CN102440265A - Nanometer silver anti-mildew spray - Google Patents

Nanometer silver anti-mildew spray Download PDF

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Publication number
CN102440265A
CN102440265A CN2010105102380A CN201010510238A CN102440265A CN 102440265 A CN102440265 A CN 102440265A CN 2010105102380 A CN2010105102380 A CN 2010105102380A CN 201010510238 A CN201010510238 A CN 201010510238A CN 102440265 A CN102440265 A CN 102440265A
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CN
China
Prior art keywords
silver
nano
mildew
nanometer silver
spray
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2010105102380A
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Chinese (zh)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Shunde Yuhong Metal Nano-Tech Co., Ltd.
Original Assignee
ZHUHAI ZHONGJIN NANO TECHNOLOGY CO LTD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHUHAI ZHONGJIN NANO TECHNOLOGY CO LTD filed Critical ZHUHAI ZHONGJIN NANO TECHNOLOGY CO LTD
Priority to CN2010105102380A priority Critical patent/CN102440265A/en
Publication of CN102440265A publication Critical patent/CN102440265A/en
Pending legal-status Critical Current

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Abstract

The invention provides a nanometer silver anti-mildew spray used for quickly preventing furniture, carpets, walls, and the like from being mildewed. The nanometer silver anti-mildew spray contains nanometer silver, an additive agent, hydrogen peroxide and de-ionized water, wherein the additive agent comprises a thickening agent comprising one or more fiber polymer, such as methylcellulose, hydroxymethyl cellulose, polyanion cellulose, and the like. In the nanometer silver anti-mildew spray, local nanometer silver can be oxidized by the hydrogen peroxide, thereby the anti-mildew and sterilizing effects can be achieved. The nanometer silver anti-mildew spray can be used for quickly preventing mildew.

Description

A kind of nano-silver mildew-proof spray
One, technical field
The present invention relates to a kind of mildew resistant spraying agent.
Two, background technology
Indoor mould is very big to health effects.Mould often is hidden in carpet, furniture or each corner and the wall seam, and the most common with Stachybotrys atra and aspergillus niger, they present black and green.Live in the indoor of mould, maximum to the harm of suffering from bronchitis and sphagitis patient.Mould also possibly cause diseases such as Hay Fever and asthma in addition, and therefore immunity weak people possibly infect.Also can have a headache, phenomenon such as fever, skin or mucous membrane inflammation.
General mould just can breed above under 70% the situation in air humidity for a long time.China's southeastern coastal areas moisture is serious; Whenever plum rain season arrives; Air humidity keeps higher level for a long time, and the main residences in these areas are indoor just to begin to grow mould, is difficult to remove; Not only furniture, leather, wall, clothing etc. are damaged, the more important thing is to have a strong impact on the healthy of people.
Nano Silver (nano silver) is exactly that particle diameter is accomplished nano level argent simple substance.As the natural antibacterial agent of latest generation, bactericidal nano-silver has broad-spectrum antiseptic, have no drug resistance and the characteristics of safety non-toxic.
The mechanism of Nano Silver broad-spectrum antiseptic maybe be relevant with the combination of Nano Silver and protein and nucleic acid.Nano-Ag particles can combine with the metabolic enzyme of crying out sulfydryl after getting into thalline, causes bacterium and fungi dead; Nano Silver also possibly combine with the DNA of bacterium and fungi, causes its structural change, suppresses dna replication dna, causes fungi to lose activity.Domestic authoritative institution discovers: it has comprehensive antibacterial activity to pathogenic bacteria of drug-resistant such as resistance Escherichia coli, resistance staphylococcus aureus, drug-resistant pseudomonas aeruginosa, streptococcus pyogenes, enterococcus, anaerobic bacteria etc.; The common bacterium of burn and scald and wound surface such as staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, Candida albicans and other G+, G-property pathogenic bacteria all there is bactericidal action; To chlamydia trachomatis, cause that the gonococcus of sexually transmitted disease also has very powerful bactericidal action.
In Compendium of Material Medica, put down in writing: give birth to silver, nontoxic; Explanation in U.S. public health bureau nineteen ninety " about the survey report of silver-colored toxicity ": silver does not have obvious toxic-side effects to human body; Nano Silver does not have any toxicity when mouse investigate is found in test at oral maximal tolerance dose 925ppm finds, in the skin irritation test of rabbit, does not also find any IR.
Domestic mould inhibitor is used for industrial circle more at present, does not also relate to aspect at home.Application number 200710190772.6 " a kind of novel nanometer mildew proofing agent " mainly applies to the mildew-resistant of cloth class, and the having relatively high expectations of nano particle, and also will carry out post processing, and the preparation process is loaded down with trivial details.
Three, summary of the invention:
The purpose that the present invention implements is to invent a kind of nano-silver mildew-proof agent, with the problem of the quick mildew-resistant protection that solves present furniture, carpet, wall etc.
The embodiment of the invention is achieved in that
It is compared with prior art a kind of that the present invention provides, for a long time the nano silver spray product of quick mildew-resistant.This spray is made up of Nano Silver, additive, hydrogen peroxide solution and deionized water.
Nano-silver mildew-proof agent among the present invention, wherein Nano Silver concentration is 20-500ppm, the additive mass percent is 0.5%-1%.
The hydrogen peroxide solution that uses among the present invention, volumetric concentration are 30%, and mass percent is 0.01%.
The deionized water that uses among the present invention, electrical conductivity are 0.3us/cm.
The Nano Silver that the present invention uses, particle diameter is 20-100nm, purity is not less than 90%, can use a kind of method preparation of discharge-induced explosion wire method, using vaporization condensation process, laser method, sol-gal process.
A kind of nano-silver mildew-proof agent contains Nano Silver and additive, and its additive is made up of thickener, and one or more form thickener by fibrid polymer such as methylcellulose, CMC, polyanion celluloses.
In the technique scheme, additive can form space steric effect, prevents the nano-Ag particles reunion together, thereby Nano Silver can be uniformly distributed in the deionized water.
In the technique scheme, the oxidable part Nano Silver of hydrogen peroxide solution makes it have the effect of dual antimycotic antiseptic.
Four, embodiment:
1, the equal particle diameter of making even is 20nm nano-silver powder 0.1g, methylcellulose 5g, and concentration is 30% hydrogen peroxide solution 0.1g, and deionized water 250g mixes, and adopting frequency is the ultrasonic echography 1 minute of 20khz, and after finishing, it is even to add the 744.8g deionized water and stirring again.
2, the equal particle diameter of making even is 40nm nano-silver powder 0.3g, methylcellulose 10g, and concentration is 30% hydrogen peroxide solution 0.1g, and deionized water 250g mixes, and adopting frequency is the ultrasonic echography 2 minutes of 28khz, and after finishing, it is even to add the 739.6g deionized water and stirring again.
3, the equal particle diameter of making even is 80nm nano-silver powder 0.5g, methylcellulose 7g, and concentration is 30% hydrogen peroxide solution 0.1g, and deionized water 250g mixes, and adopting frequency is the ultrasonic echography 3 minutes of 47khz, and after finishing, it is even to add the 742.4g deionized water and stirring again.

Claims (10)

1. nano-silver mildew-proof spray, by Nano Silver, additive, hydrogen peroxide solution and deionized water are formed.
2. like right 1 described nano-silver mildew-proof spray, its additive is made up of thickener, and one or more form thickener by the plain polymer of fibrids such as methylcellulose, CMC, polyanion cellulose.
3. like right 1 described nano-silver mildew-proof spray, its Nano Silver concentration is at 20-500ppm.
4. like right 1 described nano-silver mildew-proof spray, its Nano Silver particle diameter is at 20-100nm.
5. like right 1 described nano-silver mildew-proof spray, its Nano Silver purity is more than 90%.
6. like right 1 described hydrogen peroxide solution, its volumetric concentration is 30%.
7. like right 1 described hydrogen peroxide solution, its mass percent is 0.01%
8. like right 1 described deionized water, its electrical conductivity is 0.3us/cm.
9. like right 1 described nano-silver mildew-proof spray, the additive mass percent is 0.5%-1%.
10. nano-silver mildew-proof spray according to claim 1 is characterized in that described Nano Silver, can be by a kind of method preparation of discharge-induced explosion wire method, using vaporization condensation process, laser method, sol-gal process.
CN2010105102380A 2010-10-12 2010-10-12 Nanometer silver anti-mildew spray Pending CN102440265A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010105102380A CN102440265A (en) 2010-10-12 2010-10-12 Nanometer silver anti-mildew spray

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010105102380A CN102440265A (en) 2010-10-12 2010-10-12 Nanometer silver anti-mildew spray

Publications (1)

Publication Number Publication Date
CN102440265A true CN102440265A (en) 2012-05-09

Family

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CN2010105102380A Pending CN102440265A (en) 2010-10-12 2010-10-12 Nanometer silver anti-mildew spray

Country Status (1)

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CN (1) CN102440265A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107173396A (en) * 2017-06-05 2017-09-19 冯新平 A kind of nontoxic mildew resistant spraying agent and its preparation technology
CN113171191A (en) * 2021-03-29 2021-07-27 浙江中医药大学 Method and device for promoting osseointegration of dental implant

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
张媛媛等: "纳米银作为抗菌材料的生物安全性研究进展 ", 《中国医疗器械杂志》 *
张媛媛等: "纳米银作为抗菌材料的生物安全性研究进展", 《中国医疗器械杂志》, no. 01, 30 January 2007 (2007-01-30) *
张文钲等: "纳米银抗菌材料研发现状", 《化工新型材料》 *
程定超等: "纳米银抗菌材料在医疗器具与生活用品中的应用 ", 《医疗卫生装备》 *
程定超等: "纳米银抗菌材料在医疗器具与生活用品中的应用", 《医疗卫生装备》, no. 11, 15 November 2004 (2004-11-15) *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107173396A (en) * 2017-06-05 2017-09-19 冯新平 A kind of nontoxic mildew resistant spraying agent and its preparation technology
CN113171191A (en) * 2021-03-29 2021-07-27 浙江中医药大学 Method and device for promoting osseointegration of dental implant

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Applicant after: Foshan Shunde Yuhong Metal Nano-Tech Co., Ltd.

Address before: 5 building, No. 109 Xinghua Road, Xiangzhou District, Guangdong, Zhuhai, 519000

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Application publication date: 20120509