito-repelling wood-plastic magnetic floorboard and preparation method thereof | |
| CN102516730B (en) | Degradable pearl zipper | |
| CN104194287A (en) | Modified poly-adipic acid/butylene terephthalate composite material containing coconut shell flour and preparation method thereof | |
| CN104140582A (en) | Non-starchy light-and bio-degradable plastic transparent master batch and preparation method thereof | |
| CN101955611A (en) | Straw powder and polypropylene composite wood-plastic material for injection molding | |
| CN103232640A (en) | Spraying-free aesthetic resin composition with amber effect and preparation method thereof | |
| CN102532796A (en) | Zipper capable of changing color in encountering ultraviolet rays | |
| CN103360683A (en) | Modified polypropylene composite plastic filler and preparation method thereof | |
| CN104761866A (en) | Method for rapidly producing amino molded material | |
| CN104861209A (en) | Environmental-friendly plastic film and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130710 Termination date: 20181227 |