CN102449063A - Molded resin and protective plate for display - Google Patents
Molded resin and protective plate for display Download PDFInfo
- Publication number
- CN102449063A CN102449063A CN2010800239826A CN201080023982A CN102449063A CN 102449063 A CN102449063 A CN 102449063A CN 2010800239826 A CN2010800239826 A CN 2010800239826A CN 201080023982 A CN201080023982 A CN 201080023982A CN 102449063 A CN102449063 A CN 102449063A
- Authority
- CN
- China
- Prior art keywords
- molded body
- resin molded
- methyl
- compounds
- germicide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0058—Biocides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
Abstract
Disclosed is a molded resin which has a thickness of 0.1-5 mm and is transparent, the molded resin being obtained by curing a photocurable composition containing an antibacterial and/or a fungicide. This molded resin has antibacterial properties and/or antifungal properties, is highly transparent, and has high surface hardness and a high modulus in flexure. These properties last for an extended period. This molded resin hence is suitable for use as a protective plate for various displays.
Description
Technical field
The present invention relates to contain the resin molded body of bacterinertness and/or mildew resistance; Particularly relate to a kind of transparent membranaceous or flaky resin molded body that makes the light thermosetting composition solidify the thickness 0.1～5mm that forms; More detailed; Relate to the transparency, photostabilization, surface hardness, excellent rigidity, and then the excellent resin molded body of bacterinertness, mildew resistance, it is particularly useful as display protection plate.
Background technology
In the past, for display unit such as the liquid crystal of protecting inside to have, PDP, used the protecting sheet of glass, plastics etc. in the front of indicating meter.Especially for the top protecting sheet of portable type display unit, room external display device etc., owing to need physical strength such as shock-resistance, and use plastics sheets such as polymethylmethacrylate, polycarbonate.For these plastics sheets, require optical characteristics such as the transparency, photostabilization from much less, also require mechanical characteristics, thermotolerance, chemical reagent resistance/solvent resistances such as surface hardness, rigidity.Therefore, with regard to the plastics sheet that the surface has formed hard coat film, in order to ensure its rigidity, the plastics sheet of multiple stratification, slabization etc. becomes main flow.
In addition; Here said protecting sheet; It is the outmost plate that is positioned at indicating meter; Comprise the card of the sheet material of the measuring ability that has touch panel etc. concurrently, built-in display unit the outermost tunic, be used for waterproof, antifouling cover sheets etc., this protecting sheet with the top that is arranged on display unit, or the mode that is attached on the display unit use.
On the other hand, in recent years, protecting sheet is also required spatter property.Especially for nonspecific a large amount of people contact or near indicating meter, the protecting sheet of spatter property is guaranteed in strong expectation.For example; For the indicating meter that is used for medical treatment scene, school, station, bank, convenience store, various communal facility, food factories, dress material manufacturing works etc.; Urgent expectation has bacterinertness, mildew resistance, and the protecting sheet of functions such as antiviral property, antiallergic property.When using plastics sheet as protecting sheet; For example, when mouldy, the mould plastics sheet inside that invades; The performances such as mechanical property such as optical property, flexural strength, modulus in flexure, shock strength, surface hardness such as the transparency, form and aspect of plastics sheet are reduced; In addition, make the display performance deterioration of indicating meter, and then also cause causing the mishandle of display unit as foreign matter.Be prone to adhere to dust, dirt, food dregs, sweat, the mould nutrition source of wet goods on the protecting sheet, cause mould rapid propagation sometimes.In addition, during attached to the protecting sheet surface, bacterium is breeding easily also because of dewfall etc. for moisture.
In order to address these problems, the screening glass (for example, with reference to patent documentation 1) of the thermoset resin layer more than the surface hardness 2H that has formed the particulate that contains the mineral-type antiseptic-germicide on the polyester film has been proposed.In addition, proposed to possess the input unit (for example, with reference to patent documentation 2) of the screening glass that is formed with antimicrobial coating for the spatter property of keeping touch panel.
The prior art document
Patent documentation
Patent documentation 1: TOHKEMY 2006-299214 communique
Patent documentation 2: japanese kokai publication hei 8-185560 communique
Summary of the invention
The problem that invention will solve
But these public technologies are also hard to say can to satisfy all performances even possess, for example, 2 processing that disclosed screening glass need be coated with etc. in the patent documentation 1, and surface hardness, rigidity, chemical reagent resistance/solvent resistance etc. are also insufficient.In addition, disclosed screening glass in the patent documentation 2 owing to need special conveying function, therefore has to become expensive, and practicality is relatively poor.And then, in these public technologies, do not relate to the function of antiviral property, antiallergic property, thereby expect further improvement.
For this reason, under such background, the object of the present invention is to provide the transparency, photostabilization, surface hardness, rigidity, chemical reagent resistance/solvent resistance excellent, and bacterinertness and/or mildew resistance with and the also excellent resin molded body of long-term persistence.In addition, the object of the present invention is to provide the resin molded body of the function of also taking into account antiviral property, antiallergic property.
The scheme that is used to deal with problems
Yet; The inventor etc. further investigate in order to solve above-mentioned problem repeatedly; The result finds that transparent resin molded body forms through the light thermosetting composition [I] that contains antiseptic-germicide and/or mould inhibitor is solidified, thereby can access the transparency, photostabilization, surface hardness, rigidity, chemical reagent resistance/solvent resistance excellence; And bacterinertness, mildew resistance with and the also excellent resin molded body of long-term persistence, thereby accomplished the present invention.
That is, main idea of the present invention relates to a kind of resin molded body, it is characterized in that, it is the transparent resin molding of thickness 0.1～5mm, and this resin molded body is the light thermosetting composition [I] that contains antiseptic-germicide and/or mould inhibitor to be solidified form.
In addition, the display protection plate that is formed by said resin molded body also is provided among the present invention.
In addition, among the present invention, bacterium is meant the bacterium class, the mould Mycophyta that is meant.
In addition, the industrial products of antimicrobial resistance, mildew resistance definition is not clear, and that the level required depending on the application is different, which is based on (social) National Household Electrical Products Fair Trade Agreement will (Home? Electric? Appliances? Fair? TradeConference) criteria and definitions.That is, bacterinertness of the present invention, mildew resistance are meant when human body being brought directly or indirectly dysgenic bacterium, microorganic adhesion such as mould protecting sheet surperficial, stop the function of its growth.
Bacterinertness in the protecting sheet, the function of mildew resistance are not temporary transient, and it must continue the time to a certain degree.For example, during the antimicrobial component that in protecting sheet, is mixed etc., require the slow-releasing of antimicrobial component etc.In addition, need not exceedingly to improve functions such as bacterinertness, mildew resistance, the over-drastic multifunction is being considered security to human body, should avoided during to the load of environment.
The effect of invention
According to the present invention, can easily make optical characteristics, thermo-mechanical property function excellent, that have special excellent surface hardness and rigidity, bacterinertness and/or mildew resistance excellent, with and the also excellent resin molded body that is suitable for display protection plate of long-term persistence.
Embodiment
Below, the present invention is at length explained.
In addition, among the present invention, " (methyl) propenoate " is the general name of propenoate and methacrylic ester.
Resin molded body of the present invention is the transparent resin molding of thickness 0.1～5mm, and it obtains through the light thermosetting composition [I] that contains antiseptic-germicide and/or mould inhibitor is solidified.
Resin molded body of the present invention is tabular, and therefore the rigidity when its thickness directly has influence on as protecting sheet is that 0.1～5mm is important.Thickness easy deformation during less than lower value is difficult to keep the shape of protecting sheet, and is difficult to protect display unit.On the contrary, when surpassing higher limit, the light weight slimming of display unit becomes difficulty.The preferable range of thickness is 0.2～4mm, and more preferably 0.3～3mm further is preferably 0.4～2mm, is preferably 0.5～1.5mm especially.
Biggest characteristic of the present invention is, owing to give the function of resin molded body bacterinertness and/or mildew resistance, thereby make light thermosetting composition [I] contain antiseptic-germicide and/or mould inhibitor this point.
Among the present invention, the reason of the resin molded body that light thermosetting composition [I] is solidified form does, obtains the characteristics such as surface hardness, rigidity, anti-solvent/chemical reagent resistance as protecting sheet easily, and can keep bacterinertness and/or mildew resistance for a long time.Promptly; Usually; Near room temperature the aqueous dissolving of light thermosetting composition [I] easy and uniform ground or dispersion antiseptic-germicide and/or mould inhibitor; And, move to the protecting sheet surface with being bound in antiseptic-germicide and/or mould inhibitor time dependent in the photo-curable resin after just having solidified, embody the function of bacterinertness and/or mildew resistance for a long time.And then photo-curable resin is not dissolved in water usually, even therefore use under high humidity as protecting sheet, the unhelpful situation of antiseptic-germicide and/or mould inhibitor stripping can not take place yet.
As above-mentioned smooth thermosetting composition [I], for example can enumerate out the compsn that contains epoxy compounds, (methyl) acrylic ester compound.In these,, preferably except that containing antiseptic-germicide and/or mould inhibitor, also contain the light thermosetting composition of multifunctional (methyl) acrylic ester compound and Photoepolymerizationinitiater initiater from can productivity making the viewpoint of the resin molded body of thicker type well.
Antiseptic-germicide and/or mould inhibitor be to the unsettled material of long-time heating mostly, for example, deterioration, perhaps xanthochromic tendency in the thermofixation at thermoset composition are arranged in the high-temperature fusion of thermoplastic resin is shaped.In addition, antiseptic-germicide and/or mould inhibitor especially under the little situation of molecular weight, generating gasification in heat-processed how.Through making, can reduce Heating temperature and heat-up time and can not make that the antiseptic-germicide and/or the mould inhibitor that are mixed evapotranspire, under the situation of deterioration, obtain to add the resin molded body that antiseptic-germicide and/or mould inhibitor are arranged with light thermosetting composition [I].
As multifunctional (methyl) acrylic ester compound, can enumerate out multi-functional (methyl) acrylic ester compound that intramolecularly has (methyl) acryl more than 2.
As 2 officials ability (methyl) acrylic ester compound; For example can enumerate out ethylene glycol bisthioglycolate (methyl) propenoate, Diethylene Glycol two (methyl) propenoate, triethylene glycol two (methyl) propenoate, TEG two (methyl) propenoate, polyoxyethylene glycol two (methyl) propenoate, Ucar 35 two (methyl) propenoate, dipropylene glycol two (methyl) propenoate, W 166 two (methyl) propenoate, butyleneglycol two (methyl) propenoate, NSC 6366 two (methyl) propenoate, 1; Fatty family two (methyl) acrylic ester compounds such as 6-pinakon two (methyl) propenoate, glycerine two (methyl) propenoate, tetramethylolmethane two (methyl) propenoate, ethylene glycol diglycidylether two (methyl) propenoate, Diethylene Glycol diglycidylether two (methyl) propenoate, two (hydroxyl) three ring [5.2.1.0
2,6] decane-two (methyl) propenoate, two (methylol) three ring [5.2.1.0
2,6] decane-two (methyl) propenoate, two (hydroxyl) five rings [6.5.1.1
3,6.0
2,7.0
9,13] pentadecane-two (methyl) propenoate, two (methylol) five rings [6.5.1.1
3,6.0
2,7.0
9,13] pentadecane-two (methyl) propenoate, 2; Two [4-(β-(methyl) acryloyl-oxy base oxethyl) cyclohexyl] propane, 1 of 2-; Two ((methyl) acryloyl-oxy ylmethyl) hexanaphthenes, 1 of 3-; Two ((methyl) acryloxy ethoxyl methyl) hexanaphthenes, 1 of 3-; Two ((methyl) acryloyl-oxy ylmethyl) hexanaphthenes, 1 of 4-; Alicyclic ring family two (methyl) acrylic ester compounds such as two ((methyl) acryloxy ethoxyl methyl) hexanaphthenes of 4-, 2, fragrant family two (methyl) acrylic ester compounds such as two [4-(methyl) acryloxy phenyl] propane of 2-, oxyethane modified bisphenol A type two (methyl) propenoate, epoxy pronane modification bisphenol A-type two (methyl) propenoate etc.
As above (methyl) acrylic ester compound of 3 officials ability; For example can enumerate out trimethylolpropane tris (methyl) propenoate, tetramethylolmethane three (methyl) propenoate, tetramethylolmethane four (methyl) propenoate, Dipentaerythritol five (methyl) propenoate, Dipentaerythritol six (methyl) propenoate, three (methyl) acryloyl-oxy base oxethyl TriMethylolPropane(TMP), glycerine polyglycidyl ether gathers epoxy alkane modifications such as (methyl) propenoate, oxyethane modification Dipentaerythritol five (methyl) propenoate, oxyethane modification Dipentaerythritol six (methyl) propenoate, oxyethane modification tetramethylolmethane three (methyl) propenoate, oxyethane modification tetramethylolmethane four (methyl) propenoate and gathers fatty family multi-functional (methyl) propenoate such as (methyl) propenoate; 1; 3; 5-three ((methyl) acryloyl-oxy ylmethyl) hexanaphthene, 1; 3; Alicyclic ring family multi-functional (methyl) propenoate such as 5-three ((methyl) acryloxy ethoxyl methyl) hexanaphthene; 1,3, fragrant family (methyl) acrylic ester compounds such as 5-three ((methyl) acryloxy ethyl) benzene, cyamelide oxyethane modification triacrylate etc.
In addition, can also enumerate out multifunctional (methyl) acrylic ester compounds such as epoxy (methyl) propenoate, carbamate (methyl) propenoate, polyester (methyl) propenoate, polyethers (methyl) propenoate etc.
In the middle of these compounds, from the rigidity aspect, preferred two (hydroxyl) three ring [5.2.1.0
2,6] decane-two (methyl) propenoate, two (methylol) three ring [5.2.1.0
2,6] decane-two (methyl) propenoate etc. has alicyclic ring family two (methyl) propenoate, alicyclic ring family polyfunctional carbamate (methyl) propenoate of alicyclic ring skeleton.
In addition, above-mentioned multi-functional (methyl) acrylic ester compound can also be also with more than a kind or 2 kinds.
In addition, can also be also with above-mentioned multi-functional (methyl) acrylic ester compound and simple function (methyl) acrylic ester compound.
As Photoepolymerizationinitiater initiater; Particularly, can enumerate out UVNUL MS-40 series initiators such as methyl phenyl ketone series initiators, UVNUL MS-40, benzoyl-oil of Niobe, 4-phenyl benzophenone, dihydroxy benaophenonel such as 1-phenyl-2-hydroxy-2-methyl propane-1-ketone, 1-hydroxy-cyclohexyl benzophenone, 4-two phenoxy dichloroacetophenones, 2; 6-dimethylbenzoyl diphenyl phosphine oxide, 2; 4,6-trimethylbenzoyl diphenyl phosphine oxide, two (2,4; The 6-trimethylbenzoyl) phosphine oxide series initiators such as phenyl phosphine oxide etc. also can and be used these Photoepolymerizationinitiater initiaters.
These Photoepolymerizationinitiater initiaters; With respect to 100 weight parts multifunctional (methyl) acrylic ester compound (also with simple function (methyl) acrylic ester compound the time is the total amount of multifunctional (methyl) acrylic ester compound and simple function (methyl) acrylic ester compound); Preferred common ratio with 0.1～10 weight part is used; More preferably 0.2～5 weight part is preferably 0.3～2 weight part especially.When above-mentioned Photoepolymerizationinitiater initiater is very few, the tendency that has curing fully to carry out, in the time of too much, the tendency that the transmittance of rewarding resin molded body reduces.
As the antiseptic-germicide that uses among the present invention, mould inhibitor, can use the compound with known bacterinertness, compound with mildew resistance.Among the present invention; For example can enumerate out metals (comprising ion) such as silver, copper, zinc; MOXs such as zinc oxide, Natural manganese dioxide, titanium oxide; Metal-salts such as SPC-D, Youxiaolin, Trisilver phosphate; Boric acid compounds such as ortho-boric acid, metaboric acid, borax; Complex compound compounds such as thiosulfuric acid silver salt, 2-(4-thiazolyl) benzoglyoxaline silver salt, 2-pyridinethiol-1-oxide sodium salt, two (2-pyridinethiol-1-oxide) zinc salt; And mineral-type compound such as their zeolite-loaded thing, ceramic loaded article, silica gel load thing, montmorillonite-loaded thing; Organic compounds such as quaternary ammonium compound, monocyclic hydrocarbon compounds, phenolic cpd, pyridine compounds and their, alcohol compound 、 phosphonium salt compounds, aryl compounds, halogenated aryl sulfone compound, iodo propargyl compounds, N-halogenated alkylthio compounds, nitrile compounds, oxine compounds, benzothiazole compound, isothiazoline compounds, organic tin compound, compound in triazine class, diazthines compound, anilide compounds, adamantane compound, dithiocarbamate (dithiocarbamate) compounds, bromo indone compounds, phenolic ether compounds, sulfone compound, azoles, glyoxaline compound, benzimidazoles compound, benzoic acid derivative, phenolic ether compounds, sulfone compound, azoles, halo diaryl urea compound, guanidine compound, fatty acid ester compound, cyanic acid compounds, aldehyde compound, amides, iodine compounds, carboxyl imide analog compounds, benzoquinone compound, parabens compound, tyrosol compounds, natural compounds such as chitosan, Meng ancestor's bamboo extract, Japanese Semen Brassicae Junceae extract, horseradish extract, Japan cypress extract, oyster shells, protamine, polylysine etc.
And in the middle of these compounds, organic compounds is being preferred aspect the intermiscibility of light thermosetting composition [I].More preferably; Aspect evapotranspiring in vain in never can use in the manufacturing process of resin molded body, as protecting sheet; The organic compounds of preferred molecular weight more than 100, preferred especially organic compounds of 120～1000, further preferred 140～900.In addition, said here organic compounds mainly is the compound that is made up of carbon and hydrogen, also can contain aerobic, nitrogen, sulphur, phosphorus, silicon and/or halogen, can also contain a spot of metals ion.
In addition, avoiding to aspect human body dysgenic the acute oral toxicity LD of above-mentioned antiseptic-germicide and/or mould inhibitor
50Be preferably more than the 1g/kg.More preferably more than the 1.5g/kg, be preferably more than the 2g/kg especially.In addition, the upper limit is generally 100g/kg.
As concrete organic type the antiseptic-germicide that uses in the present invention; For example can enumerate out 3-(trimethoxysilyl) propyl-dimethyl octadecyl ammonium chloride, tetradecyl dimethyl benzyl ammonium chloride, 1-hexadecylpyridinium chloride, cetyl trimethylammonium bromide, palmityl trimethyl ammonium chloride, N-T 46155-N; N; N-trimethyl ammonium chloride, hexadecyl trimethyl ammonium chloride, OTAC, Timbercote 2000, benzalkonium chloride (benzalkonium chloride), INCROQUAT TMC-80, Solamin, 4; 4 '-(tetramethylene dicarbapentaborane diamino-) two (1-decyl pyridinium bromides), N, N '-hexa-methylene two (4-formamyl-1-decyl pyridinium salt), 4,4 '-(terephthalamide) two (1-octyl pyridinium bromides), 3; 3 '-(isophthaloyl amine) two quaternary ammonium compounds such as (the 1-n octyl iodide are for pyridine); Monohydric phenol compounds such as 5-chloro-2-(2,4 dichloro benzene oxygen base) phenol, 2-(3; 5-dimethyl pyrazole base)-pyridine compounds and theirs such as 4-hydroxyl one 6-phenylpyridine; 2-(methylol is amino) ethanol, 2-(methylol is amino)-alcohol compounds such as 2-methylpropanol, phosphonium salt compounds such as tetradecane base San Jia Ji phosphonium chloride, two decyl Er Jia Ji phosphonium chlorides, SY 1007 compounds etc.
In the middle of these compounds, aspect sunproof, preferred quaternary ammonium compound, pyridine compounds and their.Aspect cheapness, especially preferably can enumerate out 3-(trimethoxysilyl) propyl-dimethyl octadecyl ammonium chloride, tetradecyl dimethyl benzyl ammonium chloride etc.
In addition; As the bacterium among the present invention, for example can enumerate out the bacterium of Staphylococcusaureus, MRSA (methicillin-resistant Staphylococcus aureus methicillin-resistant staphylococcus aureus), Escherichia coli, Pseudomonasaeruginosa, Micrococcus sp., Pediococcus sp., Proteus vulgaris, Pseudomonas aeruginosa, Pseudomonas putida, Pseudomonasfluorescens, Pseudomonas alcaligenes, PseudomonasPseudoalcaligenes, Pseudomonas cepacia, Alcaligenesdefnitrificans, Alcaligenes faecalis, Bacillus subtils, Bacilluscerens, Acinetobacter calcoaceticus, Alcaligenes faecalis, Peptococcus sp., Neisseria sp., Salmonella typhimurium, Vibrioparahaemolyticus, Enterobacter cloacea, Citrobacter freundii, Kiebsiella pneumoniae, Actinomyces genus or Thiobacillus genus etc.
In addition, as concrete organic type the mould inhibitor that uses in the present invention, for example can enumerate out 1-((diiodomethyl) alkylsulfonyl)-halogenated aryl sulfone compounds such as 4-methylbenzene, iodo propargyl compounds such as 3-iodo-2-propargyl butyl carbamate; N, N-dimethyl--N '-(fluorine diformazan sulfenyl)-N '-phenyl-sulfamide, N, N-dimethyl--N '-(fluorine dichloromethane sulfenyl)-N '-N-halogenated alkylthio compounds such as phenyl-sulfamide, 2; 3,5,6-daconil M, 2,4; 5, nitrile compounds such as 6-daconil M, 2,3; 5, pyridine compounds and theirs such as 6-tetrachloro-4-(methyl sulphonyl) pyridine, benzothiazole compounds such as 2-(sulfo-cyanomethylthio) benzothiazole, 2-n-octyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone, 5-chloro-2-methyl-4-isothiazoline-isothiazoline compounds such as 3-ketone; Parachlorometacresol, alkylidene bisphenols sodium, 2,4,4 '-three chloro-2 '-phenolic cpd such as hydroxy diphenyl ether, orthoxenol, six hydrogen-1; 3,5-three (2-hydroxyethyl)-compound in triazine class such as s-triazine, 3,5-dimethyl--tetrahydrochysene-1; 3,5,2H-thiadiazine-diazthines compounds such as 2-thioketones, 3; 4, anilide compounds such as 5-tribromo salicylanilide, 1-(3-chlorallyl)-3,5; 7-three azepines-adamantane compounds such as 1-nitrogen diamantane muriate, dithio amino formate compounds such as tetramethyl-thiuram disulfide, two (dimethyl-thiocarbamoyl) disulphide, bis(diethylthiocarbamyl)disulfide, 2; Bromo indone compounds such as 2-two bromo-1-indones, bromotoluene acetic ester, benzoic acid derivatives such as p-Hydroxybenzoate; N-(trichloro-methylthio) phthalic imidine, N-trichloro-methylthio-4-tetrahydrobenzene-1,2-dicarboxyl imide, N-1,1; 2, phthalimide derivatives such as 2-tetrachloro ethylmercapto group tetrahydric phthalimide, N-(fluorine dichloromethane sulfenyl) phthalic imidine, glyoxaline compounds such as 2-(4-thiazolyl) benzoglyoxaline, 2-(methoxycarbonyl is amino) benzoglyoxaline, benzoglyoxaline Urethylane, 2-benzoglyoxaline methyl carbamate; Halo diaryl urea compounds such as triclocarban, guanidine compounds such as hexamethylene, chlorhexidine dihydrochloride, fatty acid ester compounds such as Ucar 35 mono fatty acid ester, glycerol fatty acid ester; 2, amidess such as 2-two bromo-2-cyanic acid propionic acid amides, diiodomethyl-to iodine compounds such as toluene sulfones; N-(1,1,2; 2-tetrachloro ethylmercapto group)-and 4-tetrahydrobenzene-1,2-dicarboxyl imide, N-(trichloro-methylthio)-4-tetrahydrobenzene-1, carboxyl imide analog compounds such as 2-dicarboxyl imide; 2, benzoquinone compounds such as 6-dimethoxy-para benzoquinone, parabens compounds such as methyl paraben, ethylparaben etc.
In the middle of these compounds, aspect sunproof, preferred phthalimide derivatives, isothiazoline compounds.Aspect the intermiscibility of light thermosetting composition [I], particularly preferably be phthalimide derivatives.
In addition; As of the present invention mould; For example can enumerate out fungies such as Candida albicnas, Aspergillus niger, Aspergillus terrus, Penicillium citrinum, Aspergillus penicilloides, Penicillium funiculosum, Penicilliumdigitatum, Aureobasidium pullulans, Phoma sp, Cladosporiumcladosporioides, Cladosporium herbabarum, Cladosporiumresinae, Aspergillus flavus, Aspergillus fumigatus, Aspergillusterreus, Geotrichum sp., Alternaria sp., Alternaria Alternata, Fusarium solani, Nigrospora Oryzae, Pestalotia adusta, Trichoderma T-1, Trichoderma sp., Trichoderma harzianu, Chaetomium globosum, Rhizopus stronifer, Rhizopus nigricans, belong to the fungi of Curvularia genus, Eurochiumu genus, Nocardia genus, Streptomyces genus, Decdrosphaera genus, Cochliobolus genus, Acremonium genus etc. etc.
In addition, the compound that has mildew resistance in the antiseptic-germicide is more, and in addition, the compound that has bacterinertness in the mould inhibitor is also more.Among the present invention, for convenience's sake, with both separately records, but what want remarks is to be difficult to both are distinguished tightly.
In addition, also more deodorization property, the preservative property of embodying of bacterinertness, mildew resistance result can be appended and are effect of the present invention.
In addition, antiseptic-germicide, mould inhibitor also are known as anti-activator, the preserving agent deposited sometimes.
In resin molded body of the present invention, preferably further contain antiviral agent, anti-allergic agent.
Particularly, light thermosetting composition [I] also contains antiviral agent, anti-allergic agent forms, and above-mentioned smooth thermosetting composition [I] is cured and becomes resin molded body.
As antiviral agent, for example can enumerate out thiosulfuric acid silver salt, Hydroxytyrosol, LUTARALDEHYDE, Hexachlorophene, chlohexidine etc.In the middle of these antiviral agents, aspect the intermiscibility of light thermosetting composition [I], preferred Hydroxytyrosol.
In addition, as the virus among the present invention, can enumerate out virus of AIDS, Measles virus, hsv, influenza virus etc. usually has film virus, no film virus such as poliovirus etc.
As anti-allergic agent; For example can enumerate out polyphenolic compounds such as polyphenol, many cresols, Polymethoxylated phenol, polyvinylphenol (polyvinylphenol) compounds, poly dihydroxyphenyl propane compounds; Lignin phenol (lignophenol) compounds, tannic acid, polytyrosine etc.In these anti-allergic agents, aspect the effect that makes the allergen inactivation, preferred polyphenolic compound, polyvinylphenol compounds.Aspect the intermiscibility of light thermosetting composition [I], special preferably polyethylene base phenol compound.
In addition; Allergen among the present invention; So long as cause the material of anaphylaxy diseases such as atopic dermatitis, bronchial asthma, allergic rhinitis; Then have no particular limits the allergenic substance that to enumerate out dust mite allergen (mite allergen), Chinese fir pollen allergen and produce by these allergens.
The content of antiseptic-germicide, mould inhibitor, antiviral agent and/or anti-allergic agent when light thermosetting composition [I] total amount is 100 weight %, is preferably 0.01～5 weight % respectively.More preferably 0.05～3 weight % is preferably 0.1～1 weight % especially.When the content of antiseptic-germicide, mould inhibitor, antiviral agent and/or anti-allergic agent is very few; The inadequate tendency of function that has bacterinertness, mildew resistance, antiviral property and/or the antiallergic property of resin molded body; On the contrary, in the time of too much, existence possibly bring dysgenic tendency to environment, human body.
In addition, in order to make antiseptic-germicide, mould inhibitor, antiviral agent and/or anti-allergic agent homodisperse, the light thermosetting composition [I] that uses among the present invention can suitably contain ancillary components such as tensio-active agent.
And then, in the light thermosetting composition [I] that uses in the present invention, can contain a spot of ancillary component in the scope of not damaging the object of the invention.For example can enumerate out thermoplastic resin, stopper, thermal polymerization, chain-transfer agent, inhibitor, anti-xanthochromia agent, UV light absorber, the agent of laying up, dye pigment, skimmer, flow agent, thixotropy imparting agent, fire retardant, thickening material, various fillers etc.
Use the light thermosetting composition [I] that obtains like this; Thereby obtain resin molded body, resin molded body of the present invention is made through following method: light thermosetting composition [I] is arranged on the smooth mould or 2 smooth moulds between, irradiates light; Make its curing, thereby make.Illumination can divide several stages to carry out.In order to promote, accomplish curing, also preferably when illumination or after the irradiation, resin molded body is heated.
The material of mould as long as make at least one mould printing opacity, then has no particular limits, and can use glass, metal system, resinous mould.In the middle of these moulds, aspect the light transmission of light, the mould of preferred glass system or transparent resin system.When using opaque mould, the mould of opposite face uses the mould of transparent material, and carries out illumination from this opposite side.
As employed light, can utilize the light of far ultraviolet rays yue, ultraviolet ray, near-ultraviolet ray, infrared rays etc., but from considerations such as the acquisition easness of curing speed, irradiating unit, prices, it is favourable utilizing uviolizing to be cured.As the light source in the uviolizing, can use chemical lamp, xenon lamp, Cooper-Hewitt lamp, high pressure mercury vapour lamp, metal halide lamp etc. usually.As irradiation energy, usually as long as irradiation 0.1～10J/cm
2About get final product.There is the tendency that causes antiseptic-germicide, mould inhibitor, antiviral agent and/or anti-allergic agent inactivation in the over-drastic irradiation.
In addition, can also be formed for giving fine concavo-convex, (can be called the Newton's ring-resisting function) that be used to avoid interference fringe fine concavo-convex of anti-corona function, water-proof function on the surface of resin molded body.Particularly because the fine concavo-convex water-proof function this point of giving also is preferred from the viewpoint that reduces bacterium, mould tack.In these cases, as long as the mould that at least one mould uses the surface to have fine concaveconvex shape forms, can form fine concavo-convex on the surface of resin molded body self.
The transmittance of resin molded body of the present invention is more than 80%, is preferred aspect this transparency as protecting sheet the time.The transmittance of resin molded body more preferably more than 85%, is preferably more than 90% especially.In addition, the higher limit of transmittance is 99% usually.
As the method that transmittance is improved; Can enumerate out special appointment light thermosetting composition [I] composition, content method (for example; Use the monomer that does not contain aromatic nucleus as multifunctional (methyl) propenoate; Perhaps adjust the amount of Photoepolymerizationinitiater initiater etc.), specify antibiotic, mildew-resistant, antiviral agent and/or the composition of anti-allergic agent, the method for content especially, cooperate the method for inhibitor etc. as ancillary component; The method of control condition of cure (for example, exceedingly do not improve light quantity, shine with reactive gasization not etc.) etc.
And then the pencil hardness of resin molded body of the present invention is more than the 2H, and the aspect of this surface hardness from as protecting sheet the time is preferred, and modulus in flexure is more than the 3GPa, is preferred aspect this rigidity as protecting sheet the time.
The pencil hardness of resin molded body more preferably more than the 3H, is preferably more than the 4H especially.When above-mentioned pencil hardness is adjusted into above-mentioned scope, can enumerate out the method for use level of kind, the composition of the above-mentioned smooth thermosetting composition of suitable control [I].For example can enumerate out the method etc. of using the compound that polyfunctional carbamate (methyl) acrylic ester compound, 3 officials can be above as multifunctional (methyl) propenoate.In addition, the higher limit of the pencil hardness of resin molded body is 8H usually.
In addition, the modulus in flexure of resin molded body more preferably more than the 3.5GPa, is preferably more than the 4GPa especially.When above-mentioned modulus in flexure is adjusted into above-mentioned scope, can enumerate out the method for use level of kind, the composition of the above-mentioned smooth thermosetting composition of suitable control [I].In addition, the higher limit of the modulus in flexure of resin molded body is 10GPa.
The resin molded body of the present invention that obtains like this, the transparency, physical strength is excellent, and bacterinertness, mildew resistance and antiviral property, antiallergic property are also excellent, are very useful as various display protection plates.
Embodiment
Below, enumerate embodiment to further explanation particularly of the present invention, under the situation that does not exceed purport of the present invention, the present invention is not limited by the following examples.
In addition, " part " in the example, " % " not having under the situation about specifying, are meant weight basis.
Carried out each item evaluation in such a way.
(1) bacterinertness
About make after 1 day with 2 months after resin molded body, make an experiment according to JIS Z 2801, estimate in such a way for Staphylococcus aureus and Escherichia coli.In addition, as the no processing of films that is used for reference, use the film of the comparative example 1 that does not contain antiseptic-germicide, mould inhibitor, antiviral agent and anti-allergic agent.
Zero is more than 2 all bacterium anti-microbial activity values
△ is more than 2 as far as any bacterium anti-microbial activity value
* as far as all equal less thaies 2 of bacterium anti-microbial activity value
(2) mildew resistance
With these 5 kinds mould being inoculated into respectively in the potato dextrose agar (PDA) of Aspergillus niger, Penicillium citrinum, Aureobasidiumpullulans, Phoma sp. and Cladosporium cladosporioides; After cultivating 10 days under 25 ℃; Use be diluted to 100 times glucose peptone meat soup (Glucose Peptonebroth) (GP), make 5 kinds of mould spore counts and be respectively 1.0 * 10
6The mixing spore liquid of cfu/ml.With this mixing spore liquid be sprayed to make after 1 day with 2 months after the surface of resin molded body, in 29 ℃, 90%RH 4 weeks of cultivation down, with the naked eye mould growth with microscopic examination, thereby estimated mildew resistance as follows.
Zero growth to mould mycelia unconfirmed.
The △ growth to mould mycelia with the naked eye unconfirmed, but confirm the growth of mould mycelia with microscope.
* with the naked eye confirm the growth of mould mycelia.
(3) antiallergic property
On resin molded body, smear the dust that contains dust mite allergen (Der1 and Der2), 25 ℃, 75%RH held 24 hours, " the Dani Scan " that uses ア サ ヒ PVC one Le drug company to make observed and has or not colour developing.
Zero does not have colour developing (no antiallergic property)
* colour developing (antiallergic property is arranged)
(4) transmittance
Use the Japanese electric look haze meter of company " NDH-2000 ", measure the total light transmittance (%) of resin molded body.
(5) pencil hardness
According to JIS K 5600-5-4, measured the pencil hardness of resin molded body.
(6) modulus in flexure
Use the test film of the resin molded body of length 25 (mm) * width 10 (mm), utilize the autograph " AG-5kNE " (length of support 20mm, 0.5mm/ minute) of Shimadzu Seisakusho Ltd.'s manufactured, the modulus in flexure (GPa) under having measured 25 ℃.
(7) solvent resistance
Resin molded body was flooded 1 hour in Virahol under 25 ℃, estimate according to following metewand.
Zero no change in appearance.
* change in appearance.
< embodiment 1 >
Will two (methylol) three ring [5.2.1.0
2,6] 98 parts of decane-diacrylates (Xin Zhong village chemical company make, " A-DCP "), as the quaternary ammonium compound of antiseptic-germicide promptly 4,4 '-(tetramethylene dicarbapentaborane diamino-) two (1-decyl pyridinium bromide) (molecular weight 740.70, LD
50(rat) is more than the 2000mg/kg) 1 part, as 1 part of the 1-hydroxy-cyclohexyl benzophenone (チ バ ガ イ ギ one Co., Ltd. makes, " Irgacure 184 ") of Photoepolymerizationinitiater initiater, under 60 ℃, be stirred to evenly, obtain light thermosetting composition [I].It is that the use metal halide lamp is with illumination 100mW/cm in the shaping dies that forms of pad (spacer) and 2 glass sheets that are provided with by subtend (23 ℃) that said composition [I] is injected into silicon plate with thickness 1.0mm
2, light quantity 5J/cm
2Behind the irradiation ultraviolet radiation, the demoulding obtains the resin molded body (A) of width 30cm * length 30cm * thickness 1.0mm.
The transmittance of the resin molded body of gained (A) is 92%, and pencil hardness is 3H, and modulus in flexure is 4GPa, and solvent resistance is good, has the good performance as protecting sheet.Bacterinertness, mildew resistance and antiallergic property are as shown in table 2.
< embodiment 2 >
Use two (methylol) three ring [5.2.1.0
2,6] 98 parts of decane-diacrylates (Xin Zhong village chemical company make, " A-DCP "), be N-(fluorine dichloromethane sulfenyl) phthalic imidine (molecular weight 280.10, LD as the phthalimide derivatives of mould inhibitor
50(three love oil companies make (rat)-2900mg/kg); " サ Application ア イ ゾ one Le 300 ") 1 part, (チ バ ガ イ ギ one Co., Ltd. makes as the 1-hydroxy-cyclohexyl benzophenone of Photoepolymerizationinitiater initiater; " Irgacure 184 ") 1 part, likewise obtain the resin molded body (B) of width 30cm * length 30cm * thickness 1.0mm in addition with embodiment 1.
The transmittance of the resin molded body of gained (B) is 92%, and pencil hardness is 3H, and modulus in flexure is 4GPa, and solvent resistance is good, has the good performance as protecting sheet.Bacterinertness, mildew resistance and antiallergic property are as shown in table 2.
< embodiment 3 >
Use two (methylol) three ring [5.2.1.0
2,6] (Xin Zhong village chemical company makes decane-diacrylate; " A-DCP ") 97 parts, as the quaternary ammonium compound of antiseptic-germicide be 1 part of tetradecyl dimethyl benzyl ammonium chloride, as the phthalimide derivatives of mould inhibitor be 1 part of N-(fluorine dichloromethane sulfenyl) phthalic imidine (サ Application ア イ ゾ one Le 300 that three love oil companies make), (チ バ ガ イ ギ one Co., Ltd. makes as the 1-hydroxy-cyclohexyl benzophenone of Photoepolymerizationinitiater initiater; " Irgacure 184 ") 1 part; In addition, likewise obtain the resin molded body (C) of width 30cm * length 30cm * thickness 1.0mm with embodiment 1.
The transmittance of the resin molded body of gained (C) is 91%, and pencil hardness is 3H, and modulus in flexure is 4GPa, and solvent resistance is good, has the good performance as protecting sheet.Bacterinertness, mildew resistance and antiallergic property are as shown in table 2.
< embodiment 4 >
Will two (methylol) three ring [5.2.1.0
2,6] (Xin Zhong village chemical company makes decane-diacrylate; " A-DCP ") 98.8 parts, as the quaternary ammonium compound of antiseptic-germicide be 0.1 part of tetradecyl dimethyl benzyl ammonium chloride, as the phthalimide derivatives of mould inhibitor be 0.1 part of N-(fluorine dichloromethane sulfenyl) phthalic imidine (サ Application ア イ ゾ one Le 300 that three love oil companies make), (チ バ ガ イ ギ one Co., Ltd. makes as the 1-hydroxy-cyclohexyl benzophenone of Photoepolymerizationinitiater initiater; " Irgacure 184 ") 1 part; Under 60 ℃, be stirred to evenly, obtain light thermosetting composition [I].It is that the use metal halide lamp is with illumination 100mW/cm in the shaping dies that forms of pad and 2 glass sheets that are provided with by subtend (23 ℃) that said composition [I] is injected into silicon plate with thickness 0.5mm
2, light quantity 5J/cm
2Behind the irradiation ultraviolet radiation, the demoulding obtains the resin molded body (D) of width 30cm * length 30cm * thickness 0.5mm.
The transmittance of the resin molded body of gained (D) is 91%, and pencil hardness is 3H, and modulus in flexure is 4GPa, and solvent resistance is good, has the good performance as protecting sheet.Bacterinertness, mildew resistance and antiallergic property are as shown in table 2.
< embodiment 5 >
Replace two (methylol) three ring [5.2.1.0
2,6] 97 parts of decane-diacrylates (Xin Zhong village chemical company make, " A-DCP "), use two (methylol) three ring [5.2.1.0
2,6] (Xin Zhong village chemical company makes decane-diacrylate; " A-DCP ") (The Nippon Synthetic Chemical Industry Co., Ltd makes for 60 parts and 6 functional alicyclic urethane propenoate; " UV7600B ") 37 parts; In addition, likewise obtain the resin molded body (E) of width 30cm * length 30cm * thickness 1.0mm with embodiment 3.
The transmittance of the resin molded body of gained (E) is 91%, and pencil hardness is 5H, and modulus in flexure is 5GPa, and solvent resistance is good, has the good performance as protecting sheet.Bacterinertness, mildew resistance and antiallergic property are as shown in table 2.
< embodiment 6 >
Use two (methylol) three ring [5.2.1.0
2,6] (Xin Zhong village chemical company makes decane-diacrylate; " A-DCP ") 96 parts, be 1 part of tetradecyl dimethyl benzyl ammonium chloride, be that (three love oil companies make N-(fluorine dichloromethane sulfenyl) phthalic imidine as the quaternary ammonium compound of antiseptic-germicide as the phthalimide derivatives of mould inhibitor; " サ Application ア イ ゾ one Le 300 ") 1 part, as 1 part of the Hydroxytyrosol of antiviral agent, (チ バ ガ イ ギ one Co., Ltd. makes as the 1-hydroxy-cyclohexyl benzophenone of Photoepolymerizationinitiater initiater; " Irgacure 184 ") 1 part; In addition, likewise obtain the resin molded body (F) of width 30cm * length 30cm * thickness 1.0mm with embodiment 1.
The transmittance of the resin molded body of gained (F) is 91%, and pencil hardness is 3H, and modulus in flexure is 4GPa, and solvent resistance is good, has the good performance as protecting sheet.Bacterinertness, mildew resistance and antiallergic property are as shown in table 2.
< embodiment 7 >
Use two (methylol) three ring [5.2.1.0
2,6] (Xin Zhong village chemical company makes decane-diacrylate; " A-DCP ") 94 parts, be 1 part of tetradecyl dimethyl benzyl ammonium chloride, be that (three love oil companies make N-(fluorine dichloromethane sulfenyl) phthalic imidine as the quaternary ammonium compound of antiseptic-germicide as the phthalimide derivatives of mould inhibitor; " サ Application ア イ ゾ one Le 300 ") 1 part, as anti-allergic agent gather (4-vinylphenol) 3 parts, (チ バ ガ イ ギ one Co., Ltd. makes as the 1-hydroxy-cyclohexyl benzophenone of Photoepolymerizationinitiater initiater; " Irgacure 184 ") 1 part; In addition, likewise obtain the resin molded body (G) of width 30cm * length 30cm * thickness 1.0mm with embodiment 1.
The transmittance of the resin molded body of gained (G) is 90%, and pencil hardness is 2H, and modulus in flexure is 4GPa, and solvent resistance is good, has the good performance as protecting sheet.Bacterinertness, mildew resistance and antiallergic property are as shown in table 2.
< comparative example 1 >
Will two (methylol) three ring [5.2.1.0
2,6] (Xin Zhong village chemical company makes decane-diacrylate; " A-DCP ") 99 parts, (チ バ ガ イ ギ one Co., Ltd. makes as the 1-hydroxy-cyclohexyl benzophenone of Photoepolymerizationinitiater initiater; " Irgacure 184 ") 1 part, under 60 ℃, be stirred to evenly, obtain the light thermosetting composition.Except using said composition, likewise obtain the resin molded body (H) of width 30cm * length 30cm * thickness 1.0mm with embodiment 1.
The transmittance of the resin molded body of gained (H) is 92%, and pencil hardness is 3H, and modulus in flexure is 4GPa, and solvent resistance is good, has the good performance as protecting sheet.Mildew-resistant and antiallergic property are as shown in table 2.
[table 1]
[table 2]
Can know from above-mentioned evaluation result; For making the light thermosetting composition contain antiseptic-germicide, mould inhibitor, antiviral agent, anti-allergic agent and solidifying the resin molded body that forms; Have excellent bacterinertness, mildew resistance, antiallergic property etc. respectively; And then, owing to form by photo-curable resin, even therefore through also keeping for a long time their performance.
Utilizability on the industry
Resin molded body of the present invention can advantageously be utilized as various optical materials, electronic material.For example can be used for using substrate, PDP to use substrate, Electronic Paper to use various indicating meters such as substrate, light guiding plate, polarizer, touch panel, optical filter to use member, optic disc base board memory storage purposes as representative with crystal liquid substrate, organic/inorganic EL; Hull cell substrate, solar cell substrate equal energy source purposes; Optical communication purposes such as light-guide wave path, and functional membrane/sheet, various blooming/sheet purposes.In addition, except optical material, the electronic material, for example can also be used for materials used in auto manufacturing, building materials with material, medical material, stationery etc.
Claims (12)
1. a resin molded body is characterized in that, it is the transparent resin molding of thickness 0.1～5mm, and this resin molded body is the light thermosetting composition [I] that contains antiseptic-germicide and/or mould inhibitor to be solidified form.
2. resin molded body according to claim 1 is characterized in that, light thermosetting composition [I] contains multifunctional (methyl) acrylic ester compound and Photoepolymerizationinitiater initiater forms.
3. resin molded body according to claim 2 is characterized in that, multifunctional (methyl) acrylic ester compound is the compound with alicyclic ring skeleton.
4. according to each described resin molded body in the claim 1～3, it is characterized in that antiseptic-germicide and/or mould inhibitor are the organic compounds of molecular weight more than 100.
5. according to each described resin molded body in the claim 1～4, it is characterized in that the acute oral toxicity LD of antiseptic-germicide and/or mould inhibitor
50More than 1g/kg.
6. according to each described resin molded body in the claim 1～5, it is characterized in that antiseptic-germicide and/or mould inhibitor are the compound more than at least a kind that is selected from quaternary ammonium compounds, phthalimide derivatives, the isothiazoline compounds.
7. according to each described resin molded body in the claim 1～6, it is characterized in that light thermosetting composition [I] also further contains antiviral agent and forms.
8. according to each described resin molded body in the claim 1～7, it is characterized in that light thermosetting composition [I] also further contains anti-allergic agent and forms.
9. according to each described resin molded body in the claim 1～8, it is characterized in that its transmittance is more than 80%.
10. according to each described resin molded body in the claim 1～9, it is characterized in that its pencil hardness is more than the 2H, and modulus in flexure is more than the 3GPa.
11., it is characterized in that it is as display protection plate according to each described resin molded body in the claim 1～10.
12. a display protection plate is characterized in that, it is formed by each described resin molded body in the claim 1～11.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009167311 | 2009-07-16 | ||
| JP2009-167311 | 2009-07-16 | ||
| PCT/JP2010/060734 WO2011007650A1 (en) | 2009-07-16 | 2010-06-24 | Molded resin and protective plate for display |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102449063A true CN102449063A (en) | 2012-05-09 |
Family
ID=43449260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010800239826A Pending CN102449063A (en) | 2009-07-16 | 2010-06-24 | Molded resin and protective plate for display |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5523948B2 (en) |
| KR (1) | KR20120038932A (en) |
| CN (1) | CN102449063A (en) |
| WO (1) | WO2011007650A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112574458A (en) * | 2019-09-30 | 2021-03-30 | Sk新技术株式会社 | Window covering film and flexible display panel comprising same |
| CN114656762A (en) * | 2022-04-15 | 2022-06-24 | 佛山市顺德区美的洗涤电器制造有限公司 | Antibacterial transparent material, preparation method thereof, water storage container and dish washing machine |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012141063A1 (en) * | 2011-04-13 | 2012-10-18 | 日本合成化学工業株式会社 | Resin molding, and laminate produced using same |
| JP6243190B2 (en) | 2013-10-30 | 2017-12-06 | 東洋製罐グループホールディングス株式会社 | Antimicrobial metal ultrafine particle-containing dispersion and method for producing the same |
| CN105764995B (en) | 2013-11-22 | 2018-04-06 | 东洋制罐集团控股株式会社 | Hardening resin composition with antibiotic property |
| CN107003440A (en) | 2014-12-05 | 2017-08-01 | 昭和电工株式会社 | Photocontrol panel and photoimaging equipment |
| JP2017143035A (en) * | 2016-02-12 | 2017-08-17 | Jsr株式会社 | Composition for light guide plate and light guide plate |
| JP7132695B2 (en) | 2016-12-20 | 2022-09-07 | Ｔｏｍａｔｅｃ株式会社 | Metal microparticles, metal microparticle-containing dispersion liquid, and method for producing the same |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08311373A (en) * | 1995-05-22 | 1996-11-26 | Tokuyama Corp | Photo-setting composition for antimicrobial film |
| JP2001278926A (en) * | 2000-03-31 | 2001-10-10 | Osaka Gas Co Ltd | Photocurable composition and coating film |
| JP2002327005A (en) * | 2001-05-02 | 2002-11-15 | Mitsubishi Rayon Co Ltd | Photocurable resin composition and its resin laminate |
| CN1479165A (en) * | 2002-08-26 | 2004-03-03 | 三星电子株式会社 | Display screen containing functional material and its manufacturing method |
| JP2006193596A (en) * | 2005-01-13 | 2006-07-27 | Nippon Synthetic Chem Ind Co Ltd:The | Resin molding, method for producing the same and its use |
| JP2009274430A (en) * | 2008-04-15 | 2009-11-26 | Sumitomo Chemical Co Ltd | Scratch-resistant resin sheet and its use |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6420455B1 (en) * | 1999-06-18 | 2002-07-16 | 3M Innovative Properties Company | Antimicrobial composition containing photosensitizers articles, and methods of use |
| JP2003342402A (en) * | 2002-05-27 | 2003-12-03 | Mitsubishi Rayon Co Ltd | Antimicrobial resin molding having scratch resistance and production method therefor |
| WO2009044648A1 (en) * | 2007-10-01 | 2009-04-09 | Toagosei Co., Ltd. | Anti-allergen agent |
-
2010
- 2010-06-24 WO PCT/JP2010/060734 patent/WO2011007650A1/en active Application Filing
- 2010-06-24 CN CN2010800239826A patent/CN102449063A/en active Pending
- 2010-06-24 JP JP2010143584A patent/JP5523948B2/en active Active
- 2010-06-24 KR KR1020117029311A patent/KR20120038932A/en not_active Application Discontinuation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08311373A (en) * | 1995-05-22 | 1996-11-26 | Tokuyama Corp | Photo-setting composition for antimicrobial film |
| JP2001278926A (en) * | 2000-03-31 | 2001-10-10 | Osaka Gas Co Ltd | Photocurable composition and coating film |
| JP2002327005A (en) * | 2001-05-02 | 2002-11-15 | Mitsubishi Rayon Co Ltd | Photocurable resin composition and its resin laminate |
| CN1479165A (en) * | 2002-08-26 | 2004-03-03 | 三星电子株式会社 | Display screen containing functional material and its manufacturing method |
| JP2006193596A (en) * | 2005-01-13 | 2006-07-27 | Nippon Synthetic Chem Ind Co Ltd:The | Resin molding, method for producing the same and its use |
| JP2009274430A (en) * | 2008-04-15 | 2009-11-26 | Sumitomo Chemical Co Ltd | Scratch-resistant resin sheet and its use |
Non-Patent Citations (4)
| Title |
|---|
| 孙启宏等: "《可持续消费》", 30 September 2001, 贵州科技出版社 * |
| 张军营等: "《丙烯酸酯胶黏剂》", 30 April 2006, 化学工业出版社 * |
| 陈仪本等: "《工业杀菌剂》", 31 May 2001, 化学工业出版社 * |
| 陈昌杰主编: "《塑料功能性包装薄膜》", 28 February 2010, 化学工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112574458A (en) * | 2019-09-30 | 2021-03-30 | Sk新技术株式会社 | Window covering film and flexible display panel comprising same |
| CN112574458B (en) * | 2019-09-30 | 2024-03-26 | Sk新技术株式会社 | Window covering film and flexible display panel including the same |
| CN114656762A (en) * | 2022-04-15 | 2022-06-24 | 佛山市顺德区美的洗涤电器制造有限公司 | Antibacterial transparent material, preparation method thereof, water storage container and dish washing machine |
| CN114656762B (en) * | 2022-04-15 | 2023-08-22 | 佛山市顺德区美的洗涤电器制造有限公司 | Antibacterial transparent material, preparation method thereof, water storage container and dish-washing machine |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2011007650A1 (en) | 2011-01-20 |
| JP2011038081A (en) | 2011-02-24 |
| JP5523948B2 (en) | 2014-06-18 |
| KR20120038932A (en) | 2012-04-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102449063A (en) | Molded resin and protective plate for display | |
| KR101413219B1 (en) | Resin compositions having insulation effect and antibiotic effect, functional film using the same | |
| KR101160190B1 (en) | Resin compositions containing silver particles of nano size and antibacterial film using the same | |
| KR101787385B1 (en) | Blue light cut privacy film having anti-bacterial function and manufacturing method of the film | |
| CN106376237A (en) | Aqueous composition, hard coat film, laminated film, transparent conductive film, and touch panel | |
| KR101586845B1 (en) | Polarizer protecting film, polarizer plate comprising the same, and method for preparing the polarizer plate | |
| JP2008006801A (en) | Method of manufacturing nano-silver coated surface material | |
| CN203845983U (en) | Flame retardant antistatic protective tape | |
| JP6799200B1 (en) | Antiviral coating film forming paints, coating films, and laminated films | |
| CN111892734A (en) | Anti-dazzle antibacterial hardened film and preparation method and application thereof | |
| KR101884193B1 (en) | Coating layer of display component having multi-function and method of manufacturing the layer | |
| WO2022025137A1 (en) | Antiviral article and antiviral resin composition | |
| JP2015074672A (en) | Plastic sheet, protective sheet for display, and method for producing plastic sheet | |
| CN204385122U (en) | A kind of PU protective membrane | |
| CN116410671A (en) | Long-acting antibacterial and antivirus protective film for touch screen | |
| US9113634B1 (en) | Panel assembly with interstitial copper | |
| CN216808668U (en) | Antibacterial protective film | |
| JP2023079170A (en) | Antiviral composition, antiviral protective film, and method for producing the same | |
| CN218290800U (en) | Peep-proof mobile phone protection film | |
| CN220224056U (en) | Scratch-proof peep-proof film | |
| CN216550236U (en) | Persistent antibacterial antiviral peep-proof membrane | |
| KR20180081223A (en) | Coating layer of display component having multi-function and method of manufacturing the layer | |
| CN212403995U (en) | Radiation-proof glass film | |
| CN204374457U (en) | A kind of antibacterial and mouldproof resistance mill reflective fabric | |
| CN205398531U (en) | Novel antibiotic mould proof resin plate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C05 | Deemed withdrawal (patent law before 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120509 |