CN102489146B - Air purifying agent - Google Patents

Air purifying agent Download PDF

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Publication number
CN102489146B
CN102489146B CN 201110429900 CN201110429900A CN102489146B CN 102489146 B CN102489146 B CN 102489146B CN 201110429900 CN201110429900 CN 201110429900 CN 201110429900 A CN201110429900 A CN 201110429900A CN 102489146 B CN102489146 B CN 102489146B
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Prior art keywords
component
air purifying
class
purifying agent
adsorbent
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Expired - Fee Related
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CN 201110429900
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CN102489146A (en
Inventor
魏海兵
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Shanghai net Industry Co., Ltd.
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魏海兵
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Abstract

The invention discloses an air purifying agent, which is composed of component A and component B. The component A is a liquid reactant prepared by percarbamide, diammonium phosphate, ammonium chloride, sodium lignosulfonate, tea polyphenol, water-soluble essence, and deionized water, while the component B is a solid reaction adsorbent prepared by a porous adsorbent, tourmaline, and a load reaction absorbent. Compared with similar products on the market, the air purifying agent of the invention has the advantages of rapid cleaning and lasting effectiveness. With the dual efficacy of sterilization and disinfection, and volatile pollution gas clearing, the air purifying agent has thorough effects and can generate objects with low toxicity or no toxicity. Characterized by easily available raw materials, simple preparation, low cost, and convenience for industrial production, the air purifying agent provided in the invention is proved by experiments to have a removal effect up to over 92% for high, medium and low concentration pollution.

Description

A kind of air purifying preparation
Technical field
The present invention relates to a kind of air purifying preparation.
Background technology
Air purifying preparation is applicable to various indoor environments such as newly-decorated room, automobile, office space, hotel, market.At present, mostly air purifying preparation is to cover based on fragrance the freshener aromatic etc. of peculiar smell, can not play sterilizing and removing formaldehyde, functions such as benzene series thing.And the product of independent removing formaldehyde can not be taken into account removing benzene series thing, ammonia, functions such as general volatile gas TOVC simultaneously.Chinese patent CN201110113811.9 discloses a kind of plants essential oil air purifying preparation and preparation method thereof, and it is with following raw materials by weight percent: eucalyptus essential oil 0.3, tea tree ethereal oil 0.3, argy wormwood essential oil 0.3, grape fruit essential oil 0.3, lime essential oil 0.4, lemon 0.4, peppermint essential oil 0.4, Lavender 0.6, fish pelargonium essential oil 0.9, cdear essential oil 0.4, Rosa Damascana 0.7, Pogostemon cablin essential oil 0.4, and diluent 94.6 is mixed with and forms.Be mainly used in removing in the automobile, indoor smoke and other peculiar smell purify the air of a room, and is of value to the healthy of people, its deficiency is that removal effect is not so good, can't act on PARA FORMALDEHYDE PRILLS(91,95), benzene series thing etc. volatility is polluted and the removing of bacterium class.Chlorine dioxide air cleanser that CN101143225 discloses a kind of applied range, cost is low, easy to use and keeping life is long and preparation method thereof.Air purifying preparation is made up of citric acid and the sodium chlorite aqueous solution that is potted in the bottle, and sodium chlorite aqueous solution's concentration is 3-25% mass concentration, and citric acid is sheet, granular or powdery, and the citric acid quality is 0.2-2% of sodium chlorite solution's quality.This air purifying preparation takes out citric acid in use, puts into the sodium chlorite aqueous solution, tightens bottle cap and shakes up, and namely slow release goes out chlorine dioxide, thereby reaches lasting, economical, safe purifying air.Its deficiency is to use not too convenient, to the benzene series thing, and ammonia, it is little that TOVC etc. remove the effect effect.
Summary of the invention
Technical problem to be solved by this invention provides a kind of free matter composition such as formaldehyde that sterilizing effect and interior decoration cause that has concurrently, benzene series thing, ammonia, the air purifying preparation that TOVC etc. pollutes.
This cleanser is divided into liquid reactants A component and solid-state adsorption reaction agent B component is formed.Place the B component again after wherein with the A component space of needs or environment place being sprayed earlier and adsorb decomposition, reach quick and durable completely to bacterium class and volatile formaldehyde jointly, the benzene series thing, ammonia, the reaction decomposes of TOVC etc. is removed effect.Be the omnibearing air cleaning prescription of the full effect of a kind of multi-functional goods.
For solving the problems of the technologies described above, air purifying preparation of the present invention is made up of A component liquid reactants, B component solid-state reaction adsorbent, by weight percentage,
A component liquid reactants is made by following material:
Percarbamide 15-55;
Diammonium hydrogen phosphate: 1-5
Ammonium chloride: 1-10;
Sodium lignin sulfonate: 0.5-5;
Tea Polyphenols: 0.5-3;
Soluble perfume: 0.1-5;
Deionized water: 40-79.9.
It is even that above-mentioned each composition is dissolved in deionized water for stirring in described ratio, is loaded in the bottle and sprays.Have the characteristic of urea and hydrogen peroxide after the percarbamide dissolving wherein concurrently.In water, be decomposed into urea, hydrogen peroxide and elemental oxygen, but the PARA FORMALDEHYDE PRILLS(91,95) molecular oxidation is removed and the dual highly effective reaction of amino addition at normal temperatures, has the sterilization to environment concurrently.
B component solid-state reaction adsorbent is made by following material:
Porous adsorbent class: 45-90;
Tourmaline: 5-20;
Load-reaction absorber class: 5-50.
Described porous adsorbent class: get active carbon, bamboo charcoal, treated earth, bentonite, attapulgite, diatomite, a kind of to multiple in the medical stone; Get the high temperature modified zeolite of acid-wash activation, sepiolite, one or more in the montmorillonite; Get activated alumina, 10X or 13X molecular sieve, Kiselgel A, a kind of to multiple in the vermiculite, mixed proportion is not limit.
Described load-reaction absorber class: by strong oxidizers such as one or more load acid potassium permanganates in the porous adsorbent or hydrogen peroxide, the mixed proportion of porous adsorbent is not limit.
Get final product stirring after the components in certain proportion mixing of 3 groups, being respectively charged into again in the ventilative class packing.Porous adsorbent is all selected bigger serface large pore volume class for use, utilize Van der Waals force to the benzene series thing, ammonia, TVOC etc. have the good adsorption removal effect, have the pyroelectric effect that the heat release temperature difference effect of utilizing when adsorbing excites the instant high-voltage of tourmaline concurrently, molecule to absorption has killing action, can also discharge the anion fine-purification air.The zeolite of modification, sepiolite, imvite has the performance of absorption and ion-exchange concurrently.Hyperthermia drying during the load-reaction absorbent is above by one or more (except tourmaline) 60 degree in the porous adsorbent, remove in the duct behind the contained gaseous impurity, be soaked in stirring and adsorbing in the strong oxidizers such as acid potassium permanganate or hydrogen peroxide, time discharges for waiting for no bubble, saturated the getting final product of duct absorption.Pick up the hyperthermia drying rear venting and remove the composition of surface absorption.Load-reaction absorbent PARA FORMALDEHYDE PRILLS(91,95) behind the load acid potassium permanganate, toluene, dimethylbenzene have extraordinary absorption afterreaction to remove effect.
The solid-state reaction adsorbent of B component is compared to load-reaction interpolations targetedly such as the single active carbon of the most products in market or bamboo charcoal PARA FORMALDEHYDE PRILLS(91,95), and it is efficiently obvious to remove effect.And the active carbon of market single component or bamboo charcoal are very limited to free formaldehyde molecule suction-operated through many-sided theory and practice confirmation, are that certain adsorption effect is arranged to the benzene series thing.And the absorption of the active carbon of single component or bamboo charcoal is saturated easily, and effective acting time is short, can only physical absorption, be subjected to the easy desorptions of ambient influnence such as temperature and humidity after the absorption, and can not use for a long time, repeatedly defective such as circular regeneration.And solid-state reaction adsorbent of the present invention not only has the absorption assimilation effect and has ion-exchange and chemical reaction oxidation scavenging action concurrently, discharges multiple adsorption removal effects such as instant high-voltage and anion, can use for a long time, and effect is not subject to the other factor influence.It is complete that this solid-state reaction adsorbent possesses the long action time effect than like product, and passive absorption is initiatively removed multi-pronged, acts on effects such as thorough, selects for use the raw material nonhazardous not constitute secondary pollution etc. advantage.
The present invention is compared to the market like product and has quick removing, lasting effectively advantage.Have sterilizing concurrently, remove volatility dusty gas double effects, effect thoroughly generates the low toxicity non-poisonous material.Raw material of the present invention are easy to get, prepare simple, cost is not high, make things convenient for industrialization production, and the removal effect of high, normal, basic concentration being polluted through experiment confirm many times all can reach more than 92%.
The specific embodiment
Embodiment 1
The A component:
Percarbamide: 15 grams;
Diammonium hydrogen phosphate: 1 gram
Ammonium chloride: 3 grams;
Sodium lignin sulfonate: 0.5 gram;
Tea Polyphenols: 0.5 gram;
Soluble perfume: 0.1 gram;
Deionized water: 79.9 grams.
The B component:
The porous adsorbent class is the high temperature modified zeolite of active carbon, acid-wash activation, activated alumina, 10X molecular sieve composition: 90 grams;
Tourmaline: 5 grams;
The load-reaction absorber class is activated carbon supported acid potassium permanganate: 5 grams.
The formaldehyde that in 1 cubic metre confined space, adds 3.5 milligrams, 3.5 milligrams of toluene.Little ventilation makes its volatilization evenly.Earlier the space is entered in 30 milliliters of sprinklings of A component, after 3 hours B component 600 grams are put into, detected formaldehyde in the primary space after 6 hours every 1 hour, toluene level is 0.07 milligram in formaldehyde, and 0.124 milligram of toluene all is lower than 0.10 milligram every cube in the formaldehyde of national standard, 0.20 milligram every cube of toluene, clearance is respectively 98% and 96.4%, and the strong oxidizing property of hydrogen peroxide can be destroyed the composition protein of bacteria, makes it dead.Do not do the specific aim experiment because relating to bacterium.
Embodiment 2
The A component:
Percarbamide: 30 grams;
Diammonium hydrogen phosphate: 2 grams;
Ammonium chloride: 3 grams;
Sodium lignin sulfonate: 3 grams;
Tea Polyphenols: 1 gram;
Soluble perfume: 2.5 grams;
Deionized water: 58.5 grams.
The B component:
The porous adsorbent class is treated earth, bentonite, high temperature modified zeolite, sepiolite, Kiselgel A, the vermiculite composition of acid-wash activation: 50 grams;
Tourmaline: 10 grams;
The load-reaction absorber class is activated alumina and the molecular sieve carried acid potassium permanganate of 13X: 40 grams.
The formaldehyde that in 1 cubic metre confined space, adds 3.5 milligrams, 3.5 milligrams of toluene.Little ventilation makes its volatilization evenly.Earlier the space is entered in 30 milliliters of sprinklings of A component, after 3 hours B component 600 grams are put into, detected formaldehyde in the primary space after 6 hours every 1 hour, toluene level is 0.043 milligram in formaldehyde, and 0.096 milligram of toluene all is lower than 0.10 milligram every cube in the formaldehyde of national standard, 0.20 milligram every cube of toluene, clearance is respectively 98.7% and 97.2%, and the strong oxidizing property of hydrogen peroxide can be destroyed the composition protein of bacteria, makes it dead.Do not do the specific aim experiment because relating to bacterium.
Embodiment 3
The A component:
Percarbamide: 45 grams;
Diammonium hydrogen phosphate: 2 grams;
Ammonium chloride: 4 grams;
Sodium lignin sulfonate: 4 grams;
Tea Polyphenols: 1.5 grams;
Soluble perfume: 2 grams;
Deionized water: 41.5 grams;
The B component:
The porous adsorbent class is attapulgite, diatomite, medical stone, bamboo charcoal, high temperature modified zeolite, montmorillonite, 13X molecular sieve, the Kiselgel A composition of acid-wash activation: 70 grams;
Tourmaline: 20 grams;
The load-reaction absorber class is activated alumina load hydrogen peroxide: 10 grams.
The formaldehyde that in 1 cubic metre confined space, adds 3.5 milligrams, 3.5 milligrams of toluene.Little ventilation makes its volatilization evenly.Earlier the space is entered in 30 milliliters of sprinklings of A component, after 3 hours B component 600 grams are put into, detected formaldehyde in the primary space after 6 hours every 1 hour, toluene level is 0.052 milligram in formaldehyde, and 0.116 milligram of toluene all is lower than 0.10 milligram every cube in the formaldehyde of national standard, 0.20 milligram every cube of toluene, clearance is respectively 98.5% and 96.6%, and the strong oxidizing property of hydrogen peroxide can be destroyed the composition protein of bacteria, makes it dead.Do not do the specific aim experiment because relating to bacterium.

Claims (1)

1. an air purifying preparation is made up of A component liquid reactants, B component solid-state reaction adsorbent, by weight percentage,
A component liquid reactants is made by following material:
Percarbamide 15-55;
Diammonium hydrogen phosphate: 1-5
Ammonium chloride: 1-10;
Sodium lignin sulfonate: 0.5-5;
Tea Polyphenols: 0.5-3;
Soluble perfume: 0.1-5;
Deionized water: 40-79.9;
B component solid-state reaction adsorbent is made by following material:
Porous adsorbent class: 45-90;
Tourmaline: 5-20;
Load-reaction absorber class: 5-50;
Described porous adsorbent class is: get active carbon, bamboo charcoal, treated earth, bentonite, attapulgite, diatomite, a kind of to multiple and get the high temperature modified zeolite of acid-wash activation, sepiolite in the medical stone, in the montmorillonite one or more and get activated alumina, 10X or 13X molecular sieve, Kiselgel A, a kind of to multiple in the vermiculite;
Described load-reaction absorber class is by one or more load acid potassium permanganates in the described porous adsorbent class or hydrogen peroxide and make.
CN 201110429900 2011-12-21 2011-12-21 Air purifying agent Expired - Fee Related CN102489146B (en)

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CN102489146B true CN102489146B (en) 2013-08-07

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Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103007891A (en) * 2012-10-26 2013-04-03 张建新 Method for preparing air purification material
CN102872796A (en) * 2012-10-30 2013-01-16 烟台迪康环境科技有限公司 Preparation method of medical stone purifying agent for adsorbing and decomposing formaldehyde
CN103055654A (en) * 2012-12-28 2013-04-24 青岛信锐德科技有限公司 Natural porous loamy air-purifying agent
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CN103447004B (en) * 2013-08-21 2015-05-27 苏州康华净化系统工程有限公司 Strong adsorption type air purifying agent and preparation method thereof
CN103586003B (en) * 2013-11-06 2016-01-06 张雯 Diatomite is the preparation method of the brilliant alcohol of nanometer purification of air opal of carrier
CN104929824A (en) * 2014-03-19 2015-09-23 上海斯米克控股股份有限公司 Novel vehicle air cleaner filter core
CN104016439B (en) * 2014-06-24 2016-06-01 潘峰 For removing the filtration medium of formaldehyde in tap water, filter core and preparation method
CN104399440A (en) * 2014-10-21 2015-03-11 繁昌县倍思生产力促进中心有限公司 Deodorization face mask adsorbent and preparation method thereof
CN105770957B (en) * 2014-12-22 2018-12-04 上海斯米克健康环境技术有限公司 A kind of air cleaning compound and its preparation method and application
CN105778859B (en) * 2014-12-22 2018-08-21 上海斯米克健康环境技术有限公司 A kind of air purifying composition and its preparation method and application of releasable negative oxygen ion
CN104645795A (en) * 2015-01-08 2015-05-27 北京博浩致远科技有限责任公司 Formaldehyde scavenger
CN105833836B (en) * 2016-05-24 2019-02-19 苏州贝达新材料科技有限公司 A kind of odor absorber and preparation method and application
CN106731640A (en) * 2016-11-21 2017-05-31 郑州诚合信息技术有限公司 A kind of material of purifying and sterilizing and its preparation method and application
CN106731641A (en) * 2016-11-21 2017-05-31 郑州诚合信息技术有限公司 A kind of material with sterilizing function and its preparation method and application
CN106729870B (en) * 2016-12-09 2020-05-26 江门市和馨香精技术有限公司 Air purifying agent containing tea polyphenol and preparation method thereof
CN106421856A (en) * 2016-12-09 2017-02-22 遂昌维康竹炭开发有限公司 Combined deodorant and packaging box thereof
CN106823748A (en) * 2017-03-16 2017-06-13 大工(青岛)新能源材料技术研究院有限公司 Administer the compound urea peroxide reagent and preparation method and application of indoor free formaldehyde
CN107096512A (en) * 2017-04-27 2017-08-29 舒尔环保科技(合肥)有限公司 A kind of formaldehyde adsorbent and preparation method thereof
CN107051194A (en) * 2017-04-27 2017-08-18 舒尔环保科技(合肥)有限公司 A kind of purification particle being filled in filter screen
CN106994334A (en) * 2017-04-27 2017-08-01 舒尔环保科技(合肥)有限公司 A kind of adsorbent being used in air purifier
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CN110583649A (en) * 2019-08-29 2019-12-20 苏州市易柯露环保科技有限公司 Deodorant composition with antibacterial function and preparation method thereof
CN110559794A (en) * 2019-10-21 2019-12-13 沈鸿裕 Formula of preparation for purifying indoor air
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Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11165007A (en) * 1997-12-04 1999-06-22 Hitachi Chem Co Ltd Environmental pollutant removing filter and air purifier
CN1628893A (en) * 2003-12-18 2005-06-22 薛雄生 Domestic air purifying device
CN1272074C (en) * 2003-12-26 2006-08-30 杜建中 Super fine active compound adsorptive indoor air purifying agent
CN1824380A (en) * 2006-02-09 2006-08-30 刘阳生 New type purification filtering material
CN101513536B (en) * 2008-12-31 2012-11-21 北京绿伞化学股份有限公司 Nanometer air purifying agent with bactericidal function and preparation method thereof
CN101947433B (en) * 2010-08-24 2012-06-13 浙江建中竹业科技有限公司 Multiple-aperture carbon granule air purification agent and preparation method thereof

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