CN102461522A - Mixed weeding composition containing bispyribac-sodium and bentazone - Google Patents

Mixed weeding composition containing bispyribac-sodium and bentazone Download PDF

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CN102461522A
CN102461522A CN2010105520413A CN201010552041A CN102461522A CN 102461522 A CN102461522 A CN 102461522A CN 2010105520413 A CN2010105520413 A CN 2010105520413A CN 201010552041 A CN201010552041 A CN 201010552041A CN 102461522 A CN102461522 A CN 102461522A
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bentazone
mixed
weed
careless ethers
killer herbicide
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CN102461522B (en
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郭崇友
彭永强
刘奎涛
陈文明
张宝俊
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NANJING HUAZHOU PARMACEUTICAL CO LTD
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NANJING HUAZHOU PARMACEUTICAL CO LTD
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Abstract

The invention belongs to the technical field of pesticides, particularly relates to the field of herbicides, and relates to a mixed weeding composition containing bispyribac-sodium and bentazone, wherein the mixed weeding composition takes the bispyribac-sodium and the bentazone as main active ingredients, and the mass ratio of the bispyribac-sodium to the bentazone is 1-80: 1-80. Adding different surfactants, thickeners, solvents or solid fillers and the like, and being capable of being processed into various formulations such as missible oil, suspending agent, water dispersible granules, wettable powder and the like. The herbicide compound preparation can prevent and kill gramineous weeds, broad-leaved weeds and cyperaceae weeds in paddy fields, delays the resistance of weeds on the premise of improving the pesticide effect compared with a single agent, has wide weeding spectrum and long persistent period, is safe to rice and next-stubble crops, and is an ideal paddy field herbicide.

Description

A kind of mixed herbicidal composite that contains two careless ethers and bentazone
Technical field
The invention belongs to pesticide field, especially the weed killer herbicide field relates to a kind of mixed herbicidal composite that contains two careless ethers and bentazone.
Background technology
Two careless ethers have another name called Nong Meili, the salicylic acid Sulfadiazine Compound, and chemical name: 2, two (4, the 6-SDM base-2-oxygen base) Sodium Benzoates of 6-.Belong to phenoxy carboxylic acid herbicides, mainly hindered aminoacid biosynthesis side chain is selective herbicide through the acid of root leaf absorption inhibition vinegar milk is synthetic, uses rice direct-seeding Tanaka, and herbicidal spectrum is wide.Its structural formula is following:
Bentazone has another name called Lysimachia sikokiana pellet, Bentazon.Chemical name: the 3-isopropyl-(1H)-and benzo-2,1,3-thiadiazine-4-ketone-2, the 2-dioxide, structural formula is:
Figure BDA0000033300360000012
This weed killer herbicide is an optionally herbicide after seedling of contact killing type tool, is used for cauline leaf processing in seedling stage, works through the blade contact.Dry land is used, and is transmitted to through the blade face infiltration earlier and suppresses photosynthesis in the chloroplast.The paddy field use can absorb through root again through the blade face infiltration, be transmitted to cauline leaf, hinders weeds photosynthesis and water metabolism strongly, causes nutrition hungry, makes physiological function lack of proper care and cause death.Active ingredient is detoxified to active weak glycoconjugates metabolism in the tolerable crop body, and to crop safety, 6-18 week bentazone can be by microbial decomposition in soil after the dispenser.
At present; Herbicide for paddy field is limit by crop safety; It is also limited to kill the grass spectrum, use the agent of a kind of weed killer herbicide list can not control the generation of paddy field weed completely effectively separately, moreover the weed killer herbicide consumption is excessive or the inhomogeneous residual hazard that also causes easily this season crop or succession crop of dispenser.Therefore, the present invention selects complementary two careless ether of pluses and minuses and bentazone to be made into the combination agent use, has so both reduced the consumption of medicament, has obviously improved herbicidal effect, has also avoided this season is done the deposits yields poisoning and to the possibility of succession crop generation residual hazard.
Summary of the invention
The present invention is according to the present situation of present paddy field herbicide after seedling; And behind the paddy field seedling weeds a situation arises; Provide a kind of by two careless ethers and the composite binary mixed herbicidal composite of another kind of weed killer herbicide bentazone; This Herbicidal combinations can not only improve the preventive effect of medicament to weeds, and to when stubble and succession crop safety, has reduced drug cost simultaneously.
The purpose of this invention is to provide a kind of mixed herbicidal composite that contains two careless ethers and bentazone; It is characterized in that this weed killer herbicide is main active ingredient with two careless ethers and bentazone; The mass ratio of two careless ethers and bentazone is 1~80: 1~80; The mass ratio of preferred two careless ether and bentazone is 1~60: 1~60, and the mass ratio of further preferred two careless ethers and bentazone is 1~30: 1~20, and the mass ratio of most preferably two careless ethers and bentazone is 1~10: 1~10.
In mixed herbicidal composite, the two quality percentage composition in weed killer herbicide of two careless ethers and bentazone is 1~85%, and the preferred mass percentage composition is 10~80%.
In the binary built preparation of two careless ether of the present invention and bentazone; Except two kinds of active ingredients; Can also add the auxiliary agent that allows on the agricultural chemicals such as different surfaces activating agent, thickener, solvent or solid packing, be processed into multiple formulations such as missible oil, suspending agent, water dispersion granule, wetting powder.
This Herbicidal combinations can delay the weeds resistance with respect to single agent under the prerequisite that has improved drug effect, herbicidal spectrum is wide, and the lasting period is long, enough prevents and kill off paddy field annual gramineous weed, broad leaved weed and sedge weed, and to paddy rice and second stubble crop safety.Herbicidal combinations of the present invention can be used for preparing the weed killer herbicide of paddy field postemergence weed control; Can be used in preparation especially and prevent and kill off the weed killer herbicide of various annual weed and perennial weed, especially can prepare the weed killer herbicide of preventing and kill off grassy weed, broad leaved weed and sedge weed.
Herbicidal combinations of the present invention has the following advantages:
1, activity of weeding is high.Herbicidal combinations of the present invention can kill weeds through two kinds of different mechanism, makes weeds resistance generation speed reduce, and greatly improves the removing activity of weed killer herbicide.
2, herbicidal spectrum is wide, and the lasting period is long.Two careless ethers are broad spectrum weeding agent, and it has good preventive effect to annual gramineous weed, and bentazone is mainly to be the weed killer herbicide of preventing and kill off sedge weed and broad leaved weed.Both can improve the preventive effect of annual gramineous weed and broad leaved weed and sedge weed, thereby prolong the lasting period of medicament after mixing.
3, safe.Medicament of the present invention is under the prerequisite that has improved drug effect, and its safety to paddy field and succession crop also is improved.
Embodiment
Herbicidal combinations of the present invention is according to the former medicine correlation properties of two careless ethers and bentazone, with and weeder reason etc., can be processed into missible oil, suspending agent, aqueous emulsion, do multiple formulations such as hanging agent, water dispersion granule, wetting powder.Two kinds of content of effective in the Herbicidal combinations of the present invention are not limited to the scope in following examples.
Embodiment 1
Two careless ethers 5%, bentazone 20%, calcium dodecyl benzene sulfonate 5%, APES 3%, solvent naphtha supplies 100%, and being mixed with active ingredient quality percentage composition according to the conventional formulation method is 25% missible oil.
Embodiment 2
Two careless ethers 10%; Bentazone 20%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE 3%, aluminium-magnesium silicate 0.5%, ethylene glycol 2%; Water to 100%, being mixed with active ingredient quality percentage composition according to the conventional formulation method is 30% suspending agent.
Embodiment 3
Two careless ethers 20%, bentazone 40%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, polyvinyl alcohol 2%, kaolin to 100% is mixed with 60% water dispersion granule.
Embodiment 4
Two careless ethers 15%, bentazone 20%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol 2%, kaolin to 100%, being mixed with active ingredient quality percentage composition according to the conventional formulation method is 35% wetting powder.
Embodiment 5
Two careless ethers 1%, bentazone 9%, calcium dodecyl benzene sulfonate 5%, APES 3%, solvent naphtha supplies 100%, and being mixed with active ingredient quality percentage composition according to the conventional formulation method is 10% missible oil.
Embodiment 6
Two careless ethers 40%, bentazone 40%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol 2%, kaolin to 100%, being mixed with active ingredient quality percentage composition according to the conventional formulation method is 80% water dispersion granule.
Embodiment 7
Two careless ethers 19%, bentazone 1%, calcium dodecyl benzene sulfonate 5%, APES 3%, solvent naphtha supplies 100%, and being mixed with active ingredient quality percentage composition according to the conventional formulation method is 20% missible oil.
Embodiment 8
Two careless ethers 20%, bentazone 60%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol 2%, kaolin to 100%, being mixed with active ingredient quality percentage composition according to the conventional formulation method is 80% water dispersion granule.
Embodiment 9
The biologicall test experiment
1), indoor active determination test
Utilize the preparation among the embodiment 1~4, measure its co-toxicity coefficient the barnyard grass grass.
Test method: the seed of quantitative barnyard grass grass is seeded in respectively in the Disposable paper cup of 9cm, sows 10~15 seeds in every glass, in illumination box, cultivate, broadcast back 3d, do the enterprising capable soil spraying of composition spray in crawler type and handle.Handle in the greenhouse, back and continue to cultivate, each handles the preventive effect to weeds routine observation, and each weeds fresh weight after handling of weighing behind the 30d is pressed the method for nineteen sixty propositions such as Sun Yunpei, calculates its toxicity regression curve and co-toxicity coefficient.Co-toxicity coefficient shows that greater than 100 two kinds of active principles have synergistic effect, and co-toxicity coefficient shows that less than 100 two kinds of active principles have antagonism.Mensuration result is as shown in table 1.
The indoor determination of activity result of table 1
Figure BDA0000033300360000041
Can find out that from last table the co-toxicity coefficient after two kinds of active principles are composite explains that all greater than 100 the present invention has obvious synergistic effect.
2) field control effectiveness test of combinations of herbicides of the present invention.
Supply the reagent agent:
4 kinds of re-compounded binary herbicides among the embodiment 1~4.
The contrast medicament:
The two careless ether suspending agents (commercially available) of 100 grams per liters, 25% bentazone aqua (commercially available).
Confession studies thing: paddy rice
The paddy rice seedling grows fine, and robust plant does not have other damage by disease and insect.
Prevent and kill off object:
Grassy weed, broad leaved weed and sedge weeds such as barnyard grass grass, moleplant seed, difformed galingale herb, needle spikesedge herb, short arrowhead, mexicana, four Ye Ping.
Test method:
According to the area of experimental plot, the accurate good various medicaments of weighing, and after converting the water dilution, utilize knapsack sprayer, and carrying out even spraying, shower nozzle is selected the special-purpose Fan spray head of weed killer herbicide for use.During spraying, note soup is evenly sprayed application in the experimental plot, accomplish not leak the phenomenon of spray, many sprays.
After the test respectively behind medicine 20d, 40d observe the weeds death condition, and the activity of weeding of more various medicaments.In addition, also to behind medicine, observe the condition of production of crop in 1~15d, whether crop had poisoning to investigate medicament.
Embodiments of the invention preparation weeding test effect see the following form (40d behind the medicine)
Figure BDA0000033300360000051
Medicament is to the security survey result of crop
Figure BDA0000033300360000061
More than handle the equal safety of paddy rice.

Claims (10)

1. a mixed herbicidal composite that contains two careless ethers and bentazone is characterized in that this mixed herbicidal composite is main active ingredient with two careless ethers and bentazone, and the mass ratio of two careless ethers and bentazone is 1~80: 1~80.
2. mixed herbicidal composite according to claim 1 is characterized in that in this weed killer herbicide that the mass ratio of two careless ethers and bentazone is 1~60: 1~60.
3. mixed herbicidal composite according to claim 2 is characterized in that in this weed killer herbicide that the mass ratio of two careless ethers and bentazone is 1~30: 1~20.
4. mixed herbicidal composite according to claim 3 is characterized in that in this weed killer herbicide that the mass ratio of two careless ethers and bentazone is 1~10: 1~10.
5. mixed herbicidal composite according to claim 1 is characterized in that two careless ethers and the two quality percentage composition in weed killer herbicide of bentazone are 1~85%.
6. mixed herbicidal composite according to claim 5 is characterized in that two careless ethers and the two quality percentage composition in weed killer herbicide of bentazone are 10~80%.
7. mixed herbicidal composite according to claim 1 is characterized in that it is that the auxiliary agent that allows on main active ingredient and the agricultural chemicals is mixed with any one formulation with two careless ethers and bentazone.
8. mixed herbicidal composite according to claim 7 is characterized in that described formulation is wetting powder, water dispersible granules, missible oil or suspending agent.
9. the application of the described mixed herbicidal composite of claim 1 in the weed killer herbicide of preparation paddy field postemergence weed control.
10. the described mixed herbicidal composite of claim 1 is prevented and kill off the application in the weed killer herbicide of grassy weed in the paddy field, broad leaved weed and sedge weed in preparation.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104222112A (en) * 2014-08-26 2014-12-24 广东中迅农科股份有限公司 Weeding composition for paddy field
EP2802211A4 (en) * 2012-01-12 2015-12-16 Dow Agrosciences Llc Herbicidal compositions containing bentazon and als inhibitor and accase inhibitor
CN106577760A (en) * 2016-12-12 2017-04-26 安徽常泰化工有限公司 Formula of herbicide for agricultural use

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101828562A (en) * 2010-06-12 2010-09-15 济南科赛基农化工有限公司 Herbicide composition with bentazon and bispyribac-sodium as active ingredients

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101828562A (en) * 2010-06-12 2010-09-15 济南科赛基农化工有限公司 Herbicide composition with bentazon and bispyribac-sodium as active ingredients

Non-Patent Citations (1)

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Title
刘长令等: "《世界农药大全.除草剂卷》", 31 August 2002, article "双草醚 灭草松", pages: 87-88 - 310 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2802211A4 (en) * 2012-01-12 2015-12-16 Dow Agrosciences Llc Herbicidal compositions containing bentazon and als inhibitor and accase inhibitor
CN104222112A (en) * 2014-08-26 2014-12-24 广东中迅农科股份有限公司 Weeding composition for paddy field
CN106577760A (en) * 2016-12-12 2017-04-26 安徽常泰化工有限公司 Formula of herbicide for agricultural use

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