CN102477637A - Polyphenylene sulfide fabric and application thereof - Google Patents
Polyphenylene sulfide fabric and application thereof Download PDFInfo
- Publication number
- CN102477637A CN102477637A CN2010105580310A CN201010558031A CN102477637A CN 102477637 A CN102477637 A CN 102477637A CN 2010105580310 A CN2010105580310 A CN 2010105580310A CN 201010558031 A CN201010558031 A CN 201010558031A CN 102477637 A CN102477637 A CN 102477637A
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- CN
- China
- Prior art keywords
- polyphenylene sulfide
- fabric
- monofilament
- filaments
- fineness
- Prior art date
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- 239000004734 Polyphenylene sulfide Substances 0.000 title claims abstract description 78
- 229920000069 polyphenylene sulfide Polymers 0.000 title claims abstract description 78
- 239000004744 fabric Substances 0.000 title claims abstract description 65
- 238000005516 engineering process Methods 0.000 claims abstract description 16
- 238000001914 filtration Methods 0.000 claims abstract description 12
- 239000011148 porous material Substances 0.000 claims abstract description 9
- 229920000642 polymer Polymers 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 abstract description 18
- 238000000926 separation method Methods 0.000 abstract 1
- 238000009987 spinning Methods 0.000 description 22
- 238000004519 manufacturing process Methods 0.000 description 16
- 238000000034 method Methods 0.000 description 8
- 239000002131 composite material Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 238000002074 melt spinning Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Woven Fabrics (AREA)
- Filtering Materials (AREA)
Abstract
The invention provides a polyphenylene sulfide fabric and application thereof, wherein the fabric is made of polyphenylene sulfide monofilaments with fineness of 4-500 dtex, and the average pore diameter of the fabric is 0.5-50 um; the polyphenylene sulfide monofilament is prepared by a fiber separation technology. The polyphenylene sulfide fabric has the advantages of lightness, thinness, softness, high density and low aperture, and can be applied to preparing filter cloth for precise high-temperature filtration.
Description
Technical field
The present invention relates to a kind of polyphenylene sulfide fabric, be specifically related to a kind of top-weight fabric by the thinner formed low aperture of polyphenylene sulfide filaments of fineness and uses thereof.
Background technology
At present, the main existence form of polyphenylene sulfide fibre goods has staple fibre on the market, long filament, brachymemma fiber and processed goods woven fabric thereof, knitted fabric, nonwoven fabric felt, paper products etc.The woven woven fabric of monofilament also has certain applications in paper grade (stock) net field.Polyphenylene sulfide fibre mainly is widely used in the gas filtration field with its excellent high temperature resistant and chemical-resistance; Wherein mainly comprise the fabric that staple fiber batt and staple fibre yarn and long filament are made into, and high-precision polyphenylene sulfide filaments fabric with and do not appear in the newspapers as yet in the application of filtration art.
Reason is, the polyphenylene sulfide filaments of passing through traditional monofilament spining technology Direct Production that exists in the market, and its fineness specification limit is about 500dtex, and the spinning engineering of the thin monofilament below the 500dtex is extremely difficult.Therefore, can't realize utilizing the less monofilament of fiber number to weave low aperture, high accuracy, the technology of cloister fabric.
TOHKEMY 2010-126838 discloses a kind of polyphenylene sulfide filaments, its manufacturing approach and industrial fabric.Provide in this invention and utilized this monofilament of at least a employing is produced in polyphenylene sulfide filaments that the monofilament production technology produces and warp thread or the weft yarn surface smoothing property industrial fabric preferably; Be applicable to conveyer belt; The paper grade (stock) net, general industrial purposes such as filtering material.This polyphenylene sulfide filaments obtains through traditional monofilament production technology spinning, and the monofilament fineness and the production efficiency of gained all are restricted, and can not be used to process the fabric in low aperture, use filter cloth so just can not be used to prepare accurate high temperature filtration.
Summary of the invention
The object of the present invention is to provide a kind of frivolous, soft, high density, the polyphenylene sulfide fabric in low aperture and uses thereof.
Technical solution of the present invention is following:
A kind of polyphenylene sulfide fabric, this fabric are that the polyphenylene sulfide filaments of 4～500dtex is made by fineness, and the average pore size of this fabric is 0.5～50um; Said polyphenylene sulfide filaments utilization divides fine technology to make.
Above-mentioned fineness is that the polyphenylene sulfide filaments of 4～500dtex is through general polyphenylene sulfide multifilament being adopted hand divide fibre or equipment to divide the fine technology of fine branch to make.The conventional method of spinning polyphenylene sulfide filaments is directly to spin through the single hole spinnerets at present, yet the monofilament fineness that this method makes receives the restriction of spinning process condition, and the monofilament fineness great majority are more than 500dtex, and production efficiency is low.Because the spinning process of multifilament can not only improve spinning speed, more can promote production capacity by the difference of spinning hole number.The raising of spinning speed increases except production capacity, also can increase fibre strength.According to present multifilament production technology, the fineness of individual thread can carefully reach 1.0dtex in the polyphenylene sulfide multifilament of production.
The thickness of fabric is very big with the monofilament fineness relation of forming fabric, and the monofilament that fineness is thinner makes low aperture, light and thin type fabric especially easily.But in technology of the present invention, if the monofilament fineness of polyphenylene sulfide less than 4dtex, then easy fracture of wire causes the fine process difficulty of branch; If monofilament fineness is greater than 500dtex, then coiling and molding is bad, and the engineering trafficability characteristic is poor.Preferred 10～the 100dtex of the monofilament fineness of using among the present invention.
Polyphenylene sulfide filaments fabric of the present invention, its fabric average pore size is 0.5～50um.When weaving; The size in fabric aperture should require according to the purposes of this fabric to adjust, if when requiring less than 0.5um to the aperture of fabric, then Density is too high; Because of friction between monofilament frequently is prone to cause the monofilament fracture of wire, just like this weave difficulty in the weaving process; The fabric aperture is during greater than 50um, is prone to cause in the fabric each monofilament to cross between rare monofilament because of the density of fabric and slides relatively easily, and the fabric moulding is bad, and the situation of poor dimensional stability takes place.The average pore size of polyphenylene sulfide fabric of the present invention is preferably 5～30um.
Above-mentioned polyphenylene sulfide filaments utilization divides fine technology to make; That is to say the further polyphenylene sulfide filaments through adopting hand to divide fibre or equipment to divide fine technology to make of polyphenylene sulfide multifilament that conventional method is made, this has not only realized making the technology of fine denier polyphenylene sulfide filaments.Simultaneously, for the PPS monofilament that the direct fabrics mode is produced, production efficiency improves, and the cost slip increases.
The raw material that above-mentioned polyphenylene sulfide filaments adopted is the polyphenylene sulfide polymer of weight average molecular weight 30000～60000.If adopt molecular weight to carry out melt spinning less than 30000 polyphenylene sulfide polymer; The viscosity of melt spinning liquid is low, and spinning tension is low, and fracture of wire takes place in spinning process easily; Cause spinning process significantly to worsen, and the mechanical property of the polyphenylene sulfide fibre that obtains is relatively poor; If adopt molecular weight to carry out spinning greater than 60000 polyphenylene sulfide polymer, because of the viscosity of melt spinning liquid is high, need have special high voltage bearing spinning equipment, can cause the manufacturing equipment cost too high.
Adopt above-mentioned polyphenylene sulfide polymer to make the polyphenylene sulfide multifilament, contain 4～40 polyphenylene sulfide filaments in the multifilament of gained through composite spinning.If the monofilament radical, can cause the fine difficulty of branch greater than 40, be entangled with winding mutually; If the monofilament radical less than 4, will cause production efficiency low excessively, the engineering trafficability characteristic is poor.Preferred monofilament radical is 6～20.
The tensile break strength of above-mentioned polyphenylene sulfide filaments is 2～10cN/dtex.If the tensile break strength of monofilament is during less than 2cN/dtex, filament strength is low excessively, bears and incessantly divides fine tension force, causes the generation of fracture of wire phenomenon easily; If the tensile break strength of monofilament is greater than 10cN/dtex; Adopt the higher polyphenylene sulfide polymer of weight average molecular weight to carry out spinning with regard to requiring; Because of the viscosity of melt spinning liquid is high, need have special high voltage bearing spinning equipment, can cause the manufacturing equipment cost too high.Tensile break strength 4～the 8cN/dtex of preferred polyphenylene sulfide filaments.
Polyphenylene sulfide fabric of the present invention have frivolous sense well, soft, advantage such as density is high, the aperture is low.Can be applicable to prepare accurate high temperature filtration and use filter cloth, the accurate high temperature filtration that specifically is applied to gas or liquid is used filter cloth, both can reach high efficiency filter, the effect that can reach a high temperature again and filter.
The specific embodiment
Through following examples, the present invention is described further.But protection scope of the present invention is not limited to embodiment.
[fabric aperture]
According to the ASTMF316-03 standard, adopt the Capillary Flow porometer to measure the fabric aperture.Fabric sample is placed in the sample room, uses surface tension wetting as the Si Weike silicone fluid (silwick silicone Fluid) of 19.1dynes/cm.It is 2.54 cm that the bottom folder of sample room has diameter, and thickness is the porous metals dish plug-in unit of 3.175 mm, and the top folder of sample room has the hole of 3.175 mm diameters.The value in fabric aperture is the mean value of twice measurement.
[tensile break strength]
The assay method of fibrous fracture intensity and percentage elongation promptly on the filament stretching-machine, is used lower clamp and is vertically clamped a fiber, draws the speed of stretching with the JIS standard: 20 ± 1mm/min; Stretch; Write down the fracture strength and the elongation at break of every fiber, every group of sample at least 35 times averaged.
Embodiment 1
To adopt weight average molecular weight be 55000 polyphenylene sulfide polymer, and to make the monofilament radical through composite spinning be that 10, fineness are the polyphenylene sulfide multifilament of 220dtex; Divide fine method with this multifilament through hand then; 10 monofilament are wound up into respectively carry out the branch fibre on the batching apparatus; Processing fineness is that 22dtex, TENSILE STRENGTH are the polyphenylene sulfide filaments of 4.8cN/dtex, and the polyphenylene sulfide filaments of gained is weaved, and being made into average pore size is that 15um, grammes per square metre are 55g/m
2Fabric.The polyphenylene sulfide filaments fabric that obtains is preparing accurate high temperature filtration with the application in the filter cloth.
Embodiment 2
To adopt weight average molecular weight be 46000 polyphenylene sulfide polymer, and to make the monofilament radical through composite spinning be that 14, fineness are the polyphenylene sulfide multifilament of 560dtex; Divide fine method with this multifilament through hand then; 14 monofilament are wound up into respectively carry out the branch fibre on the taking-up equipment; Processing fineness is that 40dtex, TENSILE STRENGTH are the polyphenylene sulfide filaments of 4.2cN/dtex, and the polyphenylene sulfide filaments of gained is weaved, and being made into average pore size is that 30um, grammes per square metre are 68 g/m
2Fabric.The polyphenylene sulfide filaments fabric that obtains is preparing accurate high temperature filtration with the application in the filter cloth.
Embodiment 3
To adopt weight average molecular weight be 55000 polyphenylene sulfide polymer, and to make the monofilament radical through composite spinning be that 6, fineness are the polyphenylene sulfide multifilament of 600dtex; Divide fine equipment to carry out the branch fibre this multifilament utilization then; Processing fineness is that 100dtex, TENSILE STRENGTH are the polyphenylene sulfide filaments of 5.3cN/dtex; The polyphenylene sulfide filaments of gained is weaved, and being made into average pore size is that 48um, grammes per square metre are 110g/m
2Fabric.The polyphenylene sulfide filaments fabric that obtains is preparing accurate high temperature filtration with the application in the filter cloth.
Embodiment 4
To adopt weight average molecular weight be 55000 polyphenylene sulfide polymer, and to make the monofilament radical through composite spinning be that 20, fineness are the polyphenylene sulfide multifilament of 156dtex; Divide fine equipment to carry out the branch fibre this multifilament utilization then; Processing fineness is that 7.8dtex, TENSILE STRENGTH are the polyphenylene sulfide filaments of 5.6cN/dtex; The polyphenylene sulfide filaments of gained is weaved, and being made into average pore size is that 1.2um, grammes per square metre are 41g/m
2Fabric.The polyphenylene sulfide filaments fabric that obtains is preparing accurate high temperature filtration with the application in the filter cloth.
Comparative example 1
Adopting molecular weight is that 55000 polyphenylene sulfide polymer is 597dtex through traditional monofilament production technology spinning monofilament fineness, and TENSILE STRENGTH is the polyphenylene sulfide filaments of 4.5cN/dtex.Adopting this polyphenylene sulfide filaments to process the fabric aperture is 130um, and fabric weight is the woven monofilament of 400 g/ ㎡.
Comparative example 2
Adopting molecular weight is that 55000 polyphenylene sulfide polymer is 700dtex through traditional monofilament production technology spinning monofilament fineness, and TENSILE STRENGTH is the polyphenylene sulfide filaments of 3.5cN/dtex.Adopting this polyphenylene sulfide filaments to process the fabric aperture is 150um, and fabric weight is the woven monofilament of 600g/ ㎡.
Claims (4)
1. polyphenylene sulfide fabric is characterized in that: this fabric is that the polyphenylene sulfide filaments of 4～500dtex is processed by fineness, and the average pore size of this fabric is 0.5～50um; Said polyphenylene sulfide filaments utilization divides fine technology to make.
2. polyphenylene sulfide fabric according to claim 1 is characterized in that: the raw material that said polyphenylene sulfide filaments adopted is the polyphenylene sulfide polymer of weight average molecular weight 30000～60000.
3. polyphenylene sulfide fabric according to claim 1 is characterized in that: the tensile break strength of said polyphenylene sulfide filaments is 2～10cN/dtex.
4. a polyphenylene sulfide fabric as claimed in claim 1 is preparing accurate high temperature filtration with the application in the filter cloth.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010558031.0A CN102477637B (en) | 2010-11-25 | 2010-11-25 | Polyphenylene sulfide fabric and purpose thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010558031.0A CN102477637B (en) | 2010-11-25 | 2010-11-25 | Polyphenylene sulfide fabric and purpose thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102477637A true CN102477637A (en) | 2012-05-30 |
| CN102477637B CN102477637B (en) | 2015-01-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010558031.0A Expired - Fee Related CN102477637B (en) | 2010-11-25 | 2010-11-25 | Polyphenylene sulfide fabric and purpose thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102477637B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014111053A1 (en) * | 2013-01-18 | 2014-07-24 | 东丽纤维研究所（中国）有限公司 | Diaphragm cloth for water electrolyzer and manufacturing method therefor |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0274613A (en) * | 1988-09-07 | 1990-03-14 | Kanebo Ltd | Splittable conjugate fiber |
| JPH10251918A (en) * | 1997-03-04 | 1998-09-22 | Toray Ind Inc | Polyphenylene sulfide fiber, monofilament and industrial woven fabric |
| CN101530696A (en) * | 2008-03-12 | 2009-09-16 | 东丽纤维研究所（中国）有限公司 | Filtering material used for removing dust by combing electrical bag and application thereof |
-
2010
- 2010-11-25 CN CN201010558031.0A patent/CN102477637B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0274613A (en) * | 1988-09-07 | 1990-03-14 | Kanebo Ltd | Splittable conjugate fiber |
| JPH10251918A (en) * | 1997-03-04 | 1998-09-22 | Toray Ind Inc | Polyphenylene sulfide fiber, monofilament and industrial woven fabric |
| CN101530696A (en) * | 2008-03-12 | 2009-09-16 | 东丽纤维研究所（中国）有限公司 | Filtering material used for removing dust by combing electrical bag and application thereof |
Non-Patent Citations (6)
| Title |
|---|
| 《合成纤维》 19821231 W.Berger等 "超细纤维的制造技术和发展重点" 第40-44页 1-4 , 第4期 * |
| 《非织造布》 20091231 吴丽丽等 "水刺复合PPS纤维耐高温过滤材料的研究与开发" 第24-26页 1-4 第17卷, 第4期 * |
| 《高科技纤维与应用》 20091231 陈志荣等 "聚苯硫醚纤维发展概况及应用前景" 第46-50页 2 第34卷, 第1期 * |
| W.BERGER等: ""超细纤维的制造技术和发展重点"", 《合成纤维》 * |
| 吴丽丽等: ""水刺复合PPS纤维耐高温过滤材料的研究与开发"", 《非织造布》 * |
| 陈志荣等: ""聚苯硫醚纤维发展概况及应用前景"", 《高科技纤维与应用》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014111053A1 (en) * | 2013-01-18 | 2014-07-24 | 东丽纤维研究所（中国）有限公司 | Diaphragm cloth for water electrolyzer and manufacturing method therefor |
| CN105027324A (en) * | 2013-01-18 | 2015-11-04 | 东丽纤维研究所（中国）有限公司 | Diaphragm cloth for water electrolyzer and manufacturing method therefor |
| CN105027324B (en) * | 2013-01-18 | 2018-11-30 | 东丽纤维研究所（中国）有限公司 | Water electrolyser diaphragm cloth and its manufacturing method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102477637B (en) | 2015-01-28 |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
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Effective date of registration: 20180328 Address after: Japan Tokyo central Nihonbashi Muromachi 1-1-2 Patentee after: TORAY INDUSTRIES, Inc. Address before: 226009 Nantong Province Economic and Technological Development Zone, the New South Road, No. 58, No. Patentee before: TORAY FIBERS & TEXTILES RESEARCH LABORATORIES (CHINA) Co.,Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150128 Termination date: 20211125 |