CN102515654A - Formula of high-intensity cement paste - Google Patents

Formula of high-intensity cement paste Download PDF

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Publication number
CN102515654A
CN102515654A CN2012100035389A CN201210003538A CN102515654A CN 102515654 A CN102515654 A CN 102515654A CN 2012100035389 A CN2012100035389 A CN 2012100035389A CN 201210003538 A CN201210003538 A CN 201210003538A CN 102515654 A CN102515654 A CN 102515654A
Authority
CN
China
Prior art keywords
cement
water
intensity
grout
condensation product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012100035389A
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Chinese (zh)
Inventor
李凯琦
刘保金
张世峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henan University of Technology
Shanxi Luan Environmental Energy Development Co Ltd
Original Assignee
Henan University of Technology
Shanxi Luan Environmental Energy Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan University of Technology, Shanxi Luan Environmental Energy Development Co Ltd filed Critical Henan University of Technology
Priority to CN2012100035389A priority Critical patent/CN102515654A/en
Publication of CN102515654A publication Critical patent/CN102515654A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The invention discloses a formula of high-intensity cement paste. According to the formula, the high-intensity cement paste consists of cement, water, high-activity metakaolin, and a sodium polyacrylate or naphthalenesulfonic acid and formaldehyde condensation product water reducing agent, wherein the mass ratio of the cement to the water is 1:(1-0.6); the using amount of the high-activity metakaolin is 5 to 10 percent based on the mass of the cement; and the using amount of the sodium polyacrylate or naphthalenesulfonic acid and formaldehyde condensation product water reducing agent is 0.3 to 0.6 percent based on the mass of the cement. The intensity of the cement paste which is prepared by the technical scheme can reach 15 MPa, and is improved by about 5 percent compared with that of the conventional cement paste under the same condition.

Description

A kind of prescription of high strength cement slurry
Technical field
The present invention relates to a kind of prescription of high strength cement slurry.
Background technology
Grout is most important injecting paste material.Be mainly used in the reinforcing of engineerings such as tunnel, ground, culvert, dam, also be used for fields such as grouting for water-blocking, fluid injection fire-fighting.
Now, the basic recipe of domestic water mud is: cement: water=1:1~0.8.Sometimes, in order to improve the setting rate of grout, add a spot of water glass.Grout solidifies later intensity and is generally about 10MPa.
Mainly contain following two kinds of grout formula techniques at present, a kind of prescription of ortho-water mud is: cement: water=1:1~0.8.Grout solidifies later intensity and is generally 10MPa.
This technological shortcoming is:
The first, the shortcoming of prior art one mainly is that intensity is low.Grout solidifies later intensity and is generally about 10MPa.
The second, the grout calculus rate of prior art for preparing is low, generally has only (the calculus rate of grout is meant the volume of formation cement stone and the ratio of grout volume) about 70%.
Another kind of prior art is water glass-sprayed concrete, claims the biliquid slurry again, and its prescription is:
Cement: water=1:1~0.8, water glass consumption are 3~6% of cement consumption.Grout solidifies later intensity and is generally 10MPa.
This technological shortcoming remains 2 points:
The first, the shortcoming of prior art one mainly is that intensity is low.Grout solidifies later intensity and is generally 10MPa.
The second, the grout calculus rate of prior art for preparing is low, generally has only (the calculus rate of grout is meant the volume of formation cement stone and the ratio of grout volume) about 70%.
Summary of the invention
Technical problem to be solved by this invention is to improve the set strength of grout and the calculus rate that suitably improves grout.
In order to solve the problems of the technologies described above; The present invention provides a kind of prescription of high strength cement slurry; The prescription of said high strength cement slurry is to be made up of cement, water, high-activity metakaolin, ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer, and wherein: the mass ratio of cement and water is 1:1~0.6; The consumption of high-activity metakaolin is 5~10% of a cement quality; The consumption of ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer is 0.3~0.6% of a cement quality.
Beneficial effect of the present invention is:
1, the grout intensity of technical scheme preparation of the present invention can reach 15MPa, under equal conditions, and than the grout intensity raising about 50% of present use.
2, the calculus rate of the grout of technical scheme preparation of the present invention can reach 85%, and under equal conditions, than the grout intensity raising about 15% of present use, the raising rate is 21%.
Below in conjunction with embodiment the present invention is described in further detail.
Embodiment
The present invention provides a kind of prescription of intensity grout, and the prescription of said high strength cement slurry is to be made up of cement, water, high-activity metakaolin, ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer, and wherein: the mass ratio of cement and water is 1:1~0.6; The consumption of high-activity metakaolin is 5~10% of a cement quality; The consumption of ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer is 0.3~0.6% of a cement quality.
The calcium hydroxide reaction that this technological enhanced mechanism produces when mainly being active aluminium sesquioxide and active silica and the hydrated cementitious in the metakaolin generates cement stone ore things such as hydrated calcium silicate and drated calcium aluminate, the set strength of raising grout; Simultaneously, water reducer has lowered the consumption of water, and intensity further improves.
The principle that this technology improves grout calculus rate is that the metakaolin particle is tiny, has certain suspension property, has stoped the sedimentation of cement granules, thereby has improved the calculus rate of grout to a certain extent.
Embodiment 1
The prescription of high strength cement slurry is to be made up of cement, water, high-activity metakaolin, ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer, and wherein: the mass ratio of cement and water is 1:1; The consumption of high-activity metakaolin is 5% of a said cement quality; The consumption of ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer is 0.3% of a said cement quality.
Embodiment 2
The prescription of high strength cement slurry is to be made up of cement, water, high-activity metakaolin, ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer, and wherein: the mass ratio of cement and water is 1:0.7; The consumption of high-activity metakaolin is 8% of a said cement quality; The consumption of ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer is 0.4% of a said cement quality.
Embodiment 3
The prescription of high strength cement slurry is to be made up of cement, water, high-activity metakaolin, ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer, and wherein: the mass ratio of cement and water is 1:0.6; The consumption of high-activity metakaolin is 10% of a said cement quality; The consumption of ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer is 0.6% of a said cement quality.
Embodiment 4
The prescription of high strength cement slurry is to be made up of cement, water, high-activity metakaolin, ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer, and wherein: the mass ratio of cement and water is 1:0.65; The consumption of high-activity metakaolin is 9% of a said cement quality; The consumption of ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer is 0.5% of a said cement quality.
Embodiment 5
The prescription of high strength cement slurry is to be made up of cement, water, high-activity metakaolin, ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer, and wherein: the mass ratio of cement and water is 1:0.9; The consumption of high-activity metakaolin is 5% of a said cement quality; The consumption of ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer is 0.3% of a said cement quality.
Protection scope of the present invention is not limited to the foregoing description, and every conspicuous technology distortion of doing according to know-why of the present invention all falls within protection scope of the present invention.

Claims (1)

1. the prescription of a high strength cement slurry is characterized in that, the prescription of said high strength cement slurry is to be made up of cement, water, high-activity metakaolin, ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer, wherein:
The mass ratio of cement and water is 1:1~0.6;
The consumption of high-activity metakaolin is 5~10% of a cement quality;
The consumption of ZX-I or naphthalene sulfonic acidformaldehyde condensation product water reducer is 0.3~0.6% of a cement quality.
CN2012100035389A 2012-01-09 2012-01-09 Formula of high-intensity cement paste Pending CN102515654A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012100035389A CN102515654A (en) 2012-01-09 2012-01-09 Formula of high-intensity cement paste

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012100035389A CN102515654A (en) 2012-01-09 2012-01-09 Formula of high-intensity cement paste

Publications (1)

Publication Number Publication Date
CN102515654A true CN102515654A (en) 2012-06-27

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Family Applications (1)

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CN2012100035389A Pending CN102515654A (en) 2012-01-09 2012-01-09 Formula of high-intensity cement paste

Country Status (1)

Country Link
CN (1) CN102515654A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105110717A (en) * 2015-07-20 2015-12-02 上海宝田新型建材有限公司 Foundation reinforcement material, preparation method and application thereof
CN106630806A (en) * 2017-01-06 2017-05-10 中国海洋石油总公司 Cement mixed component and application thereof
CN107459322A (en) * 2017-09-23 2017-12-12 江苏昶浩建材有限公司 A kind of extended slurry
CN107459323A (en) * 2017-09-23 2017-12-12 江苏昶浩建材有限公司 A kind of building building cement slurry
CN107473686A (en) * 2017-09-23 2017-12-15 江苏昶浩建材有限公司 A kind of high-strength building cement mortar

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100697221B1 (en) * 2005-08-29 2007-03-22 한국건설기술연구원 Composition for Shotcrete Having Excellent Performance Using Metakaolin

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100697221B1 (en) * 2005-08-29 2007-03-22 한국건설기술연구원 Composition for Shotcrete Having Excellent Performance Using Metakaolin

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105110717A (en) * 2015-07-20 2015-12-02 上海宝田新型建材有限公司 Foundation reinforcement material, preparation method and application thereof
CN105110717B (en) * 2015-07-20 2017-11-17 上海宝田新型建材有限公司 A kind of foundation stabilization material and its preparation method and application
CN106630806A (en) * 2017-01-06 2017-05-10 中国海洋石油总公司 Cement mixed component and application thereof
CN106630806B (en) * 2017-01-06 2019-04-26 中国海洋石油集团有限公司 A kind of cement mixing component and its application
CN107459322A (en) * 2017-09-23 2017-12-12 江苏昶浩建材有限公司 A kind of extended slurry
CN107459323A (en) * 2017-09-23 2017-12-12 江苏昶浩建材有限公司 A kind of building building cement slurry
CN107473686A (en) * 2017-09-23 2017-12-15 江苏昶浩建材有限公司 A kind of high-strength building cement mortar

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Application publication date: 20120627