CN102472282A - Rotary vane compressor with hydrofluoroolefin refrigerant gas and high speed tool steel vane - Google Patents

Rotary vane compressor with hydrofluoroolefin refrigerant gas and high speed tool steel vane Download PDF

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Publication number
CN102472282A
CN102472282A CN201080035178XA CN201080035178A CN102472282A CN 102472282 A CN102472282 A CN 102472282A CN 201080035178X A CN201080035178X A CN 201080035178XA CN 201080035178 A CN201080035178 A CN 201080035178A CN 102472282 A CN102472282 A CN 102472282A
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CN
China
Prior art keywords
blade
piston
rotary compressor
vane
refrigeration agent
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Pending
Application number
CN201080035178XA
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Chinese (zh)
Inventor
中野雅夫
饭田登
苅野健
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Panasonic Holdings Corp
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Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Publication of CN102472282A publication Critical patent/CN102472282A/en
Pending legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04CROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
    • F04C18/00Rotary-piston pumps specially adapted for elastic fluids
    • F04C18/30Rotary-piston pumps specially adapted for elastic fluids having the characteristics covered by two or more of groups F04C18/02, F04C18/08, F04C18/22, F04C18/24, F04C18/48, or having the characteristics covered by one of these groups together with some other type of movement between co-operating members
    • F04C18/34Rotary-piston pumps specially adapted for elastic fluids having the characteristics covered by two or more of groups F04C18/02, F04C18/08, F04C18/22, F04C18/24, F04C18/48, or having the characteristics covered by one of these groups together with some other type of movement between co-operating members having the movement defined in group F04C18/08 or F04C18/22 and relative reciprocation between the co-operating members
    • F04C18/356Rotary-piston pumps specially adapted for elastic fluids having the characteristics covered by two or more of groups F04C18/02, F04C18/08, F04C18/22, F04C18/24, F04C18/48, or having the characteristics covered by one of these groups together with some other type of movement between co-operating members having the movement defined in group F04C18/08 or F04C18/22 and relative reciprocation between the co-operating members with vanes reciprocating with respect to the outer member
    • F04C18/3562Rotary-piston pumps specially adapted for elastic fluids having the characteristics covered by two or more of groups F04C18/02, F04C18/08, F04C18/22, F04C18/24, F04C18/48, or having the characteristics covered by one of these groups together with some other type of movement between co-operating members having the movement defined in group F04C18/08 or F04C18/22 and relative reciprocation between the co-operating members with vanes reciprocating with respect to the outer member the inner and outer member being in contact along one line or continuous surfaces substantially parallel to the axis of rotation
    • F04C18/3564Rotary-piston pumps specially adapted for elastic fluids having the characteristics covered by two or more of groups F04C18/02, F04C18/08, F04C18/22, F04C18/24, F04C18/48, or having the characteristics covered by one of these groups together with some other type of movement between co-operating members having the movement defined in group F04C18/08 or F04C18/22 and relative reciprocation between the co-operating members with vanes reciprocating with respect to the outer member the inner and outer member being in contact along one line or continuous surfaces substantially parallel to the axis of rotation the surfaces of the inner and outer member, forming the working space, being surfaces of revolution
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01CROTARY-PISTON OR OSCILLATING-PISTON MACHINES OR ENGINES
    • F01C21/00Component parts, details or accessories not provided for in groups F01C1/00 - F01C20/00
    • F01C21/08Rotary pistons
    • F01C21/0809Construction of vanes or vane holders
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04CROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
    • F04C23/00Combinations of two or more pumps, each being of rotary-piston or oscillating-piston type, specially adapted for elastic fluids; Pumping installations specially adapted for elastic fluids; Multi-stage pumps specially adapted for elastic fluids
    • F04C23/008Hermetic pumps
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04CROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
    • F04C2230/00Manufacture
    • F04C2230/20Manufacture essentially without removing material
    • F04C2230/22Manufacture essentially without removing material by sintering
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04CROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
    • F04C2230/00Manufacture
    • F04C2230/90Improving properties of machine parts
    • F04C2230/92Surface treatment
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2203/00Non-metallic inorganic materials
    • F05C2203/08Ceramics; Oxides
    • F05C2203/0804Non-oxide ceramics
    • F05C2203/083Nitrides

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Applications Or Details Of Rotary Compressors (AREA)

Abstract

A2 refrigerant mainly containing a carbon-carbon double bond-containing hydrofluoroolefin has a function to suppress abrasive wear, compared to conventional HFC-based refrigerants, because the hydrofluoroolefin generates iron fluoride especially on the surface of the vane and piston, where sliding force is severe, from hydrogen fluoride, even if it is generated in reaction with water and oxygen. It is possible to reduce abrasive wear, by using a refrigerant containing as the base component a hydrofluoroolefin as operating refrigerant and a refrigeration oil 3 miscible with the refrigerant and a vane 10 made of a high-speed tool steel and sintered and quenched, because hydrogen fluoride generated by decomposition of the refrigerant in the region of a vane tip region 10a and a piston 9 peripheral surface, where sliding force is severe is converted to iron fluoride. It is also possible to obtain a hardened structure containing carbides of W, Mo, Cr and V dispersed in a fine martensite matrix and produces the rotary compressor more cost-effectively by quenching and sintering the vane 10.

Description

Rotary vane compressor with HF hydrocarbon refrigerant gas and Rapid Tool Steel blade
Technical field
The present invention relates to guarantee the reliability of rotary compressor; This compressor uses the refrigeration agent that mainly contains the HF hydrocarbon of carbon-carbon double key chloride atom, that have low global warming potentiality not as the duty cryogen, is used for the for example refrigeration cycle of room air conditioner, refrigerator and other airconditions.
Background technique
HFC (hydrogen fluorohydrocarbon) system with zero ozone depletion potentiality is used as the duty cryogen of conventional refrigeration plant gradually, and but then, because HFC base refrigeration agent has very high global warming potentiality, HFC base refrigeration agent has also caused problem recently.Therefore, study use and mainly comprising the not refrigeration plant of the refrigeration agent of the HF hydrocarbon of carbon-carbon double key chloride atom, that have low global warming potentiality.In order to improve reliability, blade and the piston that in this rotary compressor that adopts conventional H FC base refrigeration agent, uses various researchs (for example, referring to patent documentation 1) have been carried out.
Fig. 3 is the cross-sectional view that is illustrated in the rotary compressor of the basic refrigeration agent of use conventional H FC (hydrogen fluorohydrocarbon) described in the patent documentation 1.In this structure, the piston 43 that inserts along the internal surface of cylinder 41 rotates with the rotation of axle 42, in the suction chamber that is separated by blade 44 45 and pressing chamber 46, sucks respectively and compression refrigerant gas.In above-mentioned mechanical structure, be worn and zone that the zone of badly damaged rotary compressor is the outer circumferential face of tip and the piston 43 of blade 44 to be in contact with one another; And be wherein because under the powerful active force from blade 44 back sides that the pressure reduction between head pressure and the suction pressure causes, the tip of blade 44 is pressed in the boundary wear zone on the outer circumferential face of piston 43.
Therefore, blade stands nitriding treatment or CrN or TiN ion plating are stood in its surface, to improve wear resistance and reliability.
Reference listing
Patent documentation 1: japanese kokai publication hei 11-236890 communique
Summary of the invention
Technical problem
Yet; When the rotary compressor that consider to adopt the refrigeration agent that mainly contains the HF hydrocarbon of carbon-carbon double key chloride atom, that have low global warming potentiality not to use as the refrigeration plant of duty cryogen; There is such problem; Promptly when above-mentioned refrigeration agent and water and oxygen reaction, produce hydrogen fluoride, it causes the abrasive wear of slider to be quickened, and especially is exposed to blade and piston under the violent especially sliding force; And cause the deterioration of refrigerator oil, therefore cause reliability to worsen.In addition, because common blade handles through nitrogenize or ion plating, so very expensive.
The object of the invention of making in order to solve the problem in the routine techniques is; Blade of processing by Rapid Tool Steel through nitrogenize or sintering and the blade that quenches and process by sintered alloy steel; The state that keeps exposing surface in the iron component is the wear resistance of raising blade down, reduces production costs and guarantees the compressor long reliability.
The scheme of dealing with problems
The rotary compressor according to the present invention of realizing above-mentioned purpose is characterised in that: use the refrigeration agent that contains as the HF hydrocarbon of the carbon-carbon double key of solvent as the duty cryogen; Use can be dissolved the refrigerator oil that mixes with refrigeration agent; Its compression mechanical part has piston and blade in cylinder; And blade is processed by Rapid Tool Steel and by nitrogenize; Perhaps blade is processed and is sintered and quenched by sintered alloy steel; And because in the violent zone of sliding force between vane tip and piston outer circumferential face; The hydrogen fluoride that decomposition through refrigeration agent produces is converted into ferric flouride, so can in rotary compressor, suppress abrasive wear.And can also obtain to contain the sclerotic tissue of the carbide of the W, Mo, Cr and the V that are dispersed in the trickle martensitic matrix through sintering and quenching blade, therefore reduce production costs.
The beneficial effect of the invention
In the present invention; Because the blade of rotary compressor is processed and nitrogenize by Rapid Tool Steel; Perhaps process and sintering and quenching by sintered alloy steel; So because the hydrogen fluoride that in the reaction of the refrigeration agent that mainly contains the HF hydrocarbon of carbon-carbon double key chloride atom, that have low global warming potentiality not and water and oxygen, produces is converted into ferric flouride, therefore can prevent the abrasive wear that causes by hydrogen fluoride, and therefore the compressor of the cheapness that reliability is higher in for a long time is provided.
Description of drawings
Fig. 1 is the longitudinal section of the compression mechanical part in the rotary compressor that illustrates in the embodiments of the invention 1.
Fig. 2 is the cross-sectional view of the compression mechanical part in the rotary compressor that illustrates in the embodiments of the invention 1.
Fig. 3 is the cross-sectional view that the compression mechanical part in the conventional rotary compressor is shown.
Embodiment
First aspect of the present invention relates to a kind of rotary compressor, comprising: contain as the HF hydrocarbon of the carbon-carbon double key of solvent and as the refrigeration agent of duty cryogen; Can dissolve the refrigerator oil that mixes with refrigeration agent; And the compression mechanical part that in cylinder, has piston and blade; Wherein blade is processed by Rapid Tool Steel and is perhaps processed and be sintered and quenched by sintered alloy steel by nitrogenize; And because in the violent zone of sliding force between vane tip and piston outer circumferential face; The hydrogen fluoride that decomposition through refrigeration agent produces is converted into ferric flouride, so can in rotary compressor, suppress abrasive wear.And, can also obtain to contain the sclerotic tissue of the carbide of the W, Mo, Cr and the V that are dispersed in the trickle martensitic matrix through sintering and the blade that quenches and process by sintered alloy steel, therefore reduce production costs.
Second aspect of the present invention relates to a kind of rotary compressor, comprising: contain as the HF hydrocarbon of the carbon-carbon double key of solvent and as the refrigeration agent of duty cryogen; Can dissolve the refrigerator oil that mixes with refrigeration agent; Be placed on the motor in the seal container; Have the compression mechanical part by motor-driven axle, compression mechanical part has bearing on the two sides of cylinder; Be installed in the piston in the cylinder by the eccentric shaft rotation; And blade; It is separated into suction chamber and pressing chamber with cylinder; And its tip is pressed into the outer circumferential face of piston, and wherein blade is processed by Rapid Tool Steel and by nitrogenize or processed and be sintered and quenched by sintered alloy steel, and because in the violent zone of the sliding force between vane tip and piston outer circumferential face; The hydrogen fluoride that decomposition through refrigeration agent produces is converted into ferric flouride, so can in rotary compressor, suppress abrasive wear.
The third aspect of the invention relates to of the present invention first or second aspect, and wherein sintered alloy steel is a Rapid Tool Steel, therefore can make blade on wear resistance, be superior to other sintered alloy steels.
Fourth aspect of the present invention relates to of the present invention first arbitrary aspect to the third aspect; Wherein refrigerator oil is polyvinylether, polyol ester or PAG; And can dissolve the refrigerator oil that mixes with refrigeration agent because can use, so can guarantee the reliability of rotary compressor.
The 5th aspect of the present invention relates to the arbitrary aspect in first to fourth aspect of the present invention, and wherein refrigerator oil does not contain EP agent.Therefore, can prevent the decomposition of refrigeration agent to be quickened through the effect that is included in the EP agent in the refrigerator oil.
Below, will still should be understood that the present invention does not receive these embodiments' restriction with reference to description of drawings the preferred embodiments of the present invention.
Embodiment 1
Fig. 1 is the longitudinal section that the rotary compressor in the embodiments of the invention 1 is shown.As shown in fig. 1, the stator 2a of motor 2 is fixed in the upper area of seal container 1, and the compression mechanical part 5 with the axle 4 that is driven by rotor 2b is fixed in the lower area of seal container 1.For example, use bolt that main bearing 7 is fixed to the end face of the cylinder 6 of compression mechanical part 5, and supplementary bearing 8 is fixed to the bottom surface of cylinder 6.In cylinder 6, piston 9 is placed among the eccentric region 4a of axle 4, so that axle carries out the off-centre rotation.
In addition; Be stored in the bottom section of seal container 1 be can with the HF hydrocarbon that contains the carbon-carbon double key (for example; HFO1234yf) dissolve the refrigerator oil 3 of the polyvinylether that does not contain EP agent, polyol ester or the PAG that mix as the refrigeration agent of solvent (below, be called refrigeration agent R).
Fig. 2 is the cross-sectional view that illustrates according to the compression mechanical part in the rotary compressor of the present invention 5.As shown in Figure 2, blade 10 inserts among the blade groove 6a of cylinders 6, and leaf spring 11 is placed on the back side 10b of blade 10, makes the tip region 10a of blade 10 be forced into the outer circumferential face of piston 9 and contacts.The material of blade 10 is processed by the SKH Rapid Tool Steel and by nitrogenize, is perhaps processed and be sintered and quenched by the sintered alloy steel of for example Rapid Tool Steel.
Below explanation is had the operation and the effect of the rotary compressor of above structure.At first, through being formed at the suction port 12 in the cylinder 6, the refrigerant gas of refrigeration agent R is sucked in the suction chamber 13.Refrigerant gas in pressing chamber 14 is compressed through the left-handed rotation (direction of arrow) of piston 9, and is expelled in the seal container 1 from the exhaust port (not shown) through discharging otch 15.Be expelled to the refrigerating machine mist of oil that the compression refrigerant gas in the seal container 1 exists in container, be transported, and discharge through the discharge tube 16 that is positioned at seal container 1 top through the space around the motor 2.
Because apply with pressure and high head pressure from leaf spring 11; So through the back side 10b of blade 10 being applied sizable power with the pressure reduction of inner pressure of air cylinder; Therefore the tip region 10a of blade 10 and the outer circumferential face of piston 9 are in contact with one another under the boundary friction state, and are under the rugged environment of high temperature.Therefore, wherein refrigeration agent R is decomposed and produces hydrogen fluoride etc.
According to the present invention; In order to ensure the blade 10 and the reliability of piston 9 that are positioned under such rugged environment; The material of blade 10 is processed by the SKH Rapid Tool Steel and is processed and by being quenched by nitrogenize or by sintered alloy steel; Its iron component under the state of exposing surface with the hydrogen fluoride reaction that decomposition produced of refrigeration agent R, thereby in the vane tip zone outer circumferential face formation ferric flouride of the surface of 10a and piston 9.Therefore can reduce slip resistance and abrasive wear, and guarantee the for example reliability of the slide member of blade 10.In addition, the sintering of sintering blade and Quenching Treatment provide the sclerotic tissue of the carbide that contains the W, Mo, Cr and the V that are dispersed in the trickle martensitic matrix, and have reduced cost of production.
Because refrigerator oil does not contain EP agent, so can also suppress the decomposition of refrigeration agent itself.Because polyvinylether, polyol ester or PAG can be used as refrigerator oil with the miscible refrigerator oil of refrigeration agent R; So distribution and circuit refrigerator oil can be recovered in the rotary compressor in refrigeration cycle, therefore guarantee the high reliability of rotary compressor.
Although be used as the agglomerated material of blade 10, yet can be used to practice thrift more the production of cost like other sintered alloy steels of alloy tool steel (SKD) and stainless steel (SUS) at present embodiment 1 high speed tool steel (SKH).As everyone knows, the sintering of sintered alloy steel and Quenching Treatment and additional anneal are handled the further raising that causes toughness.
The slider of rolling piston type rotary compressor has been described; Be blade 10 and piston 9; But the present invention also is applicable to other rotary compressors of sliding-vane compressor for example, the scrollwork of scroll compressor similarly; And for example axle and other sliders of bearing, so that the slip resistance when reducing to use refrigeration agent R and improve reliability and cost benefit.
Although the driving mechanism of motor as compression mechanical part is installed in seal container in present embodiment 1, however the embodiment of driving mechanism be not limited thereto, and motor can be installed on the outside or engine of seal container and can be used to operation.
Industrial usability
As stated; Even the HF hydrocarbon that compressor according to the present invention contains the carbon-carbon double key in use is during as the refrigeration agent of solvent; Also can guarantee the reliability of compressor, compressor according to the present invention for example can be used in during water heater uses with compressor etc. with compressor, dehumidifier with compressor, deep freezer with compressor, vehicle air conditioning.

Claims (5)

1. rotary compressor comprises:
Refrigeration agent, it contains the HF hydrocarbon as the carbon-carbon double key of solvent, and as the duty cryogen;
Refrigerator oil, it can dissolve with said refrigeration agent and mix; And
Compression mechanical part, it has piston and blade in cylinder, and said blade is processed by Rapid Tool Steel and by nitrogenize, is perhaps processed and be sintered and quenched by sintered alloy steel.
2. rotary compressor comprises:
Refrigeration agent, it contains the HF hydrocarbon as the carbon-carbon double key of solvent, and as the duty cryogen;
Refrigerator oil, it can dissolve with said refrigeration agent and mix;
Motor, it is placed in the seal container;
Compression mechanical part, it has by said motor-driven axle, and said compression mechanical part has bearing on the two sides of cylinder;
Piston, it is installed in the said cylinder by said eccentric shaft rotation;
Blade, it is separated into suction chamber and pressing chamber with said cylinder, and its tip is pressed into the outer circumferential face of said piston, and said blade is processed by Rapid Tool Steel and by nitrogenize, is perhaps processed and be sintered and quenched by sintered alloy steel.
3. rotary compressor according to claim 1 and 2, wherein said sintered alloy steel is a Rapid Tool Steel.
4. according to each the described rotary compressor in the claim 1 to 3, wherein said refrigerator oil is polyvinylether, polyol ester or PAG.
5. according to each the described rotary compressor in the claim 1 to 4, wherein said refrigerator oil does not contain EP agent.
CN201080035178XA 2009-08-27 2010-08-18 Rotary vane compressor with hydrofluoroolefin refrigerant gas and high speed tool steel vane Pending CN102472282A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2009-196247 2009-08-27
JP2009196247A JP2011047329A (en) 2009-08-27 2009-08-27 Rotary compressor
PCT/JP2010/064321 WO2011024826A2 (en) 2009-08-27 2010-08-18 Rotary compressor

Publications (1)

Publication Number Publication Date
CN102472282A true CN102472282A (en) 2012-05-23

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CN201080035178XA Pending CN102472282A (en) 2009-08-27 2010-08-18 Rotary vane compressor with hydrofluoroolefin refrigerant gas and high speed tool steel vane

Country Status (5)

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US (1) US20120128519A1 (en)
EP (1) EP2470792A2 (en)
JP (1) JP2011047329A (en)
CN (1) CN102472282A (en)
WO (1) WO2011024826A2 (en)

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CN107614880A (en) * 2015-05-27 2018-01-19 三菱电机株式会社 Compressor and refrigerating circulatory device

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JP2011001897A (en) * 2009-06-19 2011-01-06 Panasonic Corp Compressor
JP2014240702A (en) * 2011-10-06 2014-12-25 パナソニック株式会社 Refrigeration device
DE102013001246A1 (en) * 2013-01-25 2014-07-31 Gkn Sinter Metals Holding Gmbh Method for producing a wing for a vane pump, wings for a vane pump and vane pump
JP2017031830A (en) * 2015-07-29 2017-02-09 株式会社富士通ゼネラル Rotary Compressor

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Publication number Priority date Publication date Assignee Title
CN107614880A (en) * 2015-05-27 2018-01-19 三菱电机株式会社 Compressor and refrigerating circulatory device
CN107614880B (en) * 2015-05-27 2020-08-21 三菱电机株式会社 Compressor and refrigeration cycle device
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Publication number Publication date
WO2011024826A3 (en) 2011-10-27
US20120128519A1 (en) 2012-05-24
WO2011024826A2 (en) 2011-03-03
EP2470792A2 (en) 2012-07-04
JP2011047329A (en) 2011-03-10

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Application publication date: 20120523