CN102489412A - Method for activating calamine in flotation process - Google Patents
Method for activating calamine in flotation process Download PDFInfo
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- CN102489412A CN102489412A CN2011104406275A CN201110440627A CN102489412A CN 102489412 A CN102489412 A CN 102489412A CN 2011104406275 A CN2011104406275 A CN 2011104406275A CN 201110440627 A CN201110440627 A CN 201110440627A CN 102489412 A CN102489412 A CN 102489412A
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- CN
- China
- Prior art keywords
- smithsonite
- flotation
- sodium
- calamine
- hydroximic acid
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000000034 method Methods 0.000 title claims abstract description 32
- 238000005188 flotation Methods 0.000 title claims abstract description 27
- 239000011787 zinc oxide Substances 0.000 title abstract description 20
- 230000003213 activating effect Effects 0.000 title abstract description 4
- 229940105847 calamine Drugs 0.000 title abstract 7
- 229910052864 hemimorphite Inorganic materials 0.000 title abstract 7
- 235000014692 zinc oxide Nutrition 0.000 title abstract 7
- CPYIZQLXMGRKSW-UHFFFAOYSA-N zinc;iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+3].[Fe+3].[Zn+2] CPYIZQLXMGRKSW-UHFFFAOYSA-N 0.000 title abstract 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 34
- 239000011734 sodium Substances 0.000 claims abstract description 34
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 34
- 230000004913 activation Effects 0.000 claims abstract description 26
- 238000012360 testing method Methods 0.000 claims abstract description 23
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 9
- 238000009837 dry grinding Methods 0.000 claims abstract description 6
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 38
- 239000002253 acid Substances 0.000 claims description 23
- 239000012190 activator Substances 0.000 claims description 17
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 11
- 229910052725 zinc Inorganic materials 0.000 claims description 11
- 239000011701 zinc Substances 0.000 claims description 11
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 7
- -1 dodecyl primary amine Chemical class 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 239000012141 concentrate Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000007127 saponification reaction Methods 0.000 claims description 5
- 238000004513 sizing Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 13
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 13
- 239000011707 mineral Substances 0.000 abstract description 13
- 238000011084 recovery Methods 0.000 abstract description 4
- 235000010755 mineral Nutrition 0.000 abstract 2
- 229910052979 sodium sulfide Inorganic materials 0.000 abstract 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 abstract 2
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 26
- 238000005516 engineering process Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052844 willemite Inorganic materials 0.000 description 1
- 229910001656 zinc mineral Inorganic materials 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
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- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention provides a method for activating calamine in the flotation process and belongs to the technical field of ore benefication. The method comprises the following steps of: dry-milling calamine pure mineral to obtain test samples which comprise 80 to 90 weight percent of 320 meshes qualified particles; adding the test samples into a flotation machine, wherein the flotation pulp volume is 50 ml and the test mineral samples at each time is 0.5 g; and adding a combined regulator of sodium hydroxamate, sodium carbonate and sodium sulfide into pulp which is stirred uniformly and taking the combined regulator as an activating agent of the calamine, wherein the total adding amount is 80 to 140 mg/L per ton of the calamine and the action time is 4 to 5 minutes, the using amount of a collector dodecylamine is 30 to 40 mg/L and the action time is 4 to 5 minutes, and the flotation time is 5 to 7 minutes. The activation effect of the method is more excellent than the conventional activation effect; the total using amount of the sodium sulfide is reduced by 20 to 30 percent; and compared with the conventional activation method of the calamine, the activation method has the advantage that: the flotation recovery rate of the calamine can be increased by 6 to 12 percent.
Description
Technical field
The present invention relates to a kind of activation method of smithsonite floatation process, relate in particular to the activation method of low-grade zinc oxide ore floatation recovery smithsonite, belong to the technique of preparing field.
Background technology
China's zinc oxide ore resource reserve is abundant; Lean ore is many, and rich ore is few, and it is concentrated relatively to distribute; Mainly be distributed in provinces such as Yunnan, Guizhou, Gansu, Shaanxi; Especially reserves are bigger in Yunnan, and only Yunnan Province's zinc metal reserves are just had an appointment 7,100,000 tons, and ground such as the Qinghai and the Inner Mongol also have a certain amount of zinc oxide mineral deposit to distribute.Yet the zinc oxide ore resource of the low-grade high impurity of China is not rationally utilized owing to lack efficiently the processed technology.
The zinc oxide mineral are one type of important zinc-bearing minerals, are the results of the long-term weathering of zinc sulfide ore, and as the secondary mineral of zinc, the zinc oxide ore thing with industrial value mainly contains smithsonite, smithsonite, willemite and marionite etc.Because its mineral species is various, the association of mixing each other, and disseminated grain size is thinner; The argillization state is more serious; Often contain a certain amount of soluble-salt, iron oxide and clay sludge in this type of oxide ore simultaneously, make the ore dressing of zinc mineral reclaim very difficulty, the rate of recovery is on the low side.
Smithsonite is common in the zinc oxide ore one of zinc oxide mineral of industrial value to be arranged most; The ratio that it accounts in zinc oxide ore is only second to smithsonite; But smithsonite is because of its complicated structure, and exclusive surface nature is thought one of extremely difficult mineral that reclaim by ore dressing circle at present.For the flotation of smithsonite, sulfuration-primary amine method that people such as external Maurice Rey, Mckenna propose extensively adopts in industry, although this method affect factor is numerous, and flotation conditions is also very harsh.But the flotation of smithsonite do not obtain stride the epoch progress before, this method has still received favor widely.Because smithsonite is normal and smithsonite association coexistence; Most studies worker wants to reclaim smithsonite simultaneously with the sulfide flotation of smithsonite; Have to abandon because of the sulfuration ten minutes difficulty of smithsonite eventually, present documents and materials both domestic and external are not all seen the relevant report that this method is used.Therefore, in order to reclaim the smithsonite in the zinc oxide ore efficiently, be badly in need of proposing a kind of activating technology of new smithsonite,, improve the resource utilization of zinc oxide ore to realize the efficient flotation of smithsonite.
Summary of the invention
Because zinc oxide ore character is complicated, contained mineral species is various, for solving in the zinc oxide ore characteristics such as smithsonite is hard to manage, the invention provides a kind of activation method of smithsonite floatation process, is used to solve the activation problem of floatation process smithsonite.
Technical scheme of the present invention is: adopt hydroximic acid sodium, sodium carbonate and vulcanized sodium combination activator to replace single activator to carry out activation, its concrete steps are passed through as follows:
(1) the quality percentage composition with smithsonite minal dry grinding to the qualified grade of 320 purposes accounts for 80 ~ 90wt%, obtains testing test portion;
(2) with the test test portion of step (1) ore pulp by solid-to-liquid ratio 1:2～1:3g/L, in the slip that stirs, add activator, it adds total amount is 80～140mg/L of ore pulp volume; Be 4～5min action time, adds collecting agent 30 ~ 40 mg/L then, and collecting agent action time is 4～5min; Carry out flotation after sizing mixing and scrape bubble; It is 5 ~ 7min that the bubble time is scraped in flotation, and the froth pulp that scrapes is flotation concentrate, and all the other are mine tailing.
Said smithsonite is for containing zinc 48.70 ~ 50.00wt%, and all the other are impurity such as calcium, magnesium, aluminium, iron, silicon, titanium.
Said activator is the emulsion of hydroximic acid sodium, sodium carbonate and vulcanized sodium, wherein hydroximic acid sodium: sodium carbonate: the mole proportioning of vulcanized sodium is 1:3:3, is common commercially available.
Activator hydroximic acid sodium in the said step (2) is by hydroximic acid formed sodium salt-hydroximic acid sodium after saponification.
Collecting agent in the said step (2) is dodecyl primary amine or dodecyl primary amine salt, is common commercially available.
Compared with prior art; The present invention has following advantage and good effect: through the combination activation of activator; Its effect is superior to the activation effect of single activator, when can improving the floatation indicators of smithsonite by a relatively large margin, can also reduce the consumption of vulcanized sodium.Combination activation effect of the present invention is superior to the effect of conventional activation, and total consumption of vulcanized sodium can reduce by 20 ~ 30%; Adopt activation method of the present invention, more conventional active flotation, the rate of recovery of smithsonite can improve 6 ~ 12 percentage points.
The specific embodiment
Below in conjunction with chart and embodiment the present invention is done further elaboration, but protection content of the present invention is not limited to said scope.
Embodiment 1
(1) taking from the plumbous zinc ore of Yunnan Province's Huize, is the pure natural mineral, and perfect crystalline is yellow or isabelline, contains the smithsonite minal of zinc 48.70wt%, and the quality percentage composition of dry grinding to the qualified grade of 320 purposes accounts for 80wt%, obtains testing test portion;
(2) with the test test portion of step (1) ore pulp by solid-to-liquid ratio 1:2g/L, in the slip that stirs, add activator, it adds total amount is the 80mg/L of ore pulp volume; Be 5min action time, adds collecting agent 30 mg/L then, and collecting agent action time is 4.5min; Carry out flotation after sizing mixing and scrape bubble; It is 5min that the bubble time is scraped in flotation, and the froth pulp that scrapes is flotation concentrate, and all the other are mine tailing.The activator that adopts is a hydroximic acid sodium: sodium carbonate: the mole proportioning of vulcanized sodium is 1:3:3, and hydroximic acid sodium is by hydroximic acid formed sodium salt-hydroximic acid sodium after saponification.The collecting agent that adopts is the dodecyl primary amine.(result is as shown in table 1)
Table 1 smithsonite combination activation effect and single activation effect are relatively
Embodiment 2
(1) taking from the plumbous zinc ore of Yunnan Province's Huize, is the pure natural mineral, and perfect crystalline is yellow or isabelline, contains zinc 49wt% smithsonite minal, and the quality percentage composition of dry grinding to the qualified grade of 320 purposes accounts for 85wt%, obtains testing test portion;
(2) with the test test portion of step (1) ore pulp by solid-to-liquid ratio 1:3g/L, in the slip that stirs, add activator, it adds total amount is the 115mg/L of ore pulp volume; Be 4.5min action time, adds collecting agent 35mg/L then, and collecting agent action time is 4min; Carry out flotation after sizing mixing and scrape bubble; It is 6min that the bubble time is scraped in flotation, and the froth pulp that scrapes is flotation concentrate, and all the other are mine tailing.The activator that adopts is a hydroximic acid sodium: sodium carbonate: the mole proportioning of vulcanized sodium is 1:3:3, and hydroximic acid sodium is by hydroximic acid formed sodium salt-hydroximic acid sodium after saponification.The collecting agent that adopts is a dodecyl primary amine salt.(result is as shown in table 2)
Table 2 smithsonite combination activation effect and single activation effect are relatively
Embodiment 3
(1) taking from the plumbous zinc ore of Yunnan Province's Huize, is the pure natural mineral, and perfect crystalline is yellow or isabelline, contains zinc 50.00wt% smithsonite minal, and the quality percentage composition of dry grinding to the qualified grade of 320 purposes accounts for 90wt%, obtains testing test portion;
(2) with the test test portion of step (1) ore pulp by solid-to-liquid ratio 1:2.5g/L, in the slip that stirs, add activator, it adds total amount is the 140mg/L of ore pulp volume; Be 4min action time, adds collecting agent 40 mg/L then, and collecting agent action time is 5min; Carry out flotation after sizing mixing and scrape bubble; It is 7min that the bubble time is scraped in flotation, and the froth pulp that scrapes is flotation concentrate, and all the other are mine tailing.The activator that adopts is a hydroximic acid sodium: sodium carbonate: the mole proportioning of vulcanized sodium is 1:3:3, and hydroximic acid sodium is by hydroximic acid formed sodium salt-hydroximic acid sodium after saponification.The collecting agent that adopts is a dodecyl primary amine salt.(result is as shown in table 3)
Table 3 smithsonite combination activation effect and single activation effect are relatively
Claims (5)
1. the activation method of a smithsonite floatation process is characterized in that through following steps:
(1) the quality percentage composition with smithsonite minal dry grinding to the qualified grade of 320 purposes accounts for 80 ~ 90wt%, obtains testing test portion;
(2) the test test portion with step (1) adds water preparation ore pulp by solid-to-liquid ratio 1:2 ~ 1:3, in the slip that stirs, adds activator, and it adds total amount is 80～140mg/L of ore pulp volume; Activator action time is 4～5min, adds collecting agent 30 ~ 40 mg/L then, and collecting agent action time is 4～5min; Carry out flotation after sizing mixing and scrape bubble; It is 5 ~ 7min that the bubble time is scraped in flotation, and the froth pulp that scrapes is flotation concentrate, and all the other are mine tailing.
2. according to the activation method of claims 1 described smithsonite floatation process, it is characterized in that: said smithsonite is for containing zinc 48.70 ~ 50.00wt%, and all the other are impurity.
3. according to the activation method of claims 1 described smithsonite floatation process, it is characterized in that: said activator is the emulsion of hydroximic acid sodium, sodium carbonate and vulcanized sodium, wherein hydroximic acid sodium: sodium carbonate: the mol ratio proportioning of vulcanized sodium is 1:3:3.
4. according to the activation method of claims 1 described smithsonite floatation process, it is characterized in that: the activator hydroximic acid sodium in the said step (2) is by hydroximic acid formed sodium salt-hydroximic acid sodium after saponification.
5. according to the activation method of claims 1 described smithsonite floatation process, it is characterized in that: the collecting agent in the said step (2) is dodecyl primary amine or dodecyl primary amine salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104406275A CN102489412A (en) | 2011-12-26 | 2011-12-26 | Method for activating calamine in flotation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104406275A CN102489412A (en) | 2011-12-26 | 2011-12-26 | Method for activating calamine in flotation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102489412A true CN102489412A (en) | 2012-06-13 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104406275A Pending CN102489412A (en) | 2011-12-26 | 2011-12-26 | Method for activating calamine in flotation process |
Country Status (1)
| Country | Link |
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| CN (1) | CN102489412A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106540815A (en) * | 2016-11-09 | 2017-03-29 | 长春黄金研究院 | A kind of microfine zinc oxide ore beneficiation method |
| CN111940146A (en) * | 2020-08-08 | 2020-11-17 | 云南省地质矿产勘查开发局中心实验室（国土资源部昆明矿产资源监督检测中心） | Low-temperature-resistant zinc oxide ore flotation composite reagent and preparation method and application thereof |
| CN112474060A (en) * | 2020-11-16 | 2021-03-12 | 福州大学 | Method for promoting heteropolar ore sulfuration flotation by using fluorine ions |
| CN115582224A (en) * | 2022-09-30 | 2023-01-10 | 昆明理工大学 | Flotation combined reagent and application thereof, and method for flotation desilication of micro-fine particle zinc oxide ore |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1066655A1 (en) * | 1982-06-21 | 1984-01-15 | Medikhanov Dalel G | Collector for flotation of zinc minerals |
| CN101734686A (en) * | 2009-09-08 | 2010-06-16 | 东北大学 | High value-added greening comprehensive utilization method for medium and low-grade zinc oxide ores |
-
2011
- 2011-12-26 CN CN2011104406275A patent/CN102489412A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1066655A1 (en) * | 1982-06-21 | 1984-01-15 | Medikhanov Dalel G | Collector for flotation of zinc minerals |
| CN101734686A (en) * | 2009-09-08 | 2010-06-16 | 东北大学 | High value-added greening comprehensive utilization method for medium and low-grade zinc oxide ores |
Non-Patent Citations (2)
| Title |
|---|
| C·A·佩雷拉等: "浮选含异极矿的锌矿石的药剂", 《国外金属矿选矿》, no. 5, 31 May 2005 (2005-05-31) * |
| 羊依金等: "羟肟酸活化异极矿浮选的研究", 《有色金属(选矿部分)》, no. 2, 28 February 1992 (1992-02-28) * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106540815A (en) * | 2016-11-09 | 2017-03-29 | 长春黄金研究院 | A kind of microfine zinc oxide ore beneficiation method |
| CN111940146A (en) * | 2020-08-08 | 2020-11-17 | 云南省地质矿产勘查开发局中心实验室（国土资源部昆明矿产资源监督检测中心） | Low-temperature-resistant zinc oxide ore flotation composite reagent and preparation method and application thereof |
| CN112474060A (en) * | 2020-11-16 | 2021-03-12 | 福州大学 | Method for promoting heteropolar ore sulfuration flotation by using fluorine ions |
| CN115582224A (en) * | 2022-09-30 | 2023-01-10 | 昆明理工大学 | Flotation combined reagent and application thereof, and method for flotation desilication of micro-fine particle zinc oxide ore |
| CN115582224B (en) * | 2022-09-30 | 2024-05-28 | 昆明理工大学 | Flotation combination reagent and application thereof, and method for flotation desilication of micro-fine zinc oxide ore |
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Application publication date: 20120613 |