CN102500361A - Ternary neterogeny structural light degradation organic matter catalyst TiO2-Bi2MoO6/Bi3.64Mo0.36O6.55 and preparation method thereof - Google Patents
Ternary neterogeny structural light degradation organic matter catalyst TiO2-Bi2MoO6/Bi3.64Mo0.36O6.55 and preparation method thereof Download PDFInfo
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- CN102500361A CN102500361A CN2011103398375A CN201110339837A CN102500361A CN 102500361 A CN102500361 A CN 102500361A CN 2011103398375 A CN2011103398375 A CN 2011103398375A CN 201110339837 A CN201110339837 A CN 201110339837A CN 102500361 A CN102500361 A CN 102500361A
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- bi2moo6
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- titanium dioxide
- tio2
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- 239000003054 catalyst Substances 0.000 title claims abstract description 27
- 230000015556 catabolic process Effects 0.000 title claims abstract description 17
- 238000006731 degradation reaction Methods 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims description 10
- 239000005416 organic matter Substances 0.000 title abstract description 5
- 229910002900 Bi2MoO6 Inorganic materials 0.000 title abstract 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 11
- 230000000694 effects Effects 0.000 claims abstract description 8
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 5
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000001354 calcination Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 9
- 230000003197 catalytic effect Effects 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 6
- 230000001939 inductive effect Effects 0.000 claims description 4
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims description 4
- 229940043267 rhodamine b Drugs 0.000 claims description 4
- 239000011609 ammonium molybdate Substances 0.000 claims description 3
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 3
- 229940010552 ammonium molybdate Drugs 0.000 claims description 3
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 claims description 3
- -1 polytetrafluoroethylene Polymers 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- DKUYEPUUXLQPPX-UHFFFAOYSA-N dibismuth;molybdenum;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mo].[Mo].[Bi+3].[Bi+3] DKUYEPUUXLQPPX-UHFFFAOYSA-N 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000003513 alkali Substances 0.000 abstract description 3
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 3
- 238000013033 photocatalytic degradation reaction Methods 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract 1
- 238000010923 batch production Methods 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 8
- 239000003344 environmental pollutant Substances 0.000 description 6
- 231100000719 pollutant Toxicity 0.000 description 6
- 230000001699 photocatalysis Effects 0.000 description 4
- 238000007146 photocatalysis Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000010865 sewage Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000013043 chemical agent Substances 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000001473 noxious effect Effects 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241001125671 Eretmochelys imbricata Species 0.000 description 1
- 238000001069 Raman spectroscopy Methods 0.000 description 1
- 238000001237 Raman spectrum Methods 0.000 description 1
- 208000036142 Viral infection Diseases 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 238000011953 bioanalysis Methods 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000006298 dechlorination reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 230000007269 microbial metabolism Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 150000003071 polychlorinated biphenyls Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
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CN2011103398375A CN102500361B (en) | 2011-11-01 | 2011-11-01 | Ternary heterostructure light degradation organic matter catalyst TiO2-Bi2MoO6/Bi3.64Mo0.36O6.55 and preparation method thereof |
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CN2011103398375A CN102500361B (en) | 2011-11-01 | 2011-11-01 | Ternary heterostructure light degradation organic matter catalyst TiO2-Bi2MoO6/Bi3.64Mo0.36O6.55 and preparation method thereof |
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CN102500361A true CN102500361A (en) | 2012-06-20 |
CN102500361B CN102500361B (en) | 2013-08-07 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103801340A (en) * | 2013-07-24 | 2014-05-21 | 南昌航空大学 | Photocatalytic degradation organic matter pollutant catalyst TiO2/Co4S4.23Se3.77 as well as preparation method thereof |
CN103962158A (en) * | 2014-04-30 | 2014-08-06 | 南昌航空大学 | Ternary hetero-structured photo-degradation organic catalyst WS2-Bi2WO6/Bi3.84W0.16O6.24 and preparation method thereof |
CN105536772A (en) * | 2015-12-23 | 2016-05-04 | 东南大学 | Preparation method for heterojunction nano-photocatalysis material and application of material |
CN106984299A (en) * | 2017-05-27 | 2017-07-28 | 北方民族大学 | Hydrothermal Synthesiss three-dimensional Bi4MoO9/TiO2The method of nanostructure heterojunction |
CN109589966A (en) * | 2019-01-21 | 2019-04-09 | 合肥学院 | A kind of hetero-junctions TiO2@Bi3.64Mo0.36O6.55The preparation method of nano composite photo-catalyst |
CN114249544A (en) * | 2022-03-01 | 2022-03-29 | 青岛理工大学 | Z-shaped heterojunction composite photo-anode membrane, one-step hydrothermal preparation method and application thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3640900A (en) * | 1969-03-06 | 1972-02-08 | Du Pont | Heat treated bismuth molybdate and phosphomolybdate-on-titania catalysts |
CN101632924A (en) * | 2009-07-19 | 2010-01-27 | 桂林理工大学 | Compound oxide photocatalyst Bi4V(2-x)MxO(11-x/2) and preparation method thereof |
-
2011
- 2011-11-01 CN CN2011103398375A patent/CN102500361B/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3640900A (en) * | 1969-03-06 | 1972-02-08 | Du Pont | Heat treated bismuth molybdate and phosphomolybdate-on-titania catalysts |
CN101632924A (en) * | 2009-07-19 | 2010-01-27 | 桂林理工大学 | Compound oxide photocatalyst Bi4V(2-x)MxO(11-x/2) and preparation method thereof |
Non-Patent Citations (4)
Title |
---|
《Advanced Materials Research》 20110831 Jing Hong Bi et al., "Visible Light Photocatalytic Activity of Zn-Doped Bi-Mo Complex Metal Oxide Prepared by Hydrothermal Synthesis Method" 第410-413页 第311-313卷, * |
《Journal of alloys and compounds》 20101231 LIJIN XIE et. al., "Preparation of a novel Bi3.64Mo0.36O6.55 nanophotocatalyst by molten salt method and evaluation for photocatalytic decomposition of rhodamine B" 第 159-162页 第503卷, 第1期 * |
JING HONG BI ET AL.,: ""Visible Light Photocatalytic Activity of Zn-Doped Bi-Mo Complex Metal Oxide Prepared by Hydrothermal Synthesis Method"", 《ADVANCED MATERIALS RESEARCH》, vol. 311313, 31 August 2011 (2011-08-31), pages 410 - 413 * |
LIJIN XIE ET. AL.,: ""Preparation of a novel Bi3.64Mo0.36O6.55 nanophotocatalyst by molten salt method and evaluation for photocatalytic decomposition of rhodamine B"", 《JOURNAL OF ALLOYS AND COMPOUNDS》, vol. 503, no. 1, 31 December 2010 (2010-12-31), pages 159 - 162 * |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103801340A (en) * | 2013-07-24 | 2014-05-21 | 南昌航空大学 | Photocatalytic degradation organic matter pollutant catalyst TiO2/Co4S4.23Se3.77 as well as preparation method thereof |
CN103801340B (en) * | 2013-07-24 | 2015-12-02 | 南昌航空大学 | A kind of photocatalysis to degrade organic matter contaminant catalyst TiO 2/ Co 4s 4.23se 3.77and preparation method thereof |
CN103962158A (en) * | 2014-04-30 | 2014-08-06 | 南昌航空大学 | Ternary hetero-structured photo-degradation organic catalyst WS2-Bi2WO6/Bi3.84W0.16O6.24 and preparation method thereof |
CN103962158B (en) * | 2014-04-30 | 2015-12-02 | 南昌航空大学 | A kind of ternary heterojunction light degradation catalytic organism agent WS 2-Bi 2wO 6/ Bi 3.84w 0.16o 6.24and preparation method thereof |
CN105536772B (en) * | 2015-12-23 | 2018-03-20 | 东南大学 | A kind of preparation method of hetero-junctions nano-photocatalyst material and the application of the material |
CN105536772A (en) * | 2015-12-23 | 2016-05-04 | 东南大学 | Preparation method for heterojunction nano-photocatalysis material and application of material |
CN106984299A (en) * | 2017-05-27 | 2017-07-28 | 北方民族大学 | Hydrothermal Synthesiss three-dimensional Bi4MoO9/TiO2The method of nanostructure heterojunction |
WO2018218728A1 (en) * | 2017-05-27 | 2018-12-06 | 北方民族大学 | Method for hydrothermal synthesis of three-dimensional bi4moo9/tio2 nanostructured heterojunction |
CN106984299B (en) * | 2017-05-27 | 2019-04-23 | 北方民族大学 | Hydrothermal synthesis three-dimensional Bi4MoO9/TiO2The method of nanostructure heterojunction |
US10486138B2 (en) * | 2017-05-27 | 2019-11-26 | Beifang Minzu University | Method for hydrothermal synthesis of three dimensional Bi4MoO9/TiO2 nanostructure heterojunction |
CN109589966A (en) * | 2019-01-21 | 2019-04-09 | 合肥学院 | A kind of hetero-junctions TiO2@Bi3.64Mo0.36O6.55The preparation method of nano composite photo-catalyst |
CN114249544A (en) * | 2022-03-01 | 2022-03-29 | 青岛理工大学 | Z-shaped heterojunction composite photo-anode membrane, one-step hydrothermal preparation method and application thereof |
CN114249544B (en) * | 2022-03-01 | 2022-05-20 | 青岛理工大学 | Z-type heterojunction composite photo-anode membrane, one-step hydrothermal preparation method and application thereof |
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CN102500361B (en) | 2013-08-07 |
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Inventor after: Zou Jianping Inventor after: Zhang Longzhu Inventor after: Xing Qiuju Inventor after: Lin Fangcheng Inventor after: Ding Lin Inventor after: Dai shunchen Inventor before: Zhang Longzhu Inventor before: Zou Jianping Inventor before: Lin Fangcheng Inventor before: Ding Lin Inventor before: Dai Shunchen Inventor before: Xing Qiuju |
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Free format text: CORRECT: INVENTOR; FROM: ZHANG LONGZHU ZOU JIANPING LIN FANGCHENG DING LIN DAI SHUNCHEN XING QIUJU TO: ZOU JIANPING ZHANG LONGZHU XING QIUJU LIN FANGCHENG DING LIN DAI SHUNCHEN |
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Granted publication date: 20130807 |