CN102514051A - Basalt continuous fiber reinforced bamboo-wood composite material and method for manufacturing same - Google Patents
Basalt continuous fiber reinforced bamboo-wood composite material and method for manufacturing same Download PDFInfo
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- CN102514051A CN102514051A CN2011104330469A CN201110433046A CN102514051A CN 102514051 A CN102514051 A CN 102514051A CN 2011104330469 A CN2011104330469 A CN 2011104330469A CN 201110433046 A CN201110433046 A CN 201110433046A CN 102514051 A CN102514051 A CN 102514051A
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- bamboo
- fiber reinforced
- basalt
- composite material
- wood composite
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- 239000002023 wood Substances 0.000 title claims abstract description 39
- 239000000835 fiber Substances 0.000 title claims abstract description 36
- 239000002131 composite material Substances 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims description 7
- 229920002748 Basalt fiber Polymers 0.000 claims abstract description 17
- 239000000853 adhesive Substances 0.000 claims abstract description 11
- 230000001070 adhesive effect Effects 0.000 claims abstract description 11
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005011 phenolic resin Substances 0.000 claims abstract description 7
- 239000003822 epoxy resin Substances 0.000 claims abstract description 6
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 6
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 6
- 229920002635 polyurethane Polymers 0.000 claims abstract description 5
- 239000004814 polyurethane Substances 0.000 claims abstract description 5
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 55
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 55
- 241001330002 Bambuseae Species 0.000 claims description 55
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 55
- 239000011425 bamboo Substances 0.000 claims description 55
- 229920005989 resin Polymers 0.000 claims description 33
- 239000011347 resin Substances 0.000 claims description 33
- 238000004026 adhesive bonding Methods 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 4
- 238000004381 surface treatment Methods 0.000 claims description 4
- 229920005749 polyurethane resin Polymers 0.000 claims description 2
- 239000006087 Silane Coupling Agent Substances 0.000 claims 2
- PXJSQKRFSPUUEX-UHFFFAOYSA-N OC1C=CC=C(O)C1=O Chemical compound OC1C=CC=C(O)C1=O PXJSQKRFSPUUEX-UHFFFAOYSA-N 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract description 7
- 229910000077 silane Inorganic materials 0.000 abstract description 7
- 239000012779 reinforcing material Substances 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 239000007822 coupling agent Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 description 10
- 101710107464 Probable pyruvate, phosphate dikinase regulatory protein, chloroplastic Proteins 0.000 description 7
- 238000013459 approach Methods 0.000 description 7
- 239000003292 glue Substances 0.000 description 5
- 230000002708 enhancing effect Effects 0.000 description 4
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 229920006387 Vinylite Polymers 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011151 fibre-reinforced plastic Substances 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 235000018783 Dacrycarpus dacrydioides Nutrition 0.000 description 1
- 244000288671 Dacrycarpus dacrydioides Species 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920013657 polymer matrix composite Polymers 0.000 description 1
- 239000011160 polymer matrix composite Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
Landscapes
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
本发明公开了一种玄武岩连续纤维增强竹材-木材复合材料及其制造方法，以玄武岩纤维为增强材料，以含硅烷类化学组成成分的化学物质为偶联剂，以聚氨酯、间苯二酚、酚醛树脂、环氧树脂等为胶粘剂，制造出玄武岩连续纤维增强竹材-木材复合材料，物理力学性能能达到日本农林集成材标准JAS1152和美国纤维增强结构用集成材AC280所规定的相关性能指标的要求。The invention discloses a basalt continuous fiber reinforced bamboo-wood composite material and a manufacturing method thereof. Basalt fiber is used as a reinforcing material, a chemical substance containing silane chemical components is used as a coupling agent, and polyurethane, resorcinol, Phenolic resin, epoxy resin, etc. are used as adhesives to manufacture basalt continuous fiber reinforced bamboo-wood composite materials. The physical and mechanical properties can meet the requirements of the relevant performance indicators specified in the Japanese agricultural and forestry glulam standard JAS1152 and the American fiber-reinforced structural glulam AC280. .
Description
Technical field
The present invention relates to a kind of basalt continuous fiber and strengthen bamboo wood-Wood composite material and manufacturing approach thereof.
Background technology
Fiber-reinforced resin (Fiber-reinforced polymer is called for short FRP) is to be the polymer matrix composites of reinforcing material with the fiber.FRP has the very high rigidity and the ratio of strength to weight.Compare with traditional structural material, FRP has good acid and alkali-resistance, decay resistance, in civilian installation, has obtained using more and more.Compare with glass fibre, basalt continuous fiber (Basalt fiber reinforced polymer is called for short BFRP) has excellent more physical property and the corrosion resistance of Geng Gao.
The fiber reinforcement wood composites is the advanced person's of function admirable a wooden engineered composite material, and composite combines the advantage of timber and fortifying fibre.Because fortifying fibre has higher strength and stiffness than timber, therefore, they can be used as reinforcing material and apply to traditional composite wooden material.Utilization reasonable structural design enhancement engineering composite wooden material is with showing good performance.Can also overcome the weak point of glass fibre and carbon fiber etc. traditionally in addition.And the price of basalt continuous fiber is suitable with glass fibre, is lower than carbon fiber, makes high-performance composite materials become possibility in the popularization of practical application.
Timber and BFRP are the materials of two kinds of different in kinds, and both differ greatly because of wood property, and glue performance is poor, and be not durable, situation such as peeling off appears in cementing layer easily, cracking.Also carried out the research of related fields both at home and abroad, but the result is desirable not to the utmost.
Bamboo wood is an inhomogeneous structure, and to bamboo spring face, density reduces gradually from bamboo strip, and elastic modelling quantity reduces gradually, shows the characteristic of the FGM of each item physical and mechanical property gradual change.The average tensile strength of bamboo wood is 200MPa, approximately is 2 times of timber, and strength character is between bamboo wood and BFRP; The performance of bamboo strip and BFRP is comparatively approaching; And the performance of bamboo spring face and timber is comparatively approaching; Bamboo wood can reduce the interfacial stress that different materials glues together in the composite as the natural buffered property material between timber and BFRP, has increased substantially the glue performance and the endurance quality of BFRP/ bamboo wood/Wood composite material.The exploitation of BFRP/ bamboo wood/Wood composite material; Not only can reduce the sectional dimension and the weight of structural wood; Improve the pliability and the durability of product; And will make low-quality timber and fast growing wood be used for becoming on the infrastructure product possibility, thereby opened up new approach for the efficient utilization of the large-area artificial forest of China, scondary forest density is less, intensity is lower, material is relatively poor timber resources.
Summary of the invention
The purpose of this invention is to provide the basalt continuous fibers that physical property is good, cost performance is high such as a kind of ratio of strength to weight is high, durability is strong, high temperature resistant and strengthen bamboo wood-Wood composite material and manufacturing approach thereof.
The objective of the invention is to realize through following technical scheme:
Be provided with bamboo board between basalt continuous fiber enhancing bamboo wood-Wood composite material timber of the present invention and the basalt fibre enhancing resin plate, three kinds of sheet materials are glued together.
The manufacturing approach of above-mentioned basalt continuous fibre enhancement resin composite material of the present invention comprises step:
A, use silane coupler to carry out surface treatment to said bamboo board.
B, the basalt fibre that will handle strengthen resin plate and bamboo board and timber plate and stick with glue the agent gummed.
Technical scheme by the invention described above provides can be found out; Basalt fibre of the present invention strengthens bamboo wood-Wood composite material and manufacturing approach thereof; Because as the function padded coaming, each item Main physical mechanical property of the basalt continuous fibre enhancement resin bamboo wood-Wood composite material that produces all can reach the requirement of correlation standard with bamboo board.
The specific embodiment
Basalt continuous fiber of the present invention strengthens bamboo wood-Wood composite material, and its preferable specific embodiment is:
Comprise that timber plate, basalt fibre strengthen resin plate, be provided with bamboo board between said timber plate and the basalt fibre enhancing resin plate, three ply board is gluing and press together.
Said timber plate and basalt fibre strengthen between the resin plate and are provided with bamboo board, and three ply board is gluing and press together.
The matrix that described basalt fibre strengthens resin plate is resinoids such as vinylite, epoxy resin, phenolic resins resorcinol-phenolic resin, polyurethane resin.
Above-mentioned basalt continuous fiber of the present invention strengthens the manufacturing approach of bamboo wood-Wood composite material, and its preferable specific embodiment comprises step:
A, use silane coupler to carry out surface treatment to said bamboo board.
B, the basalt fibre that will handle strengthen resin plate and bamboo board and timber plate and stick with glue the agent gummed.
In the described steps A, at first said basalt fibre enhancing resin plate and bamboo board are carried out the sanding processing, the bamboo board of with said silane coupler sanding being handled is then handled.
Among the described step B, at first strengthen the gluing in order assembly of resin plate with plank with through bamboo board, the basalt fibre of covering with paint, lacquer, colour wash, etc., bamboo strip and resin plate are glued, and yellow bamboo face and timber plate are glued, then said assembly are carried out compression set.
Described adhesive is the general HB709 of nation monocomponent polyurethane adhesive.
Specific embodiment:
Comprise raw material: timber, basalt continuous fiber strengthen various resin plates, bamboo board, adhesive, silane coupler etc.
The matrix of basalt continuous fibre enhancement resin plate is vinylite, polyurethane, resorcinol, phenolic resins, epoxy resin etc.;
Bamboo board is that various bamboo processing such as mao bamboon form;
Adhesive is adhesives such as polyurethane, resorcinol, phenolic resins, epoxy resin;
Silane coupler is used to promote basalt continuous fiber to combine with adhesive with resin and surf green surface.
Main implementation step:
Step 1, said basalt continuous fibre enhancement resin plate and bamboo wood surface are carried out sanding, apply surface treatments such as silane coupler.
Step 2, the material that will handle carry out assembly, gluing, compression set.
In the described step 1, at first said basalt continuous fibre enhancement resin plate and bamboo board are carried out the sanding processing; The bamboo clappers of with said coupling agent sanding being handled is then handled.
In the described step 2; At first with timber with through the bamboo board covered with paint, lacquer, colour wash, etc., basalt continuous fibre enhancement resin plate assembly in order; Bamboo board is between wood plank and basalt continuous fibre enhancement resin plate, and wherein bamboo strip and resin plate are glued, and yellow bamboo face and kahikatea plate are glued; Said assembly is carried out compression set, and the basalt continuous fiber that needing to obtain strengthens bamboo wood-Wood composite material.
Table 4 prior art and technical products performance comparison of the present invention
Can be found out by above-mentioned comparison: the physical and mechanical property of basalt continuous fibre enhancement resin/bamboo wood/Wood composite material all is superior to fiber-reinforced resin/Wood composite material that existing research obtains, and the ratio of strength to weight and cost performance are higher.
The present invention is reinforcing material with the basalt continuous fiber; Chemical substance with siliceous alkanes chemical composition is a coupling agent; With various resins is that the basalt continuous fibre enhancement resin of matrix manufacturing is a reinforcing material; As the function padded coaming, each item Main physical mechanical property of the basalt continuous fibre enhancement resin/bamboo wood that produces/Wood composite material all reaches Japanese agricultural integrated timber standard JAS1152 and the U.S.'s fiber reinforcing texture correlated performance index with integrated timber AC 280 defineds with bamboo board.The above; Be merely the preferable specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, any technical staff who is familiar with the present technique field is in the technical scope that the present invention discloses; The variation that can expect easily or replacement all should be encompassed within protection scope of the present invention.
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104330469A CN102514051A (en) | 2011-12-21 | 2011-12-21 | Basalt continuous fiber reinforced bamboo-wood composite material and method for manufacturing same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104330469A CN102514051A (en) | 2011-12-21 | 2011-12-21 | Basalt continuous fiber reinforced bamboo-wood composite material and method for manufacturing same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102514051A true CN102514051A (en) | 2012-06-27 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104330469A Pending CN102514051A (en) | 2011-12-21 | 2011-12-21 | Basalt continuous fiber reinforced bamboo-wood composite material and method for manufacturing same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102514051A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104493918A (en) * | 2014-12-12 | 2015-04-08 | 北京林业大学 | Manufacturing method of prefabricated bending integrated materials |
| CN104772798A (en) * | 2015-04-08 | 2015-07-15 | 北京林业大学 | Laminated wood used for prestress FRP (Fiber Reinforce Plastic) reinforced bamboo wood structure and manufacture method thereof |
| CN104806871A (en) * | 2015-04-08 | 2015-07-29 | 北京林业大学 | Basalt type continuous fiber coiled and reinforced bamboo-wood combined pipe |
| CN110605770A (en) * | 2019-08-16 | 2019-12-24 | 广东海鹏竹纤维新材料科技有限公司 | Fiber-woven bamboo material and rubber-coiled combined sleeper material |
| CN110728078A (en) * | 2019-11-14 | 2020-01-24 | 吉林大学 | Method for predicting mechanical property of bonding structure in full-service temperature interval based on chemical characteristics of adhesive |
| CN114059720A (en) * | 2021-11-30 | 2022-02-18 | 东北大学 | Preparation method of basalt fiber toughened bamboo reinforcement |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06297647A (en) * | 1993-04-19 | 1994-10-25 | Teijin Ltd | Continuous fiber-reinforced composite material |
| CN101235152A (en) * | 2007-06-13 | 2008-08-06 | 北京林业大学 | Basalt continuous fiber reinforced resin composite material and manufacturing method thereof |
| CN201501017U (en) * | 2009-09-24 | 2010-06-09 | 徐州市富祥木业有限公司 | Basalt continuous fiber reinforced wood material |
| CN101906250A (en) * | 2010-08-13 | 2010-12-08 | 东南大学 | Basalt fiber reinforced wood-plastic composite material and preparation method thereof |
| CN101234503B (en) * | 2007-06-13 | 2011-05-25 | 北京林业大学 | Basalt continuous fiber reinforced wood material and manufacturing method thereof |
-
2011
- 2011-12-21 CN CN2011104330469A patent/CN102514051A/en active Pending
Patent Citations (5)
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|---|---|---|---|---|
| JPH06297647A (en) * | 1993-04-19 | 1994-10-25 | Teijin Ltd | Continuous fiber-reinforced composite material |
| CN101235152A (en) * | 2007-06-13 | 2008-08-06 | 北京林业大学 | Basalt continuous fiber reinforced resin composite material and manufacturing method thereof |
| CN101234503B (en) * | 2007-06-13 | 2011-05-25 | 北京林业大学 | Basalt continuous fiber reinforced wood material and manufacturing method thereof |
| CN201501017U (en) * | 2009-09-24 | 2010-06-09 | 徐州市富祥木业有限公司 | Basalt continuous fiber reinforced wood material |
| CN101906250A (en) * | 2010-08-13 | 2010-12-08 | 东南大学 | Basalt fiber reinforced wood-plastic composite material and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李龙: "玄武岩纤维/竹材/木材复合材料胶合工艺技术研究", 《北京林业大学硕士论文》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104493918A (en) * | 2014-12-12 | 2015-04-08 | 北京林业大学 | Manufacturing method of prefabricated bending integrated materials |
| CN104772798A (en) * | 2015-04-08 | 2015-07-15 | 北京林业大学 | Laminated wood used for prestress FRP (Fiber Reinforce Plastic) reinforced bamboo wood structure and manufacture method thereof |
| CN104806871A (en) * | 2015-04-08 | 2015-07-29 | 北京林业大学 | Basalt type continuous fiber coiled and reinforced bamboo-wood combined pipe |
| CN110605770A (en) * | 2019-08-16 | 2019-12-24 | 广东海鹏竹纤维新材料科技有限公司 | Fiber-woven bamboo material and rubber-coiled combined sleeper material |
| CN110728078A (en) * | 2019-11-14 | 2020-01-24 | 吉林大学 | Method for predicting mechanical property of bonding structure in full-service temperature interval based on chemical characteristics of adhesive |
| CN110728078B (en) * | 2019-11-14 | 2022-11-25 | 吉林大学 | Method for predicting mechanical property of bonding structure in full-service temperature interval based on chemical characteristics of adhesive |
| CN114059720A (en) * | 2021-11-30 | 2022-02-18 | 东北大学 | Preparation method of basalt fiber toughened bamboo reinforcement |
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Application publication date: 20120627 |