CN102503304A - Flame-retardant polymer cement waterproof mortar - Google Patents
Flame-retardant polymer cement waterproof mortar Download PDFInfo
- Publication number
- CN102503304A CN102503304A CN2011103322925A CN201110332292A CN102503304A CN 102503304 A CN102503304 A CN 102503304A CN 2011103322925 A CN2011103322925 A CN 2011103322925A CN 201110332292 A CN201110332292 A CN 201110332292A CN 102503304 A CN102503304 A CN 102503304A
- Authority
- CN
- China
- Prior art keywords
- flame
- waterproof mortar
- cement waterproof
- proof type
- ordinary portland
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004570 mortar (masonry) Substances 0.000 title claims abstract description 16
- 239000003063 flame retardant Substances 0.000 title claims abstract description 13
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 9
- 239000011414 polymer cement Substances 0.000 title abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000000843 powder Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011398 Portland cement Substances 0.000 claims abstract description 13
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 13
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 22
- 239000011344 liquid material Substances 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical compound CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 claims description 14
- 239000004568 cement Substances 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- 150000005846 sugar alcohols Polymers 0.000 claims description 9
- 239000004576 sand Substances 0.000 claims description 8
- 229920002678 cellulose Polymers 0.000 claims description 7
- 239000001913 cellulose Substances 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 238000006277 sulfonation reaction Methods 0.000 claims description 3
- 230000007704 transition Effects 0.000 claims description 3
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 2
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 2
- 229920005646 polycarboxylate Polymers 0.000 claims description 2
- 238000010276 construction Methods 0.000 abstract description 7
- 230000002349 favourable effect Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000004078 waterproofing Methods 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract 2
- 239000002994 raw material Substances 0.000 abstract 2
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000006004 Quartz sand Substances 0.000 abstract 1
- 229920003086 cellulose ether Polymers 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 description 12
- 238000001514 detection method Methods 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920005570 flexible polymer Polymers 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000004523 agglutinating effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
Abstract
The invention relates to a flame-retardant polymer cement waterproof mortar which comprises liquid and powder in a weight ratio of 1.0:(3.5-4.5). The liquid comprises the following raw materials in percentage by weight: 50-60% of styrene-acrylate emulsion, 0.10-0.20% of preservative, 0.20-0.30% of dispersant, 0.10-0.20% of defoaming agent and 40-50% of water. The powder comprises the following raw materials in percentage by weight: 40-45% of ordinary Portland cement, 50-55% of quartz sand, 0.02-0.05% of cellulose ether, 0.4-0.5% of water reducing agent and 1.0-3.0% of flame retardant. The flame-retardant polymer cement waterproof mortar can be used for waterproof and moistureproof treatment, effectively solves the problem of waterproofing on the building waterisde or landside, has the advantages of favorable flame retardancy and high binding firmness, is simple and convenient for production, and has favorable flame retardancy and waterproof property when the construction thickness is 1-2mm.
Description
Technical field
The present invention relates to a kind of material of construction, be specially a kind of flame-proof type polyalcohol cement waterproof mortars such as toilet, bathroom, kitchen, balcony, exterior wall that are widely used in.
Background technology
In recent years, China is because the fire that material of construction causes takes place again and again, and particularly wildfires such as CCTV building, the Olympic Sports Center, Jinan, the soldier of Beijing University pang arena and Taiyuan Iron and Steel Co. factory building have caused the great attention of responsible departments of the government.
The Fire-Fighting Bureau under the Ministry of Public Security organizes units concerned such as Tianjin Fire Fighting Inst., Ministry of Public Security, Ministry of Public Security Sichuan fire-fighting Research Institute, to " Code for fire protection design of buildings " (GB50016-2006) and " Code for fire protection design of high rise buildings " (GB50045-95) integrate revision.A few days ago, revised " Code for fire protection design of buildings " accomplished exposure draft, declaration soon.
The combustionproperty of the most water-proof materials of China does not all reach the B2 level at present, in the country or industry standard of all existing water-proof materials, does not have the requirement of water-proof material flame retardant properties yet, and country does not have the TP and the standard of water-proof material fire resistance yet.Therefore, wouldn't list the combustionproperty of waterproof layer in this standard at present.Can't carry out even listed in also, lack operability.Also do not have now alternative water-proof material not only to possess the combustionproperty of clause but also can satisfy the market requirement of flood tide.After the enforcement, will be in roofworks does not have the selectable awkward condition of water-proof material that meet the specifications requires.Suggestion accelerates to formulate the fire resistance TP and the standard of relevant water-proof material immediately, and then lists this standard in.
In at all levels in the roofworks, both comprised waterproof layer, thermal insulation layer, bearing stratum, also comprised at a distance from vapour layer, sticker and various accessory.Roofing functional requirement waterproof layer must have favorable extensibility, flexibility and weather resistance.Therefore, all to be made up of non-fire material be unpractical to the material of each level of roofing.But the combination through non-fire material and combustible matl can constitute non-combustible Roof system.
Summary of the invention
In order to solve above-mentioned deficiency of the prior art, the present invention provides a kind of flame-proof type polyalcohol cement waterproof mortar.This polymer cement waterproof mortar not only can effectively solve the waterproof problem of construction work upstream face or back side; And has bonding firmly; Characteristics such as good flame retardation effect, production is simple, convenient, investment is little, and construction thickness all has excellent waterproof and flame retardant properties between 1mm～2mm.
A kind of flexible polymer cement waterproofing mortar provided by the invention comprises liquid material component and powder component, is 1: 3.5～4.5 in both ratios of weight ratio.
Wherein liquid material component comprises by weight percentage:
The powder component comprises by weight percentage:
Said ordinary Portland cement label is No. 42.5 ordinary Portland cements or 42.5R ordinary Portland cement, and said silica sand is 80 orders～120 order silica sands.
Said ether of cellulose is hydroxyethylmethyl-cellulose ether or hydroxypropyl methyl cellulose ether, and viscosity is at 10000mPa.s～40000mPa.s.The fire retardant of telling is TDE or Marinco H.
Said water reducer is sulfonation ultrapas high efficiency water reducing agent or polycarboxylate water-reducer, and said skimmer is MO or silicone antifoam agent, and the dispersion agent of telling is a ZX-I salt dispersion agent.
Said fourth propyl benzene emulsion second-order transition temperature is more than-8 ℃.
Adopt flame-proof type polyalcohol cement waterproof mortar provided by the invention not only can effectively solve the waterproof problem of construction work upstream face or back side; And has bonding firmly; Characteristics such as good flame retardation effect, production is simple, convenient, investment is little, and construction thickness all has excellent waterproof and flame retardant properties between 1mm～2mm.
Embodiment
For further setting forth the present invention, provide embodiment below and explain.
In the present invention, said ordinary Portland cement label is No. 42.5 ordinary Portland cements, and said silica sand is 80 orders～120 order silica sands.
Said ether of cellulose is a hydroxyethylmethyl-cellulose ether, and viscosity is at 40000mPa.s.
Said water reducer is a sulfonation ultrapas high efficiency water reducing agent, and said fire retardant is TDE and Marinco H, and said skimmer is mineral oil antifoam agent and silicone antifoam agent, and the dispersion agent of telling is a ZX-I salt dispersion agent.
Said propyl benzene emulsion second-order transition temperature is between 25 ℃～-25 ℃.
Based on above-mentioned scope, first embodiment that the present invention provides, the concrete weight proportion of each component is following:
1) liquid material part
Propyl benzene emulsion 55%;
Sanitas 0.2%;
ZX-I dipersant 0.3%;
Mineral oil antifoam agent 0.2%;
Water 44.2%;
2) powder part:
Ordinary Portland cement 45.00%;
Silica sand 53.90%;
Ether of cellulose 0.10%;
Water reducer 0.20%;
Marinco H 2%;
3) weight proportion of each component:
Liquid material: powder=1: 4
Based on above-mentioned scope, second embodiment that the present invention provides, the concrete weight proportion of each component is following:
1) liquid material part
Propyl benzene emulsion 50%;
Sanitas 0.2%;
ZX-I dipersant 0.3%;
Mineral oil antifoam agent 0.1%;
Water 49.40%;
2) powder part:
Ordinary Portland cement 43.70%;
Silica sand 55.00%;
Ether of cellulose 0.10%;
Water reducer 0.20%;
Marinco H 1%;
3) weight proportion of each component:
Liquid material: powder=1: 4.5
Based on above-mentioned scope, the 3rd embodiment that the present invention provides, the concrete weight proportion of each component is following:
1) liquid material part
Propyl benzene emulsion 59%;
Sanitas 0.1%;
ZX-I dipersant 0.2%;
Silicone antifoam agent 0.2%;
Water 40.50%;
2) powder part:
Ordinary Portland cement 43.70%;
Silica sand 55%;
Ether of cellulose 0.10%;
Water reducer 0.20%;
TDE 2%;
3) weight proportion of each component:
Liquid material: powder=1: 3.5
Based on above-mentioned scope, the 4th embodiment that the present invention provides, the concrete weight proportion of each component is following:
1) liquid material part
Propyl benzene emulsion 50%;
Sanitas 0.2%;
ZX-I dipersant 0.2%;
Silicone antifoam agent 0.1%;
Water 49.50%;
2) powder part:
Ordinary Portland cement 45%;
Silica sand 51.70%;
Ether of cellulose 0.10%;
Water reducer 0.20%;
TDE 3%;
3) weight proportion of each component:
Liquid material: powder=1: 4.5
Testing method of the present invention:
1, solids content, kiln are seen, cohesive strength, impervious testing method detect according to the detection method among the Q/SY YHF012-2010 " polymer-modified cement waterproof mortar ".
2, the oxygen index testing method detects according to detection method among the GB/T 2406.2-2009 " plastics are measured burning behavior with oxygen index method ".
The above-mentioned flexible polymer cement waterproofing mortar that the present invention provides, example detection result is following:
Visible by last table data contrast, the overall flame retardant resistance of emulsion amount affects in the liquid material, and selection of fire retardant also is the major cause that influences flame retardant resistance.The ratio of cement and silica sand also can influence impervious and the agglutinating performance in the powder.Substantially, there are very big relation the ratio of liquid material and powder and the surface drying time of doing solid work.In sum, reach the optimum performance of this product, proportionlity between must controlling.
Claims (5)
1. a flame-proof type polyalcohol cement waterproof mortar comprises liquid material component and powder component, in weight ratio, and liquid material component: powder component=1: 3.5～4.5;
Wherein by weight percentage, liquid material component comprises:
By weight percentage, the powder component comprises:
2. a kind of flame-proof type polyalcohol cement waterproof mortar according to claim 1; It is characterized in that: said ordinary Portland cement label is No. 42.5 ordinary Portland cements or 42.5R ordinary Portland cement, and said silica sand is 80 orders～120 order silica sands.
3. a kind of flame-proof type polyalcohol cement waterproof mortar according to claim 1, it is characterized in that: said ether of cellulose is hydroxyethylmethyl-cellulose ether or hydroxypropyl methyl cellulose ether, and viscosity is at 10000mPa.s～40000mPa.s; The fire retardant of telling is TDE or Marinco H.
4. a kind of flame-proof type polyalcohol cement waterproof mortar according to claim 1; It is characterized in that: said water reducer is sulfonation ultrapas high efficiency water reducing agent or polycarboxylate water-reducer; Said skimmer is MO or silicone antifoam agent, and the dispersion agent of telling is a ZX-I salt dispersion agent.
5. a kind of flame-proof type polyalcohol cement waterproof mortar according to claim 1 is characterized in that: said propyl benzene emulsion second-order transition temperature is more than-8 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110332292.5A CN102503304B (en) | 2011-10-27 | 2011-10-27 | Flame-retardant polymer cement waterproof mortar |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110332292.5A CN102503304B (en) | 2011-10-27 | 2011-10-27 | Flame-retardant polymer cement waterproof mortar |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102503304A true CN102503304A (en) | 2012-06-20 |
| CN102503304B CN102503304B (en) | 2015-05-20 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110332292.5A Active CN102503304B (en) | 2011-10-27 | 2011-10-27 | Flame-retardant polymer cement waterproof mortar |
Country Status (1)
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102976698A (en) * | 2012-09-29 | 2013-03-20 | 北京东方雨虹防水技术股份有限公司 | Flexible spray coating closed material for mine |
| CN103146309A (en) * | 2013-03-05 | 2013-06-12 | 广东龙马化学有限公司 | Vitreous tile adhesive |
| CN103232208A (en) * | 2013-04-17 | 2013-08-07 | 徐州卧牛山新型防水材料有限公司 | Flame-retardant waterproof material and preparation method thereof |
| CN104496367A (en) * | 2014-12-05 | 2015-04-08 | 江苏格雷特复合材料有限公司 | Preparation method of waterproof material |
| CN104496364A (en) * | 2014-12-05 | 2015-04-08 | 江苏格雷特复合材料有限公司 | Preparation method of waterproof material |
| CN105198323A (en) * | 2015-10-27 | 2015-12-30 | 北京东方雨虹防水技术股份有限公司 | Polymer-cement waterproof coating with high elongation and high strength |
| CN105565729A (en) * | 2015-12-30 | 2016-05-11 | 王璐 | Durable flame retardant fiber material for construction |
| CN106495620A (en) * | 2016-11-29 | 2017-03-15 | 安徽美琳建筑材料有限公司 | A kind of building water-proof paint |
| CN107555918A (en) * | 2017-08-21 | 2018-01-09 | 北京大津硅藻新材料股份有限公司 | A kind of polymer cement mortar and preparation method thereof and construction method |
| CN108516729A (en) * | 2018-03-07 | 2018-09-11 | 上海嘉宝莉建筑节能科技有限公司 | Polymer matrix plastering glue and preparation method thereof |
| CN109293315A (en) * | 2018-11-28 | 2019-02-01 | 华砂砂浆有限责任公司 | A kind of Polymer cement materials and preparation method thereof |
| CN113980530A (en) * | 2021-12-16 | 2022-01-28 | 河南兴安新型建筑材料有限公司 | Nano-reinforced ultrathin high-hardness organic-inorganic composite coating and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102976698A (en) * | 2012-09-29 | 2013-03-20 | 北京东方雨虹防水技术股份有限公司 | Flexible spray coating closed material for mine |
| CN103146309A (en) * | 2013-03-05 | 2013-06-12 | 广东龙马化学有限公司 | Vitreous tile adhesive |
| CN103232208A (en) * | 2013-04-17 | 2013-08-07 | 徐州卧牛山新型防水材料有限公司 | Flame-retardant waterproof material and preparation method thereof |
| CN103232208B (en) * | 2013-04-17 | 2014-12-17 | 徐州卧牛山新型防水材料有限公司 | Flame-retardant waterproof material and preparation method thereof |
| CN104496367A (en) * | 2014-12-05 | 2015-04-08 | 江苏格雷特复合材料有限公司 | Preparation method of waterproof material |
| CN104496364A (en) * | 2014-12-05 | 2015-04-08 | 江苏格雷特复合材料有限公司 | Preparation method of waterproof material |
| CN105198323A (en) * | 2015-10-27 | 2015-12-30 | 北京东方雨虹防水技术股份有限公司 | Polymer-cement waterproof coating with high elongation and high strength |
| CN105565729A (en) * | 2015-12-30 | 2016-05-11 | 王璐 | Durable flame retardant fiber material for construction |
| CN106495620A (en) * | 2016-11-29 | 2017-03-15 | 安徽美琳建筑材料有限公司 | A kind of building water-proof paint |
| CN107555918A (en) * | 2017-08-21 | 2018-01-09 | 北京大津硅藻新材料股份有限公司 | A kind of polymer cement mortar and preparation method thereof and construction method |
| CN108516729A (en) * | 2018-03-07 | 2018-09-11 | 上海嘉宝莉建筑节能科技有限公司 | Polymer matrix plastering glue and preparation method thereof |
| CN109293315A (en) * | 2018-11-28 | 2019-02-01 | 华砂砂浆有限责任公司 | A kind of Polymer cement materials and preparation method thereof |
| CN109293315B (en) * | 2018-11-28 | 2022-03-22 | 华砂砂浆有限责任公司 | Polymer cement waterproof mortar and preparation method thereof |
| CN113980530A (en) * | 2021-12-16 | 2022-01-28 | 河南兴安新型建筑材料有限公司 | Nano-reinforced ultrathin high-hardness organic-inorganic composite coating and preparation method thereof |
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Owner name: XUZHOU WONIUSHAN ADVANCED WATERPROOF MATERIALS CO. Effective date: 20121205 |
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Effective date of registration: 20121205 Address after: 100123 Beijing, Gaobeidian, Kang Kang home district, building 4, building No. Applicant after: Beijing Oriental Yuhong Waterproof Technology Co., Ltd. Applicant after: Xuzhou Woniushan New Waterproof Material Co., Ltd. Applicant after: Shanghai Oriental Yuhong Waterproof Technology Co., Ltd. Address before: 100025, Beijing, Chaoyang District Gaobeidian Kang homes District No. 4 Building Applicant before: Beijing Oriental Yuhong Waterproof Technology Co., Ltd. |
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Owner name: JIANGSU WONIUSHAN INSULATION WATERPROOF TECHNOLOGY Free format text: FORMER OWNER: BEIJING ORIENTAL YUHONG WATERPROOF TECHNOLOGY CO., LTD. Effective date: 20140430 Free format text: FORMER OWNER: XUZHOU WONIUSHAN ADVANCED WATERPROOF MATERIALS CO., LTD. SHANGHAI ORIENTAL YUHONG ATERPROOF ECHNOLOGY CO., LTD. Effective date: 20140430 |
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Inventor after: Feng Chunpeng Inventor after: Xiong Weifeng Inventor after: Liu Zhirong Inventor before: Feng Chunpeng Inventor before: Xiong Weifeng |
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Free format text: CORRECT: INVENTOR; FROM: FENG CHUNPENG XIONG WEIFENG TO: FENG CHUNPENG XIONG WEIFENG LIU ZHIRONG Free format text: CORRECT: ADDRESS; FROM: 100123 CHAOYANG, BEIJING TO: 210000 NANJING, JIANGSU PROVINCE |
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Effective date of registration: 20140430 Address after: 210000 Xuanwu Avenue, Xuanwu District, Jiangsu, Nanjing 699-1 Applicant after: Jiangsu Woniushan Insulation Waterproof Technology Co., Ltd. Address before: 100123 Beijing, Gaobeidian, Kang Kang home district, building 4, building No. Applicant before: Beijing Oriental Yuhong Waterproof Technology Co., Ltd. Applicant before: Xuzhou Woniushan New Waterproof Material Co., Ltd. Applicant before: Shanghai Oriental Yuhong Waterproof Technology Co., Ltd. |
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Address after: 210000 Xuanwu Avenue, Xuanwu District, Jiangsu, Nanjing 699-1 Patentee after: Jiangsu Funiushan building energy saving Technology Co., Ltd Address before: 210000 Xuanwu Avenue, Xuanwu District, Jiangsu, Nanjing 699-1 Patentee before: JIANGSU WONIUSHAN THERMAL INSULATION AND WATERPROOF TECHNOLOGY Co.,Ltd. |
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Address after: Jiangning District of Nanjing City, Jiangsu province 211111 streets moling Road No. 12 mo Zhou Patentee after: Jiangsu Funiushan building energy saving Technology Co., Ltd Address before: 210000 Xuanwu Avenue, Xuanwu District, Jiangsu, Nanjing 699-1 Patentee before: JIANGSU WONIUSHAN THERMAL INSULATION AND WATERPROOF TECHNOLOGY Co.,Ltd. |
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Address after: 211111 No. 12, Mazhou East Road, Mau Ling Street, Jiangning District, Nanjing, Jiangsu Patentee after: Woniushan building energy saving Co.,Ltd. Address before: 211111 No. 12, Mazhou East Road, Mau Ling Street, Jiangning District, Nanjing, Jiangsu Patentee before: Jiangsu Funiushan building energy saving Technology Co.,Ltd. |