CN102494722B - Greenhouse gas emission monitoring method of town household refuse disposal system - Google Patents

Greenhouse gas emission monitoring method of town household refuse disposal system Download PDF

Info

Publication number
CN102494722B
CN102494722B CN201110413530.5A CN201110413530A CN102494722B CN 102494722 B CN102494722 B CN 102494722B CN 201110413530 A CN201110413530 A CN 201110413530A CN 102494722 B CN102494722 B CN 102494722B
Authority
CN
China
Prior art keywords
methane
ddoc
discharge capacity
gas
content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201110413530.5A
Other languages
Chinese (zh)
Other versions
CN102494722A (en
Inventor
王媛
何彧
颜蓓蓓
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin University
Original Assignee
Tianjin University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin University filed Critical Tianjin University
Priority to CN201110413530.5A priority Critical patent/CN102494722B/en
Publication of CN102494722A publication Critical patent/CN102494722A/en
Application granted granted Critical
Publication of CN102494722B publication Critical patent/CN102494722B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a greenhouse gas emission monitoring method of a town household refuse disposal system. By monitoring methane gas and refuse components and revising the refuse components, degradable organic carbon content, proportion of methane in refuse landfill gases, a half-life period and the like, the greenhouse gas emission monitoring method puts forward selection principles of the parameters under different conditions selectively, performs connection on instruments on site and upper computer working stations and is capable of updating data in real time. The greenhouse gas emission monitoring method reduces monitoring cost, is stable in monitoring results and high in accounting accuracy.

Description

A kind of greenhouse gas emission monitoring method of town household refuse disposal system
Technical field
The present invention relates to greenhouse gas emission field, particularly a kind of greenhouse gas emission monitoring method of town household refuse disposal system.
Background technology
Greenhouse gases (GHG) discharge of the municipal solid wastes such as house refuse (MSW) in processing procedure is the important sources of greenhouse gases.For formulating house refuse reduction of greenhouse gas discharge strategy targetedly, Chinese scholars has been studied the greenhouse gas emission rule of the Different treatments such as landfill, burning, and adopt respectively the recommend method of cycle assessment method (LCA), Intergovernmental Panel on Climate Change (IPCC), and the accounting method based on Clean Development Mechanism (CDM), Prediction for Solid Waste Treatment Technology and whole disposal system are carried out to greenhouse gas emission accounting and analysis.
Iff adopting Accounting Model, according to model parameter default value measuring and calculating greenhouse gas emissions, because the object of adjusting is complicated and changeable, the air pressure facing, temperature and constituent are different, can not reflect the true greenhouse gas emissions of adjusting object merely according to parameter default value; If only depend on Monitoring Data, determine discharge capacity, because house refuse composition is totally different, the data difference that different sampled points gather is huge, and monitoring is subject to nature, artifical influence factor is numerous, monitoring result is unstable, and if it is higher to want to obtain the monitoring cost that precise information needs.So more satisfactory method is to determine the parameter in Accounting Model in conjunction with Monitoring Data, especially when selecting emission factor, will be as much as possible by investigating on the spot or monitoring, obtain accurately reflecting the emission factor of application of city life garbage discharge characteristics under different condition, then according to Accounting Model, simulate process and the quantity of greenhouse gas emission.
The monitoring method of greenhouse gases comprises at present: model assessment method, flux box method and micrometeorology method etc.Model assessment method principle is according to the concentration gradient of difference alternate (water-gas) gas componant and uses Fick law to carry out estimated flux, and it is generally only applicable to the flux estimation of water-aerosphere face.The cost of flux box method is low, easy to operate, highly sensitive, is the common method of Greenhouse.Compare with flux box method, micrometeorology method is a kind of open measuring method, is used for the measurement research of Lu Sheng ecologic environment greenhouse gases, and it surveys gas flux value is the mean value that (is generally 100~1000m) within the scope of larger space.
For the feature of city refuse landfill aerogenesis, conventionally select flux box method to monitor.But flux casing has disturbance to object of observation, inside and outside case, have that certain pressure is poor, a temperature difference etc., make test and actual conditions have the situation that necessarily departs from.Flux box method comprises static chamber and dynamic case, development from static chamber to dynamic case has overcome the problems referred to above to a certain extent, but dynamically case itself also has certain defect: on the one hand, dynamically box body balanced flow will disturb interfacial gases transmission, on the other hand, in the situation that emission flux of gas is lower, the tested gas concentration difference of the outlet of casing and porch is very little, thereby require there is very high measuring accuracy, otherwise can cause larger measuring error.
Inventor finds in realizing process of the present invention, at least has following shortcoming and defect in prior art:
The cost of monitoring method of the prior art is high, monitors suffered influence factor complexity, and monitoring result is unstable etc., and the accuracy of impact accounting.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of greenhouse gas emission monitoring method of town household refuse disposal system, and the method has reduced the cost of monitoring, and monitoring result accuracy stable and that adjust is higher, described below:
A greenhouse gas emission monitoring method of town household refuse disposal system, said method comprising the steps of:
(1) from the different rubbish of the 6 classes source that produces, gather respectively monitoring sample, obtain the content of organic carbon, and using the content typing host computer workstation of organic carbon as parameter;
(2) when in the landfill operation stage and without methane collection system, take step as unit, realize the landfill of rubbish, adopt static chamber method to monitor methane content, by methane gas analyser three ground, gather sequential control system and obtain the first methane content;
(3) when in the closing stage and without described methane collection system, natural pressure and methane content initial value in the landfill gas of all experiment wells of pre-test of bleeding, gas collection well is bled and measured bleed negative pressure and landfill gas composition, pressure and composition in monitor well monitoring landfill gas changes simultaneously, setting pressure probe, determine the coverage of bleeding, described methane gas analyser three ground gather sequential control system and obtain the second methane content according to pressure and composition;
(4) when having described methane collection system, use flue gas analyzer to monitor collecting well methane concentration, by described methane gas analyser three ground, gather sequential control system and obtain leucoaurin content;
(5) described the first methane content, described the second methane content or described leucoaurin content are sent to described host computer workstation by data service center, by described host computer workstation, obtain the gas production rate of unit weight rubbish within the unit interval;
(6) adopt single order evanescent mode, according to the content of described organic carbon, described the first methane content, described the second methane content and described leucoaurin content, obtain the discharge capacity of methane;
(7) according to the content of described organic carbon, obtain CO 2and N 2the discharge capacity of O;
(8) described host computer workstation is to the discharge capacity of described methane, described CO 2and N 2the discharge capacity of O is processed, and obtains data and curves figure;
Wherein, optional step (2) in the refuse landfill landfill process without described methane collection system, optional step (3) after closing, and in the refuse landfill that has described methane collection system omnidistance optional step (4).
The discharge capacity of described methane is specially:
Adopt single order evanescent mode, the discharge capacity of described methane:
E CH4=DDOC mdecompT×F×16/12
E cH4cH for T landfill municipal solid wastes 4discharge capacity, unit is ton; DDOC mdecopTdDOC for T decomposition m; F is the CH in the refuse landfill gas producing 4ratio; 16/12 is CH 4/ C molecular weight ratio;
The T DDOC that the year end, sanitary land fill was accumulated m:
DDOC maT=DDOC mdT+(DDOC maT-1×e -k)
The DDOC that T decomposes m:
DDOC mdecompT=DDOC maT-1×(1-e -k)
T is the inventory time; DDOC maTunit is ton; DDOC maT-1the DDOC accumulating for T-1 terminal hour sanitary land fill m, unit is ton; DDOC mdTfor T deposit to sanitary land fill DDOC m, unit is ton; K is reaction constant, k=ln (2)/t 1/2, unit is year, t 1/2for time half life period, wherein, described time half life period according to described unit weight rubbish the gas production rate within the unit interval determine.
Described CO 2discharge capacity:
E CO 2 = MSW × Σ j ( WF j × dm j × CF j × FCF j × OF j ) × 44 / 12
Figure BDA0000119058310000032
for burning the CO of municipal solid wastes 2discharge capacity, unit is ton; WF jnumber percent for ingredient j in solid waste; Dm jfor the dry matter percentage in ingredient j; CF jratio for total carbon in the dry of ingredient j; FCF jfor the ratio of mineral carbon in total carbon; OF jfor oxidation factor, get 100%; 44/12 is CO 2/ C molecular weight ratio.
Described N 2the discharge capacity of O:
E N 2 O = MSW × EF N 2 O × 10 - 6 × GWP N 2 O
for burning municipal solid wastes discharge N 2the CO2 emission equivalent that O produces, unit is ton; The municipal solid wastes quality of MSW for burning, unit is ton;
Figure BDA0000119058310000042
for N 2the emission factor of O; GWP n2Ofor N 2greenhouse effect and CO that O produces 2the multiple of comparing, gets 310.
Described method also comprises: the indirect discharge capacity to upstream and downstream is monitored,
The indirect discharge capacity of upstream comprises: upstream activity level and emission factor multiply each other and obtain CO 2discharge capacity; Wherein, described activity level is specially: the energy-output ratio and the power consumption that in transportation rubbish process, consume;
The indirect discharge capacity in downstream comprises: from output electric weight to CO 2cER monitor, be specially: after domestic rubbish disposal, externally the electric weight of output is multiplied by the CO of local generating 2average emission coefficient, the CO of described local generating 2average emission coefficient is line-based emission factor, is the weighted mean of electric weight limit emission factor and capacity limit emission factor.
A kind of greenhouse gas emission monitoring method of town household refuse disposal system provided by the invention, compared with prior art has advantages of as follows:
The present invention is by methane gas and waste component are monitored, to the CH in component of refuse, Degradable organic carbon content, refuse landfill gas 4ratio and half life period etc. revise, and bring forward the selection principle of above-mentioned parameter under different condition, and field instrument and host computer workstation are contacted, can real-time update data; The present invention has reduced the cost of monitoring, and monitoring result accuracy stable and that adjust is higher.
Accompanying drawing explanation
Fig. 1 is the structural representation of a kind of urban household waste treatment system greenhouse gas emission monitoring provided by the invention.
Embodiment
For making the object, technical solutions and advantages of the present invention clearer, below in conjunction with accompanying drawing, embodiment of the present invention is described further in detail.
Present Domestic all lacks the standard for Greenhouse method outward, and lacks especially for the standard monitoring method of domestic waste greenhouse gas emission, in the urgent need to formulating a set of standard monitoring index and method in conjunction with the object of adjusting.To monitor and adjust unification, setting up a set of monitoring Accounting System for domestic waste Different treatments.
In order to reduce monitoring account cost, utilize minimum monitoring index to improve accuracy, whole greenhouse gas emission monitoring method of town household refuse disposal system is comprised of three parts, according to technical requirement, field layer gathers the signals such as Degradable organic carbon massfraction, natural pressure and methane content that under different condition, monitoring obtains and sends to data acquisition station.Data acquisition station is done rough handling to acquired original data, adopts Industrial Ethernet mode that all data high-speeds are sent to host computer workstation.Host computer workstation calculates the reduction of greenhouse gas discharge amount of landfill and two kinds of processing modes of burning by the parameter of artificial setting and the data parameters collecting with method provided below.Host computer workstation deposits the data after calculating in database in and preserves in real time.
House refuse produces greenhouse gases and is mainly methane, after garbage loading embeading, activity due to microorganism, degradable organic component in rubbish is decomposed gradually, and this process can roughly be divided into double teacher: Hydrolysis/Aerobic degradation period, hydrolysis/fermentation stage, souring stage, product methane phase and oxidation stage.CH in rubbish 4discharge is based on single order damped system, and the method hypothesis, at CH 4and CO 2in the many decades forming, (Degradable organic carbon, DOC) decay is very slow for the degradable organic principle in discarded object.If condition is constant, CH 4generation rate depends on the carbon content of discarded object completely.So in the initial several years after deposition, the CH of the generation of waste materials depositing at disposal site 4discharge capacity is the highest, and along with Degradable organic carbon in discarded object is consumed by bacterium (causing decay), this discharge capacity also declines gradually.As can be seen here, referring to Fig. 1, the production process of methane is main relevant with the half life period of degraded with the content of Degradable organic carbon in rubbish, and the half life period is mainly subject to the impact of refuse composition, landfill condition and meteorological condition, and the half life period can be determined by the gas production rate in the monitoring unit interval.
101: from the different rubbish of the 6 classes source that produces, gather respectively monitoring sample, obtain the content of organic carbon, and using the content typing host computer workstation of organic carbon as parameter;
Wherein, this step is specially: monitoring sample should gather respectively from the different rubbish of the 6 classes source that produces, and these sampled points comprise shopping centre, resident living area, cause district, sweeping area, special section and mixed zone.After mensuration rubbish unit weight, bulk refuse breaking to particle diameter is less than to the fritter of 50mm, fully mixed stirring that pave in cement flooring, then use inquartation division 2 (or 3) inferior to 25-50kg sample, be placed in closed container and transport to analysis place.The determination and analysis method of monitoring sample carbon content adopts the Outside Heating Method in potassium bichromate titrimetric method.Under the condition of external heat, (oil bath temperature is 180 ℃, seethe with excitement 5 minutes), with organic carbon in certain density potassium dichromate-sulfuric acid solution oxidation sample, remaining potassium dichromate carrys out titration with ferrous sulphate, from consumed potassium dichromate amount, the content that calculates organic carbon, is entered into host computer workstation as parameter using the content of its organic carbon.
102: when in the landfill operation stage and without methane collection system, take step as unit, realize the landfill of rubbish, adopt static chamber method to monitor methane content, by methane gas analyser three ground, gather sequential control system and obtain the first methane content;
Wherein, this step is specially: landfill operation be take step as unit, every 1 about 12.5m of bench height; Divide two-layer landfill, every 1 layer height is 6.0m, the about 30cm of middle earthing bed thickness.After completing the landfill of 1 step, carry out end covering, the about 1m of overburden layer thickness, grade of side slope 1: 3.By static chamber method, carry out methane content monitoring, sample tap and temperature-measuring port are established in static chamber top, and fixed part is embedded in overburden layer, during test, static case lid are inserted in water sealed tank to water filling sealing.Respectively 0,10,20,30 and 40min from gas sample mouth, sample; Static the temperature inside the box is recorded in sampling simultaneously, with correcting gas concentration.In gas sample, the volume fraction of methane is tested with gas chromatographic analysis.
103: when in the closing stage and without methane collection system, natural pressure and methane content initial value in the landfill gas of all experiment wells of pre-test of bleeding, gas collection well is bled and measured bleed negative pressure and landfill gas composition, pressure and composition in monitor well monitoring landfill gas changes simultaneously, setting pressure probe, determine the coverage of bleeding, methane gas analyser three ground gather sequential control system and obtain the second methane content according to pressure and composition;
The experimental method of taking to bleed is measured, the experiment of bleeding is divided into static experiment and two stages of dynamic experiment, static experiment process comprises: at the natural pressure of the landfill gas of all experiment wells of pre-test of bleeding, dynamic experiment adopts at gas collection well and bleeds and measure bleed negative pressure and landfill gas composition, and pressure and the composition in monitor well monitoring landfill gas changes simultaneously.Experiment comprises three parts: maximum extraction flow and the suction pressure of first for measure when many mouthfuls of gas collection wells are bled simultaneously; Second portion is maximum extraction flow and the suction pressure of the independent test set gas well of difference; Third part is monitored the static pressure of each well before testing for starting in every day to bleed.The gas flow of gas collection well and suction pressure are substantially linear, and the size of its ratio is relevant with landfill thickness with the landfill time of location rubbish,, by setting pressure, pop one's head in meanwhile, determine the coverage of bleeding.
104: when having methane collection system, use flue gas analyzer to monitor collecting well methane concentration, by methane gas analyser three ground, gather sequential control system and obtain leucoaurin content;
Wherein, this step is specially: use flue gas analyzer to monitor collecting well methane concentration.Collecting cross section, well exit increase test sample device section, from test sample device section lower end and the junction air inlet of collecting well, give vent to anger and input collection tube etc. in upper end, and test sample mouth and temperature mouth are set in side.It is that example describes that flue gas analyzer in the embodiment of the present invention adopts moral figure testo350pro flue gas analyzer, and during specific implementation, the embodiment of the present invention does not limit this.Flue gas probe and the design of temp probe (K type) model size in conjunction with moral figure testo350pro flue gas analyzer can closed test sample mouth and temperature mouths.During measurement, testo350Pro flue gas analyzer is connected with dynamic case, directly carries out field monitoring, convenient and swift, the error of avoiding sample collection, transportation to bring.Moral figure testo350Pro is furnished with various flow sensors, can measure the Gas Parameters of various gases, can measure 6 kinds of parameters at most simultaneously.Also can measure differential pressure, calculate flue gas flow rate/flow, and various gas flue gas annual emissions.The long 700mm of flue gas probe of standard configuration, 500 ℃ of heatproofs.Monitoring the data obtained can transmit by data-interface.
Flow sensor configuration is as follows: the flow sensor in the embodiment of the present invention adopts imported with original packaging intelligent vortex shedding flowmeter, be total to quadruplet, gauge outfit has liquid crystal display instantaneous delivery and integrated flow, and instantaneous delivery is pressed range output 4-20MA current signal to flow totalizer meter, precision 0.5%.
Wherein, the three ground collection sequential control systems of the methane gas analyser in the embodiment of the present invention can be realized a set of gas analyzer and gather three ground gas CH 4concentration, the cost of reducing investment outlay, this system adopts Siemens S7 series PLC to control, the CH of the house steward of its collection, power generation pipeline, torch pipeline 4concentration signal is by realizing continuous coverage, the wherein CH of power generation pipeline to the sequential control of zero-pressure solenoid valve (set point or reference input signal be table execution control on schedule automatically) 4concentration signal is exported to genset by signal sub power distribution orchestration and is controlled for unit.
Flow totalizer meter adopts imported with original packaging WP series integrating instrument, and it can collecting temperature, pressure and flow signal, and instantaneous delivery and integrated flow are the mark condition flow after temperature pressure compensation.
Wherein, step 102 to the execution sequence of step 104 is to select to carry out according to the actual conditions of refuse landfill, optional step 102 in the refuse landfill landfill process without methane collection system, optional step 103 after closing, and in the refuse landfill that has methane collection system omnidistance optional step 104.
105: the first methane content, the second methane content or leucoaurin content are sent to host computer workstation by data service center, by host computer workstation, obtain the gas production rate of unit weight rubbish within the unit interval;
Wherein, this step is specially: by the rubbish total amount that produces detected gas, by host computer workstation, can calculate the gas production rate of unit weight rubbish within the unit interval, the gas production rate in this unit interval is for imitating the value of core garbage degradation half life period.
106: adopt single order evanescent mode, according to the content of organic carbon, the first methane content, the second methane content and leucoaurin content, obtain the discharge capacity of methane;
Adopt single order decay (FOD) pattern, and in conjunction with actual, the Monitoring Data of methane gas and waste component and correlative study achievement are revised its default parameter, bring forward the selection principle of parameter under different condition, the method for specifically calculating methane emission is:
CH 4calculating:
E CH4=DDOC mdecompT×F×16/12 (1)
In formula (1): E cH4cH for T landfill municipal solid wastes 4discharge capacity, unit is ton; DDOC mdecopTdDOC for T decomposition m, its computing method are shown in formula (2), (3) and (4) below; F is the CH in the refuse landfill gas producing 4ratio, determines in conjunction with investigation and actual monitoring data; 16/12 is CH 4/ C molecular weight ratio.
In first kernel response, result quantities is proportional with reaction material quantity all the time.Waste material be deposited on sanitary land fill time and the annual CH producing 4amount is irrelevant, only with the decomposing material gross mass in place was relevant at that time.If know initial time sanitary land fill in the quantity of decomposing material, each year all can be considered the First Year in evaluation method, completing that basic single order calculates can adopt this two simple formula, and decay reaction starts from depositing the January 1 of that year afterwards.
The T DDOC that the year end, sanitary land fill was accumulated m:
DDOC maT=DDOC mdT+(DDOC maT-1×e -k) (2)
The DDOC that T decomposes m:
DDOC mdecompT=DDOC maT-1×(1-e -k) (3)
In formula (2) and (3): T is the inventory time; DDOC maTfor the T DDOC that the year end, sanitary land fill was accumulated m, unit is ton; DDOC maT-1for (T-1) DDOC that terminal hour sanitary land fill is accumulated every year m, unit is ton; DDOC mdTfor T deposit to sanitary land fill DDOC m, by the content of Degradable organic carbon and the rubbish total amount of T landfill that monitoring obtains, multiplying each other and can obtain, unit is ton; K is reaction constant, k=ln (2)/t 1/2, unit is year, t 1/2for time half life period, wherein, time half life period according to unit weight rubbish the gas production rate within the unit interval determine.
In single order evanescent mode, the half life period of garbage degradation is the key parameter that affects landfill gas change of production trend, and the span that pattern is recommended is 5~10 years (a represents year), can be according to the CH of experimental monitoring gained 4gas yield is checked the concrete numerical value that the garbage degradation half life period should get.
107: according to the content of organic carbon, obtain CO 2and N 2the discharge capacity of O;
CO in waste incineration 2calculating:
E CO 2 = MSW × Σ j ( WF j × dm j × CF j × FCF j × OF j ) × 44 / 12 - - - ( 4 )
In formula (4):
Figure BDA0000119058310000082
for burning the CO of municipal solid wastes 2discharge capacity, unit is ton; WF jfor the number percent of ingredient j in solid waste, according to the data of investigation and actual measurement, obtain; Dm jfor the dry matter percentage in ingredient j; CF jratio for total carbon in the dry of ingredient j; FCF jfor the ratio (total carbon remove degradable organic carbon DOC) of mineral carbon in total carbon; OF jfor oxidation factor, get 100%; 44/12 is CO 2/ C molecular weight ratio.
N in waste incineration 2the calculating of O:
E N 2 O = MSW × EF N 2 O × 10 - 6 × GWP N 2 O - - - ( 5 )
In formula (5):
Figure BDA0000119058310000092
for burning municipal solid wastes discharge N 2the CO2 emission equivalent that O produces, unit is ton; The municipal solid wastes quality of MSW for burning, unit is ton;
Figure BDA0000119058310000093
for N 2the emission factor of O, gets IPCC default value 50gN 2o/ ton municipal solid wastes; GWP n2Ofor N 2greenhouse effect and CO that O produces 2the multiple of comparing, gets 310.
108: host computer workstation is to the discharge capacity of methane, CO 2and N 2the discharge capacity of O is processed, and obtains data and curves figure.
Wherein, on data and curves figure, can directly find out discharge capacity, the CO of methane 2and N 2the discharge capacity of O, has facilitated the multiple needs in practical application.
Wherein, in order to access the CO of garbage disposal Life cycle 2discharge capacity, the embodiment of the present invention also comprises the indirect discharge capacity of upstream and downstream.
Upstream comprises: upstream activity level and emission factor multiply each other and obtain CO 2discharge capacity.Wherein, activity level is specially: the energy-output ratio and the power consumption that in transportation rubbish process, consume.Adopt default value and the Chinese regional power grids line-based emission factor of the fossil energy greenhouse gas emission factor that IPCC provides, activity level and emission factor are multiplied each other and obtain the CO in this stage 2discharge capacity.
Downstream comprises: from output electric weight to CO 2cER monitor, output electric energy has reduced the carbon emission amount of common generating, the CO that has offset the part in garbage disposal 2discharge capacity.Be specially: after domestic rubbish disposal, externally the electric weight of output is multiplied by the local CO generating electricity 2average emission coefficient.The CO of local generating 2average emission coefficient is line-based emission factor, should be electric weight limit emission factor (EF grid, OM, y) and capacity limit emission factor (EF grid, BM, y) weighted mean, claim again combination marginal CM, weight wOM and wBM default value are 50%.For example: Tianjin is positioned at North China, adopt region, North China electric network data.In sum, the embodiment of the present invention is by methane gas and waste component are monitored, to the CH in component of refuse, Degradable organic carbon content, refuse landfill gas 4ratio and half life period etc. revise, and bring forward the selection principle of above-mentioned parameter under different condition, and field instrument and host computer workstation are contacted, can real-time update data; The embodiment of the present invention has reduced the cost of monitoring, and monitoring result accuracy stable and that adjust is higher.
It will be appreciated by those skilled in the art that accompanying drawing is the schematic diagram of a preferred embodiment, the invention described above embodiment sequence number, just to describing, does not represent the quality of embodiment.
The foregoing is only preferred embodiment of the present invention, in order to limit the present invention, within the spirit and principles in the present invention not all, any modification of doing, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.

Claims (5)

1. a greenhouse gas emission monitoring method of town household refuse disposal system, is characterized in that, said method comprising the steps of:
(1) from the different rubbish of the 6 classes source that produces, gather respectively monitoring sample, obtain the content of organic carbon, and using the content typing host computer workstation of organic carbon as parameter;
(2) when in the landfill operation stage and without methane collection system, take step as unit, realize the landfill of rubbish, adopt static chamber method to monitor methane content, by methane gas analyser three ground, gather sequential control system and obtain the first methane content;
(3) when in the closing stage and without described methane collection system, natural pressure and methane content initial value in the landfill gas of all experiment wells of pre-test of bleeding, gas collection well is bled and measured bleed negative pressure and landfill gas composition, pressure and composition in monitor well monitoring landfill gas changes simultaneously, setting pressure probe, determine the coverage of bleeding, described methane gas analyser three ground gather sequential control system and obtain the second methane content according to pressure and composition;
(4) when having described methane collection system, use flue gas analyzer to monitor collecting well methane concentration, by described methane gas analyser three ground, gather sequential control system and obtain leucoaurin content;
(5) described the first methane content, described the second methane content or described leucoaurin content are sent to described host computer workstation by data service center, by described host computer workstation, obtain the gas production rate of unit weight rubbish within the unit interval;
(6) adopt single order evanescent mode, according to the content of described organic carbon, described the first methane content, described the second methane content and described leucoaurin content, obtain the discharge capacity of methane;
(7) according to the content of described organic carbon, obtain CO 2and N 2the discharge capacity of O;
(8) described host computer workstation is to the discharge capacity of described methane, described CO 2and N 2the discharge capacity of O is processed, and obtains data and curves figure;
Wherein, optional step (2) in the refuse landfill landfill process without described methane collection system, optional step (3) after closing, and in the refuse landfill that has described methane collection system omnidistance optional step (4).
2. a kind of greenhouse gas emission monitoring method of town household refuse disposal system according to claim 1, is characterized in that, the discharge capacity of described methane is specially:
Adopt single order evanescent mode, the discharge capacity of described methane:
E CH4=DDOC mdecompT×F×16/12
E cH4cH for T landfill municipal solid wastes 4discharge capacity, unit is ton; DDOC mdecopTdDOC for T decomposition m; F is the CH in the refuse landfill gas producing 4ratio; 16/12 is CH 4/ C molecular weight ratio;
The T DDOC that the year end, sanitary land fill was accumulated m:
DDOC maT=DDOC mdT+(DDOC maT-1×e -k)
The DDOC that T decomposes m:
DDOC mdecompT=DDOC maT-1×(1-e -k)
T is the inventory time; DDOC maTunit is ton; DDOC maT-1the DDOC accumulating for T-1 terminal hour sanitary land fill m, unit is ton; DDOC mdTfor T deposit to sanitary land fill DDOC m, unit is ton; K is reaction constant, k=ln (2)/t 1/2, unit is year, t 1/2for time half life period, wherein, described time half life period according to described unit weight rubbish the gas production rate within the unit interval determine.
3. a kind of greenhouse gas emission monitoring method of town household refuse disposal system according to claim 1, is characterized in that, described CO 2discharge capacity:
E CO 2 = MSW × Σ j ( WF j × dm j × CF j × FCF j × OF j ) × 44 / 12
Figure FDA0000394239690000022
for burning the CO of municipal solid wastes 2discharge capacity, unit is ton; WF jnumber percent for ingredient j in solid waste; Dm jfor the dry matter percentage in ingredient j; CF jratio for total carbon in the dry of ingredient j; FCF jfor the ratio of mineral carbon in total carbon; OF jfor oxidation factor, get 100%; 44/12 is CO 2/ C molecular weight ratio; The municipal solid wastes quality of MSW for burning.
4. a kind of greenhouse gas emission monitoring method of town household refuse disposal system according to claim 1, is characterized in that, described N 2the discharge capacity of O:
E N 2 O = MSW × EF N 2 O × 10 - 6 × GWP N 2 O
Figure FDA0000394239690000024
for burning municipal solid wastes discharge N 2the CO2 emission equivalent that O produces, unit is ton; The municipal solid wastes quality of MSW for burning, unit is ton;
Figure FDA0000394239690000025
for N 2the emission factor of O; GWP n2Ofor N 2greenhouse effect and CO that O produces 2the multiple of comparing, gets 310.
5. a kind of greenhouse gas emission monitoring method of town household refuse disposal system according to claim 1, is characterized in that, described method also comprises: the indirect discharge capacity to upstream and downstream is monitored,
The indirect discharge capacity of upstream comprises: upstream activity level and emission factor multiply each other and obtain CO 2discharge capacity; Wherein, described activity level is specially: the energy-output ratio and the power consumption that in transportation rubbish process, consume;
The indirect discharge capacity in downstream comprises: from output electric weight to CO 2cER monitor, be specially: after domestic rubbish disposal, externally the electric weight of output is multiplied by the CO of local generating 2average emission coefficient, the CO of described local generating 2average emission coefficient is line-based emission factor, is the weighted mean of electric weight limit emission factor and capacity limit emission factor.
CN201110413530.5A 2011-12-13 2011-12-13 Greenhouse gas emission monitoring method of town household refuse disposal system Active CN102494722B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201110413530.5A CN102494722B (en) 2011-12-13 2011-12-13 Greenhouse gas emission monitoring method of town household refuse disposal system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201110413530.5A CN102494722B (en) 2011-12-13 2011-12-13 Greenhouse gas emission monitoring method of town household refuse disposal system

Publications (2)

Publication Number Publication Date
CN102494722A CN102494722A (en) 2012-06-13
CN102494722B true CN102494722B (en) 2014-03-19

Family

ID=46186566

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201110413530.5A Active CN102494722B (en) 2011-12-13 2011-12-13 Greenhouse gas emission monitoring method of town household refuse disposal system

Country Status (1)

Country Link
CN (1) CN102494722B (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103065224B (en) * 2012-12-31 2016-03-09 雷学军 A kind of living beings landfill management method
CN106198305B (en) * 2016-09-13 2019-03-08 成都创慧科达科技有限公司 A kind of greenhouse gas emissions detection device
CN108256701B (en) * 2018-04-13 2021-07-27 重庆交通大学 IPCC-SD model-based urban domestic garbage landfill methane emission reduction path optimization method
CN108444536B (en) * 2018-05-16 2024-02-13 浙江大学 Device and method for measuring sulfur-containing gas emission of portable refuse landfill
CN108920885A (en) * 2018-09-05 2018-11-30 南京大学 A kind of heavy metal cadmium Source Apportionment
CN110288355A (en) * 2019-05-27 2019-09-27 郭玥锋 A kind of accounting method for the greenhouse gas emission that castoff burning processing generates
CN113567615A (en) * 2021-07-29 2021-10-29 上海城市水资源开发利用国家工程中心有限公司 Novel DOC index determination method for degradable organic carbon in sludge
CN113899853B (en) * 2021-09-17 2023-08-25 山东省产品质量检验研究院 Rapid detection method for degradation performance of degradable plastic

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH117371A (en) * 1997-06-18 1999-01-12 Nkk Corp Multi-channel data display method of plant
JP2005152698A (en) * 2003-11-20 2005-06-16 Yanmar Co Ltd Treatment device of organic waste
CN101722173A (en) * 2008-10-28 2010-06-09 上海市机电设计研究院有限公司 Integrated garbage treatment system
CN201764988U (en) * 2010-04-30 2011-03-16 北京时代桃源环境科技有限公司 Garbage landfill gas detection system

Also Published As

Publication number Publication date
CN102494722A (en) 2012-06-13

Similar Documents

Publication Publication Date Title
CN102494722B (en) Greenhouse gas emission monitoring method of town household refuse disposal system
Phillips et al. The value of soil respiration measurements for interpreting and modeling terrestrial carbon cycling
Ozkaya et al. Neural network prediction model for the methane fraction in biogas from field-scale landfill bioreactors
Savic et al. Quo vadis water distribution model calibration?
Czepiel et al. Landfill methane emissions measured by enclosure and atmospheric tracer methods
Zhang et al. An integrated model of soil, hydrology, and vegetation for carbon dynamics in wetland ecosystems
Wilkinson et al. Rivers and coastal research in the Land Ocean Interaction Study
Mohan et al. Sensitivity of PBL parameterizations on PM10 and ozone simulation using chemical transport model WRF-Chem over a sub-tropical urban airshed in India
Spokas et al. A process‐based inventory model for landfill CH4 emissions inclusive of seasonal soil microclimate and CH4 oxidation
CN102680662B (en) Device and method for synchronously determining soil substrate and gas emission
Wen et al. A backward-time stochastic Lagrangian air quality model
Tan A multi-period source–sink mixed integer linear programming model for biochar-based carbon sequestration systems
CN105809249B (en) A kind of PM2.5 Concentration Testings based on amphineura network and forecasting system and method
Woodward et al. Uncertainty in the modelling of spatial and temporal patterns of shallow groundwater flow paths: The role of geological and hydrological site information
Hrad et al. Quantification of methane emissions from full-scale open windrow composting of biowaste using an inverse dispersion technique
Bui et al. Integrated model for methane emission and dispersion assessment from landfills: A case study of Ho Chi Minh City, Vietnam
Liu et al. ModOdor: 3D numerical model for dispersion simulation of gaseous contaminants from waste treatment facilities
Hrad et al. Comparison of forward and backward Lagrangian transport modelling to determine methane emissions from anaerobic digestion facilities
Cakir et al. A comparative study on estimating the landfill gas potential: Modeling and analysis
Huitric et al. Measuring landfill gas collection efficiency using surface methane concentrations
Benini et al. Indicators and targets for the reduction of the environmental impact of EU consumption: Overall environmental impact (resource) indicators-Deliverable 3
Chesnaux et al. Comparing isotopic groundwater age measurements with simulated groundwater ages: example of the Abbotsford–Sumas Aquifer (USA and Canada) and application
Gök Estimation of methane generation and energy potential of Nigde landfill site using first order mathematical modelling approaches
Zyakun et al. Estimation of microbial methane generation and oxidation rates in the municipal solid waste landfill of Kaluga city, Russia
Middelburg et al. Working group report Relations between scale, model approach and model parameters

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant