CN102433082A - Special material for posting gold foil - Google Patents
Special material for posting gold foil Download PDFInfo
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- CN102433082A CN102433082A CN2011100924985A CN201110092498A CN102433082A CN 102433082 A CN102433082 A CN 102433082A CN 2011100924985 A CN2011100924985 A CN 2011100924985A CN 201110092498 A CN201110092498 A CN 201110092498A CN 102433082 A CN102433082 A CN 102433082A
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Abstract
The invention discloses a special material for posting a gold foil, which consists of the following components in parts by weight: 15-20 parts of cellulose acetate butyrate (CAB); 60-65 parts of acetic ether; 8-12 parts of acetone; 5-8 parts of butyl acetate; 1-3 parts of dimethylbenzene; 0.8-1.5 parts of anilinomethyltriethoxysliane; and 0.1-0.3 part of antifoaming agent. The special material for posting the gold foil can overcome the defects that the aging resistance is low, the material is apt to become damp, the stability is low and the like in the prior art, and has the advantages that the aging resistance is high, the material is not apt to become damp and the stability is high.
Description
Technical field
The present invention relates to finishing material, particularly, relate to a kind of goldleaf proprietary material of replying to the topic.
Background technology
The goldleaf money order receipt to be signed and returned to the sender goldleaf of promptly replying to the topic (is claimed " gilding " again; Be called for short " gilding ") be the rarity of Chinese nation's folk tradition technology; The Neolithic Age before more than 5000 year; The archaeologist finds and confirms that wherein bronze work pastes decorations with gold slice in Guanghan, Sichuan Province county Sanxing Pile ruins unearthed relics.To the Shang dynasty before more than 3000 year, China's gilding technology is ripe day by day, and is widely used in the subsides decorations of imperial palace noble or figure of buddha temple, and is splendid or honorable serious to show it.
In goldleaf money order receipt to be signed and returned to the sender technology, the bonding material that requires to use must have ramollescence to broken goldleaf, also suitable adhesive effect will be arranged simultaneously, and original goldleaf layer is had no adverse effects, and does not destroy original historical relic style and features; In addition, the material of need replying to the topic will have stability to aging preferably, makes the historical relic of reparation can keep the reparation state for a long time.
Usually, when the goldleaf money order receipt to be signed and returned to the sender, use lacquer to add tung oil mostly and be tamanori, goldleaf is pasted; But because the stability to aging of lacquer and tung oil is relatively poor, As time goes on, it is curling that bond performance decline causes the goldleaf of pasting to warp, the goldleaf of need replying to the topic once more, and the goods and materials cost and the human cost that need expend are all higher.
Add the better tamanori of tung oil performance in order further to excavate than above-mentioned lacquer; Dunhuang Research Inst. uses carpenter's glue to test in early days, and carpenter's glue belongs to gelatine, needs the scene to boil in use; Owing in the process of boiling, will add a large amount of water, therefore under wet environment, be difficult for dry simultaneously; In addition, because the gelatine staple is protein, very easily receives action of microorganisms and go bad, adhesive power is disappeared, dryly then under wet environment, also is easy to go mouldy, the goldleaf of replying to the topic can not stable for extended periods of time.
In sum, in realizing process of the present invention, the contriver finds to exist at least in the prior art following defective:
⑴ stability to aging is poor: when using lacquer to add tung oil to make tamanori; Because the stability to aging of lacquer and tung oil is relatively poor, As time goes on, it is curling that bond performance decline causes the goldleaf of pasting to warp; The goldleaf of need replying to the topic once more, the goods and materials cost and the human cost that need expend are all higher;
⑵ moisture-sensitive: when using carpenter's glue to make tamanori,, under wet environment, be difficult for dry because carpenter's glue belongs to gelatine;
⑶ poor stability: because the staple of carpenter's glue is a protein, very easily receives action of microorganisms and go bad, adhesive power is disappeared, dryly then under wet environment, also is easy to go mouldy, the goldleaf of replying to the topic can not stable for extended periods of time.
Summary of the invention
The objective of the invention is to,, propose a kind of goldleaf money order receipt to be signed and returned to the sender proprietary material, to realize good, the advantage of moisture-sensitive and good stability not of stability to aging to the problems referred to above.
For realizing above-mentioned purpose, the technical scheme that the present invention adopts is: a kind of goldleaf money order receipt to be signed and returned to the sender proprietary material, and the component and the parts by weight of this material comprise: cellulose acetate butyrate CAB:15-20 part; Vinyl acetic monomer: 60-65 part; Acetone: 8-12 part; N-BUTYL ACETATE: 5-8 part; YLENE: 1-3 part; Anilinomethyl triethoxysilane: 0.8-1.5 part; Skimmer: 0.1-0.3 part.
Further; This preparation methods is following: ⑴ by weight; The vinyl acetic monomer, the acetone of 8-12 part and the N-BUTYL ACETATE of 5-8 part that in mixing tank, add 60-65 part after stirring at normal temperatures, add the cellulose acetate butyrate CAB of 15-20 part; ⑵ add YLENE, the anilinomethyl triethoxysilane of 0.8-1.5 part and the skimmer of 0.1-0.3 part of 1-3 part after said cellulose acetate butyrate CAB is dissolved to transparence fully, after stirring, filter out impurities packing.
Through experimental verification, the outward appearance of above-mentioned goldleaf money order receipt to be signed and returned to the sender proprietary material is water white transparency shape, time of drying≤6h; The scope of viscosity (being coated with-4 glasss) is 150-250Pa.s; Stability in storage was greater than 1 year, and agglutinating value(of coal) meets the request for utilization of goldleaf money order receipt to be signed and returned to the sender, and goldleaf itself is had no adverse effects.
The goldleaf money order receipt to be signed and returned to the sender proprietary material of various embodiments of the present invention is because the component and the parts by weight of this material comprise: cellulose acetate butyrate CAB 15-20 part; Vinyl acetic monomer 60-65 part; Acetone 8-12 part; N-BUTYL ACETATE 5-8 part; YLENE 1-3 part; Anilinomethyl triethoxysilane 0.8-1.5 part; Skimmer 0.1-0.3 part; Can in mixing tank, add vinyl acetic monomer, acetone and N-BUTYL ACETATE by weight ratio, after stirring at normal temperatures; Add cellulose acetate butyrate CAB; After being dissolved to transparence fully, add YLENE, anilinomethyl triethoxysilane and skimmer, after stirring; Filter out impurities, residual filtrate is goldleaf money order receipt to be signed and returned to the sender proprietary material; Utilize this goldleaf money order receipt to be signed and returned to the sender proprietary material, can play suitable softening and adhesive effect, two kinds of materials are adhered to each other well, goldleaf is had no adverse effects, play the repair of goldleaf money order receipt to be signed and returned to the sender; And, this goldleaf money order receipt to be signed and returned to the sender proprietary material, under various temperature and humidity conditions, can be dry rapidly; Stability is stronger, can make recovery project keep the long period; Thereby can overcome that stability to aging in the prior art is poor, the defective of moisture-sensitive and poor stability, to realize good, the advantage of moisture-sensitive and good stability not of stability to aging.
Other features and advantages of the present invention will be set forth in specification sheets subsequently, and, partly from specification sheets, become obvious, perhaps understand through embodiment of the present invention.The object of the invention can be realized through the structure that in the specification sheets of being write, claims, is particularly pointed out and obtained with other advantages.
Through embodiment, technical scheme of the present invention is done further detailed description below.
Embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein only is used for explanation and explains the present invention, and be not used in qualification the present invention.
Embodiment one
According to the embodiment of the invention, a kind of goldleaf money order receipt to be signed and returned to the sender proprietary material is provided, the component and the parts by weight of this material comprise:
Cellulose acetate butyrate CAB:15 part;
Vinyl acetic monomer: 60 parts;
Acetone: 8 parts;
N-BUTYL ACETATE: 5 parts;
YLENE: 1 part;
Anilinomethyl triethoxysilane: 0.8 part;
Skimmer: 0.1 part.
Wherein, cellulose acetate butyrate (Cellulose Acetate Butyrate is called for short CAB), major function comprises: improve levelling; Thereby suppress sagging and shrinkage cavity and reduce surface imperfection; Shorten time of drying; Promote aligning of metallic pigment; Anti-nip; The plasticizer-resistant migration.
Vinyl acetic monomer is claimed ETHYLE ACETATE (ethyl acetate) again; Purified ETHYLE ACETATE is the liquid that water white transparency has aromatic odour; Be a kind of broad-spectrum fine chemical product, have excellent solvability, quick-drying, of many uses; Be a kind of very important Organic Chemicals and fabulous industrial solvent, be widely used in the production process of cellulose acetate, ethyl cellulose, chlorinated rubber, ethenoid resin, acetate fiber resin, viton, coating and paint etc.Main as solvent, and be used for the synthetic of dyestuff and some medicine intermediates.Be one of synthetic perfume of large usage quantity in the food flavour, be used to allocate smell type edible essences such as banana, pears, peach, pineapple, grape in a large number.
Acetone (acetone) is also referred to as dimethyl ketone, is the simplest ketone in the saturated fatty ketone series.Fusing point-95 degree, boiling point 56 degree, colourless liquid has special odor, can dissolve cellulose acetate and cellulose nitrate.Acetone can be water-soluble, in ethanol, ether and other organic solvents.In the industry mainly as solvent be used for explosive, plastics, rubber, fiber, process hides, grease, industry such as spray paint, also can be used as the important source material of materials such as synthetic ketenes, aceticanhydride, iodoform, polyisoprene rubber, methylacrylic acid, methyl esters, chloroform, epoxy resin.In accurate copper pipe manufacturing, acetone is often used in the black ink above the wiping copper pipe.
N-BUTYL ACETATE (English be called for short s-BAC), main character is similar with n-butyl acetate, colourless liquid, fruit aroma is arranged, and is mainly used in lacquer solvent, thinner, each vegetable oil and resin solvent.Also be used for plastics and spices manufacturing.
N-BUTYL ACETATE is widely used in making paint industry, coatings industry as the organic solvent of excellent property; Be used for making soluble cotton and verivate varnish and polyurethane lacquer, and alkyd resin varnish and multicolor finish, also be used for polymer products such as camphor, Dormant oils, grease and synthetic resin, natural and viton ethene etc., vinylbenzene etc., 2-methylacrylic acid; Also be used for leatheroid and medicine industry and electronic industry simultaneously; Simultaneously be used for making paint industry in a large number, thinner also is used for plastics industry; Perfume industry, and be applied to various fields as extraction agent and dewatering agent.
YLENE (dimethylbenzene) is colourless transparent liquid; Be on the phenyl ring two hydrogen by the substituted product of methyl, exist adjacent,, to three kinds of isomer, in industry, YLENE promptly refers to above-mentioned mixture of isomers.YLENE is water insoluble, is dissolved in ethanol and ether, is widely used in organic solvent and synthetic medicine, coating, resin, dyestuff, explosive and agricultural chemicals etc.
Anilinomethyl triethoxysilane, promptly model is the bonding properties-correcting agent of Nanjing University-42, claims " anilinomethyl triethoxysilane " again, storage should be sealed in dry lucifuge place; Anilinomethyl triethoxysilane (being called for short ND-42) is a yellow oily liquid, can be dissolved in most of organic solvents such as alcohol, ketone, ester, hydrocarbon, and is water insoluble; The tackiness agent that can be used as phenolic aldehyde, epoxy, nylon and melamine resin; Also can make room temperature vulcanized silicone rubber and most metal (aluminium, red copper, silver, iron etc.), glass, pottery, cement, plastics (phenolic aldehyde, epoxy, organosilicon, synthetic glass, ABS plastic, unsaturated polyester, PS) bonding; Also can be used as the toughener that contains the mineral filler resin, and improve water tolerance, weathering resistance greatly.
Skimmer is called kilfoam again, in industrial process, can produce many harmful foams, needs to add skimmer.The kind of skimmer is a lot, organo-siloxane, polyethers, silicon and ether grafting, contains amine, imines and amides, and it is faster to have an antifoaming speed, and it is longer to press down the bubble time, and Applicable media is wider, even harsh media environment such as high temperature, strong acid and alkaline characteristics.Be widely used in removing the harmful foam that produces in the industry production processes such as latex, textile sizing, food fermentation, biological medicine, coating, petrochemical complex, papermaking, industry cleaning.
In the above-described embodiments, the preparation method of above-mentioned goldleaf money order receipt to be signed and returned to the sender proprietary material is following:
Step 1: by weight, in mixing tank, add 60 parts vinyl acetic monomer, 8 parts acetone and 5 parts N-BUTYL ACETATE, after stirring at normal temperatures, add 15 parts cellulose acetate butyrate CAB; Here, stirrer can be set in mixing tank, behind proportioning adding vinyl acetic monomer, acetone and N-BUTYL ACETATE, can start stirrer at normal temperatures and stir;
Step 2: after above-mentioned cellulose acetate butyrate CAB is dissolved to transparence fully, add 1 part YLENE, 0.8 part anilinomethyl triethoxysilane and 0.1 part skimmer, after stirring, filter out impurities, packing;
In step 2, can adopt the filtrating (being present embodiment gained goldleaf money order receipt to be signed and returned to the sender proprietary material) after plastic tank is packed above-mentioned filtering out impurities, the capacity of plastic tank can be decided to be 1 liter.
Embodiment two
Different with the foregoing description is that in the present embodiment, the component and the parts by weight of goldleaf money order receipt to be signed and returned to the sender proprietary material comprise:
Cellulose acetate butyrate CAB:20 part;
Vinyl acetic monomer: 65 parts;
Acetone: 12 parts;
N-BUTYL ACETATE: 8 parts;
YLENE: 3 parts;
Anilinomethyl triethoxysilane: 1.5 parts;
Skimmer: 0.3 part.
In the above-described embodiments, the preparation method of above-mentioned goldleaf money order receipt to be signed and returned to the sender proprietary material is following:
Step 1: by weight, in mixing tank, add 65 parts vinyl acetic monomer, 12 parts acetone and 8 parts N-BUTYL ACETATE, after stirring at normal temperatures, add 20 parts cellulose acetate butyrate CAB;
Step 2: after above-mentioned cellulose acetate butyrate CAB is dissolved to transparence fully, (need 1 hour approximately); Add 3 parts YLENE, 1.5 parts anilinomethyl triethoxysilane and 0.3 part skimmer; (need 10 minutes approximately) after stirring, filter out impurities, packing.
Embodiment three
Different with the foregoing description is that in the present embodiment, the component and the parts by weight of goldleaf money order receipt to be signed and returned to the sender proprietary material comprise:
Cellulose acetate butyrate CAB:17.5 part;
Vinyl acetic monomer: 62.5 parts;
Acetone: 10 parts;
N-BUTYL ACETATE: 6.5 parts;
YLENE: 2 parts;
Anilinomethyl triethoxysilane: 1.15 parts;
Skimmer: 0.2 part.
In the above-described embodiments, the preparation method of above-mentioned goldleaf money order receipt to be signed and returned to the sender proprietary material is following:
Step 1: by weight, in mixing tank, add 62.5 parts vinyl acetic monomer, 10 parts acetone and 6.5 parts N-BUTYL ACETATE, after stirring at normal temperatures, add 17.5 parts cellulose acetate butyrate CAB;
Step 2: after above-mentioned cellulose acetate butyrate CAB is dissolved to transparence fully, add 2 parts YLENE, 1.15 parts anilinomethyl triethoxysilane and 0.2 part skimmer, after stirring, filter out impurities, packing.
The goldleaf money order receipt to be signed and returned to the sender proprietary material of the foregoing description one to embodiment three has the following advantages: ⑴ can be rapidly dry under all temps and relative humidity condition; ⑵ insensitive to humidity, but still rapid drying under high humidity environment; ⑶ the weathering resistance that outstanding makes recovery project can go through the long period maintenance; ⑷ easy to use, uncaps and can use; ⑸ have no adverse effects to goldleaf.
Above-mentioned goldleaf money order receipt to be signed and returned to the sender proprietary material is mainly used in the softening money order receipt to be signed and returned to the sender of goldleaf, and the softening and adhesive effect through suitable adheres to each other two kinds of materials well, plays the goldleaf repair of replying to the topic; Also can be used for the protection on goldleaf surface.
When stating goldleaf money order receipt to be signed and returned to the sender proprietary material in the use, note following item: ⑴ before construction, need base material is cleared up by the protection requirement; ⑵ uncap and can use, the also available needle tubing injection of available hairbrush brushing; ⑶ reduce the use viscosity of this goldleaf money order receipt to be signed and returned to the sender proprietary material if desired, must be used special diluting agent; ⑷ remaining goldleaf money order receipt to be signed and returned to the sender proprietary material must cover tight bung, deposits in shady and cool dry place; ⑸ this goldleaf money order receipt to be signed and returned to the sender proprietary material is inflammable articles, and absolutely no smoking and No matches for the workmen; ⑹ working-yard must isolate burning things which may cause a fire disaster, guarantees that good ventilation condition to avoid fire and infringement workmen's health.
When storing and transport the goldleaf money order receipt to be signed and returned to the sender proprietary material of the foregoing description, should notice that following item: ⑴ is stored in this goldleaf money order receipt to be signed and returned to the sender proprietary material in the storehouse of air seasoning, storing temp is below 35 ℃; Prevent periods of direct sunlight; Stow away from heat, isolated burning things which may cause a fire disaster can not store with strong oxidizer; ⑵ effective shelf lives is 1 year, surpasses the shelf lives still can use through being up to the standards; ⑶ prevent to drench with rain and solar exposure in the transportation, and should meet the relevant regulations of freight department about the hazardous chemical transportation.
In sum, the goldleaf money order receipt to be signed and returned to the sender proprietary material of various embodiments of the present invention is because the component and the parts by weight of this material comprise: cellulose acetate butyrate CAB 15-20 part; Vinyl acetic monomer 60-65 part; Acetone 8-12 part; N-BUTYL ACETATE 5-8 part; YLENE 1-3 part; Anilinomethyl triethoxysilane 0.8-1.5 part; Skimmer 0.1-0.3 part; Can in mixing tank, add vinyl acetic monomer, acetone and N-BUTYL ACETATE by weight ratio, after stirring at normal temperatures; Add cellulose acetate butyrate CAB; After being dissolved to transparence fully, add YLENE, anilinomethyl triethoxysilane and skimmer, after stirring; Filter out impurities, residual filtrate is goldleaf money order receipt to be signed and returned to the sender proprietary material; Utilize this goldleaf money order receipt to be signed and returned to the sender proprietary material, can play suitable softening and adhesive effect, two kinds of materials are adhered to each other well, goldleaf is had no adverse effects, play the repair of goldleaf money order receipt to be signed and returned to the sender; And, this goldleaf money order receipt to be signed and returned to the sender proprietary material, under various temperature and humidity conditions, can be dry rapidly; Stability is stronger, can make recovery project keep the long period; Thereby can overcome that stability to aging in the prior art is poor, the defective of moisture-sensitive and poor stability, to realize good, the advantage of moisture-sensitive and good stability not of stability to aging.
What should explain at last is: the above is merely the preferred embodiments of the present invention; Be not limited to the present invention; Although the present invention has been carried out detailed explanation with reference to previous embodiment; For a person skilled in the art, it still can be made amendment to the technical scheme that aforementioned each embodiment put down in writing, and perhaps part technical characterictic wherein is equal to replacement.All within spirit of the present invention and principle, any modification of being done, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (2)
1. a goldleaf money order receipt to be signed and returned to the sender proprietary material is characterized in that, the component and the parts by weight of this material comprise:
Cellulose acetate butyrate CAB:15-20 part;
Vinyl acetic monomer: 60-65 part;
Acetone: 8-12 part;
N-BUTYL ACETATE: 5-8 part;
YLENE: 1-3 part;
Anilinomethyl triethoxysilane: 0.8-1.5 part;
Skimmer: 0.1-0.3 part.
2. goldleaf money order receipt to be signed and returned to the sender proprietary material according to claim 1 is characterized in that this preparation methods is following:
⑴ add vinyl acetic monomer, the acetone of 8-12 part and the N-BUTYL ACETATE of 5-8 part of 60-65 part by weight in mixing tank, after stirring at normal temperatures, add the cellulose acetate butyrate CAB of 15-20 part;
⑵ add YLENE, the anilinomethyl triethoxysilane of 0.8-1.5 part and the skimmer of 0.1-0.3 part of 1-3 part after said cellulose acetate butyrate CAB is dissolved to transparence fully, after stirring, filter out impurities packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110092498 CN102433082B (en) | 2011-04-13 | 2011-04-13 | Special material for posting gold foil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110092498 CN102433082B (en) | 2011-04-13 | 2011-04-13 | Special material for posting gold foil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102433082A true CN102433082A (en) | 2012-05-02 |
| CN102433082B CN102433082B (en) | 2013-05-22 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110092498 Expired - Fee Related CN102433082B (en) | 2011-04-13 | 2011-04-13 | Special material for posting gold foil |
Country Status (1)
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| CN (1) | CN102433082B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103435851A (en) * | 2013-08-30 | 2013-12-11 | 东莞冠狄塑胶有限公司 | Flavor celluloses and injection molding method |
| CN103435852A (en) * | 2013-08-30 | 2013-12-11 | 东莞冠狄塑胶有限公司 | Fragrance cellulose and method for preparing single-colour plate by applying fragrance cellulose |
| CN103497714A (en) * | 2013-09-29 | 2014-01-08 | 苏州华周胶带有限公司 | Insulating tape adhesive |
| CN104119715A (en) * | 2014-08-06 | 2014-10-29 | 吴江华诚复合材料科技有限公司 | Aqueous colorful-pattern coating material |
| CN108528123A (en) * | 2018-04-20 | 2018-09-14 | 余其姝 | A kind of goldleaf of archaeology historical relic reparation is replied to the topic method |
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| CN101555394A (en) * | 2009-05-19 | 2009-10-14 | 无锡市儒兴科技开发有限公司 | Organic adhesive for aluminum paste of silicon solar cells and preparation method thereof |
| JP2009269934A (en) * | 2008-04-07 | 2009-11-19 | Sekisui Chem Co Ltd | Adhesive composition for screen printing |
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- 2011-04-13 CN CN 201110092498 patent/CN102433082B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2009269934A (en) * | 2008-04-07 | 2009-11-19 | Sekisui Chem Co Ltd | Adhesive composition for screen printing |
| CN101555394A (en) * | 2009-05-19 | 2009-10-14 | 无锡市儒兴科技开发有限公司 | Organic adhesive for aluminum paste of silicon solar cells and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103435851A (en) * | 2013-08-30 | 2013-12-11 | 东莞冠狄塑胶有限公司 | Flavor celluloses and injection molding method |
| CN103435852A (en) * | 2013-08-30 | 2013-12-11 | 东莞冠狄塑胶有限公司 | Fragrance cellulose and method for preparing single-colour plate by applying fragrance cellulose |
| CN103435852B (en) * | 2013-08-30 | 2015-12-23 | 东莞冠狄塑胶有限公司 | Scented cellulosics and apply its method preparing monochromatic sheet material |
| CN103435851B (en) * | 2013-08-30 | 2016-03-02 | 东莞冠狄塑胶有限公司 | Scented cellulosics and injection molding forming method thereof |
| CN103497714A (en) * | 2013-09-29 | 2014-01-08 | 苏州华周胶带有限公司 | Insulating tape adhesive |
| CN104119715A (en) * | 2014-08-06 | 2014-10-29 | 吴江华诚复合材料科技有限公司 | Aqueous colorful-pattern coating material |
| CN108528123A (en) * | 2018-04-20 | 2018-09-14 | 余其姝 | A kind of goldleaf of archaeology historical relic reparation is replied to the topic method |
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| CN102433082B (en) | 2013-05-22 |
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