CN102491646B - Antique silver-plating production method of hollow glass product - Google Patents
Antique silver-plating production method of hollow glass product Download PDFInfo
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- CN102491646B CN102491646B CN201110408966.5A CN201110408966A CN102491646B CN 102491646 B CN102491646 B CN 102491646B CN 201110408966 A CN201110408966 A CN 201110408966A CN 102491646 B CN102491646 B CN 102491646B
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Abstract
The invention relates to an antique silver-plating production method of a glass product, and the method comprises the following steps: performing pretreatment on the inner surface of the glass product by adopting a surface treatment agent to attach a layer of the treatment agent on the inner surface of the glass product, and then performing a silver plating process flow, wherein the part which is attached with the treatment agent on the inner wall of the glass product can not be plated with silver during the silver plating process flow, so that the antique silver-plated glass product with natural texture and spots is formed. The antique silver-plating production method disclosed by the invention can be used for developing and obtaining the glass product with a non-uniform plated layer and an antique silver-plated effect, is simple in process, low in cost and high in benefits, and increasing a new handicraft article variety in the market.
Description
Technical field
The invention belongs to surface chemistry and Technology field, be specifically related to a kind of glasswork silver-plated production method modelled after an antique.
Technical background
In the silver-plated mode of production of conventional hollow glass products, what clean glasswork inwall obtained is the silver-plated rete of complete minute surface.Can not meet the demand of market to different shape silvered glass goods, and meet different consumer groups' hobby.The ratio of lubricating oil, wherein the ratio of diesel oil and lubricating oil is between 300: 1～200: 1.
Summary of the invention
The object of the invention is to provide a kind of production method of silvered glass goods modelled after an antique, obtains a kind of silvered glass ornament modelled after an antique of the people's of meeting demand.
The invention provides a kind of glasswork silver-plated production method modelled after an antique.The feature of the method is to adopt special surface treatment agent to carry out pre-treatment to glasswork internal surface, makes glasswork internal surface stick last layer surface treatment agent.In silver plating process process subsequently, on glasswork inwall, stick and have the position for the treatment of agent can not be coated with silver, thereby be formed with the mottled silvered glass goods modelled after an antique of natural texture.
The technical solution used in the present invention comprises the steps:
1) pre-treatment of clean glasswork internal surface:
First use industrial deionization pure water by glasswork internal washing 2 roads; Again by 3000 mass parts diesel oil, 10～15 mass parts lubricating oil, 20 mass parts ethanol join in the glasswork cleaning successively, left and right vibration 4-6 is after second, glasswork is immersed in immediately (hot water does not enter in glasswork) in the hot water of 39 to 41 ℃, 9 to 11 seconds of vibration, mixed treatment agent liquid is poured out, at this moment glasswork internal surface sticks the treatment agent that diesel oil described in last layer, lubricating oil and ethanol mix.
2) preparation of silver ammino solution:
In container, add successively 20000 mass parts deionized waters, 100 mass parts Silver Nitrates and 200 mass parts sodium hydroxide, finally drip ammoniacal liquor, and constantly stir until white precipitate completely dissolve obtains colourless transparent solution (title silver ammino solution), standby.
3) preparation of glucose solution:
In container, add 20000 mass parts deionized waters, 100 mass parts glucose and 100 mass parts ethanol, stirring and dissolving obtains glucose sugar soln.
4) glasswork is silver-plated:
Described silver ammino solution and glucose sugar soln are joined through sticking in the glasswork that has treatment agent on pre-treatment, inwall simultaneously, vibrate 1 minute, mixed solution is poured out.Use again the liquid detergent aqueous cleaning glasswork inner (sticking in treatment agent on glasswork inwall can not be cleaned) of joining 1000 kilograms of clear water by 1 kilogram of liquid detergent, by water evacuation.Finally put into 69 to 71 ℃ of baking box bakings and can obtain silvered glass goods modelled after an antique in 29 to 31 minutes.
Key of the present invention is: by controlling the ratio of diesel oil, ethanol and lubricating oil in preprocessing process, thereby reach the object of controlling silver-plated lines size.Adopt the method can obtain the different silvered glass goods of coating, and be not only confined to the hollow glass products of regular shape, also can be used for the production of hollow glass products in irregular shape.
The key link of this invention is to utilize diesel oil, and lubricating oil and ethanol are according to certain ratio.Wherein lubricating oil is used for diesel engine oil, and diesel oil is commercially available 0
#diesel oil.The effect of ethanol is to make diesel oil and lubricating oil mutually miscible better, but not dissolves completely, make lubricating oil with the form of small droplets be present in diesel oil mutually in.If the spot of coating silver is diminished, suitably improve lubricating oil ratio, in like manner, it is large that spot becomes, and reduces lubricating oil ratio.
The present invention develops and has obtained the even modelled after an antique silver-plated effect glasswork of uneven coating, and technique is simple, and low-cost high-efficiency benefit, for market has increased a new artwork kind.
Embodiment
1, hollow glass ball coated silver spheres preparation modelled after an antique
Cut-off footpath is one of the clean glass sphere of 100mm, first adds 5ml by 3000 mass parts diesel oil, 15 mass parts lubricating oil, the treatment agent that 20 mass parts ethanol form is in glass sphere, after vibration mixes, mixed processing agent liquid is poured out, obtained the glass sphere that inwall adheres to mixed processing agent liquid, standby.Then add silver ammino solution and the 5ml glucose solution that 10ml prepares in advance repeatedly to vibrate simultaneously, can obtain silvered glass ball modelled after an antique
2, close grain hollow glass ball silver-plated goods preparation modelled after an antique
Get out-of-shape, one of the clean glasswork of the about 50ml of internal volume, first add 10ml by 3000 mass parts diesel oil, 10 mass parts lubricating oil, the surface treatment agent that 15 mass parts ethanol form is in glass sphere, after vibration mixes, mixed solution is poured out, obtained the glasswork that inwall adheres to more mixed solution, standby.Then add silver ammino solution and the 5ml glucose solution that 10ml prepares in advance repeatedly to vibrate simultaneously, can obtain close grain hollow silvered glass goods modelled after an antique.
Claims (1)
1. a hollow glass products silver-plated production method modelled after an antique, the steps include:
1) adopt surface treatment agent to carry out pre-treatment to glasswork internal surface:
First use industrial deionization pure water by glasswork internal washing 2 roads; Again by 3000 mass parts diesel oil, 10～15 mass parts lubricating oil, 20 mass parts ethanol join in the glasswork cleaning successively, left and right vibration 4-6 is after second, glasswork is immersed in immediately in the hot water of 39 to 41 ℃, 9 to 11 seconds of vibration, mixed treatment agent liquid is poured out, at this moment glasswork internal surface sticks the treatment agent that diesel oil described in last layer, lubricating oil and ethanol mix; In silver plating process process subsequently, on glasswork inwall, stick and have the position for the treatment of agent can not be coated with silver, thereby be formed with the mottled silvered glass goods modelled after an antique of natural texture;
2) prepare silver ammino solution:
In container, add successively 20000 mass parts deionized waters, 100 mass parts Silver Nitrates and 200 mass parts sodium hydroxide, finally drip ammoniacal liquor, and constantly stir until white precipitate completely dissolve obtains colourless transparent solution-silver ammino solution, standby;
3) prepare glucose solution:
In container, add 20000 mass parts deionized waters, 100 mass parts glucose and 100 mass parts ethanol, stirring and dissolving obtains glucose sugar soln;
4) glasswork is silver-plated:
Described silver ammino solution and glucose sugar soln are joined through sticking in the glasswork that has treatment agent on pre-treatment, inwall simultaneously, vibrate 1 minute, mixed solution is poured out, then used the liquid detergent aqueous cleaning glasswork inside of joining 1000 kilograms of clear water by 1 kilogram of liquid detergent, by water evacuation; Finally put into 69 to 71 ℃ of baking box bakings and within 29 to 31 minutes, can obtain the mottled silvered glass goods modelled after an antique of natural texture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110408966.5A CN102491646B (en) | 2011-12-12 | 2011-12-12 | Antique silver-plating production method of hollow glass product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110408966.5A CN102491646B (en) | 2011-12-12 | 2011-12-12 | Antique silver-plating production method of hollow glass product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102491646A CN102491646A (en) | 2012-06-13 |
| CN102491646B true CN102491646B (en) | 2014-04-02 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201110408966.5A Active CN102491646B (en) | 2011-12-12 | 2011-12-12 | Antique silver-plating production method of hollow glass product |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105459718A (en) * | 2016-01-11 | 2016-04-06 | 珠海格力电器股份有限公司 | Mirror-like silver craft product |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048022A (en) * | 1989-06-14 | 1990-12-26 | 中国科学院上海硅酸盐研究所 | Novel dark brown decorative mirror and chemically plating method thereof |
| WO1998022406A1 (en) * | 1996-11-21 | 1998-05-28 | Philips Electronics N.V. | Method of applying a silver layer to a glass substrate |
| CN1974460A (en) * | 2006-12-01 | 2007-06-06 | 广东工业大学 | Silver plated hollow glass micro bead and its surface silver plating process |
-
2011
- 2011-12-12 CN CN201110408966.5A patent/CN102491646B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048022A (en) * | 1989-06-14 | 1990-12-26 | 中国科学院上海硅酸盐研究所 | Novel dark brown decorative mirror and chemically plating method thereof |
| WO1998022406A1 (en) * | 1996-11-21 | 1998-05-28 | Philips Electronics N.V. | Method of applying a silver layer to a glass substrate |
| US6027862A (en) * | 1996-11-21 | 2000-02-22 | U.S. Philips Corporation | Method of applying a silver layer to a glass substrate |
| CN1974460A (en) * | 2006-12-01 | 2007-06-06 | 广东工业大学 | Silver plated hollow glass micro bead and its surface silver plating process |
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| CN102491646A (en) | 2012-06-13 |
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Inventor after: Han Fengzhi Inventor after: Wu Hui Inventor after: Li Yijun Inventor after: Ye Hu Inventor after: Yu Jin Inventor after: Chen Qingcai Inventor after: Xing Guangyu Inventor before: Han Fengzhi Inventor before: Wu Hui Inventor before: Ye Hu Inventor before: Yu Jin Inventor before: Chen Qingcai Inventor before: Xing Guangyu |
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Free format text: CORRECT: INVENTOR; FROM: HAN FENGZHI WU HUI YE HU YU JIN CHEN QINGCAI XING GUANGYU TO: HAN FENGZHI WU HUI LI YIJUN YE HU YU JIN CHEN QINGCAI XING GUANGYU |
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