CN102448334A - Tobacco smoke filter - Google Patents

Tobacco smoke filter Download PDF

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Publication number
CN102448334A
CN102448334A CN2010800230395A CN201080023039A CN102448334A CN 102448334 A CN102448334 A CN 102448334A CN 2010800230395 A CN2010800230395 A CN 2010800230395A CN 201080023039 A CN201080023039 A CN 201080023039A CN 102448334 A CN102448334 A CN 102448334A
Authority
CN
China
Prior art keywords
filter
filter element
paper
tobacco smoke
lactone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2010800230395A
Other languages
Chinese (zh)
Inventor
P.F.克拉克
A.D.麦科尔马克
T.克拉沃塔
J.罗滕赫菲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Filtrona International Ltd
Original Assignee
Filtrona International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=40940904&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN102448334(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Filtrona International Ltd filed Critical Filtrona International Ltd
Priority to CN201610790292.2A priority Critical patent/CN106418661A/en
Publication of CN102448334A publication Critical patent/CN102448334A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/061Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/301Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by aromatic compounds
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/302Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/302Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
    • A24B15/303Plant extracts other than tobacco
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/002Cigars; Cigarettes with additives, e.g. for flavouring
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/04Cigars; Cigarettes with mouthpieces or filter-tips
    • A24D1/045Cigars; Cigarettes with mouthpieces or filter-tips with smoke filter means
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02Manufacture of tobacco smoke filters
    • A24D3/0204Preliminary operations before the filter rod forming process, e.g. crimping, blooming
    • A24D3/0212Applying additives to filter materials
    • A24D3/0225Applying additives to filter materials with solid additives, e.g. incorporation of a granular product
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/08Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
    • A24D3/10Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/14Use of materials for tobacco smoke filters of organic materials as additive
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F47/00Smokers' requisites not otherwise provided for
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10Chemical features of tobacco products or tobacco substitutes
    • A24B15/16Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
    • A24B15/165Chemical features of tobacco products or tobacco substitutes of tobacco substitutes comprising as heat source a carbon fuel or an oxidized or thermally degraded carbonaceous fuel, e.g. carbohydrates, cellulosic material
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/32Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by acyclic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Botany (AREA)
  • Molecular Biology (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

A tobacco smoke filter or filter element comprising: a tobacco smoke filtering material including paper; and a flavour enhancing additive.

Description

Tobacco smoke filter
The present invention relates to tobacco smoke filter (for example being used for cigarette) and manufacturing thereof.
Worldwide, cellulose acetate is the main material that uses in the tobacco smoke filter.Also known use paper for example is used for cigarette as the filter material in the filter tip; Paper is providing the many advantages that are superior to cellulose acetate in the biodegradability that improves aspect more filtration efficiency under the constant pressure drop and lower material cost.Although these advantages are arranged, the filter-tip application of paper is little and be limited to microhabitat (niche) purposes usually.The paper filter tip does not cause that the main cause of general market interest is that they have adverse effect to the taste of cigarette.This so-called " paper flavor " often is considered to give smoke from cigarette more puckery more dried sensation.
Therefore hope very much to overcome this " paper flavor " and produce the smoking sensation from the paper filter cigarette suitable with conventional cellulose acetate filter cigarette.In addition, the discarded cigarette base of a fruit than the cellulose acetate stub fast the degraded of Duoing, bring remarkable enhancement of environment.But any measure that overcomes the paper flavor also must bring the smoking suitable with conventional cellulose acetate filter cigarette to experience.Overcome " paper flavor " defective before attempt (for example through adding specific spices, like menthol) this point still be unrealized.
To use filter-tip another restriction of paper be them to the poisonous Fen class He Wu – of existence in the volatilization of smoke from cigarette and half volatilization mutually for example the power of holding of staying of phenol, cresols, catechol and resorcinol be lower than cellulose acetate filter; This causes carrying the higher relative yield of the phenolic compound of the filter-tip cigarette of paper.This owing to cellulose acetate filter to the known selectivity of phenolic compound but not the filter-tip any inherent shortcoming of paper.But, still hope to improve the filter-tip phenol of paper certainly and stay the power of holding, so the smoker compares with the cellulose acetate filter cigarette when inhaling the paper filter cigarette under the phenolic compound that can not be exposed to high-load more.
Therefore be desirable to provide the paper flavor effect that has the filter-tip advantage of paper (biodegradability etc.) and do not have to be harmful to and/or have the cigarette filter that stays the power of holding with the similar at least phenols of cellulose acetate filter.
According to the present invention, in first aspect, tobacco smoke filter or filter element are provided, it comprises: the tobacco smoke filter material that comprises paper; With increase flavor additive (for example be selected from the appendix 1 of Commission Regulation (EC) No.1565/2000 and/or the European Union Chemical Groupings List that lists in EU Flavour Information System (" the FLAVIS ") database the 11st type or the 21st type).This filter tip or filter element can comprise that one or more increase the flavor additive.
In this article, term " increase flavor additive " is meant that reduction compares the additive that more puckery more dried smoking is felt in the paper filter cigarette smog to harmful " paper flavor " influence and/or the reduction of cigarette taste with known cellulose acetate filter cigarette.That is to say that containing this taste that increases the paper filter cigarette of flavor additive should be between the normal cigarette relevant with the cellulose acetate filter cigarette of commercial brand in the taste difference.Made according to their chemical characteristic the various trials of flavoring substance classification they are divided into a few class formation related compounds.For this reason, European Union collected flavoring substance 34 chemical classes the name a single – in the appendix 1 of Commission Regulation (EC) No.1565/2000 He in EU Flavour Information System (' the FLAVIS ') database, mention these classifications.The present invention uses and to increase the flavor additive from the 11st type of this list and/or the 21st type.
This increases the flavor additive can be alicyclic lactone (the alicyclic lactone that for example has maximum 20 carbon atoms, for example C 3-C 20Alicyclic lactone); Aromatics lactone (the aromatics lactone that for example has maximum 20 carbon atoms, for example C 6-C 20The aromatics lactone); Aromatic ketone (aromatic ketone that for example has maximum 20 carbon atoms, for example C 6-C 20Aromatic ketone) or secondary alcohol or its ester.This increases the flavor additive can be lactone, and it is a phthalide-type, for example alkyl phthalide, for example (C 1-C 6Branched-chain or straight-chain alkyl)-phthalide.Collected the material list of generally recognized as safe (GRAS) and each material specified numbering (being known as FEMA GRAS number) of Flavor and Extract Manufacturers Association (FEMA).This increases the flavor additive and preferably has (specify and give it) FEMA GRAS number.This increases the flavor additive can be to have FEMA GRAS number lactone (the 11st type); For example χ-valerolactone (specify FEMA GRAS FEMA 3103), χ-caprolactone (FEMA 2556), δ-caprolactone (FEMA 3167), χ-heptalactone (FEMA 2539), χ-caprylolactone (FEMA 2796), δ-Xin Neizhi (FEMA 3214), 4-hydroxyl-3-penetenoic acid lactone (FEMA 3293), 5-hydroxyl-2-decylenic acid delta-lactone (FEMA 3744), 4,4-dibutyl-χ-butyrolactone (FEMA 2372), peppermint lactone (FEMA 3764), dehydrogenation menthofuran lactone (FEMA 3755), 3-butylidenephthalide (FEMA 3333), 3-normal-butyl phthalide (FEMA 3334) and Whiskey lactone (FEMA 3803).This increases the flavor additive also can be sedanolid.Can be used as and comprise the mixture that increases the flavor additive, a part (for example as the mixture that does not split, like the part of plant extracts or vegetable oil or seed or macadamia nut oil) that for example comprises the essential oil that increases the flavor additive comprises this and increases the flavor additive.Comprise that the mixture (mixture that does not for example split is like plant extracts or vegetable oil or seed or macadamia nut oil) that increases the flavor additive can comprise that one or more increase the flavor additive.For example, can comprise this with the form of celery oil (the for example essential oil of celery seed) and increase the flavor additive.The essential oil of celery seed comprises sedanolid and 3-butylphthalide.The known spices of using as cigarette of celery oil, but do not advise as yet before using celery oil with the paper filter cigarette.Comprise that the mixture (mixture that does not for example split is like plant extracts or vegetable oil or seed or macadamia nut oil) that increases the flavor additive preferably has FEMA GRAS number, for example massoia bark oil (FEMA 3747).
This increases the flavor additive and preferably is present in filter tip or filter element with the amount of maximum 1 weight % (w/w) of the paper in filter tip or the filter element.
Tobacco smoke filter of the present invention or filter element can have 14 to 28 millimeters, and for example 16 to 26 millimeters, the girth of 16 to 17 millimeters or 24 to 25 millimeters for example.Tobacco smoke filter of the present invention can have 10 to 40 millimeters, and for example 15 to 35 millimeters, 20 to 30 millimeters length for example.Tobacco smoke filter element of the present invention can have 5 to 30 millimeters, and for example 6 to 20 millimeters, for example 8 to 15 millimeters, 10 to 12 millimeters length for example.
This paper can be any paper (in any form) that is used in traditionally in filter tip or the filter element.This paper can be for example filter paper, perforate paper (aperture paper), crepe paper etc.This paper can be the paper web form, for example laterally is gathered into rod type and keeps rod type.Sheet fiber can be 100% natural fiber (for example wood pulp), 100% synthetic fibers or both mixtures (as far as perforate paper (aperture paper), this paper is preferably 100% natural fiber).When paper web comprises synthetic fibers, can comprise that adhesive (for example plasticizer) is to improve the hardness of final filter tip or filter element (bar).This paper can be the paper web form of longitudinal rippleization and/or fibrillation, for example laterally is gathered into rod type and keeps rod type as disclosed among the GB2075328.This filter tip or filter element can be (or comprising) filter material bar (for example cylindrical bars), comprise paper (for example paper web) (for example being formed by paper (for example paper web)).This filter tip or filter element can comprise the tobacco smoke filter material that comprises paper and one or more other filter materials.This filter tip or filter element can comprise and comprise paper and second filter material and choose any one kind of them or the bonding width of cloth (coherent web) the form of tobacco smog filter material of multiple other filter material (for example being formed by the material that comprises these filter materials).This filter tip or filter element can be the bars that comprises (or comprising) the bonding width of cloth (for example being formed by the bonding width of cloth).Second with optional other filter material can be for example cellulose acetate tow, (other) paper (for example being different from other paper in this filter tip or the filter element), by nonwoven web, other fibre bundle natural and/or that synthetic fibers are processed, polypropylene etc. for example.
In an instance of the present invention; Identical or the similar structure of filter tip that the tobacco smoke filter (or filter element) that comprises the tobacco smoke filter material that comprises paper has and sells with trade mark MYRIA (belonging to Filtrona International Limited), and further comprise and increase the flavor additive.In another example; Identical or the similar structure of filter tip that the tobacco smoke filter (or filter element) that comprises the tobacco smoke filter material that comprises paper has and sells with trade mark PURACEL (belonging to Filtrona International Limited), and further comprise and increase the flavor additive.In another example; Identical or the similar structure of filter tip that the tobacco smoke filter (or filter element) that comprises the tobacco smoke filter material that comprises paper has and sells with trade mark CREST (belonging to Filtrona International Limited), and further comprise and increase the flavor additive.
This filter tip or filter element (bar) can be used packaging material, and for example the air-permeable paper packaging material coat.Filter tip of the present invention or filter element can be packaged in the forming paper of critical field and can ventilate with any usual manner.
Increase that the flavor additive can be arranged on filter tip or the filter element or (if if for example be positioned at paper and/or the packaging material that exist and/or second or other filter material of existing on or be immersed in wherein).If exist more than a kind of flavor additive that increases, these additives can be present in same position (for example both/all in paper) or diverse location (a kind of flavor additive that increases on paper, a kind of on other filter material, or the like).
The applicant finds surprisingly, and one or more that in filter tip or filter element [or be described below contain the filter-tip cigarette of paper], comprise as above definition increase flavor additive [the for example essential oil of celery seed (celery oil)] and can overcome " paper flavor " and feel and the cigarette that has with the similar organoleptic feature of cellulose acetate filter cigarette is provided.
The other additive of one or more phenolic compounds that this filter tip or filter element exist in can further comprising the volatilization of selectivity minimizing smoke from cigarette and/or partly volatilizing mutually.In this article; Term " selectivity reduces the other additives of one or more phenolic compounds that exist in volatilization and/or half volatilization mutually of smoke from cigarette " is meant the additive of the output that on than the big degree of the most compounds in the smog (for example tar), reduces one or more phenolic compounds in the smoke from cigarette in proportion (for example, reduce in proportion in phenol, cresols, catechol or the resorcinol one or more).This filter tip or filter element can comprise the other additive more than one or more phenolic compounds that exist in a kind of volatilization of selectivity minimizing smoke from cigarette and/or half volatilization mutually.
The other additive of one or more phenolic compounds that said selectivity exists in reducing the volatilization of smoke from cigarette and/or partly volatilizing mutually is polyethylene glycol (for example PEG200, PEG300, PEG400) or methoxy poly (ethylene glycol) (for example mPEG350) preferably.The other additive that said selectivity reduces one or more phenolic compounds that exist in volatilization and/or half volatilization mutually of smoke from cigarette preferably is present in filter tip or the filter element with the amount of maximum 20 weight % (w/w) of the paper in filter tip or the filter element.For example, the said selectivity other additive that reduces one or more phenolic compounds can exist with the amount of 1 to the 19 weight % (for example 5 to 17 weight %) of the paper in filter tip or the filter element.If in filter tip or filter element, exist more than a kind of other additive (its selectivity reduces volatilization and/or middle mutually one or more phenolic compounds that exist of half volatilization of smoke from cigarette), the total amount of additive (selectivity reduces one or more phenolic compounds) is preferably maximum 20 weight % (w/w) of the paper in filter tip or the filter element in addition.
The other additive that said selectivity reduces one or more phenolic compounds can be arranged on filter tip or the filter element or (if for example be positioned at paper and/or packaging material and/or second or other filter material of existing on or be immersed in wherein).If exist more than a kind of other additive, these additives can be present in same position (for example both/all in paper) or diverse location (a kind of additive on paper, a kind of on other filter material, or the like).
The applicant has been found that polyethylene glycol (for example PEG200, PEG300 and PEG400) and methoxyl group-polyethylene glycol (for example mPEG 350) belong to the additive that effective as selective reduces the phenol in the tobacco smoke.Surprisingly; The applicant also finds, they with contain paper and as the filter tip that increases flavor additive (one or more) discussed among this paper or filter element unite use and can provide and have the cigarette with filter tip that the phenolic compound yield suitable with conventional cellulose acetate filter cigarette (promptly more selectively filtering than conventional paper cigarette with filter tip) and desirable paper are distinguished the flavor of and alleviated.
That filter element of the present invention can be used as is two, three or filter-tip one section of other many members (multistage).Two sections is as known in the art with other multi-segment filter.
In an example, two, three or other multi-segment filter comprise particulate additives, like active carbon, silica gel, zeolite, ion exchange resin or sepiolite.Particulate additives preferably is not included in the filter element of the present invention (promptly being included in one of other section of multi-segment filter).In an example, filter element of the present invention constitutes that section of the filter-tip mouth end of two sections, and that section of two filter-tip tobacco end comprises particulate additives.
Filter tip of the present invention can be used in the machine-made cigarette (for example large-scale production and packing those).Filter of the present invention also can be used as with the individual and rolls the filter tip that cigarette (for example manual cigarette) or Roll Your Own or Make-your-own product are used.
In cigarette with filter tip of the present invention, the filter tip of the present invention filter tip of filter element of the present invention (or a comprise) end towards tobacco be connected to the cigarette of wrapping and prop up.This filter tip can be for example be connected to the cigarette of wrapping and props up through ring tipping paper (ring tipping) (it only surrounds abutting end that [packing] filter tip and cigarette prop up to expose most of filter tip packaging material) or through being hinged with wrapping paper (it surrounds the abutting end that whole filter length and cigarette prop up) entirely.Any filter tip of the present invention or cigarette with filter tip can be stuffy, or can ventilate by means commonly known in the art, for example through use pre-punching or ventilative forming paper, and/or the laser beam perforation of forming paper and tipping wrapping paper.Final cigarette with filter tip can have any girth scope (for example 14 to c. 28 millimeters girths of c.) that tradition is used in the tobacco product.
The present invention also provides the cigarette with filter tip that comprises as above disclosed tobacco smoke filter of the present invention or filter element.
Filter tip of the present invention or filter element can be with continuous rod type manufacturings as as known in the art.This continuous bar is cut into finite length so that subsequently use from producing when machine exit is exported continuously at it.This cutting can be cut into each filter tip or the filter element that as above defines and describe, and they are connected to each cigarette of wrapping separately subsequently and prop up to form cigarette with filter tip.But the bar that more generally will be somebody's turn to do output continuously cuts into double or higher multiple (common four times or six times) length earlier so that use subsequently; When initial cutting quadruples or during higher length; Subsequently the latter is cut into the Double Length that is used for the cigarette with filter tip assembly-wherein with the filter rods assembling of this Double Length with connect (through ring tipping paper or full tipping paper) between a pair of cigarette of wrapping props up, this combination subsequently at the center cut-out to obtain two independent cigarettes with filter tip.The present invention includes (for example double and higher multiple) multilength filter rods (and/or filter element bar), comprise for example end-to-end continuous a plurality of filter rods (filter element bar).
This filter tip or filter element can comprise other flavor enhancement (in the appendix 1 that is selected from Commission Regulation (EC) No.1565/2000 and/or the 11st type of the European Union Chemical Groupings List that lists in EU Flavour Information System (" the FLAVIS ") database or the 21st type increase the flavor additive), for example menthol.
According to the present invention, in another aspect, cigarette with filter tip is provided, it comprises: the filter tip or the filter element that comprise paper; Prop up with the cigarette of wrapping; Wherein this cigarette with filter tip further comprises and increases flavor additive (for example be selected from the appendix 1 of Commission Regulation (EC) No.1565/2000 and/or the European Union Chemical Groupings List that lists in EU Flavour Information System (" the FLAVIS ") database the 11st type or the 21st type).This cigarette with filter tip can comprise that one or more increase the flavor additive.
This increases the flavor additive can be alicyclic lactone (the alicyclic lactone that for example has maximum 20 carbon atoms, for example C 3-C 20Alicyclic lactone); Aromatics lactone (the aromatics lactone that for example has maximum 20 carbon atoms, for example C 6-C 20The aromatics lactone); Aromatic ketone (aromatic ketone that for example has maximum 20 carbon atoms, for example C 6-C 20Aromatic ketone) or secondary alcohol or its ester.This increases the flavor additive can be lactone, and it is a phthalide-type, for example alkyl phthalide, for example (C 1-C 6Branched-chain or straight-chain alkyl)-phthalide.This increases the flavor additive can be to have FEMA GRAS number lactone (the 11st type); For example χ-valerolactone (specify FEMA GRAS FEMA 3103), χ-caprolactone (FEMA 2556), δ-caprolactone (FEMA 3167), χ-heptalactone (FEMA 2539), χ-caprylolactone (FEMA 2796), δ-Xin Neizhi (FEMA 3214), 4-hydroxyl-3-penetenoic acid lactone (FEMA 3293), 5-hydroxyl-2-decylenic acid delta-lactone (FEMA 3744), 4,4-dibutyl-χ-butyrolactone (FEMA 2372), peppermint lactone (FEMA 3764), dehydrogenation menthofuran lactone (FEMA 3755), 3-butylidenephthalide (FEMA 3333), 3-normal-butyl phthalide (FEMA 3334) and Whiskey lactone (FEMA 3803).This increases the flavor additive also can be sedanolid.Can be used as and comprise the mixture that increases the flavor additive, a part (for example as the mixture that does not split, like the part of plant extracts or vegetable oil or seed or macadamia nut oil) that for example comprises the essential oil that increases the flavor additive comprises this and increases the flavor additive.Comprise that the mixture (mixture that does not for example split is like plant extracts or vegetable oil or seed or macadamia nut oil) that increases the flavor additive can comprise that one or more increase the flavor additive.For example, can comprise this with the form of celery oil (the for example essential oil of celery seed) and increase flavor additive (one or more).The essential oil of celery seed comprises sedanolid and 3-butylphthalide.Comprise that the mixture (mixture that does not for example split is like plant extracts or vegetable oil or seed or macadamia nut oil) that increases the flavor additive preferably has FEMA GRAS number, for example massoia bark oil (FEMA 3747).
Increase that the flavor additive can be arranged on filter tip or the filter element or [if if for example be positioned at paper and/or the filter tip packaging material that exist and/or second or other filter material of existing on or be immersed in wherein]; And/or be arranged on the tobacco or, and/or on the packaging material that the cigarette of wrapping props up or in.If exist more than a kind of flavor additive that increases, these additives can be present in same position (for example both/all in paper) or diverse location (a kind of flavor additive that increases on paper, a kind of on other filter material, tobacco etc.).
This cigarette with filter tip can further comprise as above definition and reduce the volatilization of smoke from cigarette and/or the other additive of middle one or more phenolic compounds that exist mutually that partly volatilizees with selectivity disclosed herein.The other additive that said selectivity reduces one or more phenolic compounds can be arranged on filter tip or the filter element or [if if for example be positioned at paper and/or the filter tip packaging material that exist and/or second or other filter material of existing on or be immersed in wherein]; And/or be arranged on the tobacco or, and/or on the packaging material that the cigarette of wrapping props up or in.
According to the present invention; In another aspect, provide in the appendix 1 that is selected from Commission Regulation (EC) No.1565/2000 and/or EU Flavour Information System (" FLAVIS ") database in the 11st type of the European Union Chemical Groupings List that lists or the 21st type increase the flavor additive in filter tip, filter element or cigarette with filter tip or the purposes in their manufacturing.This filter tip, filter element or cigarette with filter tip can comprise paper (for example can comprise the tobacco smoke filter material that comprises paper).The filter tip that comprises paper can be for example to have the filter tip sold with the filter tip of selling with trade mark MYRIA or with trade mark PURACEL or the filter tip sold with trade mark CREST is identical or the filter tip of similar structure.Increase the flavor additive like preceding text and definition here; (one or more) [for example essential oil of celery seed (celery oil)] in filter tip that comprises paper or filter element [or in as described herein containing in the filter-tip cigarette of paper] but or the purposes customer service according to this aspect of the invention " paper flavor " in it is made feel; (for example such as paired sense organ comparative test as known in the art confirmation) and/or the cigarette that has with the similar organoleptic feature of cellulose acetate filter cigarette can be provided; (for example such as paired sense organ comparative test as known in the art confirmation).
This increases the flavor additive can be alicyclic lactone (the alicyclic lactone that for example has maximum 20 carbon atoms, for example C 3-C 20Alicyclic lactone); Aromatics lactone (the aromatics lactone that for example has maximum 20 carbon atoms, for example C 6-C 20The aromatics lactone); Aromatic ketone (aromatic ketone that for example has maximum 20 carbon atoms, for example C 6-C 20Aromatic ketone) or secondary alcohol or its ester.This increases the flavor additive can be lactone, and it is a phthalide-type, for example alkyl phthalide, for example (C 1-C 6Branched-chain or straight-chain alkyl)-phthalide.This increases the flavor additive can be to have FEMA GRAS number lactone (the 11st type); For example χ-valerolactone (specify FEMA GRAS FEMA 3103), χ-caprolactone (FEMA 2556), δ-caprolactone (FEMA 3167), χ-heptalactone (FEMA 2539), χ-caprylolactone (FEMA 2796), δ-Xin Neizhi (FEMA 3214), 4-hydroxyl-3-penetenoic acid lactone (FEMA 3293), 5-hydroxyl-2-decylenic acid delta-lactone (FEMA 3744), 4,4-dibutyl-χ-butyrolactone (FEMA 2372), peppermint lactone (FEMA 3764), dehydrogenation menthofuran lactone (FEMA 3755), 3-butylidenephthalide (FEMA 3333), 3-normal-butyl phthalide (FEMA 3334) and Whiskey lactone (FEMA 3803).This increases the flavor additive also can be sedanolid.Can be used as and comprise the mixture that increases the flavor additive, a part (for example as the mixture that does not split, like the part of plant extracts or vegetable oil or seed or macadamia nut oil) that for example comprises the essential oil that increases the flavor additive comprises this and increases the flavor additive.Comprise that the mixture (mixture that does not for example split is like plant extracts or vegetable oil or seed or macadamia nut oil) that increases the flavor additive can comprise that one or more increase the flavor additive.For example, can comprise this with the form of celery oil (the for example essential oil of celery seed) and increase flavor additive (one or more).The essential oil of celery seed comprises sedanolid and 3-butylphthalide.Comprise that the mixture (mixture that does not for example split is like plant extracts or vegetable oil or seed or macadamia nut oil) that increases the flavor additive preferably has FEMA GRAS number, for example massoia bark oil (FEMA 3747).
The applicant also finds surprisingly, is selected from the appendix 1 of Commission Regulation (EC) No.1565/2000 and/or the flavor additive that increases of the 11st type of the European Union Chemical Groupings List that lists in EU Flavour Information System (" the FLAVIS ") database or the 21st type is being used to heat but not improved taste is provided during the smoking product (or therewith using) of burning tobacco.
The heating but not many smoking products of burning tobacco are known.Although this type of smoking product has cellulose acetate filter usually, they often provide than have the taste of the conventional cigarette difference of cellulose acetate filter.The applicant finds surprisingly, and the additive that comprises this special regulation in heating but not in the smoking product of burning tobacco in the used cellulose acetate filter causes the improved organoleptic feature of these smoking products.
According to the present invention, in another aspect, filter tip or filter element (for example being used to heat the smoking product of tobacco) are provided, it comprises: the tobacco smoke filter material; With in the appendix 1 that is selected from Commission Regulation (EC) No.1565/2000 and/or the 11st type of the European Union Chemical Groupings List that lists in EU Flavour Information System (" the FLAVIS ") database or the 21st type increase the flavor additive.In this article, term " smoking product of heating tobacco " does not comprise the smoking product of cigarette and cigar and so on, and their use relates to result of combustion of tobacco.
According to the present invention; In aspect another, provide in the appendix 1 that is selected from Commission Regulation (EC) No.1565/2000 and/or EU Flavour Information System (" FLAVIS ") database in the 11st type of the European Union Chemical Groupings List that lists or the 21st type increase the flavor additive in filter tip that the smoking product of heating tobacco is used or filter element or its make in or in the smoking product of heating tobacco or its purposes in making.
This increases the flavor additive can be alicyclic lactone (the alicyclic lactone that for example has maximum 20 carbon atoms, for example C 3-C 20Alicyclic lactone); Aromatics lactone (the aromatics lactone that for example has maximum 20 carbon atoms, for example C 6-C 20The aromatics lactone); Aromatic ketone (aromatic ketone that for example has maximum 20 carbon atoms, for example C 6-C 20Aromatic ketone) or secondary alcohol or its ester.This increases the flavor additive can be lactone, and it is a phthalide-type, for example alkyl phthalide, for example (C 1-C 6Branched-chain or straight-chain alkyl)-phthalide.This increases the flavor additive can be to have FEMA GRAS number lactone (the 11st type); For example χ-valerolactone (specify FEMA GRAS FEMA 3103), χ-caprolactone (FEMA 2556), δ-caprolactone (FEMA 3167), χ-heptalactone (FEMA 2539), χ-caprylolactone (FEMA 2796), δ-Xin Neizhi (FEMA 3214), 4-hydroxyl-3-penetenoic acid lactone (FEMA 3293), 5-hydroxyl-2-decylenic acid delta-lactone (FEMA 3744), 4,4-dibutyl-χ-butyrolactone (FEMA 2372), peppermint lactone (FEMA 3764), dehydrogenation menthofuran lactone (FEMA 3755), 3-butylidenephthalide (FEMA 3333), 3-normal-butyl phthalide (FEMA 3334) and Whiskey lactone (FEMA 3803).This increases the flavor additive also can be sedanolid.Can be used as and comprise the mixture that increases the flavor additive, for example comprise the essential oil that increases the flavor additive a part (for example as the mixture that does not split, like plant extracts or vegetable oil or seed or macadamia nut oil, a part) comprise this and increase the flavor additive.Comprise that the mixture (mixture that does not for example split is like plant extracts or vegetable oil or seed or macadamia nut oil) that increases the flavor additive can comprise that one or more increase the flavor additive.For example, can comprise this with the form of celery oil (the for example essential oil of celery seed) and increase flavor additive (one or more).The essential oil of celery seed comprises sedanolid and 3-butylphthalide.Comprise that the mixture (mixture that does not for example split is like plant extracts or vegetable oil or seed or macadamia nut oil) that increases the flavor additive preferably has FEMA GRAS number, for example massoia bark oil (FEMA 3747).
Referring now to the present invention of the following example illustration.
Embodiment 1
Use cylindrical bar (long 15 millimeters, 24.50 millimeters of the girths) perparation of specimen paper filter tip of the paper that not window type (non-aperture) the porous width of cloth by 100% wood pulp cellulose forms according to the method for setting forth among the GB2075328A.
Forms paper by long 2.5 to 6 millimeters fiber on the oblique net paper machine and have 15 to 35 restrain/square metre final material (finished substance) (before rippleization) (method of setting forth in through GB2075328).Through flavor enhancement being applied on the finished paper that seasoning agents soln that conventional method on the paper (for example print wheel etc.) will comprise that first of celery seed essential oil [comprising the compound mixture that does not split that increases flavor additive sedanolid and 3-butylphthalide] form increases the additive of distinguishing the flavor of is applied to continuous feed (before rippleization).Also be applied on the paper through the other additive of method as known in the art with the polyethylene glycol form.The finished product paper web of length feed (having applied additive on it) is length feed between the roller of the ripple with circumferential extension of cooperation operation subsequently, and after this continuous transverse collection holds together (in paper web form length feed) and becomes rod type.Through also being that bar that method as known in the art is processed gained continuously laterally cuts into finite length continuously to produce product filter tip or filter rods.
Use the sample filtering mouth assembling sample cigarette of processing as stated.Under ISO smoking condition, measure subsequently all samples phenol, neighbour, and the yield of paracresol (being referred to as mono-hydroxy phenol).Also measure tar yield from sample cigarette so that can assess phenol/tar ratio.Yield is compared also smoking under ISO smoking condition with control cigarette (size equates, but contains traditional cellulose acetate filter).
Discovery comprises that the filter-tip sample filtering mouth selectivity of the present invention of paper reduces phenol; It is suitable with cellulose acetate filter cigarette to find that phenolic compounds mentioned above exposes.
Embodiment 2
Flavor tests (using method as known in the art) confirms, through comprise according to an aspect of the present invention increase the flavor additive, reduce or even harmful " the paper flavor " eliminated the cigarette taste influence.
Carry out the sensory testing by one group of trained professional smoker.From a collection of commodity cigarette sample of buying leading brand of retail shop.Said brand has single type cellulose acetate (" monoacetate ") filter tip, and these are provided for " contrast " cigarette (" C ") of follow procedure.
From first group of cigarette, remove filter tip and change into to have and be equal to the machine-made paper filter tip that tar stays the power of holding.These filter tips are known as unmodified paper filter cigarette (" P ") hereinafter.
Also has the machine-made paper filter tip (as the P group) that is equal to tar and stays the power of holding from removing filter tip second group of cigarette and changing into.The seasoning agents soln that increases the flavor additive comprising of metered amount (additive of distinguishing the flavor of that increases that for example comprises celery seed essential oil form) is injected each paper filter tip and makes aging about 3-4 week of cigarette.These filter tips are known as the paper filter cigarette (" P+ ") of modification hereinafter.
Be carried out to sense organ comparative test (known in this area) by evaluation group subsequently.This evaluation and test group compares unmodified paper filter cigarette (" P ") with monoacetate tester (" C "); With the paper filter tip (" P+ ") of modification is compared with " C ".
The reviewer thinks that " P " is more dried than " C ", has lower tobacco and overall local flavor.This expects.But the reviewer thinks that the characteristic of " P+ " filter tip (comprising the additive of distinguishing the flavor of that increases according to an aspect of the present invention) is in the normal bag and bag difference of " C " cigarette; In other words, " the paper flavor " that greatly reduced the cigarette taste influences.
Embodiment 3
Test is heated but not the smoking product of burning tobacco.The seasoning agents soln that increases the flavor additive comprising of metered amount (for example comprise celery seed essential oil form increase flavor additive) is injected into heating but not in the cellulose acetate filter of the smoking product of burning tobacco.Smoker evaluation group points out that this produces the organoleptic feature of comparing excellence with the unmodified form of like products.

Claims (26)

1. tobacco smoke filter or filter element, it comprises: the tobacco smoke filter material that comprises paper; With in the appendix 1 that is selected from Commission Regulation (EC) No.1565/2000 and/or the 11st type of the European Union Chemical Groupings List that lists in EU Flavour Information System (" the FLAVIS ") database or the 21st type increase the flavor additive.
2. according to the tobacco smoke filter or the filter element of claim 1, wherein this to increase the flavor additive be alicyclic lactone, aromatics lactone, aromatic ketone or secondary alcohol or its ester.
3. according to the tobacco smoke filter or the filter element of claim 1 or claim 2, wherein this to increase the flavor additive be phthalide-type.
4. according to each tobacco smoke filter or filter element of aforementioned claim; Wherein this increase the flavor additive be χ-valerolactone, χ-caprolactone, δ-caprolactone, χ-heptalactone, χ-caprylolactone, δ-Xin Neizhi, 4-hydroxyl-3-penetenoic acid lactone, 5-hydroxyl-2-decylenic acid delta-lactone, 4,4-dibutyl-χ-butyrolactone, peppermint lactone, dehydrogenation menthofuran lactone, 3-butylidenephthalide, 3-normal-butyl phthalide, Whiskey lactone or sedanolid.
5. according to each tobacco smoke filter or filter element of aforementioned claim, wherein to comprise that the compound mixture form that does not split that increases the flavor additive comprises the said flavor additive that increases.
6. according to the tobacco smoke filter or the filter element of claim 5, be essential oil comprising the compound mixture that does not split that increases the flavor additive.
7. according to claim 5 or 6 each tobacco smoke filter or filter element, be the essential oil or the massoia bark oil of celery seed comprising the compound mixture that does not split that increases the flavor additive.
8. according to each tobacco smoke filter or filter element of aforementioned claim, wherein this paper be filter paper, window paper or crepe paper.
9. according to each tobacco smoke filter or filter element of aforementioned claim, wherein this paper is the paper web that laterally is gathered into rod type and keeps rod type.
10. according to each tobacco smoke filter or filter element of aforementioned claim, wherein said tobacco smoke filter material is cylindrical filter material bar.
11. according to each tobacco smoke filter or filter element of aforementioned claim, wherein said tobacco smoke filter material comprises paper and one or more other filter materials.
12., further comprise the other additive that selectivity reduces one or more phenolic compounds that exist in volatilization and/or half volatilization mutually of smoke from cigarette according to each tobacco smoke filter or filter element of aforementioned claim.
13. according to the tobacco smoke filter or the filter element of claim 12, wherein said other additive is polyethylene glycol or methoxy poly (ethylene glycol).
14. according to the tobacco smoke filter or the filter element of claim 12 or 13, wherein said other additive exists with the amount of maximum 20 weight % (w/w) of the paper in filter tip or the filter element.
15. with packaging material pack according to each tobacco smoke filter or filter element of aforementioned claim.
16. tobacco smoke filter or the filter element described with reference to embodiment like preceding text basically.
17. cigarette with filter tip, its comprise be connected to that the cigarette wrapped props up according to aforementioned claim each filter tip or comprise according to each the filter tip of filter element of aforementioned claim.
18. comprise a plurality ofly according to each filter tip or the multilength filter rods of filter element of claim 1 to 16, said a plurality of for example end-to-end link is together according to each filter tip or filter element of claim 1 to 16.
19. cigarette with filter tip, it comprises: the filter tip or the filter element that comprise paper; Prop up with the cigarette of wrapping; Wherein this cigarette with filter tip further comprise in the appendix 1 that is selected from Commission Regulation (EC) No.1565/2000 and/or EU Flavour Information System (" FLAVIS ") database in the 11st type of the European Union Chemical Groupings List that lists or the 21st type increase the flavor additive.
20. be selected from the appendix 1 of Commission Regulation (EC) No.1565/2000 and/or the 11st type of the European Union Chemical Groupings List that lists in EU Flavour Information System (" the FLAVIS ") database or the 21st type increase the flavor additive in filter tip or cigarette with filter tip or the purposes in their manufacturing.
21. filter tip or filter element, it comprises: the tobacco smoke filter material; With in the appendix 1 that is selected from Commission Regulation (EC) No.1565/2000 and/or the 11st type of the European Union Chemical Groupings List that lists in EU Flavour Information System (" the FLAVIS ") database or the 21st type increase the flavor additive.
22. filter tip or filter element that the smoking product of heating tobacco is used according to claim 21.
23. according to the filter tip or the filter element of claim 21 or 22, wherein this increase the flavor additive be alicyclic lactone, aromatics lactone, aromatic ketone or secondary alcohol or its ester.
24. according to claim 21,22 or 23 filter tip or filter element, wherein this to increase the flavor additive be phthalide-type.
25. according to each tobacco smoke filter or filter element of claim 21 to 24; Wherein this increase the flavor additive be χ-valerolactone, χ-caprolactone, δ-caprolactone, χ-heptalactone, χ-caprylolactone, δ-Xin Neizhi, 4-hydroxyl-3-penetenoic acid lactone, 5-hydroxyl-2-decylenic acid delta-lactone, 4,4-dibutyl-χ-butyrolactone, peppermint lactone, dehydrogenation menthofuran lactone, 3-butylidenephthalide, 3-normal-butyl phthalide, Whiskey lactone or sedanolid.
26. be selected from the appendix 1 of Commission Regulation (EC) No.1565/2000 and/or the 11st type of the European Union Chemical Groupings List that lists in EU Flavour Information System (" the FLAVIS ") database or the 21st type increase the flavor additive in filter tip that the smoking product of heating tobacco is used or filter element or its make in or in the smoking product of heating tobacco or its purposes in making.
CN2010800230395A 2009-05-26 2010-05-25 Tobacco smoke filter Pending CN102448334A (en)

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KR102404917B1 (en) 2022-06-02
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GB0910373D0 (en) 2009-07-29
CA2762843A1 (en) 2010-12-02

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