CN102459685A

CN102459685A - Layered coating system with a mcralx layer and a chromium rich layer and a method to produce it

Info

Publication number: CN102459685A
Application number: CN2009801606834A
Authority: CN
Inventors: P.博克斯; H.埃文斯; T.基尔歇; T.路维斯; B.麦克莫迪; J.尼科尔斯; P.帕德利; N.西姆斯; J.维内齐亚; P.M.沃克尔; A.韦瑟里尔; M.怀特赫尔斯特
Original assignee: Siemens AG
Current assignee: Siemens Energy Global GmbH and Co KG; Praxair ST Technology Inc
Priority date: 2009-05-26
Filing date: 2009-05-26
Publication date: 2012-05-16
Anticipated expiration: 2029-05-26
Also published as: EP2435595B1; RU2011152879A; US20130040166A1; JP5653421B2; US9222163B2; EP2435595A1; CN102459685B; WO2010138096A1; JP2012528249A; RU2542870C2

Abstract

The invention relates to a layer system with a MCrX layer and a Cr-rich layer on the MCrX layer.

Description

Coat system and working method thereof with stratification of MCrAlX layer and rich chromium layer

The present invention relates to the system of the stratification of a kind of MCrAlX of having layer, rich Cr layer, it has unique antioxidant and thermal etching property, and the method for producing such system.Preferably use aluminium compound layer.

EP0587341 has described a kind of high-temperature corrosion resistance compound coating, and this method comprises following step here:

-apply the alloy-coated material of MCrAlY type.

The coating of-optional this MCrAlY type of chromaking produces the coating of the top layer with chromaking, and it has the extra chromium that is in the sosoloid in the M of coating composition.

This coating of-calorize produces the coating with upper layer, and it contains the aluminide of the M composition of coating.

-platinum layer is deposited on the surface top of coating of this calorize.

EP1327702 has described a kind of MCrAlY coat system, and it is outer that it comprises β-NiAl internal layer and γ/β-MCrAlY and TBC.In the document, it is said the scale resistance that can improve these coatings through the Si that adds 0.1-4%.This coating is to use gas phase process, and CVD, PVD wait sedimentary.

US2005/0003227 has described the system that is similar to US'227, but also comprises the middle layer of platinum types of metals here.In the document, it is said the scale resistance that can improve these coatings through the Si that adds 0.1-4%.

EP1029100/US6416882 has described a kind of bonding coating of MCrAlY type, and it comprises the highest 2% silicon.

The coat system of aluminide and/or chromium modification also is described in US7229701, US6183888, and US7060366, US6287644, EP1082216, US6001492, US5507623 is among EP1541808 and the US6569492.

-apply the alloy-coated material of MCrAlY type.

-platinum layer is deposited on the surface top of coating of this calorize.

But these coatings remain imperfect.

So target of the present invention is to address this is that.

This problem is to solve through the layer system of claim 1 with according to its working method of claim 27.

In the dependent claims, listed more advantageous embodiment, it can arbitrary combination obtain additional advantage.

Idea of the present invention is based on the different coatings chemistry, and it is suitable in some temperature and environmental standard, protecting substrate.For example in high-temperature oxidation process; β-NiAl skin provides through in pyroreaction; Form fine and close thin aluminum oxide and protection be provided with oxygen reaction in the system, this reflect typical be the similar β-NiAl coating that in industry, finds, and extensively record in document.Arrive about 950 ℃ temperature at about 750 ℃-800 ℃ high, wide preceding corrosion can take place, this has consumed Cr and the unprotected base material of Al.Equally, use the aluminum oxide that forms β-NiAl coating will protect the anti-I type corrosion.But for the corrosion of II type, the corrosion of the partial type of deteriorating is more possible.With SO ₂And SO ₃Melting salt in the combined air-flow condenses on the turbine part, and this has formed pitting on said surface.For the best defence of such corrosion is to introduce rich Cr coat system.Importance of the present invention is that rich Cr layer is a successive, and is heat-staple as far as possible, so move in II type corrosive environment like these parts; Then consumed β-NiAl; But it is outer that corrosion damage is limited to β-NiAl, and successive α-Cr layer provides suitable protection; Increased the element that improves the coating corrosion protection, such as but not limited to Si or Hf.The strain that adds the MCrAlY coating form adapts to basic unit, and it provides strain flexibility to a certain degree and the final resist that should adapt to β-NiAl and α-Cr.Through design, then the coating structure of this stratification allows environment " selection " to be suitable for providing the coating composition of protection most basically.Fig. 3 has clearly confirmed this idea.The introducing of Si or other useful elements can improve the predicted life of this α-Cr layer.

Accompanying drawing has been represented:

Fig. 1-the 5th, the embodiment of layer system

Fig. 6 is a gas turbine

Fig. 7 is a blade

Fig. 8 is the combustion chamber.

Accompanying drawing only is embodiment of the present invention with explanation.

Fig. 1 has represented a kind of exemplary parts 1, as layer system of the present invention.

Parts 1 have metal base 4, and it preferably comprises the perhaps forged nickel or the cobalt-base alloy of heat-stable casting, and it is Hastelloy X preferably.

Preferably at (a. of Fig. 4)) substrate 4 on, applied internal layer or minimum MCrX layer 7, special, apply an only MCrX layer 7 (b. of Fig. 4)), X is yttrium (Y) and/or silicon (Si) and/or boron (B) and/or aluminium (Al) here.

This MCrX internal layer 7 comprises MCrAlX', and X' is yttrium (Y) at least and preferably only is yttrium (Y).

This MCrAlX' internal layer 7 is special comprise NiCrAlY layer and very special comprising (unit: at%) Ni, 22%Cr, 10%Al, 1.0%Y, special is made up of Amdry 962.

This MCrX internal layer 7 preferably applies through HVOF.

This MCrX internal layer 7 also preferably contacts with substrate 4.

On this MCrX internal layer 7 or among, applied rich chromium layer 10 (c. of Fig. 4)), α-Cr layer specifically.This chromaking was preferably preferably carried out 1-6 hour 1000 ℃-1150 ℃ temperature, very preferably carried out 2h-4h 1050 ℃-1075 ℃ temperature.

This chromate treating at least part produce on the internal layer 7 diffusion layer (therefore in Fig. 4 c 7 represented internal layer 7 thickness, perhaps representative exists diffusion layer, is not a kind of compsn).This richness chromium layer 10 is diffusion layer preferably.

This layer system 1 is preferably heat-treated, and is diffused in the MCrAlX' internal layer 7 so that cover the Cr layer.

Preferably on this α-chromium layer 10, applied additional other Ni-based layer, MCrX'' skin 13, it is outermost layer (d. of Fig. 4) preferably).The X'' of this MCrX'' layer is silicon (Si) and boron (B) preferably.

In addition, a MCrX'' outer 13 can be the pyrolic alloy Ni-Cr-Si-B of siliceous and/or boron.

This MCrX'' outer 13 has the composition different with internal layer 7, and very specifically the NiCrSiB layer (Amdry103, it consists of (unit: at%) 74% Ni, 17% Cr, 9.2% Y, 9% Si, 0.1% B).

After having applied MCrX'' (NiCrSiB) layer, after preferably applying, preferably carry out stabilization thermal treatment through HVOF.This stabilization thermal treatment is preferably to carry out 1-6 hour in preferred 1000 ℃-1200 ℃ temperature, preferably carries out 6h 1000-1025 ℃ temperature.

Preferred second outer 19 be present on first outer 13 or among.This second skin 19 is rich aluminium laminations shown in Figure 3.Preferred outer 19 is diffusion layers.

The one MCrX'' outer 13 can calorize reaches second outer 19 (e. of Fig. 4)).It is preferably to carry out 1-10 hour in preferred 1050 ℃-1115 ℃ temperature that this calorize is handled, and preferably carries out 7h 1070 ℃-1095 ℃ temperature.Preferably carry out last anneal, it preferably carried out 1-6 hour at 1000 ℃-1150 ℃, preferably carried out 2h at 1080 ℃, very preferably carried out in a vacuum.

In Fig. 2, represented the other a kind of embodiment of the present invention.

Parts 1 have metal base 4, and it preferably comprises heat-stable casting or forged nickel or cobalt-base alloy.

In Fig. 2, this substrate is " Hastelloy X " preferably, and it is a kind of commercially available forging nickelalloy, nominally it comprises 47% Ni, and 22% Cr, 18.5% Fe, 9% Mo, 1.5% Co, 1% Si, 1% Mn, 0.1% C.

Preferably in substrate 4 (a. of Fig. 5)), apply a MCrX internal layer 7 (b. of Fig. 5)), special only two the MCrX' layer 7' that apply, 16, X' is yttrium (Y) at least and preferably only is yttrium (Y) here.

This MCrAlX' internal layer 7' is special comprise NiCrAlY layer and very special comprising (unit: at%) 67% Ni, 22% Cr, 10% Al, 1.0% Y is made up of Amdry 962 especially.The one MCrAlX' internal layer 7' preferably applies through HVOF.

With second internal layer, 16 paints the one MCrAlX' internal layer 7' (c. of Fig. 5)).Layer 16 is the MCrX'' layer particularly, and X''=Si and/or B.

This other layer 16 has the composition that is different from the first internal layer 7', and very specifically the NiCrSiB layer (Amdry103, it consists of (unit: at%) 74% Ni, 17% Cr, 9.2% Si, 0.1% B).

Second internal layer 16 preferably applies through HVOF.

On this second internal layer 16 or among, apply rich chromium layer 10, so the special α-Cr layer (d. of Fig. 5) that applies is Fig. 5 d) mark 16 represented the thickness of internal layer 16 or had diffusion layer, it is not a kind of compsn).

This chromaking was preferably preferably carried out 1-6 hour at 1000 ℃-1150 ℃, preferably carried out 2h-4h at 1050 ℃-1075 ℃.

This chromate treating will preferably be created in the diffusion layer on the first internal layer 7'.

This layer system 1 is preferably heat-treated, and is diffused among the MCrAlX' internal layer 7' so that cover α-Cr.

On rich chromium layer 10, apply aluminium compound layer 22 (e. of Fig. 5)).

This preferably electroplates through Ni, and rich chromium layer 10 and this galvanized Ni layer of calorize realize.The preferred thickness of this Ni electrolytic coating is 10 μ m-20 μ m.The thermal treatment of preferably after Ni electroplates, annealing is preferably preferably carried out 2h at 1121 ° of C.The preferred vacuum of this anneal is carried out.

Following calorize is preferably preferably carried out 7h at 1080 ℃.

After calorize, carry out last annealing thermal treatment, preferably carry out 2h at 1080 ℃.

This anneal is preferably carried out in vacuum.

General remark: this chromaking or calorize can produce like Fig. 4, the diffusion layer shown in 5 or Fig. 1, the coating shown in 2 or 3.But be not limited thereto.Two kinds of structures can exist.

Other a kind of preferred embodiment is described below:

Basic unit: the MCrAlY through HVOF or plasma spraying (can for example VPS or LPPS spray through suitable option).

Rich Cr layer: apply through CVD or top source chromaking method.

Having been found that needs the chromaking cycle of 4 h to guarantee Cr layer stable in the annealing course of processing subsequently.

Ni:Ni coating, 10 μ m-20 μ m

Calorize: use through CVD or above-mentioned source calorize method.Need last annealing to come to introduce again the mechanical property of base material.

A kind of in addition scheme is to use following structure to come the applying coating system, and Si has been incorporated in the coating here:

Rich Cr layer: came chromaking MCrAlY to reach 4h through CVD or top source method.Be to use after this HVOF or plasma method to apply NiCrSiB (Amdry103 powder or similarly chemical powder) (can for example VPS or LPPS spray through suitable option).

Calorize: apply through CVD or above-mentioned source calorize method.

Need last annealing to come to introduce again the mechanical property of base material.

Fig. 6 has represented what conduct was given an example, vertically the gas turbine 100 of part area format.In its inside, this gas turbine 100 has rotor 103, and it is to install like this, so that it can rotate around turning axle 102, and has axostylus axostyle 101, is also referred to as turibine rotor.Inlet shell 104, compressor 105a (for example the annular combustion chamber 110, annular combustion chamber particularly, the burner 107 with a plurality of arranged in co-axial alignment), turbine 108 and exhaust casing 109 are successively arranged along rotor 103 each other.Toroidal combustion chamber 110 for example links to each other with annular heating pipe 111, here for example from four successive stage of turbines 112 of turbine 108.

Each stage of turbine 112 is for example formed by two blades or fin.As visible on the flow direction of working medium 113, after the row 115 by the countervane of spinner blade 120 formed rows 125 in heating pipe 111.

Countervane 130 is fixed on the inner casing 138 of stator 143, for example relies on the turbine disk 133 to be installed on the rotor 103 and arrange 125 spinner blade 120.Generator or machine (not shown) are coupled on the rotor 103.

When gas turbine 100 operations, compressor 105 sucks air 135 through inlet shell 104, and compresses it.This air compressed (it is provided at the turbo-side end of compressor 105) is sent into burner 107, here with it and fuel mix.The burning in combustion chamber 110 then of this mixture forms working medium 133.From here, working medium 133 flows along heating pipe 111, through countervane 130 and spinner blade 120.Working medium 113 expands at spinner blade 120 places, and its momentum is shifted, and spinner blade 120 has driven rotor 103 like this, and this rotor driven said machine be coupled on it.

When gas turbine 100 operations, the parts that are exposed to this thermodynamic medium 113 have carried out thermal load.Visible on the flow direction of working medium 113, the countervane 130 and the spinner blade 120 of first stage of turbine 112 have experienced the highest thermal load with heat shield element (it is arranged in the toroidal combustion chamber 110).In order to stand main temperature here, these parts can rely on tinting material to cool off.

The substrate of said parts can have oriented structure equally, that is, they be monomorphous (SX structure) or comprise the only crystal grain of portrait orientation (DS structure).As an example, with iron-based, Ni-based or cobalt-based super heat-resistant alloy material, the material of the special material that is used for turbine blade and fin 120,130 and the parts of combustion chamber 110 as said parts.Such superalloy for example is from EP1204776 B1, EP1306454, and EP1319729 A1, known among WO99/67435 or the WO00/44949; These documents have constituted the part that the present invention forms about alloy.

Blade and fin 120,130 can have the uncorroded coating (MCrAlX of protection equally; M is chosen from Fe (Fe), cobalt (Co), and at least a element of nickel (Ni), X is an active element, and has represented yttrium (Y) and/or silicon and/or at least a REE or hafnium).Such alloy is from EP0486489 B1, and EP0786017 B1 is known among EP0412397 B1 or the EP1306454 A1, its objective is to constitute the part that the present invention forms about alloy.

By for example ZrO ₂, Y ₂O ₄-ZrO ₂The thermal barrier coating of forming (that is, it is not through yttrium oxide and/or quicklime and/or magnesia partly or stable completely) also may reside on the MCrAlX.Columnar grain is for example to produce in this thermal barrier coating such as electro beam physics vapour deposition (EB-PVD) through suitable coating method.

Countervane 130 has at the bottom of the countervane of the inner casing 138 that faces turbine 108 (not shown) here and is in the guiding head on the opposite at the bottom of this countervane.These countervane women's head-ornaments are towards rotor 103, and are fixed on the set collar 140 of stator 143.

Fig. 7 has represented the spinner blade 120 of turbo or the skeleton view of countervane 130, and it extends along the longitudinal axis 121.

This turbo can be the gas turbine that is used to generate electricity, steam turbine or the compressor in aircraft or power station.

Blade or fin 120,130 have fixed area 400, and the blade of adjacency or fin platform 403 and primary blades or main part 406 are arranged along the longitudinal axis 121 continuously.As countervane 130, said fin 130 can have other platform (not shown) at most advanced and sophisticated 415 places of its fin.

183 (they are used for fixing spinner blade 120,130 and perhaps coil on the (not shown) to axostylus axostyle) formed in fixed area 400 at the bottom of blade or the fin.183 for example are designed to tup shape at the bottom of blade or the fin.Other structure also is possible at the bottom of Chinese fir or the wedge shape for example.Blade or fin 120,130 have leading edge 409 and trailing edge 412, are used to flow through the medium of primary blades or fin part 406.

In the situation of the blade of routine or fin 120,130,, in all zones 400,403,406 of blade or fin 120,130, use solid metal material, particularly superalloy as for example.Such superalloy is for example from EP1204776 B1, EP1306454, and EP1319729 A1 is known among WO99/67435 or the WO00/44949; These documents have constituted the part that the present invention forms about alloy.Blade or fin 120,130 can pass through casting process in this case, and rely on directional freeze, and through forging method, perhaps it makes up and produces through gadolinium system method.

To have the parts of the workpiece of one or more single crystal structure as machine, it is exposed to high machinery, heat and/or chemistry load in operational process.Such monocrystalline workpiece for example is to produce through the directional freeze of melt.It has comprised casting process, and the liquid metal alloy graining forms single crystal structure therein, that is, and and the monocrystalline workpiece, that is, directed.In the method; Arborescent crystal forms on the heat flux direction; And cylindricality crystalline-granular texture (that is the crystal grain that on the whole length of workpiece, extends, and it is referred to as directional freeze according to the term of routine in this paper context) or single crystal structure have been formed; That is, whole work-piece is made up of monocrystalline.In this method, need avoid the transformation of solidifying to spherical (polycrystalline), because nondirectional growth has inevitably caused forming horizontal and vertical grain boundary, it has weakened directional freeze or the good performance of single crystal components.When mentioning the directional freeze microstructure usually; This be understood to include monocrystalline (it does not have any grain boundary or is up to the maller angle grain boundary) and columnar crystal structure (it has the grain boundary of extending in the vertical, does not still have any horizontal grain boundary) the two.In the situation of these crystalline structure of the latter, it may also be referred to as directional freeze microstructure (directional freeze structure).Such method is known from US6024792 and EP0892090 A1; These documents have constituted a part of the present invention.

Blade or fin 120,130 can also for example have protection and not receive corrosion or oxide coating (MCrAlX; M is at least a element of chosen from Fe (Fe), cobalt (Co), nickel (Ni), and X is an active element, and represents yttrium (Y) and/or silicon and/or at least a REE, perhaps hafnium (Hf)).Such alloy is from EP0486489 B1, and EP0786017 B1 is known among EP0412397 B1 or the EP1306454 A1, its objective is to constitute the part that the present invention forms about alloy.

Can also on MCrAlX, exist for example by ZrO ₂, Y ₂O ₄-ZrO ₂The thermal barrier coating of forming, that is, it is not through yttrium oxide and/or quicklime and/or the next part of Natural manganese dioxide or stable completely.Columnar grain is for example to produce in this thermal barrier coating such as electro beam physics vapour deposition (EB-PVD) through suitable coating method.

Term polishes this resist of expression again can remove (for example removing through sandblast) from parts 120,130 after they use.Then, remove this corrosion and/or zone of oxidation or product.If desired, the crackle in the parts 120,130 can also use scolder of the present invention to repair.After this is to apply this parts 120,130 again, can reuse parts 120,130 thereafter.

Blade or fin 120,130 can be solid or hollow design.If blade or fin 120,130 plan to cool off, then it is hollow, and can comprise film-cooling hole 418 (dotting).

Fig. 8 has represented the combustion chamber 110 (Fig. 6) of gas turbine 100.

Combustion chamber 110 is configured to for example some known toroidal combustion chamber, and multiple therein burner 107 (it is arranged around the turning axle 102 in a circumferential direction) opens in the combustion chamber shared space 154, and burner 107 has produced flame 156.For this purpose, combustion chamber 110 integral body are doughnut structures, and it is positioned at around the turning axle 102.

In order to realize quite high efficient, combustion chamber 110 is designed for about 1000 ℃-1600 ℃ quite high temperature of working medium M.For realize in addition when using these operating parameters (it is disadvantageous for said material) quite long working time, combustion chamber wall 153 has the liner that is formed by heat shield element 155 on it faces the side of working medium M.Each heat shield element 155 of being processed by alloy is provided on the have special refractory protection working medium side of (MCrAlX layer and/or ceramic coating) or pyritous material (solid ceramic brick) forms by standing.These resists can be similar to turbine blade or fin,, represent that for example MCrAlX:M is chosen from Fe (Fe) that is; Cobalt (Co), at least a element of nickel (Ni), X is an active element; And represent yttrium (Y) and/or silicon and/or at least a REE, perhaps hafnium (Hf).Such alloy is from EP0486489 B1, and EP0786017 B1 is known among EP0412397 B1 or the EP1306454 A1, its objective is to constitute the part that the present invention forms about alloy.

On MCrAlX, can also exist for example ceramic heat-barrier coating, it is by for example ZrO ₂, Y ₂O ₄-ZrO ₂Form, that is, it is not through yttrium oxide and/or quicklime and/or magnesia partly or stable completely.

Columnar grain is for example to produce in this thermal barrier coating such as electro beam physics vapour deposition (EB-PVD) through suitable coating method.

Term polishes this resist of expression more can remove (for example removing through sandblast) from heat shield element 155 at them after using.Then, remove this corrosion and/or zone of oxidation or product.If desired, the crackle in the heat shield element 155 can also use scolder of the present invention to repair.After this is to apply this heat shield element 155 again, can reuse heat shield element 155 thereafter.

In addition, because the high temperature of 110 inside, combustion chamber can offer heat shield element 155 and/or their holding element with cooling system.Heat shield element 155 for example is hollow in this situation, and can comprise the film-cooling hole (not shown), and it opens in the bags 154.

Claims

1. a layer system (1), it comprises substrate (4), at least one the MCrX layer in this substrate (4) (7,7'; 16), particularly as lowermost layer (7, a MCrX layer (7 7'); 7'), particularly directly contact with substrate (4), wherein X is yttrium (Y) and/or silicon (Si) and/or aluminium (Al) and/or boron (B) at least; Wherein M be nickel (Ni) and/or cobalt (Co) and at least one MCrX layer (7,16) or among rich chromium layer (10).

2. according to the layer system of claim 1, wherein only minimum MCrX layer (7) be present on the substrate (4) with rich chromium layer (10) under.

3. according to the layer system of claim 1, wherein only two MCrX layers (7', 16) be present on the substrate (4) with rich chromium layer (10) under.

4. according to the layer system of claim 2, wherein this minimum MCrX layer (7) is the MCrAlX' layer, and wherein X' is yttrium (Y) at least, and special X' is Y.

5. according to the layer system of claim 3, wherein this first internal layer (7') is the MCrAlX' layer, and wherein X' is yttrium (Y) at least, and special X' is Y.

6. according to the layer system of claim 3 or 5, wherein this second internal layer (16) is the MCrX'' layer, and wherein X'' is silicon (Si) and/or boron (B) at least, and special X'' is Si and B.

7. according to the layer system of claim 4 or 5, wherein this a MCrAlX' internal layer (7) or a MCrAlX' internal layer (7') comprise the NiCrAlY alloy, and be special in the NiCrAlY alloy composition.

8. according to the layer system of claim 7, wherein this a NiCrAlY internal layer (7) or a NiCrAlY internal layer (7') comprise (at% of unit): Ni, 22% Cr, 10% Al, 1.0%Y, and special is made up of Amdry 962.

9. according to claim 1,2,3,4,5,6,7 or 8 layer system, wherein this richness chromium layer (10) at least one MCrX layer (7,16) comprises α-chromium layer, and special is made up of α-chromium.

10. according to claim 1,2,4,7,8 or 9 layer system, wherein should richness chromium layer (10) be higher than minimum MCrAlX' layer (7) and/or be the diffusion layer in the MCrAlX' layer (7), this special richness chromium layer (10) only is a diffusion layer.

11. according to claim 1,3,6 or 9 layer system, wherein should richness chromium layer (10) be higher than second internal layer (16) and/or be the diffusion layer in the MCrX'' layer (16), this special richness chromium layer (10) only be a diffusion layer.

12. according to claim 1,2,9 or 10 layer system, wherein a MCrX'' outer (13) is present on this richness chromium layer (10), wherein X'' is Y, Si and/or B at least, and special X'' is Y, Si and/or B.

13. layer system according to claim 6 or 12; Wherein this second internal layer (16) or a MCrX'' outer (13) comprise the NiCrSiB layer; It comprises Ni, 17%Cr, 9.2%Si, 0.1%B (at%), and special is made up of and very special being made up of Amdry103 NiCrSiB.

14. according to the layer system of claim 12 or 13, wherein this second skin (19) be present on the MCrX'' outer (13) or among, this second skin (19) is an outermost layer.

15. according to the layer system of claim 14, wherein this second skin (19) is rich aluminium lamination, aluminium compound layer specifically, the very special β-NiAl structure that comprises.

16. according to claim 12,13,14 or 15 layer system, the part of this second skin (19) MCrX'' outer (13) that is calorize wherein.

17. according to claim 1,3,9,11,12 or 13 layer system; Wherein with skin (22); Aluminium compound layer (22) particularly; Very specifically NiAl layer (22) is administered on the rich chromium layer (10), and calorize is gone up in special passing through at this richness chromium layer (10) Ni electrolytic coating applies, and the special wherein thickness of this Ni layer is 10 μ m-20 μ m.

18. according to the layer system of claim 4 or 5, wherein X' only is Y.

19. according to the laser system of claim 6 or 12, wherein X'' only is Si and B.

20. according to the layer system of or multinomial aforementioned claim, it comprises substrate (4), one or two MCrX layer (7,7', 16), rich chromium layer (10) and rich aluminium outer (19,22).

21. according to one of aforementioned claim 1-20 or multinomial layer system, it is made up of substrate (4), MCrX internal layer (7), rich chromium layer (10), a MCrX'' outer (13) and second skin (19).

22. according to the layer system of one of aforementioned claim 1-20, it is made up of substrate (4), first internal layer (7'), second internal layer (16), rich chromium layer (10) and skin (22).

23. the layer system arbitrary according to aforementioned claim was heated processing before using for the first time.

24. according to claim 1,20,21 or 22 layer system, wherein this substrate (4) comprises Hastelloy X, and special is made up of Hastelloy X.

25. according to claim 1,2,3,4,5,6,7,9,10,11,12,13,14,15,18,20,21 or 22 layer system, wherein M only is Ni.

26. according to the layer system of claim 1, wherein X only is Y, Si, Al or B.

27. one kind is used to produce parts (1), the special method according to the arbitrary layer system of claim 1-26 wherein applies at least one MCrX layer (7 in substrate (4); 7', 16), the special HVOF that passes through applies; Wherein X is yttrium (Y) and/or silicon (Si) and/or aluminium (Al) and/or boron (B) at least; Wherein M is nickel (Ni) and/or cobalt (Co) and has wherein produced rich chromium layer (10), particularly α-chromium layer (10).

28. according to the method for claim 27, wherein only a MCrX layer (7) is administered in the substrate (4), it is preferably used through HVOF.

29. according to the method for claim 27, wherein only two MCrX layers (7', 16) are administered in the substrate (4), it is preferably used through HVOF.

30. according to the method for claim 29, wherein second internal layer (16) is the MCrX'' layer, and is administered on first internal layer (7'), the special HVOF that passes through uses, and wherein X'' is silicon (Si) and/or boron (B), and special X'' is silicon (Si) and boron (B).

31. according to the method for claim 30, wherein carry out stabilization thermal treatment, preferably carry out and preferably carry out 6h at 1010 ℃.

32. according to claim 27,28,29,30 or 31 method, wherein should use through chromate treating by richness chromium layer (10),, very particularly carry out 2h-4h especially 1065 ℃ temperature particularly at 1050 ℃-1080 ℃.

33., wherein should use through CVD by richness chromium layer (10) according to the method for claim 27 or 32.

34., wherein repeat this chromaking, special repetition four times according to claim 27,32 or 33 method.

35. according to claim 27,32,33 or 34 method, wherein first skin (13) is the MCrX'' layer, and is administered on the rich chromium layer (10), the special HVOF that passes through uses, and wherein X'' is silicon (Si) and/or boron (B), and special X'' is silicon (Si) and boron (B).

36. according to the method for claim 35, wherein carry out stabilization thermal treatment, preferably carry out and preferably carry out 6h at 1010 ℃.

37. according to the method for claim 35 or 36, wherein use rich aluminium outer (19), the special calorize of passing through is used.

38., wherein use rich aluminium outer (19,22) according to claim 27,32,33 or 34 method.

39. according to the method for claim 38, wherein should richness aluminium outer (22) be Ni-Al-layer (22), aluminium compound layer (22) specifically, and through electronickelling and subsequently calorize handle and realize.

40. according to claim 37,38 or 39 method, wherein this calorize is that the special CVD that passes through carries out through the steam deposition.

41. according to claim 37,38,39 or 40 method, wherein this calorize is carried out at 1080 ℃, the special 7h that carries out.

42. according to the method for claim 39, wherein carry out stabilization thermal treatment afterwards, preferably carry out and preferably carry out 2h and very preferably carry out in a vacuum at 1120 ℃ in electronickelling (Ni).

43., wherein after calorize,, particularly in a vacuum, very particularly in 1080 ℃, carry out 2h with this layer system thermal treatment according to claim 37,38,39,40,41 or 42 method.