CN102495135A - Pressure measurement and crack detection sensor based on nano carbon black and piezoelectric ceramic composite cement - Google Patents
Pressure measurement and crack detection sensor based on nano carbon black and piezoelectric ceramic composite cement Download PDFInfo
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- CN102495135A CN102495135A CN2011104136435A CN201110413643A CN102495135A CN 102495135 A CN102495135 A CN 102495135A CN 2011104136435 A CN2011104136435 A CN 2011104136435A CN 201110413643 A CN201110413643 A CN 201110413643A CN 102495135 A CN102495135 A CN 102495135A
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- 239000004568 cement Substances 0.000 title claims abstract description 35
- 239000000919 ceramic Substances 0.000 title claims abstract description 28
- 239000006229 carbon black Substances 0.000 title claims abstract description 24
- 229910021392 nanocarbon Inorganic materials 0.000 title claims abstract description 17
- 238000001514 detection method Methods 0.000 title claims abstract description 6
- 239000002131 composite material Substances 0.000 title abstract description 9
- 238000009530 blood pressure measurement Methods 0.000 title abstract description 3
- 239000011159 matrix material Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 238000002513 implantation Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000004567 concrete Substances 0.000 abstract description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 2
- 238000012544 monitoring process Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 8
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
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- 230000035945 sensitivity Effects 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000006355 external stress Effects 0.000 description 1
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- 229910001092 metal group alloy Inorganic materials 0.000 description 1
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Abstract
本发明涉及一种纳米炭黑压电陶瓷复合水泥基传感器,是一种与混凝土相容性好,能够精确定位裂缝位置,同时测定压力变化的高强度高灵敏度的纳米碳黑压电陶瓷复合水泥基传感器。将水泥与炭黑按5∶1的比例均匀混合制作成立方块体,在水泥立方块体内附加两片铜丝网,并植入3个压电陶瓷片,各压电陶瓷片分别与导线相连。本发明利用了纳米炭黑的压敏特性测力,利用压电陶瓷片进行机械损伤定位,可以同时实现压力测定和探伤定位,能够广泛应用于工程监测领域。
The invention relates to a nano-carbon black piezoelectric ceramic composite cement-based sensor, which is a high-strength and high-sensitivity nano-carbon black piezoelectric ceramic composite cement that has good compatibility with concrete, can accurately locate crack positions, and simultaneously measure pressure changes. base sensor. Cement and carbon black were uniformly mixed at a ratio of 5:1 to form a cube, and two pieces of copper wire mesh were added to the cement cube, and three piezoelectric ceramic sheets were implanted, and each piezoelectric ceramic sheet was connected to a wire. The invention utilizes the pressure-sensitive characteristics of nano-carbon black to measure force, and uses piezoelectric ceramic sheets to locate mechanical damage, so that pressure measurement and flaw detection can be realized simultaneously, and can be widely used in the field of engineering monitoring.
Description
技术领域 technical field
本发明涉及传感器领域,特别是一种与混凝土相容性好,能够精确定位裂缝位置,同时测定压力变化的高强度高灵敏度的纳米碳黑压电陶瓷复合水泥基传感器。 The invention relates to the field of sensors, in particular to a nano-carbon black piezoelectric ceramic composite cement-based sensor with high strength and high sensitivity, which has good compatibility with concrete, can accurately locate crack positions, and simultaneously measure pressure changes. the
背景技术 Background technique
目前,土木工程领域中所用的传感元件,一般都是在其他领域已经使用过比较成熟的材料,如光导纤维,压电陶瓷,记忆金属合金等。这些材料与土木工程领域中最重要的结构材料,混凝土,往往存在着明显的相容性问题,这样会是智能材料产生虚假信号,影响传感精度,甚至会导致错误的判断,对结构地正常使用造成极大损害,例如,工程中常用的光纤光栅传感器存在精度低,易受外界应力温度影响,封装材料和结构形式与基体存在不匹配的问题,导致在高频应变下,光纤光栅传感器不能有效跟踪基体的应变变化。本发明使用以水泥基为载体,内附压电陶瓷片和纳米级炭黑的传感器具有精度高,相容性好的特点,可以有效解决这一工程问题。利用压电陶瓷传感器进行裂缝定位和利用炭黑压敏特性进行测压的传感器都存在,但是并没有将两者有效结合,本发明有效的结合了两者的特性,是可以同时进行探伤定位和工程测力的水泥基传感器。 At present, the sensing elements used in the field of civil engineering are generally relatively mature materials that have been used in other fields, such as optical fibers, piezoelectric ceramics, and memory metal alloys. These materials and the most important structural material in the field of civil engineering, concrete, often have obvious compatibility problems, which will cause false signals generated by smart materials, affect the sensing accuracy, and even lead to wrong judgments, which will affect the normal structure of the structure. The use causes great damage. For example, the fiber grating sensor commonly used in engineering has low precision, is easily affected by external stress temperature, and the packaging material and structure form do not match the substrate. As a result, under high-frequency strain, the fiber grating sensor cannot Efficiently track strain changes in the substrate. The invention uses the cement base as the carrier, and the sensor with piezoelectric ceramic sheet and nano-scale carbon black inside has the characteristics of high precision and good compatibility, and can effectively solve this engineering problem. There are sensors that use piezoelectric ceramic sensors for crack location and carbon black pressure-sensitive characteristics for pressure measurement, but they do not effectively combine the two. The present invention effectively combines the characteristics of the two, and can simultaneously perform flaw detection and location. Cement-based transducers for engineering force measurement. the
发明内容 Contents of the invention
本发明克服了现有的传感器与混凝土存在的明显的相容性问题,而导致虚假信号的产生和传感精度的降低等的不足。本发明提供了一种与混凝土相容性好,能够精确定位裂缝位置,同时测定压力变化的高强度高灵敏度的纳米碳黑压电陶瓷复合水泥基传感器。不仅可以进行损伤精确定位,而且能同时分析内 部受力情况。 The invention overcomes the obvious compatibility problem between existing sensors and concrete, which leads to the generation of false signals and the reduction of sensing accuracy. The invention provides a high-strength and high-sensitivity nano-carbon black piezoelectric ceramic composite cement-based sensor that has good compatibility with concrete, can accurately locate cracks, and can simultaneously measure pressure changes. It can not only accurately locate the damage, but also analyze the internal force situation at the same time. the
本发明解决其技术问题所采用的技术方案是: The technical solution adopted by the present invention to solve its technical problems is:
该传感器包括四部分:水泥基体、压电陶瓷片、金属网和导线;水泥基体是水泥与纳米级导电炭黑按5∶1的比例均匀混合制作成的水泥立方块体;三个压电陶瓷片植入水泥立方块体内且不在同一平面内,各压电陶瓷片分别与导线相连;在水泥立方块体内设置两片金属网,通过金属网输出炭粒由于压力变化产生的信号。 The sensor consists of four parts: cement matrix, piezoelectric ceramic sheet, metal mesh and wire; the cement matrix is a cement cube made by uniformly mixing cement and nano-scale conductive carbon black at a ratio of 5:1; three piezoelectric ceramics The sheets are implanted in the cement cube and are not in the same plane, and the piezoelectric ceramic sheets are connected to the wires respectively; two metal meshes are set in the cement cube, and the signal generated by the carbon particles due to the pressure change is output through the metal mesh. the
以水泥基为载体,将压电陶瓷片和炭粒同时应用于传感器当中,利用两种物质协同完成结构性能监测工作。利用压电陶瓷片(PZT)波传播法的基本原理进行混凝土结构损伤,缺陷裂缝的精细识别;利用纳米炭黑的压敏性能,判断结构所受压力。压电材料依据正压电效应可实现传感功能,依据逆压电效应可实现驱动功能。在混凝土中加入适量的纳米碳黑后,力学性能和电学性能都有所提高,混凝土的抗折抗压强度也相应增加。 Using the cement base as the carrier, the piezoelectric ceramic sheet and carbon particles are applied to the sensor at the same time, and the two substances are used to cooperate to complete the structural performance monitoring work. Use the basic principle of piezoelectric ceramic (PZT) wave propagation method to carry out fine identification of concrete structure damage and defect cracks; use the pressure-sensitive properties of nano-carbon black to judge the pressure on the structure. The piezoelectric material can realize the sensing function according to the positive piezoelectric effect, and can realize the driving function according to the inverse piezoelectric effect. After adding an appropriate amount of nano-carbon black in concrete, the mechanical and electrical properties are improved, and the flexural and compressive strength of concrete is also increased accordingly. the
本发明与已有技术相比的突出效果为: The outstanding effect of the present invention compared with prior art is:
其一:与混凝土相容性好,本发明是由与混凝土相容性好的水泥基压电复合材料为传感单元,经水泥块包裹而成。该传感器与土木工程中最常用的混凝土材料具有良好的相容性,如相似的声阻抗、等同的收缩率及相近的热胀系数等;它埋在混凝土中,与周围混凝土之间不存在不连续的界面问题,即不会改变结构的特性,也不会出现应力突变现象。 One: Good compatibility with concrete. The present invention is made of cement-based piezoelectric composite material with good compatibility with concrete as the sensing unit, which is wrapped by cement block. The sensor has good compatibility with the most commonly used concrete materials in civil engineering, such as similar acoustic impedance, equivalent shrinkage rate and similar thermal expansion coefficient, etc.; it is buried in concrete, and there is no difference between it and the surrounding concrete. The continuous interface problem will not change the characteristics of the structure, nor will there be a sudden change in stress. the
其二:强度高,耐久性好,纳米炭黑材料,具有优良的导电性,尺寸很小,比表面积大,界面性能优异,已有研究人员将其应用在混凝土中,改善混凝土材料微观结构和力学性。 Second: high strength, good durability, nano-carbon black material, excellent electrical conductivity, small size, large specific surface area, and excellent interface properties. Some researchers have applied it to concrete to improve the microstructure of concrete materials and mechanics. the
其三:感知灵敏度高,充分结合了压电陶瓷片和纳米炭黑的优点,可以进 行损伤精确定位,同时利用材料的压敏特性分析内部受力情况。 Third: High sensing sensitivity, fully combining the advantages of piezoelectric ceramics and nano-carbon black, can accurately locate damage, and use the pressure-sensitive characteristics of materials to analyze internal force conditions. the
其四:能同时进行损伤精确定位和分析内部受力情况。利用压电陶瓷片(PZT)波传播法的基本原理进行混凝土结构损伤,缺陷裂缝的精细识别;利用纳米炭黑的压敏性能,判断结构所受压力。 Fourth: It can accurately locate the damage and analyze the internal stress situation at the same time. Use the basic principle of piezoelectric ceramic (PZT) wave propagation method to carry out fine identification of concrete structure damage and defect cracks; use the pressure-sensitive properties of nano-carbon black to judge the pressure on the structure. the
附图说明 Description of drawings
图1是纳米炭黑压电陶瓷复合水泥基传感器的外观整体示意图。 Figure 1 is a schematic diagram of the overall appearance of the nano-carbon black piezoelectric ceramic composite cement-based sensor. the
图2是纳米炭黑压电陶瓷复合水泥基传感器的剖面结构示意图。 Fig. 2 is a schematic cross-sectional structure diagram of nano-carbon black piezoelectric ceramic composite cement-based sensor. the
图3是纳米炭黑压电陶瓷复合水泥基传感器的透视结构示意图。 Fig. 3 is a schematic diagram of the perspective structure of the nano-carbon black piezoelectric ceramic composite cement-based sensor. the
图中:1导线;2纳米级导电炭黑;3压电陶瓷片;4金属网。 In the figure: 1 wire; 2 nanometer conductive carbon black; 3 piezoelectric ceramic sheet; 4 metal mesh. the
具体实施方式 Detailed ways
以下结合技术方案和附图详细叙述本发明的具体实施例。 Specific embodiments of the present invention will be described in detail below in conjunction with technical solutions and accompanying drawings. the
将水泥与纳米级导电炭黑按5∶1的比例利用分散剂均匀混合制作成5cm×5cm×5cm的立方块体,在水泥立方块体内附加两片铜丝网,植入3个不在同一平面内且分别与导线相连的压电陶瓷片,并利用导线对外传递声发射信号。炭黑采用表面处理或未处理的纳米级导电炭黑,分散剂为水性分散剂。 Mix cement and nano-scale conductive carbon black at a ratio of 5:1 with a dispersant to make a cube of 5cm×5cm×5cm, add two pieces of copper wire mesh to the cement cube, and implant 3 pieces that are not on the same plane. The piezoceramic sheets inside and connected to the wires respectively, and use the wires to transmit the acoustic emission signal to the outside. The carbon black adopts surface-treated or untreated nano-scale conductive carbon black, and the dispersant is a water-based dispersant. the
所制作的水泥基体,可以按所需制作成各种尺寸的立方体,也可以采用其他的非立方体形状,都没有超出本专利保护的范围。 The prepared cement matrix can be made into cubes of various sizes as required, and can also adopt other non-cubic shapes, all within the protection scope of this patent. the
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104458075A (en) * | 2014-12-31 | 2015-03-25 | 中国矿业大学 | Stress distribution monitoring device and method |
CN106087696A (en) * | 2016-06-15 | 2016-11-09 | 大连理工大学 | A kind of Filled Steel Tubular Arch Bridge concrete filled steel tube grouting density monitoring method utilizing piezoceramic transducer |
CN106402124A (en) * | 2016-09-29 | 2017-02-15 | 大连理工大学 | Intelligent bolt device for monitoring dynamic stress conditions of bolt connection |
CN107702828A (en) * | 2017-09-26 | 2018-02-16 | 沈阳建筑大学 | Concrete perceives intelligence sensor and its preparation method and application certainly with hypersensibility |
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CN1450234A (en) * | 2003-04-17 | 2003-10-22 | 同济大学 | Layered cement base piezoelectric intelligent composite material and preparation method thereof |
CN1844025A (en) * | 2006-04-20 | 2006-10-11 | 武汉理工大学 | Nano carbon black conductive concrete |
CN101493368A (en) * | 2009-03-02 | 2009-07-29 | 北京航空航天大学 | Method for producing alertness cement-based material pressure sensor and monitoring device |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN1450234A (en) * | 2003-04-17 | 2003-10-22 | 同济大学 | Layered cement base piezoelectric intelligent composite material and preparation method thereof |
CN1844025A (en) * | 2006-04-20 | 2006-10-11 | 武汉理工大学 | Nano carbon black conductive concrete |
CN101493368A (en) * | 2009-03-02 | 2009-07-29 | 北京航空航天大学 | Method for producing alertness cement-based material pressure sensor and monitoring device |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104458075A (en) * | 2014-12-31 | 2015-03-25 | 中国矿业大学 | Stress distribution monitoring device and method |
CN106087696A (en) * | 2016-06-15 | 2016-11-09 | 大连理工大学 | A kind of Filled Steel Tubular Arch Bridge concrete filled steel tube grouting density monitoring method utilizing piezoceramic transducer |
CN106087696B (en) * | 2016-06-15 | 2018-02-16 | 大连理工大学 | A kind of Filled Steel Tubular Arch Bridge concrete filled steel tube grouting density monitoring method using piezoceramic transducer |
CN106402124A (en) * | 2016-09-29 | 2017-02-15 | 大连理工大学 | Intelligent bolt device for monitoring dynamic stress conditions of bolt connection |
CN106402124B (en) * | 2016-09-29 | 2018-11-09 | 大连理工大学 | A kind of intelligent bolt device for monitoring bolt connection dynamic stress situation |
CN107702828A (en) * | 2017-09-26 | 2018-02-16 | 沈阳建筑大学 | Concrete perceives intelligence sensor and its preparation method and application certainly with hypersensibility |
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